GB1274812A - Aqueous emulsions - Google Patents

Aqueous emulsions

Info

Publication number
GB1274812A
GB1274812A GB4014/70A GB401470A GB1274812A GB 1274812 A GB1274812 A GB 1274812A GB 4014/70 A GB4014/70 A GB 4014/70A GB 401470 A GB401470 A GB 401470A GB 1274812 A GB1274812 A GB 1274812A
Authority
GB
United Kingdom
Prior art keywords
alcohol
acid
units
water
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4014/70A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB1274812A publication Critical patent/GB1274812A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/427—Amino-aldehyde resins modified by alkoxylated compounds or alkylene oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Colloid Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

1,274,812. Rendering textiles water-repellent. CIBA-GEIGY A.G. 27 Jan., 1970 [29 Jan., 1969], No. 4014/70. Heading D1P. [Also in Divisions C3 and C5] An aqueous emulsion for treating textiles to render them water-repellent comprises 10- 40 wt% of solids, which solids comprise (a) 17-86 wt% of a reaction product of a methylolaminotriazine with a C12<SP>+</SP> fatty acid or amide or alcohol, (b) 8-77 wt% of a hydrophobic wax, (c) 0.7-14 wt% of a watersoluble nonionic polyethylene glycol compound containing 6-200 -CH 2 CH 2 O- units and a hydrophobic residue, and (d) 0.4-13 wt% of a colourless metal salt of an alkylbenzenesulphonic acid having at least 8 C atoms in the alkyl group(s), the components (a) + (b) totalling 85-96 wt% and (c) + (d) correspondingly 15-4 wt%. Suitable compounds (a) may be derived from formo-, aceto- or benzo-guanamine or melamine, preferably etherified with a C1-4 alkanol, and preferably have at least 75% of the methylol groups modified, 15-50% of them with the fatty acid compounds; suitable waxes (b) are beeswax and paraffin wax of m.p. 45-70‹C; compounds (c) most preferably contain 20-50 -CH 2 CH 2 O- units and may derive from alcohols, thioalcohols, phenols, thiophenols, amines, carboxylic acids and amides. In Examples hexamethylolmelamine is methylated or butylated, then heated with stearic or myristic acid, or arachyl, behing myristyl or a mixed fatty alcohol, or stearamide, or (Ex. 5) melamine is heated with paraformaldehyde, isobutanol and a palmitic/stearic acid mixture. These products (a) are emulsified in water with (b) beeswax or paraffin 50-52‹C, 60-62‹C or 69-71‹C, and (c) polyoxyethylenated tributylphenol, hydroabietyl alcohol, nonyl phenol, di-t-butyl-pcresol, stearyl or oleyl alcohol, stearyl, hydroabietyl or oleyl amine or a mixed fatty amine, dodecyl mercaptan, oleic acid or oleamide or stearamide having 9-80 -CH 2 CH 2 O- units, and (d) Ca, Ba, Zn, Pb, Mg, Zr, Al, Sn, Ti, Na, K, Li or Cs dodecylbenzenesulphonate or Ca or Na undecylbenzenesulphonate, with curing catalysts Al 2 (SO 4 ) 3 . 18H 2 O, AlCl 3 . 6H 2 O, NH 4 Cl, ZnCl 2 MgCl 2 . 6H 2 O or H 3 PO 4 . The emulsions are used to impregnate cotton gaberdine fabric, which is then dried and cured.
GB4014/70A 1969-01-27 1970-01-27 Aqueous emulsions Expired GB1274812A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH120269A CH515379A (en) 1969-01-27 1969-01-27 Use of aqueous emulsions to make textile materials permanently water-repellent

Publications (1)

Publication Number Publication Date
GB1274812A true GB1274812A (en) 1972-05-17

Family

ID=4204888

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4014/70A Expired GB1274812A (en) 1969-01-27 1970-01-27 Aqueous emulsions

Country Status (8)

Country Link
US (1) US3660303A (en)
JP (1) JPS4834558B1 (en)
AT (1) AT309382B (en)
BE (1) BE744932A (en)
CH (1) CH515379A (en)
DE (1) DE2002003A1 (en)
FR (1) FR2029471A1 (en)
GB (1) GB1274812A (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4932760B2 (en) * 1972-03-23 1974-09-02
DE2733493C2 (en) * 1976-05-17 1986-11-13 Henkel KGaA, 4000 Düsseldorf Smoothing agent for textile fiber material
DE2621881C2 (en) * 1976-05-17 1985-10-31 Henkel KGaA, 4000 Düsseldorf Smoothing agent for textile fiber material
GB1601360A (en) * 1977-07-12 1981-10-28 Procter & Gamble Textile treatment composition
US4240795A (en) * 1979-07-09 1980-12-23 Sun Chemical Corporation Treatment of textiles with modified alpha-olefins
JPS5657605U (en) * 1979-10-11 1981-05-18
US5024697A (en) * 1986-01-13 1991-06-18 Ashland Oil, Inc. Coating composition and method for forming a self-heating corrosion preventative film
US5153032A (en) * 1986-01-13 1992-10-06 Ashland Oil, Inc. Coating compositions and method for forming a self-healing corrosion preventative film
US5397231A (en) * 1987-06-23 1995-03-14 Bald; Hubert Position assembly for use in assembling two components
DE3739148A1 (en) * 1987-11-19 1989-06-01 Basf Ag METHOD FOR COATING TEXTILES
GB8921041D0 (en) * 1989-09-16 1989-11-01 Rtz Chemicals Ltd Water-borne water repellents and their use
DE19750019A1 (en) * 1997-11-12 1999-05-20 Basf Ag Expandable styrene polymers containing atherman particles
BR112017024575B1 (en) * 2015-05-18 2022-09-20 Teijin Aramid Gmbh TEXTILE FABRIC AND METHOD FOR MANUFACTURING A TEXTILE FABRIC

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE534102A (en) * 1954-02-03

Also Published As

Publication number Publication date
JPS4834558B1 (en) 1973-10-22
US3660303A (en) 1972-05-02
DE2002003A1 (en) 1970-07-30
BE744932A (en) 1970-07-27
CH120269A4 (en) 1970-09-30
FR2029471A1 (en) 1970-10-23
AT309382B (en) 1973-08-10
CH515379A (en) 1971-12-31

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees