GB1176803A - Composition and process for producing a Water-Repellent Finish - Google Patents

Composition and process for producing a Water-Repellent Finish

Info

Publication number
GB1176803A
GB1176803A GB25998/67A GB2599867A GB1176803A GB 1176803 A GB1176803 A GB 1176803A GB 25998/67 A GB25998/67 A GB 25998/67A GB 2599867 A GB2599867 A GB 2599867A GB 1176803 A GB1176803 A GB 1176803A
Authority
GB
United Kingdom
Prior art keywords
wax
mixture
alcohol
mols
stearylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25998/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB1176803A publication Critical patent/GB1176803A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423Amino-aldehyde resins
    • D06M15/427Amino-aldehyde resins modified by alkoxylated compounds or alkylene oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164Coating or impregnation specified as water repellent
    • Y10T442/2197Nitrogen containing

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Colloid Chemistry (AREA)

Abstract

1,176,803. Textile-treating compositions. CIBA Ltd. 6 June, 1967 [16 June, 1966], No. 25998/67. Headings C3P and C3R. [Also in Division D1] An aqueous composition for treating fibrous materials comprises (a) a methylolaminotriazine esterified with at least one C14<SP>+</SP> fatty acid or etherified with at least one C14<SP>+</SP> alcohol, (b) a hydrophobic wax-like substance, (c) a polyoxyalkylated amine having at least 16 C atoms in an N-bound aliphatic hydrocarbon group and at least 10 oxyalkylene residues in the molecule, (d) a protective colloid, and (e) a curing catalyst, the ratio of (a): (b) being 2:3-9:1 by weight. The component (a) may be derived from guanamine, acetoguanamine, benzoguanamine, or melamine; the wax (b) may be beeswax, paraffin wax or a polyethylene wax; the component (c) may be obtained from ethylene oxide and an N - monoalkyl - ethylene- or -propylenediamine or N-alkylamine, and the tertiary N atom may be quaternated, e.g. with an alkyl chloride or bromide, chloro- or bromo-acetic acid amide, ethylene chlorhydrin, benzyl chloride or epichlorhydrin; the colloid (d) may be hydroxyethylcellulose, sodium carboxymethylcellulose, polyethylene glycol, polyacrylamide, polyvinylpyrrolidone, a carboxyvinyl polymer or polyvinyl alcohol; the catalyst (e) may be NH 4 Cl, NH 4 CNS, Zn(NO 3 ) 2 , ZnCl 2 , Zn(BF 4 ) 2 , MgCl 2 , HCl, H 3 PO 4 , HÀCOOH, AlCl 3 or Al 2 (SO 4 ) 3 . The emulsion may be prepared as a concentrate; before use it is diluted with water to 2-10 wt. per cent of (a)+(b), 0À15-4 wt. per cent of (c) and 0À05-5 wt. per cent of (d), and the catalyst (e) is added. In Examples the components used are (a) hexamethylol methyl ether condensed with 1 mol. of stearic or myristic or arachic alcohol, or hexamethylol butyl ether condensed with arachic alcohol, (b) paraffin waxes of 50-52‹ or 60-62‹ C. m.p., isocerin, beeswax or polyethylene wax, (c) ethylene oxide adducts: 30 mols with a stearylamine/arachidylamine/behenylamine mixture (the product optionally quaternized with ethylene chlorhydrin, epichorhydrin or benzyl chloride); or 30 or 70 mols with a palmitylamine/stearylamine / arachidylamine / behenylamine mixture; or 30 mols with a hexadecylamine/stearylamine/ octadecylamine mixture or a hexadecylamine/ octadecylamine / octadecenylamine mixture, (d) polyvinyl alcohol, hydroxyethylcellulose, sodium carboxymethylcellulose, polyethylene glycol, polyvinylpyrrolidone or a carboxyvinyl polymer, (e) Al 2 (SO 4 ) 3 and NH 4 Cl, ZnCl 2 , MgCl 2 and Zn(BF 4 ) 2 once each.
GB25998/67A 1966-06-16 1967-06-06 Composition and process for producing a Water-Repellent Finish Expired GB1176803A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH874766A CH458278A (en) 1966-06-16 1966-06-16 Process for the production of a washable water-repellent finish on textiles, the means for it and the textile goods refined in this way

Publications (1)

Publication Number Publication Date
GB1176803A true GB1176803A (en) 1970-01-07

Family

ID=4344252

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25998/67A Expired GB1176803A (en) 1966-06-16 1967-06-06 Composition and process for producing a Water-Repellent Finish

Country Status (8)

Country Link
US (1) US3508958A (en)
AT (1) AT277155B (en)
BE (1) BE699978A (en)
CH (1) CH458278A (en)
DE (1) DE1594977A1 (en)
GB (1) GB1176803A (en)
NL (1) NL6708333A (en)
SE (1) SE323951B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115012224A (en) * 2022-05-20 2022-09-06 苍南县永顺毛绒有限公司 Waterproof plush and surface treatment process thereof

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH510166A (en) * 1969-04-09 1971-03-31 Ciba Geigy Ag Process for producing a washable water-repellent finish on textile materials
US20110171422A1 (en) * 2010-01-13 2011-07-14 Ben Meaige Hydrophobic layer for foam tape system
DE102013209170A1 (en) 2013-05-17 2013-09-12 Cht R. Beitlich Gmbh Composition useful e.g. for waterproofing of absorbent materials, comprises silicone polymer, wax and/or fatty acid esters, aminoplast, urea derivatives and/or melamine derivatives, solvent, crosslinking agent, and dispersing auxiliaries
CN103739773A (en) * 2013-12-04 2014-04-23 常熟市福亿印花炼染有限公司 Preparation method of a three-proofing fabric finishing agent

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2763649A (en) * 1956-09-18 Melamine hardenable ternary
US2371892A (en) * 1941-08-30 1945-03-20 American Cyanamid Co Permanent finish for textiles
LU28759A1 (en) * 1942-03-12
US2491249A (en) * 1945-04-30 1949-12-13 American Cyanamid Co Water repellent composition containing stearamide and methylated methylol melamine
US2509174A (en) * 1947-05-22 1950-05-23 Monsanto Chemicals Process of waterproofing textile fabrics
US2971930A (en) * 1956-05-22 1961-02-14 American Cyanamid Co Textile treatment with novel aqueous dispersion to achieve water-repellent finishes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115012224A (en) * 2022-05-20 2022-09-06 苍南县永顺毛绒有限公司 Waterproof plush and surface treatment process thereof

Also Published As

Publication number Publication date
US3508958A (en) 1970-04-28
DE1594977A1 (en) 1969-09-18
CH458278A (en) 1968-08-30
SE323951B (en) 1970-05-19
BE699978A (en) 1967-12-15
AT277155B (en) 1969-12-10
NL6708333A (en) 1967-12-18
CH874766A4 (en) 1967-10-31

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