GB602109A - Wax emulsions and method of preparing the same - Google Patents
Wax emulsions and method of preparing the sameInfo
- Publication number
- GB602109A GB602109A GB17662/45A GB1766245A GB602109A GB 602109 A GB602109 A GB 602109A GB 17662/45 A GB17662/45 A GB 17662/45A GB 1766245 A GB1766245 A GB 1766245A GB 602109 A GB602109 A GB 602109A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- chain
- oxyethyl
- emulsifiers
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 8
- 239000003995 emulsifying agent Substances 0.000 abstract 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 7
- -1 amine salts Chemical class 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 4
- 125000001931 aliphatic group Chemical group 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 4
- 238000002844 melting Methods 0.000 abstract 4
- 230000008018 melting Effects 0.000 abstract 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 159000000013 aluminium salts Chemical class 0.000 abstract 3
- 229910000329 aluminium sulfate Inorganic materials 0.000 abstract 3
- 150000001768 cations Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000001993 wax Substances 0.000 abstract 3
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- 150000001450 anions Chemical class 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000005160 aryl oxy alkyl group Chemical group 0.000 abstract 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000008117 stearic acid Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 abstract 1
- WGKYSFRFMQHMOF-UHFFFAOYSA-N 3-bromo-5-methylpyridine-2-carbonitrile Chemical compound CC1=CN=C(C#N)C(Br)=C1 WGKYSFRFMQHMOF-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 235000010919 Copernicia prunifera Nutrition 0.000 abstract 1
- 244000180278 Copernicia prunifera Species 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 1
- 241001553290 Euphorbia antisyphilitica Species 0.000 abstract 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 abstract 1
- 229930195725 Mannitol Natural products 0.000 abstract 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- JAOOCXVJFQFIOB-UHFFFAOYSA-M S(=O)(=O)(OCC)[O-].C(CCCCCCCCCCCCCCCCC)(=O)OCC[N+](CC)(CCO)CCO Chemical compound S(=O)(=O)(OCC)[O-].C(CCCCCCCCCCCCCCCCC)(=O)OCC[N+](CC)(CCO)CCO JAOOCXVJFQFIOB-UHFFFAOYSA-M 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- QBKCNGFIHKRAGH-UHFFFAOYSA-M [Cl-].C(CCCCCCCCCCCCCCCCC)OCC[N+](CC1=CC=CC=C1)(C)C Chemical compound [Cl-].C(CCCCCCCCCCCCCCCCC)OCC[N+](CC1=CC=CC=C1)(C)C QBKCNGFIHKRAGH-UHFFFAOYSA-M 0.000 abstract 1
- 239000002535 acidifier Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 230000002152 alkylating effect Effects 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000012164 animal wax Substances 0.000 abstract 1
- 235000013871 bee wax Nutrition 0.000 abstract 1
- 239000012166 beeswax Substances 0.000 abstract 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 abstract 1
- 229940073608 benzyl chloride Drugs 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229960002887 deanol Drugs 0.000 abstract 1
- WCOATMADISNSBV-UHFFFAOYSA-K diacetyloxyalumanyl acetate Chemical compound [Al+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WCOATMADISNSBV-UHFFFAOYSA-K 0.000 abstract 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 abstract 1
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 abstract 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid ester group Chemical class C(CCCCCCCCCCC)(=O)O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000000594 mannitol Substances 0.000 abstract 1
- 235000010355 mannitol Nutrition 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 239000012184 mineral wax Substances 0.000 abstract 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229920000847 nonoxynol Polymers 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 235000011007 phosphoric acid Nutrition 0.000 abstract 1
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 238000009877 rendering Methods 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 239000012178 vegetable wax Substances 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/14—Derivatives of phosphoric acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/18—Quaternary ammonium compounds
Abstract
Natural, mineral, vegetable or animal waxes or paraffin wax, melting above about 20 DEG C., are emulsified together with a saturated aliphatic acid, having at least 12 carbon atoms and melting above about 20 DEG C., and an aluminium salt of a short chain organic acid having not more than 6 carbon atoms, in water, using a "non-anion active" i.e. "non ionic" or "cation active" emulsifier miscible with the wax in the molten state. "Cation active" emulsifiers are defined as forming a cation, containing a chain of at least 12 carbon atoms, which is unbroken or broken by only a single amide or ester linkage. "Non-ionic" emulsifiers do not ionise and include an unbroken chain of at least 12 carbon atoms. Preferably the melting points of the wax, the acid, and the emulsifier coincide as nearly as possible. Ceresin, carnauba, candelilla, montan, japan or beeswax are specified. The aliphatic acid may be lauric, myristic, palmitic, stearic, arachidic, behenic, lignoceric or mixtures which may be commercial and contain unsaturated acids. Aluminium acetate or formate are specified. The "non-ionic" emulsifiers may be partial esters of polyhydric alcohols, e.g. glycerol, diethylene glycol, mannitol, sorbitol, or nonaethylene glycol with stearic, palmitic or lauric acids. The cation-active emulsifiers may be quaternary ammonium or amine salts, having a small monovalent anion which may be inorganic, e.g. chloride, bromide or organic, e.g. from acetic, glycollic, or alkyl sulphuric or phosphoric acids containing not more than 4 carbon atoms. These salts in addition to the long chain group may have alkyl, hydroxyalkyl, aryl, aralkyl, or aryl oxyalkyl groups attached to the nitrogen. The long carbon chain may be e.g. octadecyl, cetyl, lauryl or oxyethyl groups esterified with stearoyl, lauroyl, myriotyl, palmitoyl groups. Assistant emulsifiers of high viscosity, e.g. methyl cellulose or polyvinyl alcohol may be added. The preferred proportions are 5-20 parts each of acid and emulsifier per 100 parts wax, a water concentration of 50-90 p.c. and an aluminium salt concentration of 0.3-3 p.c. by weight calculated as Al2O3. The mixture may be emulsified by agitating at least 5 DEG C. above the melting point of the mix, the aluminium salt being however preferably added after cooling the emulsion. The emulsions are useful for rendering textile fibres or fabrics water-repellent.ALSO:Quaternary ammonium salts containing an aliphatic chain of at least 12 carbon atoms broken by one ester linkage, the other groups being alkyl, hydroxyalkyl, aryl, aralkyl or aryloxyalkyl containing not more than 8 carbon atoms, are produced by alkylating or aralkylating a long chain amine. Stearic acid is warmed at 150-180 DEG C. with triethanolamine until the tertiary amine ester is formed and the ester warmed with diethyl sulphate to produce stearoyl oxyethyl-di-(hydroxyethyl)-ethyl ammonium ethyl sulphate. Stearic acid reacted with dimethylamino-ethanol and benzyl chloride yields stearyl oxyethyl-dimethyl-benzyl ammonium chloride. Compounds containing myristoyl oxyethyl, lauroyl oxyethyl and trimethylpalmitoyl oxyethyl groups are also specified. Quaternary salts containing an aliphatic chain of at least 12 carbon atoms broken by a single amide group are also mentioned.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US602109XA | 1944-06-14 | 1944-06-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB602109A true GB602109A (en) | 1948-05-20 |
Family
ID=22028058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17662/45A Expired GB602109A (en) | 1944-06-14 | 1945-07-11 | Wax emulsions and method of preparing the same |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB602109A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE976508C (en) * | 1952-03-15 | 1963-10-10 | Hoechst Ag | Process for making fibrous material water repellent |
| DE977270C (en) * | 1952-03-15 | 1965-09-09 | Hoechst Ag | Process for making fibrous material water repellent |
| EP0326702A2 (en) * | 1988-02-01 | 1989-08-09 | Pfersee Chemie GmbH | Amine salts as stabilizers for the oil and water repellent finishing of fibre materials |
| EP0363855A1 (en) * | 1988-10-11 | 1990-04-18 | Hoechst Aktiengesellschaft | Concentrated and liquid aqueous surfactant composition and its use |
| EP0924333A1 (en) * | 1997-12-19 | 1999-06-23 | HENKEL-ECOLAB GmbH & CO. OHG | Fabric treatment composition and process for hydrophobing textile surfaces |
| WO2002036873A2 (en) * | 2000-11-01 | 2002-05-10 | Cognis Iberia S.L. | Textile treatment agents |
| WO2010069731A1 (en) * | 2008-12-16 | 2010-06-24 | Unilever Nv | Method and composition for the treatment of a substrate |
| WO2011123737A1 (en) * | 2010-04-01 | 2011-10-06 | The Procter & Gamble Company | Care polymers |
| EP2809757B1 (en) | 2012-01-31 | 2016-04-27 | Unilever N.V. | A composition and method for treating substrates |
-
1945
- 1945-07-11 GB GB17662/45A patent/GB602109A/en not_active Expired
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE976508C (en) * | 1952-03-15 | 1963-10-10 | Hoechst Ag | Process for making fibrous material water repellent |
| DE977270C (en) * | 1952-03-15 | 1965-09-09 | Hoechst Ag | Process for making fibrous material water repellent |
| EP0326702A2 (en) * | 1988-02-01 | 1989-08-09 | Pfersee Chemie GmbH | Amine salts as stabilizers for the oil and water repellent finishing of fibre materials |
| EP0326702A3 (en) * | 1988-02-01 | 1991-07-03 | Pfersee Chemie GmbH | Amine salts as stabilizers for the oil and water repellent finishing of fibre materials |
| EP0363855A1 (en) * | 1988-10-11 | 1990-04-18 | Hoechst Aktiengesellschaft | Concentrated and liquid aqueous surfactant composition and its use |
| EP0924333A1 (en) * | 1997-12-19 | 1999-06-23 | HENKEL-ECOLAB GmbH & CO. OHG | Fabric treatment composition and process for hydrophobing textile surfaces |
| WO2002036873A2 (en) * | 2000-11-01 | 2002-05-10 | Cognis Iberia S.L. | Textile treatment agents |
| WO2002036873A3 (en) * | 2000-11-01 | 2002-12-12 | Cognis Iberia Sl | Textile treatment agents |
| WO2010069731A1 (en) * | 2008-12-16 | 2010-06-24 | Unilever Nv | Method and composition for the treatment of a substrate |
| WO2011123737A1 (en) * | 2010-04-01 | 2011-10-06 | The Procter & Gamble Company | Care polymers |
| US8440174B2 (en) | 2010-04-01 | 2013-05-14 | The Procter & Gamble Company | Compositions comprising surfactants and alkyloxy-modified silicone |
| US8586015B2 (en) | 2010-04-01 | 2013-11-19 | The Procter & Gamble Company | Compositions comprising surfactants and glycerol-modified silicones |
| US8940284B2 (en) | 2010-04-01 | 2015-01-27 | The Procter & Gamble Company | Organosilicones |
| US9212338B2 (en) | 2010-04-01 | 2015-12-15 | The Procter & Gamble Company | Organosilicones |
| US9650593B2 (en) | 2010-04-01 | 2017-05-16 | The Procter & Gamble Company | Organosilicones |
| EP2809757B1 (en) | 2012-01-31 | 2016-04-27 | Unilever N.V. | A composition and method for treating substrates |
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