GB1272592A - Vapour phase oxidation of hydroxy compounds - Google Patents

Vapour phase oxidation of hydroxy compounds

Info

Publication number
GB1272592A
GB1272592A GB2142268A GB2142268A GB1272592A GB 1272592 A GB1272592 A GB 1272592A GB 2142268 A GB2142268 A GB 2142268A GB 2142268 A GB2142268 A GB 2142268A GB 1272592 A GB1272592 A GB 1272592A
Authority
GB
United Kingdom
Prior art keywords
glyoxal
glycol
compounds
present
formaldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2142268A
Other languages
English (en)
Inventor
Brian Keith Howe
Francis Robert Frederick Hardy
Douglas Alfred Clarke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik LCL Ltd
Original Assignee
Laporte Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laporte Chemicals Ltd filed Critical Laporte Chemicals Ltd
Priority to GB2142268A priority Critical patent/GB1272592A/en
Priority to NO184469A priority patent/NO133034C/no
Priority to CH684269A priority patent/CH535193A/de
Priority to NL6906866A priority patent/NL168487C/xx
Priority to BR20855169A priority patent/BR6908551D0/pt
Priority to FR6914418A priority patent/FR2007925A1/fr
Priority to DE19691967147 priority patent/DE1967147C2/de
Priority to BE732584D priority patent/BE732584A/xx
Priority to DE19691923048 priority patent/DE1923048C3/de
Priority to SE637769A priority patent/SE363816B/xx
Priority to ES366867A priority patent/ES366867A1/es
Publication of GB1272592A publication Critical patent/GB1272592A/en
Priority to JP8137872A priority patent/JPS4930807B1/ja
Priority to US05/451,228 priority patent/US3948997A/en
Priority to NLAANVRAGE8104458,A priority patent/NL175291C/xx
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/60—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/783—Separation; Purification; Stabilisation; Use of additives by gas-liquid treatment, e.g. by gas-liquid absorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/79—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/17—Saturated compounds containing keto groups bound to acyclic carbon atoms containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/185—Saturated compounds containing keto groups bound to acyclic carbon atoms containing —CHO groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/40—Two or more oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Paper (AREA)
GB2142268A 1968-05-06 1968-05-06 Vapour phase oxidation of hydroxy compounds Expired GB1272592A (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
GB2142268A GB1272592A (en) 1968-05-06 1968-05-06 Vapour phase oxidation of hydroxy compounds
NO184469A NO133034C (de) 1968-05-06 1969-05-05
CH684269A CH535193A (de) 1968-05-06 1969-05-05 Verfahren zur Herstellung von Carbonylverbindungen
NL6906866A NL168487C (nl) 1968-05-06 1969-05-05 Werkwijze voor het in de dampfase oxideren van diolen tot de overeenkomstige dicarbonylverbindingen.
BE732584D BE732584A (de) 1968-05-06 1969-05-06
FR6914418A FR2007925A1 (de) 1968-05-06 1969-05-06
DE19691967147 DE1967147C2 (de) 1968-05-06 1969-05-06 Verfahren zur Herstellung von Glyoxal durch Dampfphasenoxydation von Athylenglykol
BR20855169A BR6908551D0 (pt) 1968-05-06 1969-05-06 Um processo de oxidacao catalitica de compostos hidroxi
DE19691923048 DE1923048C3 (de) 1968-05-06 1969-05-06 Verfahren zur Herstellung von Dicarbonylverbindungen durch Dampfphasenoxydation eines aliphatischen Diols bzw. von Cyclohexan-l,2-diol
SE637769A SE363816B (de) 1968-05-06 1969-05-06
ES366867A ES366867A1 (es) 1968-05-06 1969-05-06 Un procedimiento para la oxidacion en fase de vapor de un compuesto hidroxilado al correspondiente compuesto carboni- lico.
JP8137872A JPS4930807B1 (de) 1968-05-06 1972-08-14
US05/451,228 US3948997A (en) 1968-05-06 1974-03-14 Vapour phase oxidation process
NLAANVRAGE8104458,A NL175291C (nl) 1968-05-06 1981-09-29 Werkwijze voor het in de dampfase oxideren van diolen tot de overeenkomstige dicarbonylverbindingen.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2142268A GB1272592A (en) 1968-05-06 1968-05-06 Vapour phase oxidation of hydroxy compounds

Publications (1)

Publication Number Publication Date
GB1272592A true GB1272592A (en) 1972-05-03

Family

ID=10162679

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2142268A Expired GB1272592A (en) 1968-05-06 1968-05-06 Vapour phase oxidation of hydroxy compounds

Country Status (11)

Country Link
JP (1) JPS4930807B1 (de)
BE (1) BE732584A (de)
BR (1) BR6908551D0 (de)
CH (1) CH535193A (de)
DE (2) DE1923048C3 (de)
ES (1) ES366867A1 (de)
FR (1) FR2007925A1 (de)
GB (1) GB1272592A (de)
NL (1) NL168487C (de)
NO (1) NO133034C (de)
SE (1) SE363816B (de)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2634439A1 (de) * 1975-07-31 1977-02-10 American Cyanamid Co Verfahren zur herstellung von glyoxal
EP0007570A1 (de) * 1978-07-24 1980-02-06 BASF Aktiengesellschaft Verfahren zur Herstellung von Glyoxal aus Äthylenglykol
US4258216A (en) * 1975-07-31 1981-03-24 American Cyanamid Company Vapor phase oxidation process for glyoxal
JPS5838227A (ja) * 1981-09-01 1983-03-05 Mitsui Toatsu Chem Inc アルデヒドの製造法
EP0091060A2 (de) * 1982-04-08 1983-10-12 BASF Aktiengesellschaft Verfahren zur Herstellung von Formaldehyd
US4439625A (en) * 1982-09-29 1984-03-27 E. I. Du Pont De Nemours And Company Production of formaldehyde
US4503261A (en) * 1982-07-22 1985-03-05 Basf Aktiengesellschaft Preparation of glyoxal
US4511739A (en) * 1979-06-02 1985-04-16 Basf Aktiengesellschaft Continuous preparation of glyoxal
US4555583A (en) * 1982-08-30 1985-11-26 Mitsui Toatsu Chemicals, Incorporated Preparation process for glyoxal
US4599459A (en) * 1984-08-31 1986-07-08 Masanao Hirose Method for the ultrasonic treatment of a dilute alcoholic solution
US4851584A (en) * 1987-04-15 1989-07-25 Basf Aktiengesellschaft Preparation of carbonyl compounds
WO2007132011A1 (de) * 2006-05-17 2007-11-22 Basf Aktiengesellschaft Verfahren zur herstellung vicinaler dioxoverbindungen durch oxidation vicinaler dihydroxyverbindungen an einer strukturierten katalysatorschüttung
DE102008002535A1 (de) 2007-06-25 2009-01-02 Basf Se Verfahren zur Herstellung vicinaler Dioxoverbindungen durch Oxidation vicinaler Dihydroxyverbindungen an Silber enthaltenden Dünnschichtkatalysatoren
US8461396B2 (en) 2010-10-01 2013-06-11 Basf Se Process for purifying aqueous glyoxal solutions
WO2022058188A1 (en) 2020-09-17 2022-03-24 Basf Se Process for the production of glyoxal

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5490109A (en) * 1977-12-24 1979-07-17 Basf Ag Manufacture of fatty hydroxycarbonyl compound etherified with fatty group
DE2803318A1 (de) * 1978-01-26 1979-08-09 Basf Ag Verfahren zur herstellung von glyoxal
DE3012004A1 (de) * 1980-03-28 1981-10-15 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von methylglyoxal
DE3643469A1 (de) * 1986-12-19 1988-06-30 Basf Ag Verfahren zur herstellung von carbonylverbindungen
EP2019816B1 (de) * 2006-05-17 2019-01-09 Basf Se Temperierung bei der durchführung von oxidationsreaktionen von kohlenwasserstoffen
DE102008018480B4 (de) 2007-04-13 2020-10-15 Basf Se Verfahren zur Herstellung vicinaler Dioxoverbindungen durch Oxidation vicinaler Dihydroxyverbindungen
CN102272084A (zh) 2008-12-29 2011-12-07 巴斯夫欧洲公司 提纯乙二醛水溶液的方法
CN103153929B (zh) 2010-10-01 2015-06-03 巴斯夫欧洲公司 提纯乙二醛水溶液的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1497817A (en) * 1918-08-13 1924-06-17 Seth B Hunt Process of making acetone and other ketones
US2051266A (en) * 1935-03-23 1936-08-18 Shell Dev Catalytic oxidation of polyhydric alcohols
US2462107A (en) * 1943-05-03 1949-02-22 Ninol Dev Co Process for preparation of diacetyl
FR1060331A (fr) * 1951-08-02 1954-04-01 Basf Ag Procédé pour obtenir les uréines du glyoxal
US3049446A (en) * 1960-02-05 1962-08-14 Sun Chemical Corp Process for the manufacture of urea, glyoxal and formaldehye reaction product useful for improving cellulosic textile materials

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2634439A1 (de) * 1975-07-31 1977-02-10 American Cyanamid Co Verfahren zur herstellung von glyoxal
US4258216A (en) * 1975-07-31 1981-03-24 American Cyanamid Company Vapor phase oxidation process for glyoxal
EP0007570A1 (de) * 1978-07-24 1980-02-06 BASF Aktiengesellschaft Verfahren zur Herstellung von Glyoxal aus Äthylenglykol
US4282374A (en) * 1978-07-24 1981-08-04 Basf Aktiengesellschaft Preparation of glyoxal from ethylene glycol
US4511739A (en) * 1979-06-02 1985-04-16 Basf Aktiengesellschaft Continuous preparation of glyoxal
JPS5838227A (ja) * 1981-09-01 1983-03-05 Mitsui Toatsu Chem Inc アルデヒドの製造法
EP0091060A2 (de) * 1982-04-08 1983-10-12 BASF Aktiengesellschaft Verfahren zur Herstellung von Formaldehyd
EP0091060A3 (en) * 1982-04-08 1986-07-23 Basf Aktiengesellschaft Process for producing formaldehyde
US4503261A (en) * 1982-07-22 1985-03-05 Basf Aktiengesellschaft Preparation of glyoxal
US4555583A (en) * 1982-08-30 1985-11-26 Mitsui Toatsu Chemicals, Incorporated Preparation process for glyoxal
EP0104666A2 (de) * 1982-09-29 1984-04-04 E.I. Du Pont De Nemours And Company Verfahren zur Herstellung von Formaldehyd
EP0104666A3 (en) * 1982-09-29 1985-10-23 E.I. Du Pont De Nemours And Company Production of formaldehyde
US4439625A (en) * 1982-09-29 1984-03-27 E. I. Du Pont De Nemours And Company Production of formaldehyde
US4599459A (en) * 1984-08-31 1986-07-08 Masanao Hirose Method for the ultrasonic treatment of a dilute alcoholic solution
US4851584A (en) * 1987-04-15 1989-07-25 Basf Aktiengesellschaft Preparation of carbonyl compounds
WO2007132011A1 (de) * 2006-05-17 2007-11-22 Basf Aktiengesellschaft Verfahren zur herstellung vicinaler dioxoverbindungen durch oxidation vicinaler dihydroxyverbindungen an einer strukturierten katalysatorschüttung
DE102008002535A1 (de) 2007-06-25 2009-01-02 Basf Se Verfahren zur Herstellung vicinaler Dioxoverbindungen durch Oxidation vicinaler Dihydroxyverbindungen an Silber enthaltenden Dünnschichtkatalysatoren
US8461396B2 (en) 2010-10-01 2013-06-11 Basf Se Process for purifying aqueous glyoxal solutions
WO2022058188A1 (en) 2020-09-17 2022-03-24 Basf Se Process for the production of glyoxal

Also Published As

Publication number Publication date
DE1923048B2 (de) 1979-07-19
NL6906866A (de) 1969-11-10
FR2007925A1 (de) 1970-01-16
BE732584A (de) 1969-11-06
NL168487C (nl) 1982-04-16
DE1923048C3 (de) 1980-06-19
ES366867A1 (es) 1971-06-16
SE363816B (de) 1974-02-04
DE1967147C2 (de) 1980-02-14
NO133034B (de) 1975-11-17
JPS4930807B1 (de) 1974-08-16
NL168487B (nl) 1981-11-16
DE1967147B1 (de) 1979-06-13
NO133034C (de) 1976-02-25
DE1923048A1 (de) 1969-11-20
BR6908551D0 (pt) 1973-01-04
CH535193A (de) 1973-03-31

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PE20 Patent expired after termination of 20 years