GB1258292A - - Google Patents

Info

Publication number
GB1258292A
GB1258292A GB240569A GB1258292DA GB1258292A GB 1258292 A GB1258292 A GB 1258292A GB 240569 A GB240569 A GB 240569A GB 1258292D A GB1258292D A GB 1258292DA GB 1258292 A GB1258292 A GB 1258292A
Authority
GB
United Kingdom
Prior art keywords
zeolite
disproportionation
alkyl aromatics
hydrogenating component
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB240569A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1258292A publication Critical patent/GB1258292A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/755Nickel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00Chemistry of hydrocarbon compounds
    • Y10S585/929Special chemical considerations
    • Y10S585/942Production of carbonium ion or hydrocarbon free-radical

Abstract

1,258,292. Reaction of alkyl aromatics. BRITISH PETROLEUM CO. Ltd. 4 Dec., 1968 [15 Jan., 1969], No. 2405/69. Heading C5E. [Also in Division C1] Alkyl aromatics having a non-aromatic hydrocarbon content of less than 0À5 wt. per cent are subjected to isomerization, disproportionation or transalkylation at elevated temperature and pressure in the presence of hydrogen and in contact with a catalyst comprising an alkali metal cation-deficient zeolite having pores of at least 6 Š and a hydrogenating component selected from the metals of Groups I B , V A , VI A VII A and VIII of the Mendeleev Periodic Table. Suitable zeolites are faujasite, Zeolite Y, Zeolite L or preferably mordenite, suitable in the hydrogen form but optionally also containing Group II or rare earth metal cations. Nickel is the preferred hydrogenating component. Suitable feeds are C 7-15 alkylaromatics including naphthalenes, and the only example relates to the disproportionation of toluene.
GB240569A 1969-01-15 1969-01-15 Expired GB1258292A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB240569 1969-01-15

Publications (1)

Publication Number Publication Date
GB1258292A true GB1258292A (en) 1971-12-30

Family

ID=9738978

Family Applications (1)

Application Number Title Priority Date Filing Date
GB240569A Expired GB1258292A (en) 1969-01-15 1969-01-15

Country Status (7)

Country Link
US (1) US3629351A (en)
BE (1) BE744461A (en)
CA (1) CA935186A (en)
DE (1) DE2000491A1 (en)
FR (1) FR2028365A1 (en)
GB (1) GB1258292A (en)
NL (1) NL6918966A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996035498A1 (en) * 1995-05-10 1996-11-14 Denim Engineering, Inc. Method and apparatus for removing ethylbenzene from mixed xylenes stream
US6342649B1 (en) * 1995-05-10 2002-01-29 Denim Engineering, Inc Method for removing ethylbenzene from a para-xylene feed stream

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1051463A (en) * 1974-01-07 1979-03-27 Mobil Oil Corporation Disproportionation of toluene
US4180693A (en) * 1976-10-15 1979-12-25 Institut Francais Du Petrole New preparation process of a catalyst for converting aromatic hydrocarbons
US4210770A (en) * 1976-10-15 1980-07-01 Institut Francais Du Petrole Process for aromatic hydrocarbon conversion and catalyst therefor
US4217248A (en) * 1978-01-03 1980-08-12 Phillips Petroleum Company Hydroalkylation catalyst composition comprising a rhenium, nickel, rare earth zeolite
US4405503A (en) * 1980-11-21 1983-09-20 The British Petroleum Company Limited Production of zeolite agglomerates
US5202516A (en) * 1987-11-23 1993-04-13 The Dow Chemical Company Process of recovering monoalkylbenzene and pure 1,3,5-trialkylbenzene from a mixture of dialkyl- and trialkylbenzenes
US5827422A (en) * 1996-06-26 1998-10-27 Phillips Petroleum Company Process for the conversion of a gasoline to a C6 to C8 aromatic compound and an olefin
US5698757A (en) * 1996-06-26 1997-12-16 Phillips Petroleum Company Hydrodealkylation catalyst composition and process therewith
US5945364A (en) * 1996-06-26 1999-08-31 Phillips Petroleum Company Catalyst composition comprising acid-base leached zeolites
US6462247B1 (en) * 1996-07-15 2002-10-08 Fina Technology, Inc. Toluene disproportionation process
DE10042467A1 (en) * 2000-08-29 2002-03-28 Bosch Gmbh Robert Brush assembly for an electrical machine
US8063259B2 (en) * 2008-08-18 2011-11-22 Fina Technology, Inc. Toluene disproportionation using Nb/mordenite catalyst

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996035498A1 (en) * 1995-05-10 1996-11-14 Denim Engineering, Inc. Method and apparatus for removing ethylbenzene from mixed xylenes stream
GB2304349A (en) * 1995-05-10 1997-03-19 Denim Engineering Inc Method and apparatus for removing ethylbenzene from mixed xylenes stream
GB2304349B (en) * 1995-05-10 1998-09-16 Denim Engineering Inc Method and apparatus for removing ethylbenzene from mixed xylenes stream
US6342649B1 (en) * 1995-05-10 2002-01-29 Denim Engineering, Inc Method for removing ethylbenzene from a para-xylene feed stream

Also Published As

Publication number Publication date
BE744461A (en) 1970-07-15
DE2000491A1 (en) 1971-02-25
FR2028365A1 (en) 1970-10-09
CA935186A (en) 1973-10-09
NL6918966A (en) 1970-07-17
US3629351A (en) 1971-12-21

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees