GB1254576A - Electrolytic copper plating bath and a method for depositing copper films therefrom - Google Patents

Electrolytic copper plating bath and a method for depositing copper films therefrom

Info

Publication number
GB1254576A
GB1254576A GB28519/69A GB2851969A GB1254576A GB 1254576 A GB1254576 A GB 1254576A GB 28519/69 A GB28519/69 A GB 28519/69A GB 2851969 A GB2851969 A GB 2851969A GB 1254576 A GB1254576 A GB 1254576A
Authority
GB
United Kingdom
Prior art keywords
ions
mole
film
electro
plating bath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28519/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Business Machines Corp
Original Assignee
International Business Machines Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Business Machines Corp filed Critical International Business Machines Corp
Publication of GB1254576A publication Critical patent/GB1254576A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/56Electroplating: Baths therefor from solutions of alloys
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/38Electroplating: Baths therefor from solutions of copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

1,254,576. Electro-depositing copper. INTERNATIONAL BUSINESS MACHINES CORP. June 5, 1969 [June 17, 1968], No.28519/69. Heading C7B. A thick (3-12 microns) Cu film is electrodeposited from an aquous plating bath comprising Cu ions e.g. 0.20-0.36 mole/l, SO 4 ions e.g. 0.21-0.47 mole/l, NO 3 ions e.g. 0.22-0.52 mole/l, formic acid e.g. 0.21-0.62 mole/l, acetic acid e.g. 0.10-0.32 mole/ l, and optionally a surfactant e.g. 0.4-0.7 g/l (Registered Trade Mark), "Triton" in which the molar ratio of SO 4 to NO 3 ions is 0.52- 1.90. Cu SO 4 may be the source of SO 4 and Cu ions, with HNO 3 ; or Cu (NO 3 ) 2 may be the source of NO 3 and Cu ions, with H 2 SO 4 . The bath is preferably flowed over the area to be plated while passing a current of density 40-50 ma/cm<SP>2</SP>. The invention is preferably used to electro-plate a thick Cu film on to a permalloy film, such as electro-deposited by the method disclosed in Specification 1, 139, 987, in the formation of a magnetic coupled film memory device (see Specification 1, 254, 575.
GB28519/69A 1968-06-17 1969-06-05 Electrolytic copper plating bath and a method for depositing copper films therefrom Expired GB1254576A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US73736768A 1968-06-17 1968-06-17

Publications (1)

Publication Number Publication Date
GB1254576A true GB1254576A (en) 1971-11-24

Family

ID=24963642

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28519/69A Expired GB1254576A (en) 1968-06-17 1969-06-05 Electrolytic copper plating bath and a method for depositing copper films therefrom

Country Status (4)

Country Link
US (1) US3527681A (en)
DE (1) DE1929563A1 (en)
FR (1) FR2011036A1 (en)
GB (1) GB1254576A (en)

Also Published As

Publication number Publication date
US3527681A (en) 1970-09-08
DE1929563A1 (en) 1970-02-12
FR2011036A1 (en) 1970-02-27

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