GB1234034A - - Google Patents

Info

Publication number
GB1234034A
GB1234034A GB3984667A GB1234034DA GB1234034A GB 1234034 A GB1234034 A GB 1234034A GB 3984667 A GB3984667 A GB 3984667A GB 1234034D A GB1234034D A GB 1234034DA GB 1234034 A GB1234034 A GB 1234034A
Authority
GB
United Kingdom
Prior art keywords
polymers
silicon
methyl methacrylate
organic
free radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3984667A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1234034A publication Critical patent/GB1234034A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C08L43/04—Homopolymers or copolymers of monomers containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00—Use of unspecified macromolecular compounds as moulding material
    • B29K2101/10—Thermosetting resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2301/00—Use of unspecified macromolecular compounds as reinforcement
    • B29K2301/10—Thermosetting resins

Abstract

1,234,034. Crosslinking polymers. MIDLAND SILICONES Ltd. 19 Sept., 1968 [31 Aug., 1967], No. 39846/67. Heading C3P. Organic polymers are crosslinked by mechanical working to induce the formation of free radical sites in the presence of at least one organosilicon compound containing at least one silicon-bonded hydrolysable atom or radical and at least one silicon-bonded atom or radical reactive with free radical sites, and exposing the polymer to moisture. The working may be supplemented by incorporating a free radical generator, e.g. an organic peroxide or azobisnitrile. Specified polymers are hydrocarbon and halogenated hydrocarbon polymers, polyacrylates, polysulphides, polyamides, polyesters, aminoplasts and epoxides. The silicon compound may contain halogen atoms or alkoxy, oximo, acyloxy or amino radicals; and olefinically unsaturated radicals. Unsaturated organic compounds, e.g. methyl methacrylate, ethyl acrylate and maleic anhydride, and silanol condensation catalysts, e.g. organic metal compounds, bases and acids, and polyfunctional silicon compounds such as tetraalkyl silicates, may also be present. Examples describe the crosslinking of compositions comprising dibutyl tin diacetate with (1) polyethylene and vinyltriethoxysilane, together with (2, 4 and 5) dicumyl peroxide and (3) benzoyl peroxide and tetraethyl orthosilicate; and comprising dibutyl tin diacetate and 8-methacryloxypropyl trimethoxysilane with (6) a polyacrylate, (7) polyvinyl chloride and methyl methacrylate and (8) ABS terpolymer and methyl methacrylate.
GB3984667A 1967-08-31 1967-08-31 Expired GB1234034A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3984667 1967-08-31

Publications (1)

Publication Number Publication Date
GB1234034A true GB1234034A (en) 1971-06-03

Family

ID=10411809

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3984667A Expired GB1234034A (en) 1967-08-31 1967-08-31

Country Status (6)

Country Link
BE (1) BE720199A (en)
DE (1) DE1794028C3 (en)
FR (1) FR1577875A (en)
GB (1) GB1234034A (en)
IL (1) IL30601A (en)
NL (1) NL150483C (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2353783A1 (en) * 1972-10-28 1974-05-09 Dow Corning Ltd METHOD FOR CROSSLINKING POLYOLEFS
DE2554525A1 (en) * 1974-12-06 1976-06-16 Bicc Ltd METHOD OF MANUFACTURING EXTRUDED PRODUCTS
US4212756A (en) 1979-05-17 1980-07-15 Union Carbide Corporation Dielectric composition stabilized against water treeing with organo silane compounds
US4551504A (en) * 1984-01-18 1985-11-05 Union Carbide Corporation Water curable, azide sulfonyl silane modified ethylene polymers
US4593071A (en) * 1983-09-23 1986-06-03 Union Carbide Corporation Water-curable, silane modified ethylene polymers
US5043393A (en) * 1988-12-02 1991-08-27 Mitsui Petrochemical Industries, Ltd. Process for producing fluorine-containing copolymer and fluorine-containing copolymer composition
EP0839864A2 (en) * 1996-10-31 1998-05-06 Kaneka Corporation Curable resin composition
EP1566412A1 (en) * 2002-11-01 2005-08-24 Kaneka Corporation Curable composition and method for improving recovery properties and creep properties
US8211982B2 (en) 2004-03-17 2012-07-03 Dow Global Technologies Llc Functionalized ethylene/α-olefin interpolymer compositions
US8318864B2 (en) * 2004-03-17 2012-11-27 Dow Global Technologies Llc Functionalized ethylene/α-olefin interpolymer compositions
EP3074462B1 (en) 2013-11-25 2017-12-20 Dow Global Technologies LLC Moisture-and peroxide-crosslinkable polymeric compositions
WO2021128127A1 (en) * 2019-12-26 2021-07-01 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with high glass adhesion

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE794718Q (en) * 1968-12-20 1973-05-16 Dow Corning Ltd OLEFINS CROSS-LINKING PROCESS
GB1357549A (en) * 1971-11-12 1974-06-26 Dow Corning Ltd Cross-linking of polymers
CH618450A5 (en) * 1974-03-08 1980-07-31 Kabel Metallwerke Ghh Process for the crosslinking of thermoplastic or elastomeric base material by grafting silane or a silane compound onto the base material in the presence of water
DE2422914C2 (en) * 1974-05-11 1983-12-22 kabelmetal electro GmbH, 3000 Hannover High or extra high voltage electrical cable
AR218611A1 (en) * 1975-06-23 1980-06-30 Kabel Metallwerke Ghh PROCEDURE FOR THE ELABORATION OF THERMOPLASTICS OR ELASTOMERS RETICULABLE BY GRAFTING OF A SILANO COMPOUND IN THE PRESENCE OF MOISTURE
DE2555017A1 (en) * 1975-12-06 1977-06-08 Kabel Metallwerke Ghh TUBE-SHAPED STRUCTURE FOR TRANSPORTING LIQUID OR GAS-SHAPED MEDIA, ESPECIALLY AT HIGH TEMPERATURES AND HIGH PRESSURE
DE2554942A1 (en) * 1975-12-06 1977-06-16 Kabel Metallwerke Ghh Coating mixts. of fillers and elastomers - contg. grafted or adducted cpds. to cause crosslinking when exposed to moisture
JPS6017353B2 (en) * 1978-03-03 1985-05-02 古河電気工業株式会社 Crosslinking method for polyolefin resin
US4243767A (en) * 1978-11-16 1981-01-06 Union Carbide Corporation Ambient temperature curable hydroxyl containing polymer/silicon compositions
DE3003156A1 (en) * 1980-01-30 1981-08-06 Kabel- und Metallwerke Gutehoffnungshütte AG, 3000 Hannover Crosslinking moisture-crosslinkable coiled material - in sealed chamber, by sucking out air mixing with satd. steam and reintroducing steam-air mixt.
DE3066667D1 (en) * 1980-03-05 1984-03-29 Kanegafuchi Chemical Ind Curable composition
DE3028839C2 (en) * 1980-07-30 1984-08-23 Chemische Werke Hüls AG, 4370 Marl Process for the preparation of homo- and copolymers of 1,3-dienes which carry reactive silyl groups and their use
FR2535726B1 (en) * 1982-11-09 1986-01-10 Ceat Ste Fse PROCESS FOR GRAFTING A SILANE ONTO A POLYOLEFIN WITH A VIEW TO CROSS-LINKING AS WELL AS THE SILANE-BASED MIXTURES NECESSARY FOR THE IMPLEMENTATION OF SUCH A PROCESS, IN PARTICULAR ON ORDINARY EXTRUDERS
DE3306909A1 (en) * 1983-02-26 1985-01-10 Dynamit Nobel Ag, 5210 Troisdorf Process for the production of crosslinked mouldings based on polyethylene
DE3327149A1 (en) * 1983-07-28 1985-04-04 Dynamit Nobel Ag, 5210 Troisdorf METHOD FOR THE PRODUCTION OF SEMI-PRODUCTS OR MOLDED PARTS FROM POLYPROPYLENE
DE3327596C2 (en) * 1983-07-30 1986-04-03 Dynamit Nobel Ag, 5210 Troisdorf Silane-modified molding compositions based on vinylidene fluoride polymer, crosslinked moldings made therefrom and processes for producing the same
GB8427615D0 (en) * 1984-11-01 1985-01-03 Bp Chem Int Ltd Cross-linkable elastomeric materials
DE3533507A1 (en) * 1985-09-20 1987-04-02 Kabelmetal Electro Gmbh Overhead electrical line, in particular a facade cable
DE3533510A1 (en) * 1985-09-20 1987-04-02 Kabelmetal Electro Gmbh Low-voltage electrical cable or electrical line
DE3533508A1 (en) * 1985-09-20 1987-04-02 Kabelmetal Electro Gmbh Cable sheath or protective tube
EP0252061A1 (en) * 1986-07-04 1988-01-07 Cableries Et Corderies Du Hainaut S.A. Process for the preparation of vinylpolymers and vinylpolymers crosslinkable by the grafting of a hydrolysable silane compound
JPH0288639A (en) * 1988-09-27 1990-03-28 Shin Etsu Chem Co Ltd Organopolysiloxane compound

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE698389C (en) * 1939-06-20 1940-11-08 F Raschig G M B H Dr
US2843555A (en) * 1956-10-01 1958-07-15 Gen Electric Room temperature curing organopolysiloxane
GB876033A (en) * 1958-04-25 1961-08-30 Hoeganasmetoder Ab Modified resin binders for siliceous materials
DE1270797B (en) * 1965-09-29 1968-06-20 Dynamit Nobel Ag Decrease the flammability of plastics
US3503943A (en) * 1965-10-21 1970-03-31 Exxon Research Engineering Co Silane modified ethylene-propylene terpolymer

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2353783A1 (en) * 1972-10-28 1974-05-09 Dow Corning Ltd METHOD FOR CROSSLINKING POLYOLEFS
DE2554525A1 (en) * 1974-12-06 1976-06-16 Bicc Ltd METHOD OF MANUFACTURING EXTRUDED PRODUCTS
US4212756A (en) 1979-05-17 1980-07-15 Union Carbide Corporation Dielectric composition stabilized against water treeing with organo silane compounds
US4593071A (en) * 1983-09-23 1986-06-03 Union Carbide Corporation Water-curable, silane modified ethylene polymers
US4551504A (en) * 1984-01-18 1985-11-05 Union Carbide Corporation Water curable, azide sulfonyl silane modified ethylene polymers
US5043393A (en) * 1988-12-02 1991-08-27 Mitsui Petrochemical Industries, Ltd. Process for producing fluorine-containing copolymer and fluorine-containing copolymer composition
US6183551B1 (en) 1996-10-31 2001-02-06 Kaneka Corporation Curable resin composition
EP0839864A3 (en) * 1996-10-31 1999-07-28 Kaneka Corporation Curable resin composition
EP0839864A2 (en) * 1996-10-31 1998-05-06 Kaneka Corporation Curable resin composition
EP1566412A1 (en) * 2002-11-01 2005-08-24 Kaneka Corporation Curable composition and method for improving recovery properties and creep properties
EP1566412A4 (en) * 2002-11-01 2006-02-01 Kaneka Corp Curable composition and method for improving recovery properties and creep properties
US7910682B2 (en) 2002-11-01 2011-03-22 Kaneka Corporation Curable composition and methods for improving recovery properties and creep properties
US8586688B2 (en) 2002-11-01 2013-11-19 Kaneka Corporation Curable composition and method for improving recovery properties and creep properties
US8211982B2 (en) 2004-03-17 2012-07-03 Dow Global Technologies Llc Functionalized ethylene/α-olefin interpolymer compositions
US8318864B2 (en) * 2004-03-17 2012-11-27 Dow Global Technologies Llc Functionalized ethylene/α-olefin interpolymer compositions
US8609779B2 (en) 2004-03-17 2013-12-17 Dow Global Technologies Llc Functionalized ethylene/alpha-olefin interpolymer compositions
EP3074462B1 (en) 2013-11-25 2017-12-20 Dow Global Technologies LLC Moisture-and peroxide-crosslinkable polymeric compositions
US10308829B2 (en) 2013-11-25 2019-06-04 Dow Global Technologies Llc Moisture-and peroxide-crosslinkable polymeric compositions
WO2021128127A1 (en) * 2019-12-26 2021-07-01 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer compositions with high glass adhesion

Also Published As

Publication number Publication date
NL150483C (en) 1980-08-15
NL6812217A (en) 1969-03-04
IL30601A (en) 1971-08-25
IL30601A0 (en) 1968-10-24
DE1794028C3 (en) 1982-08-12
BE720199A (en) 1969-02-03
DE1794028A1 (en) 1972-04-27
FR1577875A (en) 1969-08-08
DE1794028B2 (en) 1973-10-18
NL150483B (en) 1976-08-16

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years