GB1306992A - Cationic unsaturated amine-functional silane coupling agents - Google Patents

Cationic unsaturated amine-functional silane coupling agents

Info

Publication number
GB1306992A
GB1306992A GB1818670A GB1818670A GB1306992A GB 1306992 A GB1306992 A GB 1306992A GB 1818670 A GB1818670 A GB 1818670A GB 1818670 A GB1818670 A GB 1818670A GB 1306992 A GB1306992 A GB 1306992A
Authority
GB
United Kingdom
Prior art keywords
bonded
alkyl
treated
compound
cationic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1818670A
Inventor
E Plueddemann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Silicones Corp
Original Assignee
Dow Corning Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Corp filed Critical Dow Corning Corp
Publication of GB1306992A publication Critical patent/GB1306992A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/1095—Coating to obtain coated fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0836—Compounds with one or more Si-OH or Si-O-metal linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F30/08—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/72—Cured, e.g. vulcanised, cross-linked

Abstract

1306992 Laminated products DOW CORNING CORP 16 April 1970 [15 May 1969] 18186/70 Heading B5N [Also in Divisions B2 and C3] Resin-bonded laminates are made from glass cloth which has been treated with a cationic organosilicon compound of the general formula in which X is OH or a hydrolysable radical; R is C 1-6 alkyl ; R<SP>1</SP> is H, C 1-6 alkyl or a heterocyclic organic radical containing the N atom, to which R<SP>1</SP> is attached, as ring member; Q is a divalent radical consisting of C and H optionally with O in the form of -COC-, -COOC-, >C=O or >COH or N in the form of R<SP>11</SP>N<, with the proviso that when Q contains C=O, R<SP>1</SP> is not H; m is 1 when R<SP>1</SP> is heterocyclic or 2 when R<SP>1</SP> is H or alkyl; Z is a divalent radical having a double bond conjugated with the CH 2 =CR<SP>11</SP>- moiety and is bonded to the N by C; R<SP>11</SP> is H or C 1-6 alkyl; n is 1, 2 or 3; end Y is an acid anion. Examples 2 and 5 describe the manufacture of polyester bonded treated glass cloth laminates. In a modification, the cationic silicon compounds can first be copolymerized with an unsaturated compound and the reinforcing material laminated to the vinylic copolymer. Aluminium or steel may be treated with the organosilicon compounds and subsequently bonded to a sheet of vinyl polymer (many specified). Steel or ceramics are bonded to a layer of a copolymer of one of the silicon compounds with an acrylate. In Example 6, a compound is copolymerized with butadiene and the copolymeric rubber bonded to untreated glass tyre cord fabric.
GB1818670A 1969-05-15 1970-04-16 Cationic unsaturated amine-functional silane coupling agents Expired GB1306992A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US82503569A 1969-05-15 1969-05-15

Publications (1)

Publication Number Publication Date
GB1306992A true GB1306992A (en) 1973-02-14

Family

ID=25242964

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1818670A Expired GB1306992A (en) 1969-05-15 1970-04-16 Cationic unsaturated amine-functional silane coupling agents

Country Status (10)

Country Link
JP (1) JPS4820609B1 (en)
AT (1) AT312307B (en)
BE (1) BE750393A (en)
CA (1) CA939378A (en)
CH (2) CH557842A (en)
FR (1) FR2042658A1 (en)
GB (1) GB1306992A (en)
NL (1) NL7007089A (en)
SE (1) SE369722B (en)
ZA (1) ZA702681B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3047994A1 (en) * 1980-12-19 1982-07-22 Degussa Ag, 6000 Frankfurt AQUEOUS SOLUTION OF CATIONIC ORGANOSILIC COMPOUNDS AND METHOD FOR PRODUCING THE SOLUTIONS
GB2147225A (en) * 1983-09-28 1985-05-09 Richard Hall Clucas Method of manufacturing coated resin bonded glass fibre rods
US9453113B2 (en) 2004-04-15 2016-09-27 Sinvent As Method for the manufacture of polybranched organic/inorganic hybrid polymers

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2377982A1 (en) 1977-01-19 1978-08-18 Saint Gobain COMPOSITIONS FOR COATING FIBERS OF GLASS AND FIBERS SO OBTAINED
JP4677664B2 (en) * 2000-11-02 2011-04-27 日東紡績株式会社 Silane coupling agent, sizing agent containing the same, glass fiber bundle coated with the sizing agent, and polyester resin containing the glass fiber bundle
US7531588B2 (en) * 2004-07-30 2009-05-12 Momentive Performance Materials Inc. Silane compositions, processes for their preparation and rubber compositions containing same
US7759408B2 (en) * 2005-12-21 2010-07-20 Bausch & Lomb Incorporated Silicon-containing monomers end-capped with polymerizable cationic hydrophilic groups
US7622512B2 (en) * 2005-12-21 2009-11-24 Bausch & Lomb Incorporated Cationic hydrophilic siloxanyl monomers
US7960447B2 (en) * 2006-04-13 2011-06-14 Bausch & Lomb Incorporated Cationic end-capped siloxane prepolymer for reduced cross-link density
JP4697456B2 (en) * 2006-07-28 2011-06-08 信越化学工業株式会社 Composite material modifier and composite material
JP5648823B2 (en) * 2009-10-01 2015-01-07 星光Pmc株式会社 Copolymer for aqueous primer and aqueous primer composition
CN106132999B (en) * 2014-03-31 2018-02-13 日本瑞翁株式会社 The manufacture method of modified conjugated diene rubber

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3047994A1 (en) * 1980-12-19 1982-07-22 Degussa Ag, 6000 Frankfurt AQUEOUS SOLUTION OF CATIONIC ORGANOSILIC COMPOUNDS AND METHOD FOR PRODUCING THE SOLUTIONS
GB2147225A (en) * 1983-09-28 1985-05-09 Richard Hall Clucas Method of manufacturing coated resin bonded glass fibre rods
US9453113B2 (en) 2004-04-15 2016-09-27 Sinvent As Method for the manufacture of polybranched organic/inorganic hybrid polymers
US9487632B2 (en) 2004-04-15 2016-11-08 Sinvent As Method for the manufacture of polybranched organic/inorganic hybrid polymers

Also Published As

Publication number Publication date
CH554374A (en) 1974-09-30
DE2023968A1 (en) 1971-02-04
CH557842A (en) 1975-01-15
JPS4820609B1 (en) 1973-06-22
SE369722B (en) 1974-09-16
BE750393A (en) 1970-11-16
CA939378A (en) 1974-01-01
AT312307B (en) 1973-12-27
NL7007089A (en) 1970-11-17
ZA702681B (en) 1971-01-27
FR2042658A1 (en) 1971-02-12
DE2023968B2 (en) 1977-06-16

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years