GB1225039A - Fuel additives - Google Patents
Fuel additivesInfo
- Publication number
- GB1225039A GB1225039A GB06485/68A GB1648568A GB1225039A GB 1225039 A GB1225039 A GB 1225039A GB 06485/68 A GB06485/68 A GB 06485/68A GB 1648568 A GB1648568 A GB 1648568A GB 1225039 A GB1225039 A GB 1225039A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- oleate
- fuel
- oil
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002816 fuel additive Substances 0.000 title 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 4
- -1 alkyl phenols Chemical class 0.000 abstract 4
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 3
- 239000005864 Sulphur Substances 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 abstract 2
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 abstract 2
- 229920002367 Polyisobutene Polymers 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 2
- 229910001863 barium hydroxide Inorganic materials 0.000 abstract 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 abstract 2
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 2
- 239000002283 diesel fuel Substances 0.000 abstract 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000000446 fuel Substances 0.000 abstract 2
- 239000000295 fuel oil Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229960005068 monoethanolamine oleate Drugs 0.000 abstract 2
- 229940055577 oleyl alcohol Drugs 0.000 abstract 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 abstract 2
- 229920000098 polyolefin Polymers 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 239000003784 tall oil Substances 0.000 abstract 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 abstract 1
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 abstract 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 abstract 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 abstract 1
- VYDBDDDTZMNNMM-UHFFFAOYSA-N 11:0(10Me,10Me) Chemical compound CC(C)(C)CCCCCCCCC(O)=O VYDBDDDTZMNNMM-UHFFFAOYSA-N 0.000 abstract 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 abstract 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract 1
- 229930185605 Bisphenol Natural products 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005639 Lauric acid Substances 0.000 abstract 1
- 239000005642 Oleic acid Substances 0.000 abstract 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- XABJJJZIQNZSIM-UHFFFAOYSA-N azane;phenol Chemical compound [NH4+].[O-]C1=CC=CC=C1 XABJJJZIQNZSIM-UHFFFAOYSA-N 0.000 abstract 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 abstract 1
- VSRHJGWIUVFJCJ-KVVVOXFISA-N butan-1-amine;(z)-octadec-9-enoic acid Chemical compound CCCCN.CCCCCCCC\C=C/CCCCCCCC(O)=O VSRHJGWIUVFJCJ-KVVVOXFISA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000010771 distillate fuel oil Substances 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000010763 heavy fuel oil Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract 1
- 229940102253 isopropanolamine Drugs 0.000 abstract 1
- 239000003350 kerosene Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 229940049964 oleate Drugs 0.000 abstract 1
- 229960002969 oleic acid Drugs 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 235000019809 paraffin wax Nutrition 0.000 abstract 1
- 235000019271 petrolatum Nutrition 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000779 smoke Substances 0.000 abstract 1
- 239000001593 sorbitan monooleate Substances 0.000 abstract 1
- 229940035049 sorbitan monooleate Drugs 0.000 abstract 1
- 235000011069 sorbitan monooleate Nutrition 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- 229940117013 triethanolamine oleate Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/04—Reaction products of phosphorus sulfur compounds with hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
1,225,039. Fuel. ESSO RESEARCH & ENG. CO. 6 March, 1969 [5 April, 1968], No. 16485/68. Heading C5G. [Also in Division C3] Fuel oil compositions comprise anti-smoke additives prepared by introducing carbon dioxide and (A) an alkali metal or alkaline earth metal oxide or hydroxide into a mixture of (B) a phenol, thiophenol, or metal or ammonium phenate or thiophenate and (C) a dispersant for the metal carbonate produced, a long-chain compound (D) which is an organic acid containing at least 6 carbon atoms or salt thereof, an alcohol containing at least 6 carbon atoms or alcoholate thereof or an ester containing at least 8 carbon atoms being introduced before, during or after reaction. The fuel may be a light fuel oil, diesel gas oil, furnace heavy oil, kerosene diesel oil or residual fuel. Preferred reactants are (A) barium oxide or hydroxide, (B) alkyl phenols, polyhydric phenols and alkylene bisphenols and (C) acidic sulphur-containing hydrocarbon derivatives such as reaction products of sulphur and sulphur-containing materials with terpenes, paraffins, olefins, petroleum fractions and paraffin waxes, particularly phosphosulphurized polyolefins and polyolefin sulphonic acids. (D) may be a C 12-40 mono- or poly-basic acid, mono- or poly-hydric alcohol or ester. Many suitable reactants are listed and examples describe diesel fuel compositions comprising additives obtained by reacting carbon dioxide, barium hydroxide and C 8-10 alkyl phenols with (I) polyisobutylene sulphonic acid and oleyl alcohol; and with phosphosulphurized polyisobutylene in the presence of (II) oleyl alcohol, (III-V) oleic and monoethanolamine, and (VI) monoethanolamine oleate, and with the subsequent addition of (VII) neotridecanoic acid, naphthanoic acid, sorbitan mono-oleate, tall oil, tall oil acids, neodecanoic acid, lauric acid, C 20-22 fatty acids, oleylamine, oleic acid, triethanolamine oleate, monoethanolamine oleate, isopropanolamine oleate and butylamine oleate.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB06485/68A GB1225039A (en) | 1968-04-05 | 1968-04-05 | Fuel additives |
| DE19691914338 DE1914338A1 (en) | 1968-04-05 | 1969-03-21 | Fuel additive and method of making the same |
| NL6905133A NL6905133A (en) | 1968-04-05 | 1969-04-02 | |
| BE731022D BE731022A (en) | 1968-04-05 | 1969-04-03 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB06485/68A GB1225039A (en) | 1968-04-05 | 1968-04-05 | Fuel additives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1225039A true GB1225039A (en) | 1971-03-17 |
Family
ID=10078206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB06485/68A Expired GB1225039A (en) | 1968-04-05 | 1968-04-05 | Fuel additives |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE731022A (en) |
| DE (1) | DE1914338A1 (en) |
| GB (1) | GB1225039A (en) |
| NL (1) | NL6905133A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3857790A (en) * | 1971-05-27 | 1974-12-31 | Cooper & Co Ltd Edwin | Improvement in the preparation of overbased magnesium lubricant additives |
| US4137184A (en) * | 1976-12-16 | 1979-01-30 | Chevron Research Company | Overbased sulfonates |
| US6090759A (en) * | 1986-11-29 | 2000-07-18 | Lubrizol Adibis Holdings (Uk) Ltd. | Alkaline earth metal hydrocarbyl phenates, their sulphurized derivatives, their production and use thereof |
| US6090760A (en) * | 1986-11-29 | 2000-07-18 | Lubrizol Adibis Holdings (Uk) Ltd. | Sulphurized alkaline earth metal hydrocarbyl phenates, their production and use thereof |
| CN114369479A (en) * | 2022-03-22 | 2022-04-19 | 玉门祥天新能源产业发展有限公司 | Alcohol-based fuel for compression ignition type internal combustion engine and preparation method thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2708601C2 (en) * | 1977-02-28 | 1986-12-18 | Hübner Gummi- und Kunststoff GmbH, 3500 Kassel | Bracket for a corner mirror to be assigned to an armored vehicle |
| US5944858A (en) * | 1990-09-20 | 1999-08-31 | Ethyl Petroleum Additives, Ltd. | Hydrocarbonaceous fuel compositions and additives therefor |
| EP0482253A1 (en) * | 1990-10-23 | 1992-04-29 | Ethyl Petroleum Additives Limited | Environmentally friendly fuel compositions and additives therefor |
-
1968
- 1968-04-05 GB GB06485/68A patent/GB1225039A/en not_active Expired
-
1969
- 1969-03-21 DE DE19691914338 patent/DE1914338A1/en active Pending
- 1969-04-02 NL NL6905133A patent/NL6905133A/xx unknown
- 1969-04-03 BE BE731022D patent/BE731022A/xx unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3857790A (en) * | 1971-05-27 | 1974-12-31 | Cooper & Co Ltd Edwin | Improvement in the preparation of overbased magnesium lubricant additives |
| US4137184A (en) * | 1976-12-16 | 1979-01-30 | Chevron Research Company | Overbased sulfonates |
| US6090759A (en) * | 1986-11-29 | 2000-07-18 | Lubrizol Adibis Holdings (Uk) Ltd. | Alkaline earth metal hydrocarbyl phenates, their sulphurized derivatives, their production and use thereof |
| US6090760A (en) * | 1986-11-29 | 2000-07-18 | Lubrizol Adibis Holdings (Uk) Ltd. | Sulphurized alkaline earth metal hydrocarbyl phenates, their production and use thereof |
| CN114369479A (en) * | 2022-03-22 | 2022-04-19 | 玉门祥天新能源产业发展有限公司 | Alcohol-based fuel for compression ignition type internal combustion engine and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1914338A1 (en) | 1970-04-23 |
| NL6905133A (en) | 1969-10-07 |
| BE731022A (en) | 1969-10-03 |
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