GB1193249A - A process for improving the Dyeability of Polyester Filaments - Google Patents

A process for improving the Dyeability of Polyester Filaments

Info

Publication number
GB1193249A
GB1193249A GB295469A GB295469A GB1193249A GB 1193249 A GB1193249 A GB 1193249A GB 295469 A GB295469 A GB 295469A GB 295469 A GB295469 A GB 295469A GB 1193249 A GB1193249 A GB 1193249A
Authority
GB
United Kingdom
Prior art keywords
filaments
temperature
polyethylene terephthalate
isophthalate
dyeability
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB295469A
Inventor
Evan Franklin Evans
John Barry Nash
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1193249A publication Critical patent/GB1193249A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)

Abstract

1,193,249. Improving the dyeability of polyester fibres. E. I. DU PONT DE NEMOURS & CO. 17 Jan., 1969 [17 Jan., 1968], No. 2954/69. Heading B5B. The dyeability of polyester filaments is improved by sequentially: (a) drawing the amorphous filaments at a temperature below their " apparent minimum crystallization temperature "; (b) effecting limited crystallization of the filaments to increase their tenacity by heating them to a temperature above their apparent minimum crystallization temperature while allowing the filaments to relax no more than 45% of their drawn length; and (c) further crystallizing the filaments to dimensionally stabilize them with an annealing treatment by heating them under tension at a temperature higher than the temperature during relaxation and lower than the softening temperature of the filaments, with the proviso that during the further crystallization, if the filaments are stretched the extent of elongation does not exceed the extent that the filaments were allowed to relax in step (b). As an alternative to step (c) of Claim 1 the filaments may be further crystallized by exposing them to the vapour of a boiling chlorinated hydrocarbon which is a swelling agent for the filaments at the temperature of treatment. The amorphous filaments may be drawn at a temperature within the range 50‹ to 80‹ C., relaxed at a temperature within the range of 100‹ to 180‹ C. while allowing a relaxation of 5 to 45% of their drawn length, and annealed at a temperature of at least 185‹ C. The filaments may be held at constant length and at a temperature within the range of 200‹ to 230‹ C. during the annealing step (c). The polyester filaments may consist of polyethylene terephthalate, poly (p-hexahydroxylylene terephthalate), poly (diphenylolpropane isophthalate), a polyethylene naphthalene dicarboxylate, polyethylene terephthalate/hexahydroterephthalate of which at least 85 mole per cent is polyethylene terephthalate, polyethylene terephthalate/5 - (sodium sulpho) - isophthalate of which at least 95 mole per cent is polyethylene terephthalate, and polyethylene terephthalate/ isophthalate of which at least 85 mole per cent is polyethylene terephthalate.
GB295469A 1968-01-17 1969-01-17 A process for improving the Dyeability of Polyester Filaments Expired GB1193249A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US69862168A 1968-01-17 1968-01-17

Publications (1)

Publication Number Publication Date
GB1193249A true GB1193249A (en) 1970-05-28

Family

ID=24806005

Family Applications (1)

Application Number Title Priority Date Filing Date
GB295469A Expired GB1193249A (en) 1968-01-17 1969-01-17 A process for improving the Dyeability of Polyester Filaments

Country Status (3)

Country Link
FR (1) FR2000335A1 (en)
GB (1) GB1193249A (en)
NL (1) NL6900836A (en)

Also Published As

Publication number Publication date
NL6900836A (en) 1969-07-21
FR2000335A1 (en) 1969-09-05

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Legal Events

Date Code Title Description
CSNS Application of which complete specification have been accepted and published, but patent is not sealed