GB1189682A - Organic Amalgams - Google Patents
Organic AmalgamsInfo
- Publication number
- GB1189682A GB1189682A GB1752967A GB1752967A GB1189682A GB 1189682 A GB1189682 A GB 1189682A GB 1752967 A GB1752967 A GB 1752967A GB 1752967 A GB1752967 A GB 1752967A GB 1189682 A GB1189682 A GB 1189682A
- Authority
- GB
- United Kingdom
- Prior art keywords
- onium
- amalgams
- radical
- organic
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000497 Amalgam Inorganic materials 0.000 title abstract 6
- 150000003839 salts Chemical class 0.000 abstract 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052753 mercury Inorganic materials 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- -1 tetrafluoroborate Chemical compound 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/103—Mercury compounds without C-Mercury linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,189,682. Organic " onium " amalgams. IMPERIAL CHEMICAL INDUSTRIES Ltd. 19 Jan., 1968, No. 476/68. Divided out of 1,189,681. Heading C2C. [Also in Division C7] " Onium " amalgams, which are amalgams of the quaternary ammonium radical R 4 N<SP>+</SP>, the quaternary phosphonium radical R 4 P<SP>+</SP> or the ternary sulphonium radical R 3 S<SP>+</SP>, where R is an organic group, may be prepared by reducing a solution of the corresponding " onium " salt at a mercury surface in a substantially inert polar aprotic medium. The radicals R are preferably alkyl radicals, or " onium " amalgams may be prepared from " onium " salts having two or more atoms of the non-metallic element linked by a difunctional hydrocarbon group. Anions which may be incorporated in the " onium " salt starting material include p-toluene sulphonate, tetrafluoroborate, C1-, Br-, I- and bicarbonate, and the reduction is preferably effected in the absence of air at - 30‹ to +10‹ C. either by electrolysis at a mercury cathode or by reaction with an alkali metal amalgam.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US700720A US3534078A (en) | 1967-02-07 | 1968-01-26 | Onium amalgams |
| BE710349D BE710349A (en) | 1967-02-07 | 1968-02-05 | |
| FR1565481D FR1565481A (en) | 1967-02-07 | 1968-02-07 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB47668 | 1967-02-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1189682A true GB1189682A (en) | 1970-04-29 |
Family
ID=9705027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1752967A Expired GB1189682A (en) | 1967-02-07 | 1967-02-07 | Organic Amalgams |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1189682A (en) |
-
1967
- 1967-02-07 GB GB1752967A patent/GB1189682A/en not_active Expired
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |