GB933430A - Process for the prepaartion of group ó¾ metals of the periodic system - Google Patents

Process for the prepaartion of group ó¾ metals of the periodic system

Info

Publication number
GB933430A
GB933430A GB2133862A GB2133862A GB933430A GB 933430 A GB933430 A GB 933430A GB 2133862 A GB2133862 A GB 2133862A GB 2133862 A GB2133862 A GB 2133862A GB 933430 A GB933430 A GB 933430A
Authority
GB
United Kingdom
Prior art keywords
indium
cathode
metal
pure
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2133862A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Schuckertwerke AG
Siemens AG
Original Assignee
Siemens Schuckertwerke AG
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Schuckertwerke AG, Siemens AG filed Critical Siemens Schuckertwerke AG
Publication of GB933430A publication Critical patent/GB933430A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/34Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/22Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

933,430. Making pure indium and gallium, electrolytically. SIEMENS - SCHUCKERTWERKE A.G. June 1, 1962 [June 13, 1961], No. 21338/62. Class 41. Pure gallium and indium are prepared electrolytically using as electrolyte a compound of general formula [Al 2 R 6 X]M, where R is an alkyl radical, X is halogen, and M is alkali metal, ammonium, or preferably a tetra-alkyl N group. The impure Ga or In metal is used as anode and pure metal, e.g. as foil as cathode. In examples, [Al 2 Et 6 Cl]N(CH 3 ) 4 or the equivalent isobutyl compound is heated at 120‹ C., with indium of 99.95% purity as an anode enclosed in a fine-pored linen bag, and 99.999% indium as cathode. Electrolysis is effected at 2 to 5V and C.D. of 1.3A. sq. dm. for several days. The electrolyte is siphoned off and the metal deposit on the cathode after washing in hot benzene, is re-melted under liquid paraffin.
GB2133862A 1961-06-13 1962-06-01 Process for the prepaartion of group ó¾ metals of the periodic system Expired GB933430A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DES74309A DE1170658B (en) 1961-06-13 1961-06-13 Process for the fine cleaning of gallium, indium and thallium by electrolytic refining

Publications (1)

Publication Number Publication Date
GB933430A true GB933430A (en) 1963-08-08

Family

ID=7504557

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2133862A Expired GB933430A (en) 1961-06-13 1962-06-01 Process for the prepaartion of group ó¾ metals of the periodic system

Country Status (6)

Country Link
BE (1) BE618864A (en)
CH (1) CH415073A (en)
DE (1) DE1170658B (en)
FR (1) FR1374976A (en)
GB (1) GB933430A (en)
SE (1) SE303200B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10309022B2 (en) * 2011-08-10 2019-06-04 Sumitomo Electric Industries, Ltd. Element recovery method and element recovery apparatus

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54111100A (en) * 1978-02-20 1979-08-31 Nihon Mediphysics Co Ltd Method of making thallium target for irradiation in cyclotron

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10309022B2 (en) * 2011-08-10 2019-06-04 Sumitomo Electric Industries, Ltd. Element recovery method and element recovery apparatus

Also Published As

Publication number Publication date
BE618864A (en) 1962-12-14
FR1374976A (en) 1964-10-16
SE303200B (en) 1968-08-19
DE1170658B (en) 1964-05-21
CH415073A (en) 1966-06-15

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