GB1139507A - Preparation of peracids - Google Patents

Preparation of peracids

Info

Publication number
GB1139507A
GB1139507A GB1644665A GB1644665A GB1139507A GB 1139507 A GB1139507 A GB 1139507A GB 1644665 A GB1644665 A GB 1644665A GB 1644665 A GB1644665 A GB 1644665A GB 1139507 A GB1139507 A GB 1139507A
Authority
GB
United Kingdom
Prior art keywords
hydrogen peroxide
liquid
mono
peracids
miscible
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1644665A
Inventor
Edwin George Edward Hawkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB1644665A priority Critical patent/GB1139507A/en
Publication of GB1139507A publication Critical patent/GB1139507A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00Peroxy compounds
    • C07C409/24Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00Preparation of peroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00Peroxy compounds
    • C07C409/24Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
    • C07C409/30Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids a >C=O group being bound to a carbon atom of a six-membered aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrrole Compounds (AREA)

Abstract

1,139,507. Peracids. DISTILLERS CO. Ltd. 9 May, 1966 [20 April, 1965], No. 16446/65. Heading C2C. Mono-percarboxylic acids are prepared by reacting hydrogen peroxide with the anhydride of a dicarboxylic acid in the presence of a liquid which is miscible with hydrogen peroxide and which has a dielectric constant greater than 20, provided that said liquid does not comprise solely water or sulphuric acid. It is preferred to use substantially inert organic liquids, e.g. N,N-dialkyl formamides, N-alkyl pyrrolidones and formic acid. The reaction mixture may also include a high dielectric liquid which is not miscible with hydrogen peroxide, e.g., nitromethane and nitrobenzene, or a low dielectric liquid, e.g. chloroform. It is preferred to use aqueous hydrogen peroxide having a concentration greater than 80% w./w. and to effect the reaction at a temperature below 50‹ C. Examples relate to the preparation of mono-peracids from maleic, phthalic and succinic anhydrides. The mono-peracid may be used to oxidize cyclohexanone to caprolactone.
GB1644665A 1965-04-20 1965-04-20 Preparation of peracids Expired GB1139507A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1644665A GB1139507A (en) 1965-04-20 1965-04-20 Preparation of peracids

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1644665A GB1139507A (en) 1965-04-20 1965-04-20 Preparation of peracids

Publications (1)

Publication Number Publication Date
GB1139507A true GB1139507A (en) 1969-01-08

Family

ID=10077469

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1644665A Expired GB1139507A (en) 1965-04-20 1965-04-20 Preparation of peracids

Country Status (1)

Country Link
GB (1) GB1139507A (en)

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