GB1133867A - Production of improved vinyl acetate copolymer emulsions - Google Patents
Production of improved vinyl acetate copolymer emulsionsInfo
- Publication number
- GB1133867A GB1133867A GB2355366A GB2355366A GB1133867A GB 1133867 A GB1133867 A GB 1133867A GB 2355366 A GB2355366 A GB 2355366A GB 2355366 A GB2355366 A GB 2355366A GB 1133867 A GB1133867 A GB 1133867A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl acetate
- emulsion
- catalyst
- water
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title abstract 8
- 229920001577 copolymer Polymers 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000004094 surface-active agent Substances 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- ISJNRPUVOCDJQF-UHFFFAOYSA-N (1-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)CC(C)(C)C(O)OC(=O)C(C)C ISJNRPUVOCDJQF-UHFFFAOYSA-N 0.000 abstract 1
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 abstract 1
- JCIIKRHCWVHVFF-UHFFFAOYSA-N 1,2,4-thiadiazol-5-amine;hydrochloride Chemical compound Cl.NC1=NC=NS1 JCIIKRHCWVHVFF-UHFFFAOYSA-N 0.000 abstract 1
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- 229920013683 Celanese Polymers 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- 229910010413 TiO 2 Inorganic materials 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 1
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 229940096826 phenylmercuric acetate Drugs 0.000 abstract 1
- -1 poly (ethyleneoxy) ethanol Chemical class 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46152965A | 1965-06-04 | 1965-06-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1133867A true GB1133867A (en) | 1968-11-20 |
Family
ID=23832926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2355366A Expired GB1133867A (en) | 1965-06-04 | 1966-05-26 | Production of improved vinyl acetate copolymer emulsions |
Country Status (7)
| Country | Link |
|---|---|
| AT (1) | AT274351B (en)) |
| BE (1) | BE671091A (en)) |
| CH (1) | CH471170A (en)) |
| DE (2) | DE1570390A1 (en)) |
| ES (1) | ES327334A1 (en)) |
| GB (1) | GB1133867A (en)) |
| NL (1) | NL6607727A (en)) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4267090A (en) | 1979-01-22 | 1981-05-12 | National Distillers And Chemical Corp. | Process for preparing vinyl acetate-ethylene copolymer latices |
| US4409355A (en) | 1980-03-10 | 1983-10-11 | National Distillers And Chemical Corporation | Process for preparing high solids copolymer latices with low viscosity |
| CN119101388A (zh) * | 2024-10-23 | 2024-12-10 | 山东米娅文化用品有限公司 | 一种水性丙烯绘画颜料及其制备方法 |
-
1965
- 1965-10-07 DE DE19651570390 patent/DE1570390A1/de active Pending
- 1965-10-19 BE BE671091D patent/BE671091A/xx unknown
-
1966
- 1966-05-26 GB GB2355366A patent/GB1133867A/en not_active Expired
- 1966-05-30 ES ES0327334A patent/ES327334A1/es not_active Expired
- 1966-06-01 DE DE19661595421 patent/DE1595421A1/de active Pending
- 1966-06-03 NL NL6607727A patent/NL6607727A/xx unknown
- 1966-06-03 CH CH804966A patent/CH471170A/fr not_active IP Right Cessation
- 1966-06-03 AT AT531866A patent/AT274351B/de active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4267090A (en) | 1979-01-22 | 1981-05-12 | National Distillers And Chemical Corp. | Process for preparing vinyl acetate-ethylene copolymer latices |
| US4409355A (en) | 1980-03-10 | 1983-10-11 | National Distillers And Chemical Corporation | Process for preparing high solids copolymer latices with low viscosity |
| CN119101388A (zh) * | 2024-10-23 | 2024-12-10 | 山东米娅文化用品有限公司 | 一种水性丙烯绘画颜料及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE671091A (en)) | 1966-02-14 |
| NL6607727A (en)) | 1966-12-05 |
| DE1570390A1 (de) | 1969-11-27 |
| ES327334A1 (es) | 1967-03-16 |
| CH471170A (fr) | 1969-04-15 |
| DE1595421A1 (de) | 1970-04-23 |
| AT274351B (de) | 1969-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1089597A (en) | Process for suspension polymerization of vinyl chloride employing mixed protective colloids | |
| EP0153728B1 (en) | A method for preparing a vinyl acetate/ethylene emulsion using two polyvinyl alcohols as a stabilising system and an adhesive composition comprising the emulsion | |
| EP0133899B1 (de) | Verfahren zur Herstellung wässriger Polymerdispersionen und ihre Verwendung | |
| GB1272171A (en) | Process for the preparation of an aqueous dispersion of a copolymer | |
| GB1524225A (en) | Polymerisation of ethylene-vinyl acetate | |
| GB1305481A (en)) | ||
| GB1182253A (en) | Improvements in or relating to Aqueous Compositions for Pigment Coating Permeable Substrates. | |
| SE7508653L (sv) | Ymppolymerkompositioner och forfarande for framstellning derav | |
| GB1133867A (en) | Production of improved vinyl acetate copolymer emulsions | |
| GB1239588A (en)) | ||
| GB1224693A (en) | Polymerisation of vinyl chloride | |
| GB932389A (en) | Improvements in or relating to polymer emulsions or dispersions | |
| US3741922A (en) | Aqueous latex paint thickening composition | |
| GB1144316A (en) | Improved emulsions of alkali-soluble copolymers | |
| GB1131177A (en) | Process for the production of vinyl chloride polymers | |
| US3060139A (en) | Stable polyvinyl alkanoate latexes containing hydroxyalkyl alkyl cellulose and process for preparing the same | |
| GB1465440A (en) | Aqueous emulsion adhesive | |
| GB1191649A (en) | Production of Vinyl Acetate Polymer and Copolymer Emulsions | |
| ES256984A1 (es) | Procedimiento de fabricaciën de pinturas en emulsiën tixotrëpica | |
| GB1340398A (en) | Stable vinyl acetate n-methylolacrylamide latexes with polyvinyl alcohol | |
| GB899382A (en) | Process for the production of copolymers of vinyl chloride and fumaric acid esters | |
| GB1276257A (en) | Novel emulsion adhesive compositions | |
| GB1113350A (en) | Process for the suspension polymerisation of vinyl chloride | |
| GB1229989A (en)) | ||
| JPS5645912A (en) | Vinyl acetate/ethylene copolymer emulsion |