GB1120242A - Preparation of formaldehyde - Google Patents
Preparation of formaldehydeInfo
- Publication number
- GB1120242A GB1120242A GB3273565A GB3273565A GB1120242A GB 1120242 A GB1120242 A GB 1120242A GB 3273565 A GB3273565 A GB 3273565A GB 3273565 A GB3273565 A GB 3273565A GB 1120242 A GB1120242 A GB 1120242A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methanol
- reaction
- gaseous
- superheated steam
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
An aqueous formaldehyde solution is produced by a process in which methanol is oxidized and dehydrated in the presence of a silver catalyst using steam and preheated air at a temperature of from 500 DEG to 600 DEG C. with incomplete reaction of the methanol, in which the resulting gaseous reaction mixture obtained in the reaction is cooled to a temperature of substantially 100 DEG C. with simultaneous production of superheated steam, and is washed with the condensate obtained by further cooling the gaseous mixture and with water, in which the resulting aqueous formaldehyde-methanol solution is distilled in vacuo using the heat obtained in the condensation step and contained in the superheated steam, and in which the gaseous methanol constituting the overhead effluent of the distillation stage is partly recycled into the distillation stage with the addition of the methanol used for the reaction and partly returned in gaseous form to the methanol oxidation stage after having been compressed to the pressure used in the latter stage, the compression being carried out with the aid of a steam turbine which is operated with the superheated steam obtained in cooling the reaction gases.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF43636A DE1221621B (en) | 1964-08-01 | 1964-08-01 | Process for the production of aqueous formaldehyde solutions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1120242A true GB1120242A (en) | 1968-07-17 |
Family
ID=7099661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3273565A Expired GB1120242A (en) | 1964-08-01 | 1965-07-30 | Preparation of formaldehyde |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE666935A (en) |
DE (1) | DE1221621B (en) |
GB (1) | GB1120242A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4450301A (en) * | 1982-10-21 | 1984-05-22 | Celanese Corporation | Process for converting methanol to formaldehyde |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE615885C (en) * | 1930-04-22 | 1935-07-15 | Merck Ag E | Process for the production of absolute alcohol from alcoholic mashes by simultaneous distillation, dewatering and purification |
DE1162822B (en) * | 1959-06-15 | 1964-02-13 | Koppers Gmbh Heinrich | Process for the production of pure benzene from mixtures containing n-heptane and cyclohexane by distillation |
-
1964
- 1964-08-01 DE DEF43636A patent/DE1221621B/en active Pending
-
1965
- 1965-07-15 BE BE666935D patent/BE666935A/xx unknown
- 1965-07-30 GB GB3273565A patent/GB1120242A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4450301A (en) * | 1982-10-21 | 1984-05-22 | Celanese Corporation | Process for converting methanol to formaldehyde |
Also Published As
Publication number | Publication date |
---|---|
BE666935A (en) | 1965-11-03 |
DE1221621B (en) | 1966-07-28 |
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