GB1108865A - Triazolyl stilbene derivatives - Google Patents
Triazolyl stilbene derivativesInfo
- Publication number
- GB1108865A GB1108865A GB42376/66A GB4237666A GB1108865A GB 1108865 A GB1108865 A GB 1108865A GB 42376/66 A GB42376/66 A GB 42376/66A GB 4237666 A GB4237666 A GB 4237666A GB 1108865 A GB1108865 A GB 1108865A
- Authority
- GB
- United Kingdom
- Prior art keywords
- agents
- washing
- brightening
- aminonaphthalene
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 Triazolyl stilbene derivatives Chemical class 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 7
- 238000005282 brightening Methods 0.000 abstract 5
- 150000003839 salts Chemical class 0.000 abstract 5
- 238000005406 washing Methods 0.000 abstract 5
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 abstract 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 4
- 229910052801 chlorine Inorganic materials 0.000 abstract 4
- 239000000460 chlorine Substances 0.000 abstract 4
- 230000008878 coupling Effects 0.000 abstract 3
- 238000010168 coupling process Methods 0.000 abstract 3
- 238000005859 coupling reaction Methods 0.000 abstract 3
- 239000003599 detergent Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 2
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 125000001153 fluoro group Chemical group F* 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
- C07D249/22—Naphthotriazoles
- C07D249/24—Naphthotriazoles with stilbene radicals directly attached in position 2
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/657—Optical bleaching or brightening combined with other treatments, e.g. finishing, bleaching, softening, dyeing or pigment printing
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Photoreceptors In Electrophotography (AREA)
Abstract
o-Aminoazo dyestuffs of the stilbene series are obtained by coupling, suitably in aqueous pyridine solution, diazotized 4-amino-31-chloro (or fluoro)-stilbene-2-sulphonic acid with 2-amino-naphthalene or 2-aminonaphthalene sulphonated in the 1-position. The dyes are oxidized to naphtho triazole stilbene derivatives (see Division C2). Washing agents, washing liquors and detergents contain brightening agents of formula <FORM:1108865/C4-C5/1> wherein X is F or Cl or a salt thereof. The washing liquor may contain ionogenic washing agents and also agents which give off chlorine, i.e. bleaching agents and many are specified. Fillers, auxiliaries and foam stabilizators that may be present are also specified. In brightening detergents the brightening agents are suitably incorporated as solutions in neutral, water miscible and/or easily volatile organic solvents but may be admixed in finely divided form with or without dispersing agents. Reference has been directed by the Comptroller to Specification 717,889.ALSO:The invention comprises stilbene derivatives of formula <FORM:1108865/C2/1> wherein X is F or Cl and salts thereof. They are prepared by oxidation of the o-aminoazo dyestuff obtained by coupling a diazotized 4-amino-31 - halogenostilbene - 2 - sulphonic acid with either 2-aminonaphthalene or 2-aminonaphthalene sulphonated in the 1-position and optionally forming a salt of the product. The coupling is preferably carried out in aqueous pyridine solution and the oxidation may be effected with air in the presence of Cu-(II) salts. The compounds may be used as brightening agents (see Divisions C5 and D1). Reference has been directed by the Comptroller to Specification 717,889.ALSO:Fibres and fabrics of cellulose or synthetic polyamides e.g cotton and nylon are brightened by treatment with compounds of formula:- <FORM:1108865/D1-D2/1> wherein X is F or Cl or a salt thereof. The brightening agents may be used as additives in washing and detergent compositions. 717,889.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1314965A CH449570A (en) | 1965-09-23 | 1965-09-23 | Process for the optical brightening of textile fibers made of cellulose or synthetic polyamide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1108865A true GB1108865A (en) | 1968-04-03 |
Family
ID=4389752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB42376/66A Expired GB1108865A (en) | 1965-09-23 | 1966-09-22 | Triazolyl stilbene derivatives |
Country Status (8)
| Country | Link |
|---|---|
| AT (1) | AT263002B (en) |
| BE (1) | BE687232A (en) |
| CH (1) | CH449570A (en) |
| DE (1) | DE1695089B2 (en) |
| ES (1) | ES331514A1 (en) |
| FR (1) | FR1494442A (en) |
| GB (1) | GB1108865A (en) |
| SE (1) | SE321481B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012160382A1 (en) | 2011-05-26 | 2012-11-29 | The Centre For Process Innovation Ltd | Semiconductor compounds |
-
1965
- 1965-09-23 CH CH1314965A patent/CH449570A/en unknown
-
1966
- 1966-09-22 SE SE12758/66A patent/SE321481B/xx unknown
- 1966-09-22 ES ES0331514A patent/ES331514A1/en not_active Expired
- 1966-09-22 AT AT890766A patent/AT263002B/en active
- 1966-09-22 FR FR77290A patent/FR1494442A/en not_active Expired
- 1966-09-22 BE BE687232D patent/BE687232A/xx unknown
- 1966-09-22 GB GB42376/66A patent/GB1108865A/en not_active Expired
- 1966-09-22 DE DE1966G0047957 patent/DE1695089B2/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012160382A1 (en) | 2011-05-26 | 2012-11-29 | The Centre For Process Innovation Ltd | Semiconductor compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| SE321481B (en) | 1970-03-09 |
| ES331514A1 (en) | 1967-07-01 |
| BE687232A (en) | 1967-03-22 |
| CH1314965A4 (en) | 1967-09-30 |
| DE1695089B2 (en) | 1977-02-03 |
| DE1695089A1 (en) | 1970-12-10 |
| AT263002B (en) | 1968-07-10 |
| CH449570A (en) | 1968-04-11 |
| FR1494442A (en) | 1967-09-08 |
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