GB1108210A - Process for the hydrogenative cracking of a hydrocarbon oil - Google Patents

Process for the hydrogenative cracking of a hydrocarbon oil

Info

Publication number
GB1108210A
GB1108210A GB5793866A GB5793866A GB1108210A GB 1108210 A GB1108210 A GB 1108210A GB 5793866 A GB5793866 A GB 5793866A GB 5793866 A GB5793866 A GB 5793866A GB 1108210 A GB1108210 A GB 1108210A
Authority
GB
United Kingdom
Prior art keywords
support
catalyst
metal
fluorine
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5793866A
Inventor
Ross Edwin Van Dyke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1108210A publication Critical patent/GB1108210A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/14—Inorganic carriers the catalyst containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Hydrocarbon oils are cracked by contacting an oil containing less than 200 m. moles aromatics per 100 g. of oil in the presence of hydrogen at elevated temperature and pressure with a catalyst comprising fluorine and at least one metal of the iron group of the Periodic Table intimately associated with an acid-acting support comprising at least one refractory oxide, the intimate association of the metal with the support having been achieved by contacting the support in hydrogel form with an aqueous solution of one or more soluble salts of said metal or metals, fluorine having been incorporated into the support while the support is in hydrogel form, and the catalyst having been washed, dried, calcined and activated with hydrogen at 480-650 DEG C. The catalyst preferably contains 0.1-5% by wt. fluorine and 0.1-15% by wt. iron group metal, e.g. nickel. It may also contain tungsten and/or molybdenum in amount 0.1-5% by wt. based on the total catalyst. The support may comprise 40-90% SiO2 and 60-10% Al2O3, MgO, ZrO2, B2O3 and/o TiO2 by wt. Hydrocracking may take place at 260-400 DEG C., a hydrogen partial pressure of 52.5-140 atmospheres absolute and a L.H.S.V. of 0.1-5 vols. of oil per hour per vol. of catalyst.
GB5793866A 1965-12-29 1966-12-28 Process for the hydrogenative cracking of a hydrocarbon oil Expired GB1108210A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US51747765A 1965-12-29 1965-12-29

Publications (1)

Publication Number Publication Date
GB1108210A true GB1108210A (en) 1968-04-03

Family

ID=24059974

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5793866A Expired GB1108210A (en) 1965-12-29 1966-12-28 Process for the hydrogenative cracking of a hydrocarbon oil

Country Status (4)

Country Link
DE (1) DE1545389A1 (en)
FR (1) FR1506791A (en)
GB (1) GB1108210A (en)
NL (1) NL6618233A (en)

Also Published As

Publication number Publication date
NL6618233A (en) 1967-06-30
DE1545389A1 (en) 1969-08-28
FR1506791A (en) 1967-12-22

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