GB1107320A - Epoxidation of olefinically unsaturated compounds - Google Patents

Epoxidation of olefinically unsaturated compounds

Info

Publication number
GB1107320A
GB1107320A GB4592367A GB4592367A GB1107320A GB 1107320 A GB1107320 A GB 1107320A GB 4592367 A GB4592367 A GB 4592367A GB 4592367 A GB4592367 A GB 4592367A GB 1107320 A GB1107320 A GB 1107320A
Authority
GB
United Kingdom
Prior art keywords
olefinically unsaturated
epoxidation
vanadium
unsaturated compounds
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4592367A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon International Inc
Original Assignee
Halcon International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halcon International Inc filed Critical Halcon International Inc
Publication of GB1107320A publication Critical patent/GB1107320A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)

Abstract

An epoxy compound is obtained by contacting an olefinically unsaturated compound having from 2 to 4 carbon atoms in the olefinically unsaturated aliphatic chain with an organic hydroperoxide in the liquid phase in the presence of a catalytic amount of a vanadium catalyst added in the form of an inorganic compound of vanadium. The reaction is suitably effected at -20 to 200 DEG C. and a solvent may be present. In an example propylene is oxidized to propylene oxide with tertiary butyl hydroperoxide in the presence of vanadium pentoxide.
GB4592367A 1964-05-08 1965-05-04 Epoxidation of olefinically unsaturated compounds Expired GB1107320A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US36617064A 1964-05-08 1964-05-08

Publications (1)

Publication Number Publication Date
GB1107320A true GB1107320A (en) 1968-03-27

Family

ID=23441937

Family Applications (2)

Application Number Title Priority Date Filing Date
GB1875465A Expired GB1104821A (en) 1964-05-08 1965-05-04 Epoxidation of olefinically unsaturated compounds
GB4592367A Expired GB1107320A (en) 1964-05-08 1965-05-04 Epoxidation of olefinically unsaturated compounds

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB1875465A Expired GB1104821A (en) 1964-05-08 1965-05-04 Epoxidation of olefinically unsaturated compounds

Country Status (10)

Country Link
BE (1) BE663452A (en)
CH (1) CH426756A (en)
DE (1) DE1300919B (en)
DK (1) DK129930B (en)
ES (1) ES312742A1 (en)
GB (2) GB1104821A (en)
LU (1) LU48529A1 (en)
NL (1) NL148604B (en)
NO (1) NO121603B (en)
SE (1) SE342038B (en)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB682067A (en) * 1949-03-26 1952-11-05 Distillers Co Yeast Ltd Manufacture of 1,2-epoxy-2,4,4-trimethylpentane
DE942088C (en) * 1952-03-13 1956-04-26 Distillers Co Yeast Ltd Process for the production of 2,3-epoxybutane
US2870171A (en) * 1956-05-21 1959-01-20 Shell Dev Epoxidation process
US3013024A (en) * 1958-08-29 1961-12-12 Shell Oil Co Epoxidation of carbonyl compounds with hydroperoxides
DE1158951B (en) * 1962-02-20 1963-12-12 Union Rheinische Braunkohlen Process for the production of glycerin

Also Published As

Publication number Publication date
GB1104821A (en) 1968-02-28
NL6505552A (en) 1965-11-09
DK129930B (en) 1974-12-02
DE1300919B (en) 1969-08-14
CH426756A (en) 1966-12-31
ES312742A1 (en) 1965-07-16
NO121603B (en) 1971-03-22
LU48529A1 (en) 1966-11-07
DK129930C (en) 1975-05-12
BE663452A (en) 1965-11-05
SE342038B (en) 1972-01-24
NL148604B (en) 1976-02-16

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