GB1221988A - Oxidation process - Google Patents

Oxidation process

Info

Publication number
GB1221988A
GB1221988A GB3727668A GB3727668A GB1221988A GB 1221988 A GB1221988 A GB 1221988A GB 3727668 A GB3727668 A GB 3727668A GB 3727668 A GB3727668 A GB 3727668A GB 1221988 A GB1221988 A GB 1221988A
Authority
GB
United Kingdom
Prior art keywords
oxidation
vanadium
vanadate
catalyst
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3727668A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Progil SARL
Original Assignee
Progil SARL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Progil SARL filed Critical Progil SARL
Publication of GB1221988A publication Critical patent/GB1221988A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/005—Compounds of elements of Group 5 of the Periodic System without metal-carbon linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium

Abstract

1,221,988. Oxidation in the presence of a vanadium catalyst. PROGIL. 5 Aug., 1968 [3 Aug., 1967], No. 37276/68. Heading C2C. A process for the oxidation of an organic compound, capable of oxidation in the presence of a vanadium catalyst, comprises oxidizing the organic compound with a per-acid or organic hydroperoxide in the liquid phase in the presence, as catalyst of an alkyl vanadate of the formula (R) 3 VO 4 in which R is an alkyl radical preferably having 1 to 12 carbon atoms and may be present as the reaction product of vanadium pentoxide and an excess of aliphatic alcohol. The alkyl vanadate may be present in an amount of 0À01 to 5% by weight calculated as vanadium, based on the weight of the reaction mixture. In examples n-propyl vanadate is prepared from V 2 O 5 and n-propanol and used in the production of glycidol from allyl alcohol.
GB3727668A 1967-08-03 1968-08-05 Oxidation process Expired GB1221988A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR69049011A FR1539209A (en) 1967-08-03 1967-08-03 New oxidation catalyst

Publications (1)

Publication Number Publication Date
GB1221988A true GB1221988A (en) 1971-02-10

Family

ID=9694792

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3727668A Expired GB1221988A (en) 1967-08-03 1968-08-05 Oxidation process

Country Status (6)

Country Link
JP (1) JPS5338273B1 (en)
AT (1) AT281867B (en)
BE (1) BE719023A (en)
FR (1) FR1539209A (en)
GB (1) GB1221988A (en)
NL (1) NL6810555A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5595023U (en) * 1978-12-19 1980-07-01
JPH07248106A (en) * 1994-03-11 1995-09-26 Matsuoka Yoko Kk Incinerator
JP2001106680A (en) * 1999-10-04 2001-04-17 Nof Corp Method for producing glycidol

Also Published As

Publication number Publication date
JPS5338273B1 (en) 1978-10-14
BE719023A (en) 1969-01-16
DE1793112A1 (en) 1972-04-13
NL6810555A (en) 1969-02-05
FR1539209A (en) 1968-09-13
DE1793112B2 (en) 1973-02-01
AT281867B (en) 1970-06-10

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Legal Events

Date Code Title Description
414F Notice of opposition given (sect. 14/1949)
414A Case decided by the comptroller ** specification amended (sect. 14/1949)
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee