GB1089745A - New sultone condensation compounds and their use as brighteners for electrolytic baths - Google Patents
New sultone condensation compounds and their use as brighteners for electrolytic bathsInfo
- Publication number
- GB1089745A GB1089745A GB17297/65A GB1729765A GB1089745A GB 1089745 A GB1089745 A GB 1089745A GB 17297/65 A GB17297/65 A GB 17297/65A GB 1729765 A GB1729765 A GB 1729765A GB 1089745 A GB1089745 A GB 1089745A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nickel
- acetylenically unsaturated
- glycol
- butyne
- sultone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 230000005494 condensation Effects 0.000 title abstract 2
- 238000009833 condensation Methods 0.000 title abstract 2
- 150000008053 sultones Chemical class 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- KDKYADYSIPSCCQ-UHFFFAOYSA-N but-1-yne Chemical compound CCC#C KDKYADYSIPSCCQ-UHFFFAOYSA-N 0.000 abstract 4
- 150000002334 glycols Chemical class 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- -1 bishydroxyethyl ether butyne diol Chemical class 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000007859 condensation product Substances 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 2
- 238000007747 plating Methods 0.000 abstract 2
- FZWBGUCUIVJVNZ-UHFFFAOYSA-N C(C#CC)(O)O.OC(COCC(O)O)O Chemical compound C(C#CC)(O)O.OC(COCC(O)O)O FZWBGUCUIVJVNZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 abstract 1
- HJSXWIZOWRQPPY-UHFFFAOYSA-N O=S=O.O=S=O.[Ni+2] Chemical compound O=S=O.O=S=O.[Ni+2] HJSXWIZOWRQPPY-UHFFFAOYSA-N 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 abstract 1
- 229940081974 saccharin Drugs 0.000 abstract 1
- 235000019204 saccharin Nutrition 0.000 abstract 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/24—Polysulfonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
- C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
- C25D3/16—Acetylenic compounds
Abstract
An electrolytic bath, suitably a nickel-plating bath, comprises, per litre of electrolyte, from 0.05 to 2 g. of at least one condensation compound of naphtho-1,8-seltone with an acetylenically unsaturated glycol or an etherified derivative of such a glycol containing at least one hydroxyl group. The electrolyte may comprise nickel sulphate, nickel sulphanate or nickel fluoborate, nickel chloride, boric acid, a stabilizer such as saccharin, paratoluene sulphonamide, hetamine or cyanuric acid, a levelling agent, a voltage lowering agent such as lauryl sulphate, and said condensation product. Specified acetylenically unsaturated glycols are butyne diole and bishydroxyethyl ether butyne diol. Typically the nickel-plating baths are used at pH 3 to 5.5 and a temperature of from 20 to 70 DEG C. with a current density of from 2 to 15 amps/dm2.ALSO:A condensation product of naphtho-1,8-sultone with an acetylenically unsaturated glycol or an etherified derivative of such a glycol containing at least one hydroxyl group may be obtained by reacting the two components together in substantially stoichiometric proportions by heating at 80 DEG C. and then cooling. Preferred acetylenically unsaturated glycols are butyne diol and bis-hydroxyethyl ether butyne diol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR990781A FR1418245A (en) | 1964-10-08 | 1964-10-08 | New brightening agents for galvanic baths, in particular for nickel plating baths |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1089745A true GB1089745A (en) | 1967-11-08 |
Family
ID=8839949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17297/65A Expired GB1089745A (en) | 1964-10-08 | 1965-04-23 | New sultone condensation compounds and their use as brighteners for electrolytic baths |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3457146A (en) |
| BE (1) | BE662877A (en) |
| DE (1) | DE1232799B (en) |
| FR (1) | FR1418245A (en) |
| GB (1) | GB1089745A (en) |
| IL (1) | IL23689A (en) |
| NL (1) | NL6504674A (en) |
| SE (1) | SE305787B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4046647A (en) * | 1976-06-17 | 1977-09-06 | M&T Chemicals Inc. | Additive for improved electroplating process |
| US20050249968A1 (en) * | 2004-05-04 | 2005-11-10 | Enthone Inc. | Whisker inhibition in tin surfaces of electronic components |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2469727A (en) * | 1944-03-30 | 1949-05-10 | Du Pont | Electrodeposition of nickel |
| NL205377A (en) * | 1955-03-16 |
-
1964
- 1964-10-08 FR FR990781A patent/FR1418245A/en not_active Expired
-
1965
- 1965-01-12 DE DEP35856A patent/DE1232799B/en active Pending
- 1965-04-13 NL NL6504674A patent/NL6504674A/xx unknown
- 1965-04-22 BE BE662877D patent/BE662877A/xx unknown
- 1965-04-23 GB GB17297/65A patent/GB1089745A/en not_active Expired
- 1965-04-23 SE SE5313/65A patent/SE305787B/xx unknown
- 1965-06-08 IL IL23689A patent/IL23689A/en unknown
- 1965-10-01 US US500462A patent/US3457146A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US3457146A (en) | 1969-07-22 |
| NL6504674A (en) | 1966-04-12 |
| IL23689A (en) | 1969-01-29 |
| FR1418245A (en) | 1965-11-19 |
| DE1232799B (en) | 1967-01-19 |
| BE662877A (en) | 1965-10-22 |
| SE305787B (en) | 1968-11-04 |
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