GB1083184A - Improvements in and relating to coating compositions - Google Patents
Improvements in and relating to coating compositionsInfo
- Publication number
- GB1083184A GB1083184A GB975264A GB975264A GB1083184A GB 1083184 A GB1083184 A GB 1083184A GB 975264 A GB975264 A GB 975264A GB 975264 A GB975264 A GB 975264A GB 1083184 A GB1083184 A GB 1083184A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- acrylic
- monomers
- methacrylic
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
Coating compositions are made by mixing hexamethoxymethyl-melamine with a solution, in a solution of a base, of a copolymer made by copolymerizing an acrylic or methacrylic ester, an unsaturated carboxylic acid and a further monomer different therefrom in an amount of up to 50% of the total monomers in the presence of an aqueous solution or dispersion of an alkali-soluble copolymer of an acrylic or methacrylic ester. Monomers specified for copolymerization with the ester and acid are styrene and its derivatives, vinyl acetate, butadiene, isoprene, hydroxyethyl acrylate, ethoxyethyl methacrylate, acrylamide, methacrylamide, methylol acrylamide and acrylonitrile. The examples describe making coating compositions by the aqueous emulsion copolymerization of methyl acrylate, styrene and methacrylic acid in the presence of sodium lauryl sulphate, a mercaptan and sodium and potassium persulphates, with gradual addition of monomers as the reaction proceeds, followed by the copolymerization in the resulting copolymer dispersion of differently proportioned mixtures of the same monomers. The copolymers are then dissolved in ammonia and titanium dioxide and hexamethoxymethyl melamine are added thereto. The compositions are applied to metal surfaces and then stoved.ALSO:Mild steel panels and chromated aluminium foil are coated by applying thereto a mixture of hexamethoxymethyl melamine and a basic solution of a copolymer prepared by copolymerising an acrylic or methacrylic ester, an unsaturated carboxylic acid and another monomer in an aqueous solution or dispersion of an alkali-soluble copolymer of an acrylic or methacrylic ester (see Division C3). The Examples describe the use in coating of ammonia-solutions of copolymer mixtures derived from methyl acrylate, stepene and methacrylic acids, the solutions containing titanium dioxide and hexamethoxymethyl melamine. After application to the metal surfaces, the compositions are stored.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB975264A GB1083184A (en) | 1961-08-23 | 1964-03-07 | Improvements in and relating to coating compositions |
FR8042A FR87480E (en) | 1961-08-23 | 1965-03-05 | Improvements in the manufacture of copolymers, in particular acrylic copolymers |
DE19651519105 DE1519105A1 (en) | 1964-03-07 | 1965-03-05 | Coating compounds and processes for their production |
NL6502810A NL6502810A (en) | 1961-08-23 | 1965-03-05 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB30346/61A GB1003318A (en) | 1961-08-23 | 1961-08-23 | Improvements in the manufacture of copolymers |
GB975264A GB1083184A (en) | 1961-08-23 | 1964-03-07 | Improvements in and relating to coating compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1083184A true GB1083184A (en) | 1967-09-13 |
Family
ID=26243146
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB975264A Expired GB1083184A (en) | 1961-08-23 | 1964-03-07 | Improvements in and relating to coating compositions |
Country Status (3)
Country | Link |
---|---|
FR (1) | FR87480E (en) |
GB (1) | GB1083184A (en) |
NL (1) | NL6502810A (en) |
-
1964
- 1964-03-07 GB GB975264A patent/GB1083184A/en not_active Expired
-
1965
- 1965-03-05 FR FR8042A patent/FR87480E/en not_active Expired
- 1965-03-05 NL NL6502810A patent/NL6502810A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
FR87480E (en) | 1966-05-06 |
NL6502810A (en) | 1965-09-08 |
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