GB1363432A - Coating compositions - Google Patents

Coating compositions

Info

Publication number
GB1363432A
GB1363432A GB5607170A GB5607170A GB1363432A GB 1363432 A GB1363432 A GB 1363432A GB 5607170 A GB5607170 A GB 5607170A GB 5607170 A GB5607170 A GB 5607170A GB 1363432 A GB1363432 A GB 1363432A
Authority
GB
United Kingdom
Prior art keywords
weight
monomers
mixture
acid
dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5607170A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB5607170A priority Critical patent/GB1363432A/en
Priority to ZA717666A priority patent/ZA717666B/en
Priority to DE19712158038 priority patent/DE2158038A1/en
Priority to AU36114/71A priority patent/AU460881B2/en
Priority to FR7142055A priority patent/FR2115991A5/fr
Priority to IT197131610A priority patent/IT941320B/en
Priority to CA128,607A priority patent/CA964390A/en
Publication of GB1363432A publication Critical patent/GB1363432A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
    • C08F263/02—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids

Abstract

1363432 Vinyl ester copolymer compositions IMPERIAL CHEMICAL INDUSTRIES Ltd 17 Nov 1971 [25 Nov 1970] 56071/70 Heading C3P An aqueous dispersion of a random copolymer of monomers (a) 50 to 95% by weight of a vinyl ester of a saturated C 1 -C 18 aliphatic monocarboxylic acid, e.g. vinyl acetate, (b) 5 to 45% by weight of a C 2 -C 12 alkyl ester of acrylic or methacrylic acid (e.g. ethyl, butyl or 2 ethyl hexyl acrylate and (c) 0À5 to 8% by weight of a glycidyl ester of a monocarboxylic ethylenically unsaturated acid (e.g. glycidyl acrylate or methacrylate), the weight per cent of monomers being based on the total weight of monomers used, is prepared by the emulsion polymerization of not more than 10% by weight (based on total monomer weight) of monomer (a) or a mixture of monomers (a) and (b) to form a primary dispersion which is further co-polymerized by emulsion polymerization with a mixture of the remaining monomers. Not more than 2% by weight of an ethylenically unsaturated carboxylic acid (e.g. acrylic acid) may also be present in the monomer mixture. Anionic surfactants and colloids, e.g. polyvinyl alcohol or hydroxyethyl cellulose may be present. The dispersions may be used as coating compositions. In the examples a seed dispersion of polyvinyl acetate is prepared to which is added simultaneously (a) a mixture of vinylacetate, 2-ethylhexylacrylate and glycidylmethacrylate to acrylic acid and (b) a mixture of water, ammonium nonyl phenol polyglycol ether sulphate, a condensate of ethylene oxide with nonyl phenol, ammonium persulphate and sodium tetraborate to give a dispersion of pH 5À5 of a polymer of 0À3 Á particle size. Also in comparative examples the glycidyl methacryl. ate was omitted or added after the other monomers. The product dispersions, adjusted to pH 8-9 with NH 3 and containing TiO 2 were applied to hardboard.
GB5607170A 1970-11-25 1970-11-25 Coating compositions Expired GB1363432A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
GB5607170A GB1363432A (en) 1970-11-25 1970-11-25 Coating compositions
ZA717666A ZA717666B (en) 1970-11-25 1971-11-15 Coating compositions
DE19712158038 DE2158038A1 (en) 1970-11-25 1971-11-23 Facing compositions
AU36114/71A AU460881B2 (en) 1970-11-25 1971-11-24 Coating compositions
FR7142055A FR2115991A5 (en) 1970-11-25 1971-11-24
IT197131610A IT941320B (en) 1970-11-25 1971-11-25 COMPOSITIONS FOR COVERINGS
CA128,607A CA964390A (en) 1970-11-25 1971-11-25 Process of preparing aqueous vinyl ester copolymer dispersions using a seed latex

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5607170A GB1363432A (en) 1970-11-25 1970-11-25 Coating compositions

Publications (1)

Publication Number Publication Date
GB1363432A true GB1363432A (en) 1974-08-14

Family

ID=10475643

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5607170A Expired GB1363432A (en) 1970-11-25 1970-11-25 Coating compositions

Country Status (7)

Country Link
AU (1) AU460881B2 (en)
CA (1) CA964390A (en)
DE (1) DE2158038A1 (en)
FR (1) FR2115991A5 (en)
GB (1) GB1363432A (en)
IT (1) IT941320B (en)
ZA (1) ZA717666B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4409355A (en) 1980-03-10 1983-10-11 National Distillers And Chemical Corporation Process for preparing high solids copolymer latices with low viscosity
WO2015155157A1 (en) * 2014-04-11 2015-10-15 Basf Se Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer
WO2015155085A1 (en) * 2014-04-11 2015-10-15 Basf Se Method for preparing an aqueous polymer dispersion
WO2015155159A1 (en) * 2014-04-11 2015-10-15 Basf Se Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer prepared in the presence of a starch derivative

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2918827A1 (en) * 1979-05-10 1980-11-20 Basf Ag COATING, IMPREGNATING AND BINDING AGENTS BASED ON AQUEOUS DISPERSIONS OF COPOLYMERISATS HAVING EPOXY GROUPS
CA1185033A (en) * 1980-03-10 1985-04-02 Manfred Heimberg Preparation of high solids copolymer latices with low viscosity
DE3820154A1 (en) * 1988-06-14 1989-12-21 Basf Ag AQUEOUS DISPERSIONS OF COPOLYMERISATES CONTAINING EPOXY GROUPS AND THEIR USE

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4409355A (en) 1980-03-10 1983-10-11 National Distillers And Chemical Corporation Process for preparing high solids copolymer latices with low viscosity
WO2015155157A1 (en) * 2014-04-11 2015-10-15 Basf Se Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer
WO2015155085A1 (en) * 2014-04-11 2015-10-15 Basf Se Method for preparing an aqueous polymer dispersion
WO2015155159A1 (en) * 2014-04-11 2015-10-15 Basf Se Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer prepared in the presence of a starch derivative
CN106460342A (en) * 2014-04-11 2017-02-22 巴斯夫欧洲公司 Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer
CN106459646A (en) * 2014-04-11 2017-02-22 巴斯夫欧洲公司 Aqueous polymer dispersion for paper with copolymer of vinyl acetate and acrylate monomer prepared in presence of starch derivative
US10167407B2 (en) 2014-04-11 2019-01-01 Basf Se Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer prepared in the presence of a starch derivative
US10414938B2 (en) 2014-04-11 2019-09-17 Basf Se Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer
US10544249B2 (en) 2014-04-11 2020-01-28 Basf Se Method for preparing an aqueous polymer dispersion
US10793740B2 (en) 2014-04-11 2020-10-06 Basf Se Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer prepared in the presence of a starch derivative

Also Published As

Publication number Publication date
ZA717666B (en) 1972-08-30
CA964390A (en) 1975-03-11
AU3611471A (en) 1973-05-31
FR2115991A5 (en) 1972-07-07
AU460881B2 (en) 1975-04-15
DE2158038A1 (en) 1972-07-06
IT941320B (en) 1973-03-01

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years