GB1077088A - Metallizing process - Google Patents
Metallizing processInfo
- Publication number
- GB1077088A GB1077088A GB5126964A GB5126964A GB1077088A GB 1077088 A GB1077088 A GB 1077088A GB 5126964 A GB5126964 A GB 5126964A GB 5126964 A GB5126964 A GB 5126964A GB 1077088 A GB1077088 A GB 1077088A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filler
- metal
- particles
- plating
- conductive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000000945 filler Substances 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 3
- 238000007747 plating Methods 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 239000002923 metal particle Substances 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000004033 plastic Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000000498 ball milling Methods 0.000 abstract 1
- 238000005422 blasting Methods 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000004020 conductor Substances 0.000 abstract 1
- 238000009713 electroplating Methods 0.000 abstract 1
- 238000005530 etching Methods 0.000 abstract 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 239000000123 paper Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000005060 rubber Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000010944 silver (metal) Substances 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
- C25D5/56—Electroplating of non-metallic surfaces of plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
Abstract
A metal layer is bonded to a non-metallic object by moulding a non-metallic composition having dispersed therein a filler consisting of metal particles, preferably filaments, e.g. of Cu, Ni, Zn or Ag, and friable non-metallic conductor particles, e.g. of graphite or other conductive carbon or conductive or semi-conductive metal salts, removing a surface of, e.g. by etching, vapour grit blasting or otherwise abrading, and metallizing, preferably electroplating, the moulded object. The process is particularly suitable for chromium or rhodium plating of resinous polymer plastic articles, but can be used for other nonmetallic compositions, e.g. paper, ceramics or rubber. Preferably the volume proportion of filler in the composition is 0.2 to 0.7 and of metal in the filler is between 0.01 and 0.7. The filler may be incorporated into a plastic matrix before or after polymerisating, being kneaded into the polymer particles by ball milling; for a thermosetting resin such as of melamine-formaldehyde, moulding may be effected at the curing temperature of the resin. An initial ductile base-plating of copper and/or soft nickel may be applied from fluoborate baths on to the surface of the moulded object, sufficiently etched e.g. with sodium hydroxide, aqua regia, sulphuric or nitric acid to expose dispersed metal particles, prior to chrome plating from a chromic acid bath.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US33285163A | 1963-12-23 | 1963-12-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1077088A true GB1077088A (en) | 1967-07-26 |
Family
ID=23300124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5126964A Expired GB1077088A (en) | 1963-12-23 | 1964-12-16 | Metallizing process |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE657424A (en) |
| GB (1) | GB1077088A (en) |
| NL (1) | NL6414908A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2825735A1 (en) * | 1977-06-10 | 1978-12-21 | Sumitomo Naugatuck | PROCESS FOR MANUFACTURING GALVANIC COATED PRODUCTS |
| DE19742867C1 (en) * | 1997-09-29 | 1998-12-24 | Raschig Gmbh | Thermosetting moulding material, used for direct electrostatic powder coating |
| DE19742865C1 (en) * | 1997-09-29 | 1998-12-24 | Raschig Gmbh | Thermosetting moulding material for direct electrophoretic coating |
| DE19742866C1 (en) * | 1997-09-29 | 1998-12-24 | Raschig Gmbh | Thermosetting moulding material, used for direct electroplating |
| ES2159477A1 (en) * | 1999-08-17 | 2001-10-01 | Montana Exposito Vicenta De | Metal coating of eg. sports shoes for decoration purposes consists of application of eg. gold by electrolysis after covering the shoe with a conductive metal and varnish mixture |
-
1964
- 1964-12-16 GB GB5126964A patent/GB1077088A/en not_active Expired
- 1964-12-21 BE BE657424A patent/BE657424A/xx unknown
- 1964-12-21 NL NL6414908A patent/NL6414908A/xx unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2825735A1 (en) * | 1977-06-10 | 1978-12-21 | Sumitomo Naugatuck | PROCESS FOR MANUFACTURING GALVANIC COATED PRODUCTS |
| DE19742867C1 (en) * | 1997-09-29 | 1998-12-24 | Raschig Gmbh | Thermosetting moulding material, used for direct electrostatic powder coating |
| DE19742865C1 (en) * | 1997-09-29 | 1998-12-24 | Raschig Gmbh | Thermosetting moulding material for direct electrophoretic coating |
| DE19742866C1 (en) * | 1997-09-29 | 1998-12-24 | Raschig Gmbh | Thermosetting moulding material, used for direct electroplating |
| ES2159477A1 (en) * | 1999-08-17 | 2001-10-01 | Montana Exposito Vicenta De | Metal coating of eg. sports shoes for decoration purposes consists of application of eg. gold by electrolysis after covering the shoe with a conductive metal and varnish mixture |
Also Published As
| Publication number | Publication date |
|---|---|
| BE657424A (en) | 1965-04-16 |
| NL6414908A (en) | 1965-06-24 |
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