GB1065547A - - Google Patents
Info
- Publication number
- GB1065547A GB1065547A GB1458764A GB1458764A GB1065547A GB 1065547 A GB1065547 A GB 1065547A GB 1458764 A GB1458764 A GB 1458764A GB 1458764 A GB1458764 A GB 1458764A GB 1065547 A GB1065547 A GB 1065547A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymerize
- containing compound
- acid derivative
- carbamic acid
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 phosphonium halide Chemical class 0.000 abstract 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 abstract 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 abstract 2
- 239000000835 fiber Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- NQPJDJVGBDHCAD-UHFFFAOYSA-N 1,3-diazinan-2-one Chemical compound OC1=NCCCN1 NQPJDJVGBDHCAD-UHFFFAOYSA-N 0.000 abstract 1
- JFFYKITVXPZLQS-UHFFFAOYSA-N 2-methylidenepropane-1,3-diol Chemical group OCC(=C)CO JFFYKITVXPZLQS-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- 239000005695 Ammonium acetate Substances 0.000 abstract 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 229940043376 ammonium acetate Drugs 0.000 abstract 1
- 235000019257 ammonium acetate Nutrition 0.000 abstract 1
- 239000001099 ammonium carbonate Substances 0.000 abstract 1
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 150000002429 hydrazines Chemical class 0.000 abstract 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 abstract 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 150000005219 trimethyl ethers Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/667—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain
- D06M15/673—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain containing phosphorus and nitrogen in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
- D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
- D06M15/431—Amino-aldehyde resins modified by phosphorus compounds by phosphines or phosphine oxides; by oxides or salts of the phosphonium radical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
- Y10S428/921—Fire or flameproofing
Abstract
A cellulosic material is impregnated with a composition comprising 10-40% of a tetrakis (a -hydroxy-organo) phosphonium halide, 0.25-0.75 equivalents of an alkaline inorganic stabilizer per mole of phosphonium halide, 5-15% of a copolymerisable cyclic nitrogen-containing compound, 1-10% of a copolymerizable carbamic acid derivative, and 35-80% of water, heating to polymerize the composition partially and treating with a nitrogen base to polymerize completely. A number of phosphonium halides are specified. The stabilizer may be sodium hydroxide, carbonate, or bicarbonate. The cyclic nitrogen-containing compound may be mono, di, or tri methylol melamine, trimethyl ether of trimethylol melamine, dimethylol triazone, or dimethylol ethylene or propylene urea. The carbamic acid derivative may be urea, thiourea, biuret, ethyleneurea, or dicyandiamide. The nitrogen base may be gaseous or aqueous ammonia, ammonium carbonate, acetate, or formate, hydrazine, alkyl-substituted hydrazine or a primary amine. The cellulosic material may be in the form of fibre, yarn, fabric film, pulp, paper, fibre board, or wood. Impregnation may be at 65-85 DEG F. Heating to polymerize partially may be at 200-320 DEG F for 0.5 min. to 1 hr. The fire-proofed material may contain 16-24% of resin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US273272A US3310419A (en) | 1963-04-16 | 1963-04-16 | Process for treating cellulosic material with flameproofing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1065547A true GB1065547A (en) | 1964-04-08 |
Family
ID=23043251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1458764A Expired GB1065547A (en) | 1963-04-16 | 1964-04-08 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3310419A (en) |
| BE (1) | BE675066A (en) |
| DE (1) | DE1285442B (en) |
| GB (1) | GB1065547A (en) |
| NL (1) | NL6404149A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2200148A (en) * | 1987-01-19 | 1988-07-27 | Albright & Wilson | Rendering cellulosic fabrics flame retardant |
| US5139531A (en) * | 1987-01-19 | 1992-08-18 | Albright & Wilson Limited | Fabric treatment processes |
| WO2000021892A1 (en) * | 1998-10-14 | 2000-04-20 | Albright & Wilson Uk Limited | Leaching divalent metal salts |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3607356A (en) * | 1968-10-04 | 1971-09-21 | Us Agriculture | Imparting flame resistance to fibrous textiles from an alkaline medium |
| US4156747A (en) * | 1972-04-17 | 1979-05-29 | Hooker Chemicals & Plastics Corp. | Process for flame retarding cellulosics |
| US4154890A (en) * | 1972-04-17 | 1979-05-15 | Hooker Chemicals & Plastics Corp. | Process for imparting flame retardant property to cellulosic containing materials |
| US4123574A (en) * | 1972-04-17 | 1978-10-31 | Hooker Chemicals & Plastics Corp. | Process for flame retarding cellulosics |
| US4137346A (en) * | 1972-04-17 | 1979-01-30 | Hooker Chemicals & Plastics Corp. | Flame retarding process for proteinaceous material |
| US4068026A (en) * | 1972-04-17 | 1978-01-10 | Hooker Chemicals & Plastics Corporation | Process for flame retarding cellulosics |
| CH561323A (en) * | 1972-12-15 | 1975-04-30 | ||
| US4170670A (en) * | 1975-03-05 | 1979-10-09 | The United States Of America As Represented By The Secretary Of Agriculture | Formulations for imparting flame retardance to cellulosic fabrics via transfer techniques |
| US4088592A (en) * | 1976-02-23 | 1978-05-09 | Velsicol Chemical Corporation | Durable flame retardant finishes for textile materials |
| US4092251A (en) * | 1976-02-23 | 1978-05-30 | Velsicol Chemical Corporation | Durable flame retardant finishes for textile materials |
| US4104172A (en) * | 1976-02-23 | 1978-08-01 | Velsicol Chemical Corporation | Durable flame retardant finishes for textile materials |
| US4046701A (en) * | 1976-02-23 | 1977-09-06 | Velsicol Chemical Corporation | Durable flame retardant finishes for textile materials |
| DE3876264T2 (en) * | 1987-03-24 | 1993-06-24 | Komatsu Seiren Co | METHOD FOR TREATING FIBROUS MATERIALS. |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2809941A (en) * | 1952-04-22 | 1957-10-15 | Wilson A Reeves | Producing phosphorus containing amino resins and flameproofing organic textiles |
| US2772188A (en) * | 1953-11-18 | 1956-11-27 | Wilson A Reeves | Ammonia insolubilized methylol-phosphorus polymers and cellulosic materials impregnated therewith |
| US2812311A (en) * | 1954-04-05 | 1957-11-05 | Albright & Wilson | Water dispersible solid nitrilo-methylolphosphorus polymers |
| US2810701A (en) * | 1954-11-09 | 1957-10-22 | Wilson A Reeves | Aqueous emulsion-suspension textile treating compositions and processes of treating textiles with same |
| US2922726A (en) * | 1955-03-18 | 1960-01-26 | American Cyanamid Co | Flame-proofing nylon with thiourea containing resin |
| US2911322A (en) * | 1957-10-29 | 1959-11-03 | Klein Elias | Field treatment for making cellulosic fabrics flameproof and resistant to certain chemical warfare gases |
| US2993746A (en) * | 1959-03-27 | 1961-07-25 | Thomas D Miles | Treatment of thpc flame-resistant fabrics with strong mineral acids to improve theirtear strength and products produced thereby |
| GB906314A (en) * | 1960-05-30 | 1962-09-19 | Albright & Wilson | Process for improving the properties of cellulose material |
| NL129265C (en) * | 1959-10-05 | 1900-01-01 |
-
1963
- 1963-04-16 US US273272A patent/US3310419A/en not_active Expired - Lifetime
-
1964
- 1964-04-08 GB GB1458764A patent/GB1065547A/en not_active Expired
- 1964-04-16 NL NL6404149A patent/NL6404149A/xx unknown
- 1964-04-16 DE DEH52385A patent/DE1285442B/en active Pending
-
1966
- 1966-01-13 BE BE675066D patent/BE675066A/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2200148A (en) * | 1987-01-19 | 1988-07-27 | Albright & Wilson | Rendering cellulosic fabrics flame retardant |
| GB2200148B (en) * | 1987-01-19 | 1990-12-19 | Albright & Wilson | Fabric treatment processes |
| US5139531A (en) * | 1987-01-19 | 1992-08-18 | Albright & Wilson Limited | Fabric treatment processes |
| WO2000021892A1 (en) * | 1998-10-14 | 2000-04-20 | Albright & Wilson Uk Limited | Leaching divalent metal salts |
Also Published As
| Publication number | Publication date |
|---|---|
| US3310419A (en) | 1967-03-21 |
| DE1285442B (en) | 1968-12-19 |
| NL6404149A (en) | 1965-03-25 |
| BE675066A (en) | 1966-05-03 |
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