GB975095A - Flame proofing of cellulosic materials - Google Patents
Flame proofing of cellulosic materialsInfo
- Publication number
- GB975095A GB975095A GB4146961A GB4146961A GB975095A GB 975095 A GB975095 A GB 975095A GB 4146961 A GB4146961 A GB 4146961A GB 4146961 A GB4146961 A GB 4146961A GB 975095 A GB975095 A GB 975095A
- Authority
- GB
- United Kingdom
- Prior art keywords
- urea
- softening point
- polyvinyl chloride
- chloride resin
- methylol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 5
- 229920005989 resin Polymers 0.000 abstract 10
- 239000011347 resin Substances 0.000 abstract 10
- 235000013877 carbamide Nutrition 0.000 abstract 8
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 6
- 239000004202 carbamide Substances 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 6
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 6
- 239000004800 polyvinyl chloride Substances 0.000 abstract 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 4
- 150000003973 alkyl amines Chemical group 0.000 abstract 4
- 238000001035 drying Methods 0.000 abstract 4
- -1 methylol cyclic alkylene ureas Chemical class 0.000 abstract 4
- 150000003918 triazines Chemical class 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- YTVQIZRDLKWECQ-UHFFFAOYSA-N 2-benzoylcyclohexan-1-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCCC1=O YTVQIZRDLKWECQ-UHFFFAOYSA-N 0.000 abstract 2
- XYOSFLPUWVWHOA-UHFFFAOYSA-N 2-ethylidenepropane-1,3-diol;urea Chemical compound NC(N)=O.CC=C(CO)CO XYOSFLPUWVWHOA-UHFFFAOYSA-N 0.000 abstract 2
- 240000000491 Corchorus aestuans Species 0.000 abstract 2
- 235000011777 Corchorus aestuans Nutrition 0.000 abstract 2
- 235000010862 Corchorus capsularis Nutrition 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- 229920000297 Rayon Polymers 0.000 abstract 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 abstract 2
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical compound NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 abstract 2
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 239000011111 cardboard Substances 0.000 abstract 2
- 125000004122 cyclic group Chemical group 0.000 abstract 2
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- AIRPJJGSWHWBKS-UHFFFAOYSA-N hydroxymethylphosphanium;chloride Chemical compound [Cl-].OC[PH3+] AIRPJJGSWHWBKS-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 239000011087 paperboard Substances 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 239000002964 rayon Substances 0.000 abstract 2
- 238000005096 rolling process Methods 0.000 abstract 2
- 238000005507 spraying Methods 0.000 abstract 2
- 150000005219 trimethyl ethers Chemical class 0.000 abstract 2
- 210000002268 wool Anatomy 0.000 abstract 2
- 240000008564 Boehmeria nivea Species 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 1
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
- D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
- D06M15/431—Amino-aldehyde resins modified by phosphorus compounds by phosphines or phosphine oxides; by oxides or salts of the phosphonium radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5407—Acyclic saturated phosphonium compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
- Y10S428/921—Fire or flameproofing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2631—Coating or impregnation provides heat or fire protection
- Y10T442/2672—Phosphorus containing
- Y10T442/268—Phosphorus and nitrogen containing compound
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A treating composition for cellulosic material comprises a hydroxymethyl phosphonium chloride compound, a methylol substituted triazine, triazone or cyclic alkylene urea, a water soluble tertiary alkyl amine, urea, a polyvinyl chloride resin having a softening point, when substantially pure, above 170 DEG C., and water. Compounds referred to are triazines and d-i. methylol cyclic alkylene ureas, e.g. methylol melamine and its tri-methyl ether, triazones, dimethylol ethylene urea and dimethylol propylene urea. Triethylamine, triethanolamine and triisopropanolamine are suitable tertiary alkyl amines. The polyvinyl chloride resin is preferably unplasticized. It may contain minor proportions of other monomers and plasticizers provided the softening point is not reduced below 160 DEG C. The composition can be applied to cotton, rayon, ramic, jute, wool, paper and cardboard, by spraying, padding, rolling or other methods After drying, the treated material is heated to use the resin and may then be scoured. In an example "battle-ax" fabric is impregnated with an aqueous mixture of tetrakis-(hydroxymethyl) phosphonium chloride, triethanolamine, trimethylol melamine, urea, and an aqueous dispersion of polyvinyl chloride resin (n.p. 180 DEG C.). After drying at 121 DEG C. curing is effected at 370 DEG C. for 10 secs. in an infrated oven. Other examples (some for comparison) describe the use of P.V.C. resins of softening point 40 DEG -50 DEG C., 70 DEG to 80 DEG C., 110 DEG to 120 DEG C., 140-150 DEG C., 180 DEG -200 DEG C. and 190 DEG to 200 DEG C.ALSO:A treating composition for cellulosic material comprises a hydroxymethyl phosphonium chloride compound, a methylol substituted triazine, triazone or cyclic alkylene urea, a water-soluble tertiary alkyl amine, urea, polyvinyl chloride resin having a softening point, when substantially pure, above 170 DEG C., and water. Nitrogen compounds referred to are triazines and dimethylol cyclic alkylene ureas, e.g. methylol melamine and its tri-methyl ether, tri-azones, dimethylol ethylene urea and dimethylol propylene urea. Triethylamine, triethanolamine and tri-isopropanolamine are suitable tertiary alkyl amines. The polyvinyl chloride resin is preferably unplasticised. It may contain minor proportions of other monomers and plasticisers provided the softening point is not reduced below 160 DEG C. The composition can be applied to cotton, rayon, ramie, jute, wool, paper and cardboard, by spraying, podding rolling or other methods. After drying, the treated material is heated to use the resin and may then be scoured. In an example "battle-ax" fabric is impregnated with an aqueous mixture of tetrakis- (hydroxy-methyl) phosphonium chloride, triethanolamine, trimethylol melamine, urea, and an aqueous dispersion of polyvinyl chloride resin (m.p. 180 DEG C.). After drying at 121 DEG C. curing is effected at 370 DEG C. for 10 secs. in an infrared oven. Other examples (some for comparison) describe the use of P.V.C. resins of softening point 40 DEG -50 DEG C., 70 DEG to 80 DEG C., 110 to 120 DEG C., 140-150 DEG C., 180 DEG -200 DEG C., and 190 DEG to 200 DEG C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7038760 US3054698A (en) | 1960-11-21 | 1960-11-21 | Flame proofing of cellulosic materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB975095A true GB975095A (en) | 1964-11-11 |
Family
ID=22094992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4146961A Expired GB975095A (en) | 1960-11-21 | 1961-11-20 | Flame proofing of cellulosic materials |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3054698A (en) |
| DE (1) | DE1419474A1 (en) |
| GB (1) | GB975095A (en) |
| NL (2) | NL126452C (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3243391A (en) * | 1962-03-21 | 1966-03-29 | Hooker Chemical Corp | Composition and process for treating cellulosic materials to make them flame-retardant |
| US3219478A (en) * | 1962-05-14 | 1965-11-23 | Hooker Chemical Corp | Flameproofing of cellulosic material |
| US3376168A (en) * | 1962-08-02 | 1968-04-02 | Yardney International Corp | Metal-containing graft-polymerized product and method of making same |
| US3310856A (en) * | 1962-10-12 | 1967-03-28 | Deering Milliken Res Corp | Method of producing a dimensional stable fabric |
| US3318659A (en) * | 1962-11-14 | 1967-05-09 | Joel B Bullock | Process of treating cellulose textiles with polyvinyl chloride polymers, a polysiloxane and zirconium acetate and optionally with flame resistant and rot resistant agents |
| US3309425A (en) * | 1963-07-30 | 1967-03-14 | American Cyanamid Co | Thermoplastic resins containing phosphonium salts as flame-retardant agents |
| US3322861A (en) * | 1964-06-12 | 1967-05-30 | American Cyanamid Co | Vinyl resins containing diphosphonium halides as flame-retardants |
| US3294632A (en) * | 1964-08-31 | 1966-12-27 | Hooker Chemical Corp | Controlling bacteria on textile materials with reaction products of tetrakis (alpha-hydroxyorgano) phosphonium halides combined with formaldehyde source materials |
| US3428480A (en) * | 1965-02-18 | 1969-02-18 | Hooker Chemical Corp | Flame-retardant cellulosic material,composition and method for making same |
| US3530164A (en) * | 1965-08-13 | 1970-09-22 | American Cyanamid Co | Flame retardant agents for thermoplastic products |
| US3488139A (en) * | 1966-04-18 | 1970-01-06 | Hooker Chemical Corp | Textile treating process |
| US3617193A (en) * | 1967-09-12 | 1971-11-02 | Stevens & Co Inc J P | Flame-retardant bis(epoxyalkyl) methylphosphonate treated substrate and process therefor |
| US3915915A (en) * | 1971-05-07 | 1975-10-28 | Us Agriculture | Flame proofing textile treating composition of tris(hydroxymethyl) phosphine-urea adduct and polyvinylbromide |
| US3914106A (en) * | 1972-01-04 | 1975-10-21 | Us Agriculture | Process for treating organic textiles with flame retardant polymers made from hydroxymethylphosphorus compounds and guanazoles |
| US3949108A (en) * | 1973-06-01 | 1976-04-06 | The United States Of America As Represented By The Secretary Of Agriculture | Process for producing fire resistant organic textile materials |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2684953A (en) * | 1952-03-29 | 1954-07-27 | Dow Chemical Co | Intumescent coating composition and an article of manufacture thereof |
| US2810701A (en) * | 1954-11-09 | 1957-10-22 | Wilson A Reeves | Aqueous emulsion-suspension textile treating compositions and processes of treating textiles with same |
-
0
- NL NL271608D patent/NL271608A/xx unknown
- NL NL126452D patent/NL126452C/xx active
-
1960
- 1960-11-21 US US7038760 patent/US3054698A/en not_active Expired - Lifetime
-
1961
- 1961-11-20 DE DE19611419474 patent/DE1419474A1/en not_active Withdrawn
- 1961-11-20 GB GB4146961A patent/GB975095A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL126452C (en) | 1900-01-01 |
| US3054698A (en) | 1962-09-18 |
| DE1419474A1 (en) | 1969-02-13 |
| NL271608A (en) | 1900-01-01 |
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