GB1063086A - Heterocyclic compounds - Google Patents

Heterocyclic compounds

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Publication number
GB1063086A
GB1063086A GB11069/64A GB1106964A GB1063086A GB 1063086 A GB1063086 A GB 1063086A GB 11069/64 A GB11069/64 A GB 11069/64A GB 1106964 A GB1106964 A GB 1106964A GB 1063086 A GB1063086 A GB 1063086A
Authority
GB
United Kingdom
Prior art keywords
organic
groups
amine
reacting
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11069/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH384062A external-priority patent/CH407114A/en
Priority claimed from CH327563A external-priority patent/CH460000A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1063086A publication Critical patent/GB1063086A/en
Expired legal-status Critical Current

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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F1/00Shielding characterised by the composition of the materials
    • G21F1/02Selection of uniform shielding materials
    • G21F1/10Organic substances; Dispersions in organic carriers
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    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02Boron compounds
    • C07F5/022Boron compounds without C-boron linkages
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    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
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    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
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    • C07F7/02Silicon compounds
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    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
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    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C07F9/6581Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
    • C07F9/6587Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms having two phosphorus atoms as ring hetero atoms in the same ring
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Abstract

Compounds of Formula (IV) <FORM:1063086/C3/1> wherein R4, R5 and R6 are each an organic group joined to the ring by a carbon atom, or R4 and R5 together represent a polymethylene group, are prepared by heating compounds of Formula (I) R6NH-SiR4R5-NHR6, (II) XR5R4Si-NR6-SiR4R5R9 or <FORM:1063086/C3/2> wherein R9 and R10 are each organic groups uinted to the silicon atom through a carbon atom, and X is a halogen atom. Novel compounds (IV) are those wherein R4, R5 are each hydrocarbon or hydrocarbonoxy hydrocarbon groups or, together, a polymethylene group, and R13 is a hydrocarbon group optionally substituted by one or more halogen, nitro, cyano, acyl, ether, ester, hydrocarbonoxy, ammo, or organosilyl groups. In embodiments the (I) may be formed by reacting R6NH2 with a tri-or tetra-silazane, or with X2SiR4R5 where X is a halogen atom, and the product may be heated to form the cyclic silazane without isolation. Amine (II) may be prepared by reacting an organic silicon dihalide with the alkali-metal or Grignard derivative of the reaction product of R6NH2 and an organic monohalosilane. Amine (III) may be prepared forming a diorganometallic of amine (I) and reacting this with R4R5R10SiX. Cyclic silazanes (IV) containing unsaturated groups may be polymerized; no examples are given.
GB11069/64A 1962-03-30 1964-03-16 Heterocyclic compounds Expired GB1063086A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH384062A CH407114A (en) 1962-03-30 1962-03-30 Process for the preparation of heterocyclic four-membered ring compounds
CH327563A CH460000A (en) 1963-03-15 1963-03-15 Process for the production of high-temperature resistant cyclodisilazanes

Publications (1)

Publication Number Publication Date
GB1063086A true GB1063086A (en) 1967-03-30

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Family Applications (2)

Application Number Title Priority Date Filing Date
GB12527/63A Expired GB1040726A (en) 1962-03-30 1963-03-29 Heterocyclic compounds
GB11069/64A Expired GB1063086A (en) 1962-03-30 1964-03-16 Heterocyclic compounds

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB12527/63A Expired GB1040726A (en) 1962-03-30 1963-03-29 Heterocyclic compounds

Country Status (4)

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BE (2) BE645148A (en)
DE (3) DE1214683B (en)
GB (2) GB1040726A (en)
NL (1) NL290900A (en)

Also Published As

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DE1291338B (en) 1969-03-27
NL290900A (en)
DE1214683B (en) 1966-04-21
GB1040726A (en) 1966-09-01
DE1252683B (en) 1967-10-26
BE645148A (en) 1964-09-14
BE630249A (en)

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