GB1043606A - Preparation of carbonyl compounds by a redox process - Google Patents
Preparation of carbonyl compounds by a redox processInfo
- Publication number
- GB1043606A GB1043606A GB14631/64A GB1463164A GB1043606A GB 1043606 A GB1043606 A GB 1043606A GB 14631/64 A GB14631/64 A GB 14631/64A GB 1463164 A GB1463164 A GB 1463164A GB 1043606 A GB1043606 A GB 1043606A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal
- oxidant
- compound
- olefinic
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001728 carbonyl compounds Chemical class 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 abstract 8
- 239000002184 metal Substances 0.000 abstract 8
- 239000007800 oxidant agent Substances 0.000 abstract 7
- 239000003054 catalyst Substances 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 6
- 239000002253 acid Substances 0.000 abstract 4
- 150000003839 salts Chemical class 0.000 abstract 3
- 229910052723 transition metal Inorganic materials 0.000 abstract 3
- 150000003624 transition metals Chemical class 0.000 abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 abstract 2
- -1 e.g. O2 Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229910052737 gold Inorganic materials 0.000 abstract 2
- 229910052741 iridium Inorganic materials 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052745 lead Inorganic materials 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 230000007935 neutral effect Effects 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 229910052762 osmium Inorganic materials 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical compound CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000001447 alkali salts Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 150000005676 cyclic carbonates Chemical class 0.000 abstract 1
- 150000001925 cycloalkenes Chemical class 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 125000005594 diketone group Chemical group 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
- 239000003495 polar organic solvent Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000001174 sulfone group Chemical group 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0222—Metal clusters, i.e. complexes comprising 3 to about 1000 metal atoms with metal-metal bonds to provide one or more all-metal (M)n rings, e.g. Rh4(CO)12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US272877A US3365498A (en) | 1963-04-15 | 1963-04-15 | Redox catalytic oxidation of olefins to aldehydes and ketones |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1043606A true GB1043606A (en) | 1966-09-21 |
Family
ID=23041666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14631/64A Expired GB1043606A (en) | 1963-04-15 | 1964-04-09 | Preparation of carbonyl compounds by a redox process |
Country Status (7)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0237108A1 (en) * | 1986-03-06 | 1987-09-16 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of carbonyl compounds |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3534093A (en) * | 1966-03-21 | 1970-10-13 | Gulf Research Development Co | Ethylene oxidation in the presence of palladium metal |
| GB1213165A (en) * | 1967-05-05 | 1970-11-18 | Ici Ltd | Electrolytic oxidation process |
| US3992456A (en) * | 1969-04-16 | 1976-11-16 | Union Carbide Corporation | Synthesis of alkadienols |
| US3965185A (en) * | 1972-07-03 | 1976-06-22 | Union Oil Company Of California | Oxidation of olefins to ketones and aldehydes |
| NL7309563A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-07-17 | 1974-01-21 | ||
| US3849911A (en) * | 1973-04-06 | 1974-11-26 | L Longenecker | Painting guide kit |
| FR2231653B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-05-28 | 1976-11-12 | Rhone Poulenc Ind | |
| US4170571A (en) * | 1977-12-27 | 1979-10-09 | Union Carbide Corporation | Novel combustion catalyst |
| US4203927A (en) * | 1978-04-11 | 1980-05-20 | Phillips Petroleum Company | Olefin oxidation process |
| US4220604A (en) * | 1978-07-14 | 1980-09-02 | Phillips Petroleum Company | Oxidative rearrangement of olefins |
| EP0013467A1 (en) * | 1979-01-16 | 1980-07-23 | The Standard Oil Company | Process for the manufacture of furan compounds |
| WO1980002023A1 (en) * | 1979-03-28 | 1980-10-02 | Gallaher Ltd | Catalytic processes and catalysts |
| US4237331A (en) * | 1979-10-26 | 1980-12-02 | Phillips Petroleum Company | Olefin oxidation process |
| US4481373A (en) * | 1981-07-01 | 1984-11-06 | Toa Nenryo Kogyo Kabushiki Kaisha | Method of manufacturing ketones |
| US4507506A (en) * | 1983-04-21 | 1985-03-26 | Phillips Petroleum Company | Alpha-olefin conversion |
| CA1242457A (en) * | 1984-01-27 | 1988-09-27 | Taiji Kamiguchi | Process for producing acetone |
| US4717675A (en) * | 1984-08-03 | 1988-01-05 | Sievers Research, Inc. | Method for selective conversion of organic compounds and detecting same by gas chromotography and chemiluminescence detection |
| JP2592680B2 (ja) * | 1989-08-30 | 1997-03-19 | 日本ゼオン株式会社 | α，β―不飽和カルボニル化合物の製造方法 |
| EP0498305B1 (en) * | 1991-02-01 | 1995-12-27 | Idemitsu Kosan Company Limited | Process for preparing carbonyl compounds |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE635230A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | ||||
| DE1061767B (de) * | 1957-06-07 | 1959-07-23 | Consortium Elektrochem Ind | Verfahren zur Herstellung von Aldehyden und Ketonen |
| DE1080994B (de) * | 1957-06-28 | 1960-05-05 | Consortium Elektrochem Ind | Verfahren zur Herstellung von Aldehyden und Ketonen |
| US3080425A (en) * | 1957-06-28 | 1963-03-05 | Consortium Elektrochem Ind | Process for the production of aldehydes and ketones compounds |
| DE1118183B (de) * | 1957-07-10 | 1961-11-30 | Consortium Elektrochem Ind | Verfahren zur Herstellung von Aldehyden, Ketonen oder den Aldehyden entsprechenden Saeuren |
| US3086994A (en) * | 1957-08-01 | 1963-04-23 | Consortium Elektrochem Ind | Process for the production of aldehydes and ketones |
| GB884963A (en) * | 1957-08-01 | 1961-12-20 | Consortium Elektrochem Ind | Process for the manufacture of aldehydes and ketones |
| US3076032A (en) * | 1957-10-31 | 1963-01-29 | Hoechst Ag | Process for oxidizing olefins to aldehydes and ketones |
| US3144488A (en) * | 1959-06-29 | 1964-08-11 | Consortium Elektrochem Ind | Process for the production of 3-chlorobutanone-2 and butanone |
| FR77302E (fr) * | 1959-10-02 | 1962-02-16 | Hoechst Ag | Procédé d'oxydation d'oléfines en aldéhydes, cétones, et acides |
| FR77458E (fr) * | 1959-10-31 | 1962-03-09 | Hoechst Ag | Procédé d'oxydation d'oléfines en aldéhydes, cétones et acides |
| FR77459E (fr) * | 1959-11-18 | 1962-03-09 | Hoechst Ag | Procédé d'oxydation d'oléfines en aldéhydes, cétones et acides |
| FR1250710A (fr) * | 1959-12-19 | 1961-01-13 | Hoechst Ag | Procédé d'oxydation d'oléfines en aldéhydes, cétones ou acides |
| FR1271821A (fr) * | 1960-09-26 | 1961-09-15 | Hoechst Ag | Procédé d'oxydation d'oléfines en aldéhydes, cétones et acides |
-
1963
- 1963-04-15 US US272877A patent/US3365498A/en not_active Expired - Lifetime
-
1964
- 1964-04-09 GB GB14631/64A patent/GB1043606A/en not_active Expired
- 1964-04-13 NL NL6403962A patent/NL6403962A/xx unknown
- 1964-04-13 BE BE646482D patent/BE646482A/xx unknown
- 1964-04-14 ES ES0298676A patent/ES298676A1/es not_active Expired
- 1964-04-14 DE DEU10656A patent/DE1281421B/de active Pending
- 1964-04-15 AT AT330964A patent/AT258259B/de active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0237108A1 (en) * | 1986-03-06 | 1987-09-16 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of carbonyl compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| ES298676A1 (es) | 1964-09-01 |
| DE1281421B (de) | 1968-10-31 |
| AT258259B (de) | 1967-11-10 |
| BE646482A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1964-07-31 |
| NL6403962A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1964-10-16 |
| US3365498A (en) | 1968-01-23 |
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