GB1043045A - Detergent compositions - Google Patents
Detergent compositionsInfo
- Publication number
- GB1043045A GB1043045A GB38578/64A GB3857864A GB1043045A GB 1043045 A GB1043045 A GB 1043045A GB 38578/64 A GB38578/64 A GB 38578/64A GB 3857864 A GB3857864 A GB 3857864A GB 1043045 A GB1043045 A GB 1043045A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- potassium
- sulphates
- specified
- sulphonates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 4
- 229910052700 potassium Inorganic materials 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 3
- 239000011591 potassium Substances 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- 229910052708 sodium Inorganic materials 0.000 abstract 3
- 239000011734 sodium Substances 0.000 abstract 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical class CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- -1 quaternary ammonium halide Chemical class 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical class CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 239000005708 Sodium hypochlorite Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical class [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- REDXAOYRXGBORL-UHFFFAOYSA-M benzyl-diethyl-icosylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[N+](CC)(CC)CC1=CC=CC=C1 REDXAOYRXGBORL-UHFFFAOYSA-M 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 229910021538 borax Inorganic materials 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Chemical class 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000001913 cellulose Chemical class 0.000 abstract 1
- 229920002678 cellulose Chemical class 0.000 abstract 1
- 150000007973 cyanuric acids Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229940051250 hexylene glycol Drugs 0.000 abstract 1
- 150000003949 imides Chemical class 0.000 abstract 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- NIXKBAZVOQAHGC-UHFFFAOYSA-N phenylmethanesulfonic acid Chemical class OS(=O)(=O)CC1=CC=CC=C1 NIXKBAZVOQAHGC-UHFFFAOYSA-N 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 229940096992 potassium oleate Drugs 0.000 abstract 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 abstract 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 abstract 1
- 239000001488 sodium phosphate Substances 0.000 abstract 1
- 235000011008 sodium phosphates Nutrition 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000004328 sodium tetraborate Substances 0.000 abstract 1
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 1
- 239000012798 spherical particle Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3955—Organic bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3958—Bleaching agents combined with phosphates
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
- G06F3/14—Digital output to display device ; Cooperation and interconnection of the display device with other functional units
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Theoretical Computer Science (AREA)
- Human Computer Interaction (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Detergent Compositions (AREA)
Abstract
Detergent compositions comprise (a) a water-soluble anionic, non-soap, organic detergent, (b) a water-soluble salt of a C8- 18 fatty acid, and (c) a quaternary ammonium halide having one C10- 20 alkyl group. Component (a) may be one or more of many known anionic detergents containing sulphate, sulphonate, carboxyl or phosphate groups, including alkyl-benzene sulphonates, salts of sulphated polyethenoxylated phenols and alcohols, alkyl sulphates, isethionates, fatty ethanolamide sulphates, taurides, and hydroxy-alkane sulphonates. Specified cations in the anionic detergents are Na, K, Li, and Mg. Component (b) may be a conventional sodium or potassium soap, e.g. potassium oleate, others being specified. Typical of many specified components (c) are cetyl trimethyl ammonium bromide and arachidyl diethyl benzyl ammonium chloride. The compositions may also contain an inorganic or organic builder salt, including neutral and acid sodium phosphates and condensed phosphates, sodium silicate and meta-silicate, sodium carbonate, sodium sulphate, borax, tri-sodium nitrilo-tri-acetate, and the tetra-sodium salt of EDTA. Further optional ingredients mentioned include fatty acid alkanolamides, xylene and toluene sulphonates, ethanol, ethylene glycol, hexylene glycol, sodium carboxymethyl-cellulose and other cellulose derivatives including ethers and sulphates, polyvinyl alcohol, and a wide variety of bleaching agents, including sodium hypochlorite, sodium and potassium perborates, potassium permonosulphate, chlorinated cyanuric acid derivatives, and N-chloro hydantoins and imides. The compositions may take the form of beads, grains, flakes, chips, powders, and tablets. In particular, they may be prepared by spray-drying an aqueous slurry of the ingredients to give hollow, thin-walled spherical particles.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US313128A US3325414A (en) | 1963-10-01 | 1963-10-01 | Heavy duty detergent composition containing a quaternary ammonium salt |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1043045A true GB1043045A (en) | 1966-09-21 |
Family
ID=23214502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB38578/64A Expired GB1043045A (en) | 1963-10-01 | 1964-09-22 | Detergent compositions |
Country Status (9)
Country | Link |
---|---|
US (1) | US3325414A (en) |
BE (1) | BE653763A (en) |
CH (1) | CH475346A (en) |
DE (1) | DE1261976B (en) |
DK (1) | DK127734B (en) |
FR (1) | FR1413248A (en) |
GB (1) | GB1043045A (en) |
MY (1) | MY6800014A (en) |
NL (1) | NL6411363A (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3668136A (en) * | 1969-07-07 | 1972-06-06 | Witco Chemical Corp | Compatible anionic-catonic surfactant compositions |
US3658717A (en) * | 1969-07-07 | 1972-04-25 | Atlas Chem Ind | Surfactants for solvent/water systems and textile treating compositions |
US3716499A (en) * | 1970-05-28 | 1973-02-13 | Colgate Palmolive Co | Ternary foam control composition and built anionic detergent composition containing same |
DE2135266C3 (en) * | 1971-07-15 | 1979-09-06 | Chemische Werke Huels Ag, 4370 Marl | Process for the production of free-flowing, powdery, fuel-containing rubber mixtures from rubber solutions |
JPS4971003A (en) * | 1972-11-06 | 1974-07-09 | ||
US3920565A (en) * | 1973-02-23 | 1975-11-18 | Procter & Gamble | Fabric softener composition and method |
US4427410A (en) | 1974-09-06 | 1984-01-24 | Colgate-Palmolive Company | Fabric softening composition containing molecular sieve zeolite |
US4255294A (en) * | 1975-04-01 | 1981-03-10 | Lever Brothers | Fabric softening composition |
GB2040990B (en) * | 1977-11-17 | 1982-10-06 | Procter & Gamble | Granular detergent compositions for improved greasy soil removal |
US4326971A (en) * | 1978-12-11 | 1982-04-27 | Colgate Palmolive Company | Detergent softener compositions |
US4230590A (en) * | 1978-12-11 | 1980-10-28 | Colgate Palmolive Company | Detergent softener compositions containing a soap-cellulose ether mixture |
US4298480A (en) * | 1978-12-11 | 1981-11-03 | Colgate Palmolive Co. | Detergent softener compositions |
US4416811A (en) * | 1979-11-21 | 1983-11-22 | Colgate-Palmolive Company | Detergent softener compositions |
US4329237A (en) * | 1979-11-21 | 1982-05-11 | Colgate-Palmolive Company | Detergent softener compositions |
US4411803A (en) * | 1980-10-27 | 1983-10-25 | Colgate Palmolive Company | Detergent softener compositions |
US4450085A (en) * | 1981-05-01 | 1984-05-22 | Colgate Palmolive Company | Detergent softener compositions |
US4800036A (en) * | 1985-05-06 | 1989-01-24 | The Dow Chemical Company | Aqueous bleach compositions thickened with a viscoelastic surfactant |
US4704221A (en) * | 1986-10-22 | 1987-11-03 | The Procter & Gamble Company | Granular detergents which contain high levels of anionic surfactant that forms a middle-phase, surface treated with a water soluble cationic surfactant |
US5055219A (en) * | 1987-11-17 | 1991-10-08 | The Clorox Company | Viscoelastic cleaning compositions and methods of use therefor |
DE19948668A1 (en) * | 1999-10-08 | 2001-04-19 | Cognis Deutschland Gmbh | Detergent tablets |
DE102006039873B4 (en) * | 2006-08-25 | 2013-10-31 | Henkel Ag & Co. Kgaa | Reinforcement of the cleaning performance of detergents by cotton-active soil release cellulose derivative |
US9237972B2 (en) * | 2008-12-16 | 2016-01-19 | Kimberly-Clark Worldwide, Inc. | Liquid surfactant compositions that adhere to surfaces and solidify and swell in the presence of water and articles using the same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA525648A (en) * | 1956-05-29 | W. Stewart Alex | Detergent composition | |
US2634239A (en) * | 1949-06-24 | 1953-04-07 | Colgate Palmolive Peet Co | Detergent composition |
US2861955A (en) * | 1954-10-22 | 1958-11-25 | Emery Industries Inc | Detergent for hard water |
BE551361A (en) * | 1955-10-27 | |||
BE572404A (en) * | 1957-10-31 | |||
CA688539A (en) * | 1960-11-01 | 1964-06-09 | Colgate-Palmolive Company | Solid detergent compositions |
-
1963
- 1963-10-01 US US313128A patent/US3325414A/en not_active Expired - Lifetime
-
1964
- 1964-09-21 DE DEC33936A patent/DE1261976B/en active Pending
- 1964-09-22 GB GB38578/64A patent/GB1043045A/en not_active Expired
- 1964-09-29 CH CH1264764A patent/CH475346A/en not_active IP Right Cessation
- 1964-09-29 FR FR989695A patent/FR1413248A/en not_active Expired
- 1964-09-30 DK DK483164AA patent/DK127734B/en unknown
- 1964-09-30 BE BE653763D patent/BE653763A/xx unknown
- 1964-09-30 NL NL6411363A patent/NL6411363A/xx unknown
-
1968
- 1968-12-31 MY MY196814A patent/MY6800014A/en unknown
Also Published As
Publication number | Publication date |
---|---|
DK127734B (en) | 1973-12-24 |
US3325414A (en) | 1967-06-13 |
CH475346A (en) | 1969-07-15 |
NL6411363A (en) | 1965-04-02 |
BE653763A (en) | 1965-03-30 |
FR1413248A (en) | 1965-10-08 |
MY6800014A (en) | 1968-12-31 |
DE1261976B (en) | 1968-02-29 |
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