GB1034547A - Hydrofining and hydrocracking process - Google Patents

Hydrofining and hydrocracking process

Info

Publication number
GB1034547A
GB1034547A GB32866/64A GB3286664A GB1034547A GB 1034547 A GB1034547 A GB 1034547A GB 32866/64 A GB32866/64 A GB 32866/64A GB 3286664 A GB3286664 A GB 3286664A GB 1034547 A GB1034547 A GB 1034547A
Authority
GB
United Kingdom
Prior art keywords
vol
hydrocracking
hydrofining
nitrogen
effected
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32866/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1034547A publication Critical patent/GB1034547A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

The hydrocracking of a nitrogen-containing hydrocarbon oil is effected by hydrofining to a nitrogen content of 15-200 p.p.m., followed by hydrocracking in the presence of a crystalline zeolitic aluminosilicate having a pore size of 6-15 <\>rA, containing a platinum group metal and containing less than 10% weight of alkali metal oxide. The feed preferably boils above 400 DEG F. and contains at least 100 p.p.m. nitrogen which is reduced by hydrofining over a Group VI and/or VIII metal oxide or sulphide, supported, if desired, at 500-800 DEG F., 500-3000 p.s.i.g., 0.1-10 vol./vol./hour with 1,000-20,000 SCF hydrogen per barrel. After removal of ammonia, hydrocracking is effected at 450-800 DEG F., 500-3,000 p.s.i.g., 0.1-10 vol./vol./hour with 1,000-20,000 SCF hydrogen per barrel. Alkali metal ions are removed by base exchange to introduce another metal or hydrogen ions and impregnated or base exchanged to introduce 0.01-5% weight platinum or palladium.
GB32866/64A 1963-08-23 1964-08-12 Hydrofining and hydrocracking process Expired GB1034547A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US30416163A 1963-08-23 1963-08-23
US304163A US3272734A (en) 1963-08-23 1963-08-23 Hydrofining and hydrocracking process

Publications (1)

Publication Number Publication Date
GB1034547A true GB1034547A (en) 1966-06-29

Family

ID=26973843

Family Applications (2)

Application Number Title Priority Date Filing Date
GB32866/64A Expired GB1034547A (en) 1963-08-23 1964-08-12 Hydrofining and hydrocracking process
GB33721/64A Expired GB1071467A (en) 1963-08-23 1964-08-18 Hydrocracking process

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB33721/64A Expired GB1071467A (en) 1963-08-23 1964-08-18 Hydrocracking process

Country Status (6)

Country Link
US (1) US3272734A (en)
DE (2) DE1297794B (en)
FR (1) FR1410457A (en)
GB (2) GB1034547A (en)
NL (2) NL146529B (en)
NO (1) NO115299B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3477943A (en) * 1967-04-25 1969-11-11 Atlantic Richfield Co Two-stage treatment of high sulfur content petroleum materials
US3617507A (en) * 1968-02-17 1971-11-02 Basf Ag Process for hydrocracking heavy hydrocarbons
DE1767074C2 (en) * 1968-03-28 1973-01-04 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Process for the production of crystalline zeolites
US3506568A (en) * 1969-01-10 1970-04-14 Chevron Res Process of hydrofining high nitrogen hydrocarbons followed by catalytic cracking with zeolitic aluminosilicates
US4153540A (en) * 1977-05-04 1979-05-08 Mobil Oil Corporation Upgrading shale oil
US4210521A (en) * 1977-05-04 1980-07-01 Mobil Oil Corporation Catalytic upgrading of refractory hydrocarbon stocks
JPS58120694A (en) * 1982-01-13 1983-07-18 Mitsubishi Oil Co Ltd Preparation of raw material pitch for carbon fiber
US4515680A (en) * 1983-05-16 1985-05-07 Ashland Oil, Inc. Naphthenic lube oils
US4755280A (en) * 1985-07-31 1988-07-05 Exxon Research And Engineering Company Process for improving the color and oxidation stability of hydrocarbon streams containing multi-ring aromatic and hydroaromatic hydrocarbons
US8066867B2 (en) * 2008-11-10 2011-11-29 Uop Llc Combination of mild hydrotreating and hydrocracking for making low sulfur diesel and high octane naphtha
US10711207B2 (en) * 2014-10-22 2020-07-14 Uop Llc Integrated hydrotreating and slurry hydrocracking process

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE622012A (en) *
GB541067A (en) * 1939-04-03 1941-11-12 Standard Oil Dev Co Improvements relating to the catalytic treatment of hydrocarbons
US2962435A (en) * 1956-12-14 1960-11-29 Union Oil Co Hydrocarbon cracking process and catalyst
CA645825A (en) * 1957-02-05 1962-07-31 Esso Research And Engineering Company Hydrocarbon conversion
US2971904A (en) * 1957-02-12 1961-02-14 Exxon Research Engineering Co Petroleum process catalyst supported on a molecular sieve zeolite
US3132089A (en) * 1960-12-23 1964-05-05 Union Oil Co Hydrocracking process with pre-hydrogenation
US3159568A (en) * 1961-10-02 1964-12-01 Union Oil Co Low pressure hydrocracking process with hydrofining of feed
US3132090A (en) * 1962-01-23 1964-05-05 Union Oil Co Hydrocracking process with regulation of the aromatic content of the product

Also Published As

Publication number Publication date
NO115299B (en) 1968-09-16
NL6409703A (en) 1965-02-24
FR1410457A (en) 1965-09-10
DE1250039B (en) 1967-09-14
DE1250039C2 (en) 1973-02-22
NL146529B (en) 1975-07-15
DE1297794B (en) 1969-06-19
US3272734A (en) 1966-09-13
GB1071467A (en) 1967-06-07
NL6409702A (en) 1965-02-24

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