GB1010410A - Preparation of dinitroparaffins, nitro alcohols and nitroolefins - Google Patents

Preparation of dinitroparaffins, nitro alcohols and nitroolefins

Info

Publication number
GB1010410A
GB1010410A GB3113863A GB3113863A GB1010410A GB 1010410 A GB1010410 A GB 1010410A GB 3113863 A GB3113863 A GB 3113863A GB 3113863 A GB3113863 A GB 3113863A GB 1010410 A GB1010410 A GB 1010410A
Authority
GB
United Kingdom
Prior art keywords
nitroolefins
mixture
dinitroparaffins
nitroalcohols
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3113863A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlantic Richfield Co
Original Assignee
Atlantic Refining Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlantic Refining Co filed Critical Atlantic Refining Co
Publication of GB1010410A publication Critical patent/GB1010410A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/14—Preparation of nitro compounds by formation of nitro groups together with reactions not involving the formation of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/16—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/01—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to acyclic carbon atoms
    • C07C205/02—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to acyclic carbon atoms of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/01—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to acyclic carbon atoms
    • C07C205/03—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to acyclic carbon atoms of an unsaturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
    • C07C205/14—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to acyclic carbon atoms
    • C07C205/15—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to acyclic carbon atoms of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Dinitroparaffins of the formula <FORM:1010410/C2/1> nitroalcohols of the formula nitroalcohols of the formula <FORM:1010410/C2/2> or nitroolefins of the formula R-CH=CH-NO2 wherein R represents a C1- 22 normal alkyl radical are prepared by contacting a C3- 24 normal alpha-olefin with an equilibrium mixture of NO2 and N2O4 in the presence of a paraffin solvent at a temperature ranging from 50 DEG to 150 DEG C. for a time ranging from 0.1 second to 10 minutes and subjecting the nitrated product (a mixture of said dinitroparaffins with nitro-nitrites of the formula <FORM:1010410/C2/3> to controlled hydrolysis or alcoholysis by (a) a catalytic amount of a base and a C1- 6 aliphatic alcohol or a mixture thereof with water to produce a mixture of said nitroalcohols and said nitroolefins, or (b) only said C1- 6 aliphatic alcohol, or water, or a mixture of said C1- 6 aliphatic alcohol and water to produce a mixture of said nitroalcohols and said dinitroparaffins. The nitroalcohols may be separated from the dinitroparaffins or nitroolefins and either dehydrated to nitroolefins by treatment with an alcoholic alkali metal hydroxide solution or hydrogenated to corresponding amino alcohols. The separated dinitroparaffins may be hydrolyzed to nitroolefins by contacting them with an aqueous slurry of a Group II metal oxide. Alternatively, treatment (b) of the second stage of the process may be followed by treatment (a) to give a mixture of said nitroalcohols and said nitroolefins.
GB3113863A 1962-09-19 1963-08-07 Preparation of dinitroparaffins, nitro alcohols and nitroolefins Expired GB1010410A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US22473162A 1962-09-19 1962-09-19

Publications (1)

Publication Number Publication Date
GB1010410A true GB1010410A (en) 1965-11-17

Family

ID=22841937

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3113863A Expired GB1010410A (en) 1962-09-19 1963-08-07 Preparation of dinitroparaffins, nitro alcohols and nitroolefins

Country Status (4)

Country Link
BE (1) BE636129A (en)
DE (1) DE1443380A1 (en)
GB (1) GB1010410A (en)
NL (1) NL296871A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996003479A1 (en) * 1994-07-21 1996-02-08 Basf Aktiengesellschaft Use of reaction products of polyolefins and nitrogen oxides or mixtures of nitrogen oxides and oxygen as fuel additives
US5879420A (en) * 1994-07-21 1999-03-09 Basf Aktiengesellschaft Reaction products of polyisobutenes and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen and their use as fuel and lubricant additives

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4196217A (en) * 1976-02-17 1980-04-01 Laboratoires Pharmascience Hydroxylated amines with bacteriostatic activity

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996003479A1 (en) * 1994-07-21 1996-02-08 Basf Aktiengesellschaft Use of reaction products of polyolefins and nitrogen oxides or mixtures of nitrogen oxides and oxygen as fuel additives
US5879420A (en) * 1994-07-21 1999-03-09 Basf Aktiengesellschaft Reaction products of polyisobutenes and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen and their use as fuel and lubricant additives
US5972856A (en) * 1994-07-21 1999-10-26 Basf Aktiengesellschaft Reaction products of polyisobutenes and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen and their use as fuel and lubricant additives
US5980594A (en) * 1994-07-21 1999-11-09 Basf Aktiengesellschaft Use of reaction products of polyolefins and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen as additives for fuels
US6005144A (en) * 1994-07-21 1999-12-21 Basf Aktiengesellschaft Reaction products of polyisobutenes and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen and their use as fuel and lubricant additives

Also Published As

Publication number Publication date
DE1443380A1 (en) 1968-10-24
BE636129A (en)
NL296871A (en)

Similar Documents

Publication Publication Date Title
GB959507A (en) Catalytic hydrogenation of nitrophenol
GB1010410A (en) Preparation of dinitroparaffins, nitro alcohols and nitroolefins
GB822834A (en) A method of processing waste of polyethylene terephthalate by hydrolysis
GB772345A (en) Improvements in or relating to preparation of polyvinylamine
ES394885A1 (en) &#39; -methylfluorene-2-acetic acid
GB999255A (en) Novel unsaturated alcohols and a process for the preparation thereof
UA7014A1 (en) METHOD OF PREPARATION OF 4-AMINO-5-CHLORINE-1-PHENYLPYRIDAZONE- (6)
GB743941A (en) Improvements in or relating to manufacture of propyl nitrate
GB591027A (en) 11-amino-undecyclic acid and its method of preparation
SU382613A1 (en)
SU111826A1 (en) The method of obtaining 2,5-dinigrofenol
GB494666A (en) Process of preparing monohydric alcohols
GB856393A (en) A process for the manufacture of 4-amino-isoxazolidone-(3)
GB951275A (en) Process for the production of glycolic acid nitrile from methyl semiformal and hydrocyanic acid
GB899370A (en) A process for the production of tropolone
ES291917A1 (en) Procedure for the obtaining of monogychonic ester of tertifylic acid (Machine-translation by Google Translate, not legally binding)
GB379677A (en) Improvements in and relating to therapeutic compounds containing silver
GB569157A (en) Sulphanilamide derivatives
GB689393A (en) Process for the preparation of 10-amino-decanoic acid
ES217930A1 (en) A procedure for obtaining mono-, di- or poly-hydroxy-alcohylxyantins and their nitric esters (Machine-translation by Google Translate, not legally binding)
GB1466043A (en) Method of preparing 5-nitrofurfural diacetate
GB772832A (en) Improvements on or relating to process of production of hydroxylamine salts
CA528234A (en) Process for treating aqueous mixture of methyl acetate, methyl alcohol and acetic acid
GB728682A (en) Dichloracetoxy-amino-propanol salts and process for the manufacture thereof
GB844866A (en) Process for the manufacture of partially acylated polyvinyl alcohol