GB1009950A - Process for polymerizing 1,3-butadiene - Google Patents
Process for polymerizing 1,3-butadieneInfo
- Publication number
- GB1009950A GB1009950A GB1568764A GB1568764A GB1009950A GB 1009950 A GB1009950 A GB 1009950A GB 1568764 A GB1568764 A GB 1568764A GB 1568764 A GB1568764 A GB 1568764A GB 1009950 A GB1009950 A GB 1009950A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diiodo
- butene
- catalyst
- butadiene
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title abstract 8
- 238000000034 method Methods 0.000 title abstract 2
- 230000000379 polymerizing effect Effects 0.000 title 1
- VBMRTRMBWBOEGL-OWOJBTEDSA-N (e)-1,4-diiodobut-2-ene Chemical compound IC\C=C\CI VBMRTRMBWBOEGL-OWOJBTEDSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 5
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 2
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 abstract 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910010068 TiCl2 Inorganic materials 0.000 abstract 1
- 229910010062 TiCl3 Inorganic materials 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 150000005840 aryl radicals Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N diisobutylaluminium hydride Substances CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 abstract 1
- KMYFNYFIPIGQQZ-UHFFFAOYSA-N magnesium;octane Chemical compound [Mg+2].CCCCCCC[CH2-].CCCCCCC[CH2-] KMYFNYFIPIGQQZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- -1 titanium halide Chemical class 0.000 abstract 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 abstract 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 abstract 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
- JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US27300663A | 1963-04-15 | 1963-04-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1009950A true GB1009950A (en) | 1965-11-17 |
Family
ID=23042156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1568764A Expired GB1009950A (en) | 1963-04-15 | 1964-04-15 | Process for polymerizing 1,3-butadiene |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE646578A (enrdf_load_stackoverflow) |
| DE (1) | DE1300238B (enrdf_load_stackoverflow) |
| ES (1) | ES298688A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1009950A (enrdf_load_stackoverflow) |
| NL (2) | NL6404066A (enrdf_load_stackoverflow) |
| SE (1) | SE327541B (enrdf_load_stackoverflow) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL296313A (enrdf_load_stackoverflow) * | 1961-08-08 |
-
0
- NL NL126426D patent/NL126426C/xx active
-
1964
- 1964-04-14 ES ES298688A patent/ES298688A1/es not_active Expired
- 1964-04-15 NL NL6404066A patent/NL6404066A/xx unknown
- 1964-04-15 SE SE463364A patent/SE327541B/xx unknown
- 1964-04-15 DE DE1964P0034047 patent/DE1300238B/de active Pending
- 1964-04-15 GB GB1568764A patent/GB1009950A/en not_active Expired
- 1964-04-15 BE BE646578D patent/BE646578A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE646578A (enrdf_load_stackoverflow) | 1964-10-15 |
| ES298688A1 (es) | 1964-10-16 |
| NL126426C (enrdf_load_stackoverflow) | |
| NL6404066A (enrdf_load_stackoverflow) | 1964-10-16 |
| DE1300238B (de) | 1969-07-31 |
| SE327541B (enrdf_load_stackoverflow) | 1970-08-24 |
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