GB1407569A - Process for preparing ethylene homo-or co-polymers and the catalyst therefor - Google Patents

Process for preparing ethylene homo-or co-polymers and the catalyst therefor

Info

Publication number
GB1407569A
GB1407569A GB2622373A GB2622373A GB1407569A GB 1407569 A GB1407569 A GB 1407569A GB 2622373 A GB2622373 A GB 2622373A GB 2622373 A GB2622373 A GB 2622373A GB 1407569 A GB1407569 A GB 1407569A
Authority
GB
United Kingdom
Prior art keywords
ticl
formula
aluminium
compound
june
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2622373A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP5645472A external-priority patent/JPS513516B2/ja
Priority claimed from JP47056455A external-priority patent/JPS513517B2/ja
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Publication of GB1407569A publication Critical patent/GB1407569A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1407569 Tri-component Ziegler catalyst ASAHI KASEI KOGYO KK 1 June 1973 [8 June 1972 (2)] 26223/73 Heading C3P [Also in Division C2] Ethylene is homo- or copolymerized in the presence of as catalyst (A) a hydrocarboninsoluble reaction product of (i) an organoaluminium compound of the formula R a Al(OR) 3-a , where R is a hydrocarbon group and a is 2À20 to 2À85, with (ii) a titanium compound containing at least three halide groups, at a temperature up to 50‹ C., (B) (iii) an organo-aluminium compound of the formula R b Al(OR) 3-b where b is 2À02 to 2À20, or (iv) a compound of the formula AlR c (OR) d X 3-(c+d) where X is halogen, c is 1À0 to 2À0 and d is 0À1 to 0À9, and (C) a titanium compound of formula (RO) e TiCl 4-e where e is 1À0-2À0. Components A (i) and B (iii) can be obtained by reacting the corresponding trihydrocarbyl- and trihydrocarbyloxy-aluminium compounds, while component B (iv) may be obtained by reaction of the corresponding dihydrocarbyl aluminium hydrocarbyloxide and hydrocarbyl aluminium mono-, di- or sesquihalides. In typical examples polyethylene or ethylene-propylene copolymer are obtained using heptane reaction medium and hydrogen gas, and catalysts of (A) (C 2 H 5 ) 2À40 Al(OC 2 H 5 ) 0À60 - TiCl 4 (C 2 H 5 ) 2À80 Al(OC 2 H 5 ) 0À20 - TiCl 4 (C 2 H 5 ) 2À80 Al(OC 2 H 5 ) 0À20 - TiCl 3À5 - (OC 4 - H 9 ) 0À5 , (i-C 4 H 9 ) 2À4 Al(OC 2 H 5 ) 0À6 - TiCl 4 or (CH 3 ) 1À0 (C 2 H 5 ) 1À55 Al(O-n-C 4 H 9 ) 0À45 - Ti(O-n- C 4 H 9 ) 0À5 Cl 3À5 , (B) Al(C 2 H 5 ) 2À20 (OC 2 H 5 ) 0À80 or (n - C 6 H 3 ) 2 Al(OC 2 H 5 ) 0À67 Cl 0À33 , and (C) T : (OC 4 H 9 )Cl 3 , Ti(OC 4 H 9 ) 1À5 Cl 2À5 , Ti(OC 8 H 17 )Cl 3 or Ti(OC 2 H 5 ) 2 Cl 2 , or, in control procedures, TiCl 4 or Ti(OC 4 H 9 ) 4 .
GB2622373A 1972-06-08 1973-06-01 Process for preparing ethylene homo-or co-polymers and the catalyst therefor Expired GB1407569A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP5645472A JPS513516B2 (en) 1972-06-08 1972-06-08
JP47056455A JPS513517B2 (en) 1972-06-08 1972-06-08

Publications (1)

Publication Number Publication Date
GB1407569A true GB1407569A (en) 1975-09-24

Family

ID=26397395

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2622373A Expired GB1407569A (en) 1972-06-08 1973-06-01 Process for preparing ethylene homo-or co-polymers and the catalyst therefor

Country Status (4)

Country Link
DE (1) DE2329087C3 (en)
ES (1) ES415647A1 (en)
GB (1) GB1407569A (en)
RO (1) RO63445A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5222794B2 (en) * 1974-05-16 1977-06-20
GB2030156B (en) * 1978-09-11 1983-01-19 Asahi Chemical Ind Catalyst for preparating a polyolefin

Also Published As

Publication number Publication date
ES415647A1 (en) 1976-12-16
RO63445A (en) 1978-07-15
DE2329087C3 (en) 1980-09-11
DE2329087A1 (en) 1973-12-20
DE2329087B2 (en) 1979-12-20

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee