GB1007165A - Process for the manufacture of stable aqueous dispersions of vinyl ester polymers - Google Patents
Process for the manufacture of stable aqueous dispersions of vinyl ester polymersInfo
- Publication number
- GB1007165A GB1007165A GB17555/62A GB1755562A GB1007165A GB 1007165 A GB1007165 A GB 1007165A GB 17555/62 A GB17555/62 A GB 17555/62A GB 1755562 A GB1755562 A GB 1755562A GB 1007165 A GB1007165 A GB 1007165A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl acetate
- vinyl
- polyethylene glycol
- polyvinyl alcohol
- acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001567 vinyl ester resin Polymers 0.000 title abstract 5
- 239000006185 dispersion Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 9
- 229920000578 graft copolymer Polymers 0.000 abstract 6
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 6
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract 6
- 239000002202 Polyethylene glycol Substances 0.000 abstract 5
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 5
- 229920001223 polyethylene glycol Polymers 0.000 abstract 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- 239000003995 emulsifying agent Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 1
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- VYGBQXDNOUHIBZ-UHFFFAOYSA-L sodium formaldehyde sulphoxylate Chemical compound [Na+].[Na+].O=C.[O-]S[O-] VYGBQXDNOUHIBZ-UHFFFAOYSA-L 0.000 abstract 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 abstract 1
- 229940070710 valerate Drugs 0.000 abstract 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 abstract 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
- C08F261/02—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols
- C08F261/04—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols on to polymers of vinyl alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF33867A DE1169670B (de) | 1961-05-06 | 1961-05-06 | Verfahren zur Herstellung von stabilen waessrigen Dispersionen von Vinylester-Polymerisaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1007165A true GB1007165A (en) | 1965-10-13 |
Family
ID=7095296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17555/62A Expired GB1007165A (en) | 1961-05-06 | 1962-05-07 | Process for the manufacture of stable aqueous dispersions of vinyl ester polymers |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3301805A (enrdf_load_stackoverflow) |
| AT (1) | AT239530B (enrdf_load_stackoverflow) |
| BE (1) | BE617324A (enrdf_load_stackoverflow) |
| CH (1) | CH453683A (enrdf_load_stackoverflow) |
| DE (1) | DE1169670B (enrdf_load_stackoverflow) |
| GB (1) | GB1007165A (enrdf_load_stackoverflow) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1122397A (en) * | 1964-08-04 | 1968-08-07 | Ici Ltd | Polymer dispersion and dispersants |
| DE1260145B (de) * | 1965-02-05 | 1968-02-01 | Basf Ag | Verfahren zur Herstellung von Polymerisatdispersionen |
| DE1260791B (de) * | 1965-05-26 | 1968-02-08 | Hoechst Ag | Verfahren zur Herstellung von waessrigen Vinylesterhomo- oder -copolymerisatdispersionen |
| SE341637B (enrdf_load_stackoverflow) * | 1967-07-08 | 1972-01-10 | Hoechst Ag | |
| US4348309A (en) * | 1980-10-09 | 1982-09-07 | The Dow Chemical Company | Preparation of vinyl ester resin polymer spheres |
| JP2735847B2 (ja) * | 1988-12-12 | 1998-04-02 | 三菱レイヨン株式会社 | トナー用重合体の製造法 |
| DE3902536A1 (de) * | 1989-01-28 | 1990-08-16 | Akzo Gmbh | Sterisch stabilisierte waessrige polymer-dispersionen |
| DE19901307C1 (de) | 1999-01-15 | 2000-06-21 | Clariant Gmbh | Dispersionspulver enthaltend teilacetalisierte, wasserlösliche Polyvinylalkohole, Verfahren zu deren Herstellung sowie deren Verwendung |
| US6673862B1 (en) * | 1999-12-10 | 2004-01-06 | Air Products Polymers, L.P. | Vinyl acetate ethylene emulsions stabilized with poly(ethylene/poly (vinyl alcohol) blend |
| DE102005003122A1 (de) * | 2005-01-21 | 2006-07-27 | Henkel Kgaa | Antiadhäsive Polymere zur Verhinderung der Adhäsion von Mikroorganismen an Textilien und zur Verhinderung von Wäschegeruch |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB834900A (en) * | 1955-09-08 | 1960-05-11 | Celanese Corp | Emulsions |
| GB857514A (en) * | 1956-01-30 | 1960-12-29 | Lewis Berger & Sons Ltd | Improvements in or relating to the production of emulsion polymers and aqueous mediatherefor |
| BE574616A (enrdf_load_stackoverflow) * | 1958-01-10 | |||
| DE1077430B (de) * | 1958-04-15 | 1960-03-10 | Hoechst Ag | Verfahren zur Herstellung von Pfropfpolymerisaten von Polyvinylestern |
| NL125862C (enrdf_load_stackoverflow) * | 1958-04-24 | |||
| US3218281A (en) * | 1958-09-22 | 1965-11-16 | Shawinigan Chem Ltd | Polymer emulsions with vinyl acetate-polyoxyalkylene compound copolymer as stabilizer |
| US3030326A (en) * | 1959-06-10 | 1962-04-17 | Nat Starch Chem Corp | Preparing a graft copolymer of vinyl acetate and a propylene oxide, ethylene oxide and ethylene diamine reaction product and compositions containing same |
-
0
- BE BE617324D patent/BE617324A/xx unknown
-
1961
- 1961-05-06 DE DEF33867A patent/DE1169670B/de active Pending
-
1962
- 1962-05-04 CH CH534062A patent/CH453683A/de unknown
- 1962-05-04 AT AT364662A patent/AT239530B/de active
- 1962-05-07 US US192645A patent/US3301805A/en not_active Expired - Lifetime
- 1962-05-07 GB GB17555/62A patent/GB1007165A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AT239530B (de) | 1965-04-12 |
| DE1169670B (de) | 1964-05-06 |
| BE617324A (enrdf_load_stackoverflow) | |
| CH453683A (de) | 1968-03-31 |
| US3301805A (en) | 1967-01-31 |
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