FR3135086B1 - Composition silicone réticulable par irradiation comprenant du Pt(octane-2,4-dione)2 comme catalyseur - Google Patents

Composition silicone réticulable par irradiation comprenant du Pt(octane-2,4-dione)2 comme catalyseur Download PDF

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Publication number
FR3135086B1
FR3135086B1 FR2204023A FR2204023A FR3135086B1 FR 3135086 B1 FR3135086 B1 FR 3135086B1 FR 2204023 A FR2204023 A FR 2204023A FR 2204023 A FR2204023 A FR 2204023A FR 3135086 B1 FR3135086 B1 FR 3135086B1
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Prior art keywords
silicone composition
dione
octane
catalyst
radiation
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FR2204023A
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FR3135086A1 (fr
Inventor
Cédric Ysacco
Jean Raynaud
Vincent Monteil
Cyril Bosset
Vivien Henryon
Jérôme Monbrun
Perrine Theil
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Activation
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Elkem Silicones France SAS
Universite Claude Bernard Lyon 1
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Activation
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Elkem Silicones France SAS
Universite Claude Bernard Lyon 1
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Priority to FR2204023A priority Critical patent/FR3135086B1/fr
Application filed by Activation, Centre National de la Recherche Scientifique CNRS, Ecole Superieure de Chimie Physique Electronique de Lyon, Elkem Silicones France SAS, Universite Claude Bernard Lyon 1 filed Critical Activation
Priority to PCT/EP2023/061214 priority patent/WO2023209140A1/fr
Priority to CN202380035939.9A priority patent/CN120344315A/zh
Priority to EP23723184.0A priority patent/EP4514534A1/fr
Priority to US18/859,727 priority patent/US20250197671A1/en
Priority to JP2024563891A priority patent/JP2025514392A/ja
Priority to KR1020247038681A priority patent/KR20250094626A/ko
Publication of FR3135086A1 publication Critical patent/FR3135086A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/32—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming a linkage containing silicon in the main chain of the macromolecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11—Compounds covalently bound to a solid support
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C07F15/0093—Platinum compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)

Abstract

La présente invention a pour objet une composition silicone X réticulable par des réactions de polyaddition pour former un élastomère silicone. En particulier, la présente invention a pour objet une composition silicone X réticulable par irradiation photonique catalysée par un catalyseur d’hydrosilylation C qui est du Pt(octane-2,4-dione)2.
FR2204023A 2022-04-28 2022-04-28 Composition silicone réticulable par irradiation comprenant du Pt(octane-2,4-dione)2 comme catalyseur Active FR3135086B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2204023A FR3135086B1 (fr) 2022-04-28 2022-04-28 Composition silicone réticulable par irradiation comprenant du Pt(octane-2,4-dione)2 comme catalyseur
CN202380035939.9A CN120344315A (zh) 2022-04-28 2023-04-28 包含Pt(辛烷-2,4-二酮)2作为催化剂的可辐射交联组合物
EP23723184.0A EP4514534A1 (fr) 2022-04-28 2023-04-28 Composition silicone réticulable par irradiation comprenant du pt(octane-2,4-dione)2 comme catalyseur
US18/859,727 US20250197671A1 (en) 2022-04-28 2023-04-28 Irradiation-crosslinkable silicone composition comprising pt(octane-2,4-dione)2 as a catalyst
PCT/EP2023/061214 WO2023209140A1 (fr) 2022-04-28 2023-04-28 Composition silicone réticulable par irradiation comprenant du pt(octane-2,4-dione)2 comme catalyseur
JP2024563891A JP2025514392A (ja) 2022-04-28 2023-04-28 Ｐｔ（オクタン－２，４－ジオン）２を触媒として含む照射架橋性組成物
KR1020247038681A KR20250094626A (ko) 2022-04-28 2023-04-28 촉매로 Pt(옥탄-2,4-디온)2를 포함하는 조사-가교성 조성물

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2204023A FR3135086B1 (fr) 2022-04-28 2022-04-28 Composition silicone réticulable par irradiation comprenant du Pt(octane-2,4-dione)2 comme catalyseur
FR2204023 2022-04-28

Publications (2)

Publication Number Publication Date
FR3135086A1 FR3135086A1 (fr) 2023-11-03
FR3135086B1 true FR3135086B1 (fr) 2025-07-04

Family

ID=82019492

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2204023A Active FR3135086B1 (fr) 2022-04-28 2022-04-28 Composition silicone réticulable par irradiation comprenant du Pt(octane-2,4-dione)2 comme catalyseur

Country Status (7)

Country Link
US (1) US20250197671A1 (fr)
EP (1) EP4514534A1 (fr)
JP (1) JP2025514392A (fr)
KR (1) KR20250094626A (fr)
CN (1) CN120344315A (fr)
FR (1) FR3135086B1 (fr)
WO (1) WO2023209140A1 (fr)

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US346A (en) 1837-08-08 Improved mode of protecting the metallic sheathing of vessels
US4347A (en) 1845-12-31 Medicated bath
US3188299A (en) 1963-02-28 1965-06-08 Gen Electric Preparation of stable mixtures of organosilicon compositions in the presence of a nitrogen-containing ligand
NL129346C (fr) 1966-06-23
US3923705A (en) 1974-10-30 1975-12-02 Dow Corning Method of preparing fire retardant siloxane foams and foams prepared therefrom
US3989667A (en) 1974-12-02 1976-11-02 Dow Corning Corporation Olefinic siloxanes as platinum inhibitors
US4256870A (en) 1979-05-17 1981-03-17 General Electric Company Solventless release compositions, methods and articles of manufacture
CA2014996A1 (fr) 1989-05-19 1990-11-19 Joel D. Oxman Reaction d'hydrosilation activee par les rayonnements
FR2717482B1 (fr) 1994-03-18 1996-06-21 Rhone Poulenc Chimie Complexes organoplatiniques et systèmes catalytiques photoactivables d'hydrosilylation en contenant.
WO2010051355A2 (fr) * 2008-10-31 2010-05-06 Dow Corning Corporation Module de piles photovoltaïques et procédé de formation
EP2938678B1 (fr) * 2012-12-27 2018-12-19 Dow Silicones Corporation Composition pour former un article ayant une excellente réflectance et d'excellentes propriétés ignifugeantes et article formé à partir de celle-ci
CN112980355B (zh) * 2021-04-23 2022-05-27 上海锐朗光电材料有限公司 一种uv光和热双重固化高气密性聚异丁烯胶及其制备方法

Also Published As

Publication number Publication date
FR3135086A1 (fr) 2023-11-03
CN120344315A (zh) 2025-07-18
JP2025514392A (ja) 2025-05-02
WO2023209140A1 (fr) 2023-11-02
US20250197671A1 (en) 2025-06-19
KR20250094626A (ko) 2025-06-25
EP4514534A1 (fr) 2025-03-05

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