FR3113057B1 - Agent épaississant pour composition hydro-alcoolique - Google Patents

Agent épaississant pour composition hydro-alcoolique Download PDF

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Publication number
FR3113057B1
FR3113057B1 FR2008245A FR2008245A FR3113057B1 FR 3113057 B1 FR3113057 B1 FR 3113057B1 FR 2008245 A FR2008245 A FR 2008245A FR 2008245 A FR2008245 A FR 2008245A FR 3113057 B1 FR3113057 B1 FR 3113057B1
Authority
FR
France
Prior art keywords
hydro
thickening agent
alcoholic composition
acrylamide
methylol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2008245A
Other languages
English (en)
Other versions
FR3113057A1 (fr
Inventor
Yves Kensicher
Benoît Magny
Laurie Parrenin
Jean-Marc Suau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coatex SAS
Original Assignee
Coatex SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Coatex SAS filed Critical Coatex SAS
Priority to FR2008245A priority Critical patent/FR3113057B1/fr
Priority to CN202180057548.8A priority patent/CN116096342A/zh
Priority to PCT/FR2021/000087 priority patent/WO2022029372A1/fr
Priority to US18/005,893 priority patent/US20230287162A1/en
Priority to EP21762068.1A priority patent/EP4188970A1/fr
Publication of FR3113057A1 publication Critical patent/FR3113057A1/fr
Application granted granted Critical
Publication of FR3113057B1 publication Critical patent/FR3113057B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52Amides or imides
    • C08F220/54Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26Emulsion polymerisation with the aid of emulsifying agents anionic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Cosmetics (AREA)

Abstract

L’invention concerne un agent P épaississant pour composition aqueuse, en particulier pour composition hydro-alcoolique. L’agent épaississant P est préparé en l’absence d’acrylamide par une réaction de polymérisation mettant en œuvre du N-méthylol-acrylamide ou l’un de ses dérivés, un acide et un ester d’acide. Un condensat particulier d’acide (méth)acrylique et de N-méthylol-acrylamide fait partie de l’invention. L’invention fournit également une composition hydro-alcoolique dont la viscosité est contrôlée.
FR2008245A 2020-08-03 2020-08-03 Agent épaississant pour composition hydro-alcoolique Active FR3113057B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR2008245A FR3113057B1 (fr) 2020-08-03 2020-08-03 Agent épaississant pour composition hydro-alcoolique
CN202180057548.8A CN116096342A (zh) 2020-08-03 2021-07-29 用于水醇组合物的增稠剂
PCT/FR2021/000087 WO2022029372A1 (fr) 2020-08-03 2021-07-29 Agent epaississant pour composition hydro-alcoolique
US18/005,893 US20230287162A1 (en) 2020-08-03 2021-07-29 Thickening agent for a hydro-alcoholic composition
EP21762068.1A EP4188970A1 (fr) 2020-08-03 2021-07-29 Agent epaississant pour composition hydro-alcoolique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2008245A FR3113057B1 (fr) 2020-08-03 2020-08-03 Agent épaississant pour composition hydro-alcoolique
FR2008245 2020-08-03

Publications (2)

Publication Number Publication Date
FR3113057A1 FR3113057A1 (fr) 2022-02-04
FR3113057B1 true FR3113057B1 (fr) 2023-09-29

Family

ID=74045563

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2008245A Active FR3113057B1 (fr) 2020-08-03 2020-08-03 Agent épaississant pour composition hydro-alcoolique

Country Status (5)

Country Link
US (1) US20230287162A1 (fr)
EP (1) EP4188970A1 (fr)
CN (1) CN116096342A (fr)
FR (1) FR3113057B1 (fr)
WO (1) WO2022029372A1 (fr)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4828555B1 (fr) 1969-07-14 1973-09-03
FR2087531A5 (fr) * 1970-05-22 1971-12-31 Ugine Kuhlmann
JPS512114B2 (fr) * 1971-08-18 1976-01-23
DE2531235A1 (de) * 1975-07-12 1977-02-03 Basf Ag Verdickungsmittel fuer polymerisatdispersionen
FR2872815B1 (fr) * 2004-07-08 2008-06-27 Coatex Soc Par Actions Simplif Utilisation de copolymeres acryliques hydrosolubles dans des formations aqueuses eventuellement pigmentees et formulations obtenues
FR2879607B1 (fr) * 2004-12-16 2007-03-30 Seppic Sa Nouveaux latex inverse concentre, procede pour sa preparation, et utilisation dans l'industrie
IN2014MN01461A (fr) * 2012-01-31 2015-04-17 Unilever Plc
FR2987839B1 (fr) * 2012-03-08 2014-05-09 Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic Nouveau polymere d'acrylate de silicone et d'acide acrylique epaississant et reduisant le caractere collant des formules cosmetiques a base de glycerine
JP2019003926A (ja) * 2017-06-09 2019-01-10 松本油脂製薬株式会社 蓄電デバイススラリー及びその利用

Also Published As

Publication number Publication date
WO2022029372A1 (fr) 2022-02-10
CN116096342A (zh) 2023-05-09
EP4188970A1 (fr) 2023-06-07
FR3113057A1 (fr) 2022-02-04
US20230287162A1 (en) 2023-09-14

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