FR3104603B1 - Utilisation d’un catalyseur a base d’izm-2 ayant une faible teneur en alcalin pour l’isomerisation de charges paraffiniques en distillats moyens - Google Patents

Utilisation d’un catalyseur a base d’izm-2 ayant une faible teneur en alcalin pour l’isomerisation de charges paraffiniques en distillats moyens Download PDF

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Publication number
FR3104603B1
FR3104603B1 FR1914593A FR1914593A FR3104603B1 FR 3104603 B1 FR3104603 B1 FR 3104603B1 FR 1914593 A FR1914593 A FR 1914593A FR 1914593 A FR1914593 A FR 1914593A FR 3104603 B1 FR3104603 B1 FR 3104603B1
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FR
France
Prior art keywords
ppm
weight
preferably less
catalyst
izm
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FR1914593A
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English (en)
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FR3104603A1 (fr
Inventor
Christophe Bouchy
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1914593A priority Critical patent/FR3104603B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to US17/785,197 priority patent/US20230019569A1/en
Priority to EP20819768.1A priority patent/EP4077595A1/fr
Priority to PCT/EP2020/085217 priority patent/WO2021122198A1/fr
Priority to JP2022536736A priority patent/JP2023506856A/ja
Priority to CN202080087880.4A priority patent/CN114929841A/zh
Priority to BR112022010601A priority patent/BR112022010601A2/pt
Publication of FR3104603A1 publication Critical patent/FR3104603A1/fr
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Publication of FR3104603B1 publication Critical patent/FR3104603B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La présente invention concerne un procédé d'isomérisation de charges paraffiniques opérant à une température comprise entre 200°C et 500°C, à une pression totale comprise entre 0,45 MPa et 7 MPa, à une pression partielle d’hydrogène comprise entre 0,3 et 5,5 MPa, à une vitesse spatiale horaire comprise entre 0,1 et 10 kilogramme de charge introduite par kilogramme de catalyseur et par heure et mettant en œuvre un catalyseur comprenant au moins un métal du groupe VIII de la classification périodique des éléments, au moins une matrice et au moins une zéolithe IZM-2, ledit catalyseur étant caractérisé en ce que la teneur pondérale totale en éléments alcalin et/ou alcalinoterreux est inférieure à 200 ppm en poids par rapport à la masse totale dudit catalyseur, de préférence inférieure à 150 ppm, de manière préférée inférieure à 100 ppm, de préférence inférieure à 90 ppm en poids, de manière préférée inférieure à 85 ppm en poids de manière plus préférée inférieure à 80 ppm en poids, de manière très préférée inférieure à 75 ppm en poids et de manière encore plus préférée inférieure à 70 ppm en poids et supérieure à 20 ppm en poids et de préférence supérieur à 30 ppm en poids.
FR1914593A 2019-12-17 2019-12-17 Utilisation d’un catalyseur a base d’izm-2 ayant une faible teneur en alcalin pour l’isomerisation de charges paraffiniques en distillats moyens Active FR3104603B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1914593A FR3104603B1 (fr) 2019-12-17 2019-12-17 Utilisation d’un catalyseur a base d’izm-2 ayant une faible teneur en alcalin pour l’isomerisation de charges paraffiniques en distillats moyens
EP20819768.1A EP4077595A1 (fr) 2019-12-17 2020-12-09 Utilisation d'un catalyseur a base d'izm-2 ayant une faible teneur en alcalin pour l'isomerisation de charges paraffiniques en distillats moyens
PCT/EP2020/085217 WO2021122198A1 (fr) 2019-12-17 2020-12-09 Utilisation d'un catalyseur a base d'izm-2 ayant une faible teneur en alcalin pour l'isomerisation de charges paraffiniques en distillats moyens
JP2022536736A JP2023506856A (ja) 2019-12-17 2020-12-09 パラフィン系供給原料の中間留分への異性化のための、低アルカリ金属含有率を有するｉｚｍ－２をベースとする触媒の使用
US17/785,197 US20230019569A1 (en) 2019-12-17 2020-12-09 Use of a catalyst based on izm-2 with a content of low alkali metal for the isomerization of paraffinic feedstocks to middle distillates
CN202080087880.4A CN114929841A (zh) 2019-12-17 2020-12-09 具有低碱金属含量的基于izm-2的催化剂用于将链烷烃原料异构化为中间馏出物的用途
BR112022010601A BR112022010601A2 (pt) 2019-12-17 2020-12-09 Utilização de um catalisador à base de izm-2 tendo um baixo teor de alcalino para a isomerização de cargas parafínicas em destilados médios

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1914593A FR3104603B1 (fr) 2019-12-17 2019-12-17 Utilisation d’un catalyseur a base d’izm-2 ayant une faible teneur en alcalin pour l’isomerisation de charges paraffiniques en distillats moyens
FR1914593 2019-12-17

Publications (2)

Publication Number Publication Date
FR3104603A1 FR3104603A1 (fr) 2021-06-18
FR3104603B1 true FR3104603B1 (fr) 2022-07-22

Family

ID=69700187

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1914593A Active FR3104603B1 (fr) 2019-12-17 2019-12-17 Utilisation d’un catalyseur a base d’izm-2 ayant une faible teneur en alcalin pour l’isomerisation de charges paraffiniques en distillats moyens

Country Status (7)

Country Link
US (1) US20230019569A1 (fr)
EP (1) EP4077595A1 (fr)
JP (1) JP2023506856A (fr)
CN (1) CN114929841A (fr)
BR (1) BR112022010601A2 (fr)
FR (1) FR3104603B1 (fr)
WO (1) WO2021122198A1 (fr)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2642414B1 (fr) 1989-02-01 1991-04-26 Rhone Poulenc Chimie Procede de fabrication d'agglomeres d'alumine active, agglomeres obtenus par le procede et dispositif pour sa mise en oeuvre
FR2910483B1 (fr) 2006-12-21 2010-07-30 Inst Francais Du Petrole Procede de conversion de charges issues de sources renouvelables en bases carburants gazoles de bonne qualite.
FR2918050B1 (fr) 2007-06-29 2011-05-06 Inst Francais Du Petrole Solide cristallise izm-2 et son procede de preparation
FR2934794B1 (fr) * 2008-08-08 2010-10-22 Inst Francais Du Petrole Procede de production de distillats moyens par hydrocraquage de charges issues du procede fischer-trospch en presence d'un catalyseur comprenant un solide izm-2
FR2950895B1 (fr) 2009-10-06 2012-02-17 Inst Francais Du Petrole Procede d'hydrotraitement et d'hydroisomerisation de charges issues de source renouvelable mettant en oeuvre un catalyseur a base de carbure de silicium
FR2984911B1 (fr) * 2011-12-22 2014-08-29 IFP Energies Nouvelles Procede de conversion de charges paraffiniques issues de la biomasse en bases distillats moyens mettant en oeuvre au moins un catalyseur a base de zeolithe izm-2
US20140296601A1 (en) * 2013-03-29 2014-10-02 Uop Llc Isomerization process with mtw catalyst
FR3074428B1 (fr) 2017-12-06 2022-01-21 Ifp Energies Now Procede de preparation d'un catalyseur a base d'izm-2 a partir d'une solution comprenant des precurseurs specifiques et utilisation pour l'isomerisation de charges paraffiniques

Also Published As

Publication number Publication date
FR3104603A1 (fr) 2021-06-18
US20230019569A1 (en) 2023-01-19
CN114929841A (zh) 2022-08-19
JP2023506856A (ja) 2023-02-20
WO2021122198A1 (fr) 2021-06-24
EP4077595A1 (fr) 2022-10-26
BR112022010601A2 (pt) 2022-08-16

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