FR3102373B1 - catalyseur à base de molybdate de bismuth - Google Patents

catalyseur à base de molybdate de bismuth Download PDF

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Publication number
FR3102373B1
FR3102373B1 FR1911836A FR1911836A FR3102373B1 FR 3102373 B1 FR3102373 B1 FR 3102373B1 FR 1911836 A FR1911836 A FR 1911836A FR 1911836 A FR1911836 A FR 1911836A FR 3102373 B1 FR3102373 B1 FR 3102373B1
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FR
France
Prior art keywords
catalyst
bismuth molybdate
precursors
catalytic system
molybdate catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1911836A
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English (en)
Other versions
FR3102373A1 (fr
Inventor
Virginie Belliere-Baca
Jean-Marc Millet
Aziz Cherifi
Catarina Rocha
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite Claude Bernard Lyon 1 UCBL
Adisseo France SAS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite Claude Bernard Lyon 1 UCBL
Adisseo France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite Claude Bernard Lyon 1 UCBL, Adisseo France SAS filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1911836A priority Critical patent/FR3102373B1/fr
Priority to TW109125792A priority patent/TW202112444A/zh
Priority to JP2022505270A priority patent/JP2022542370A/ja
Priority to US17/631,717 priority patent/US20220266223A1/en
Priority to KR1020227006519A priority patent/KR20220037501A/ko
Priority to PCT/FR2020/051408 priority patent/WO2021019188A1/fr
Priority to EP20820241.6A priority patent/EP4003592A1/fr
Priority to CN202080055816.8A priority patent/CN114650880A/zh
Publication of FR3102373A1 publication Critical patent/FR3102373A1/fr
Application granted granted Critical
Publication of FR3102373B1 publication Critical patent/FR3102373B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/344—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy
    • B01J37/346—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy of microwave energy
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Electromagnetism (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L’invention concerne un procédé pour la fabrication d’un catalyseur d’oxydes mixtes et multiphasique comprenant au moins une phase active à base de molybdate de bismuth et un co-catalyseur à base de molybdate de fer et d’au moins l’un des deux éléments cobalt et nickel, ledit procédé comprenant les étapes suivantes : on prépare un mélange des précurseurs desdits oxydes mixtes dans un solvant, on fait réagir lesdits précurseurs par réaction hydrothermale assistée par microondes, et on isole les oxydes mixtes pour obtenir le catalyseur. Un catalyseur et un système catalytique ainsi préparés font l’objet de l’invention ainsi que les utilisations de ce catalyseur et ce système catalytique, notamment dans l’oxydation du propène en acroléine.
FR1911836A 2019-07-31 2019-10-23 catalyseur à base de molybdate de bismuth Active FR3102373B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1911836A FR3102373B1 (fr) 2019-10-23 2019-10-23 catalyseur à base de molybdate de bismuth
TW109125792A TW202112444A (zh) 2019-07-31 2020-07-30 基於鉬酸鉍之催化劑
US17/631,717 US20220266223A1 (en) 2019-07-31 2020-07-31 Bismuth molybdate-based catalyst, process for the production thereof and use of this catalyst in the oxidation of propene to acrolein
KR1020227006519A KR20220037501A (ko) 2019-07-31 2020-07-31 비스무트 몰리브덴산염계 촉매, 이의 제조 방법 및 프로펜의 아크롤레인으로의 산화에서의 이 촉매의 용도
JP2022505270A JP2022542370A (ja) 2019-07-31 2020-07-31 モリブデン酸ビスマス系触媒、その製造方法及びプロペンをアクロレインとする酸化におけるこの触媒の使用
PCT/FR2020/051408 WO2021019188A1 (fr) 2019-07-31 2020-07-31 Catalyseur à base de molybdate de bismuth, procédé de sa fabrication et utilisation de ce catalyseur dans l'oxydation du propène en acroléine
EP20820241.6A EP4003592A1 (fr) 2019-07-31 2020-07-31 Catalyseur à base de molybdate de bismuth, procédé de sa fabrication et utilisation de ce catalyseur dans l'oxydation du propène en acroléine
CN202080055816.8A CN114650880A (zh) 2019-07-31 2020-07-31 钼酸铋基催化剂、其制备方法和该催化剂在丙烯氧化成丙烯醛中的用途

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1911836A FR3102373B1 (fr) 2019-10-23 2019-10-23 catalyseur à base de molybdate de bismuth
FR1911836 2019-10-23

Publications (2)

Publication Number Publication Date
FR3102373A1 FR3102373A1 (fr) 2021-04-30
FR3102373B1 true FR3102373B1 (fr) 2022-10-21

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FR1911836A Active FR3102373B1 (fr) 2019-07-31 2019-10-23 catalyseur à base de molybdate de bismuth

Country Status (1)

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115845879A (zh) * 2022-09-26 2023-03-28 汉江师范学院 简单水热法合成MoS2/Bi2MoO6复合材料的方法及其高效降解环丙沙星

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060183626A1 (en) * 2005-02-11 2006-08-17 Cavalcanti Fernando Antonio Pe Process for preparing catalysts and catalysts produced therefrom
EP3219386A1 (fr) 2016-03-14 2017-09-20 Evonik Degussa GmbH Procédé de fabrication hydrothermal de catalyseurs d'oxydes mixtes à base de molybdène, bismuth, cobalt et fer

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FR3102373A1 (fr) 2021-04-30

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