FR3099173B1 - Procédé de production d'une essence a basse teneur en soufre et en mercaptans - Google Patents

Procédé de production d'une essence a basse teneur en soufre et en mercaptans Download PDF

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Publication number
FR3099173B1
FR3099173B1 FR1908338A FR1908338A FR3099173B1 FR 3099173 B1 FR3099173 B1 FR 3099173B1 FR 1908338 A FR1908338 A FR 1908338A FR 1908338 A FR1908338 A FR 1908338A FR 3099173 B1 FR3099173 B1 FR 3099173B1
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France
Prior art keywords
metal
gasoline
mercaptans
production
low sulfur
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Active
Application number
FR1908338A
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English (en)
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FR3099173A1 (fr
Inventor
Clementina Lopez-Garcia
Philibert Leflaive
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1908338A priority Critical patent/FR3099173B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to CN202080053034.0A priority patent/CN114127235B/zh
Priority to EP20736701.2A priority patent/EP4004159A1/fr
Priority to KR1020227002012A priority patent/KR20220035392A/ko
Priority to PCT/EP2020/069032 priority patent/WO2021013526A1/fr
Priority to US17/629,067 priority patent/US11866656B2/en
Priority to BR112021024801A priority patent/BR112021024801A2/pt
Publication of FR3099173A1 publication Critical patent/FR3099173A1/fr
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Publication of FR3099173B1 publication Critical patent/FR3099173B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/38—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/06—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a selective hydrogenation of the diolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/14—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature

Abstract

La présente demande concerne un procédé de traitement d'une essence contenant des composés soufrés, des oléfines et des dioléfines comprenant les étapes suivantes:a) une étape d'hydrodésulfuration en présence d’un catalyseur comprenant un support d’oxyde et une phase active comprenant un métal du groupe VIB et un métal du groupe VIII,b) une étape d'hydrodésulfuration d’au moins une partie de l’effluent de l’étape a) à un rapport débit hydrogène/charge plus élevé et à une température plus élevés que ceux de l’étape a) sans élimination de l’H2S formé en présence d’un catalyseur comprenant un support d’oxyde et une phase active constituée d’au moins un métal du groupe VIII, c) une étape de séparation de l'H2S formé dans l’effluent issu de l’étape b).
FR1908338A 2019-07-23 2019-07-23 Procédé de production d'une essence a basse teneur en soufre et en mercaptans Active FR3099173B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1908338A FR3099173B1 (fr) 2019-07-23 2019-07-23 Procédé de production d'une essence a basse teneur en soufre et en mercaptans
EP20736701.2A EP4004159A1 (fr) 2019-07-23 2020-07-06 Procédé de production d'une essence a basse teneur en soufre et en mercaptans
KR1020227002012A KR20220035392A (ko) 2019-07-23 2020-07-06 낮은 황 및 메르캅탄 함량을 갖는 휘발유의 제조 방법
PCT/EP2020/069032 WO2021013526A1 (fr) 2019-07-23 2020-07-06 Procédé de production d'une essence a basse teneur en soufre et en mercaptans
CN202080053034.0A CN114127235B (zh) 2019-07-23 2020-07-06 具有低硫和硫醇含量的汽油的生产方法
US17/629,067 US11866656B2 (en) 2019-07-23 2020-07-06 Method for producing a petrol with low sulphur and mercaptan content
BR112021024801A BR112021024801A2 (pt) 2019-07-23 2020-07-06 Processo de produção de uma gasolina à base de teor de enxofre e mercaptanos

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1908338 2019-07-23
FR1908338A FR3099173B1 (fr) 2019-07-23 2019-07-23 Procédé de production d'une essence a basse teneur en soufre et en mercaptans

Publications (2)

Publication Number Publication Date
FR3099173A1 FR3099173A1 (fr) 2021-01-29
FR3099173B1 true FR3099173B1 (fr) 2021-07-09

Family

ID=68581956

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1908338A Active FR3099173B1 (fr) 2019-07-23 2019-07-23 Procédé de production d'une essence a basse teneur en soufre et en mercaptans

Country Status (7)

Country Link
US (1) US11866656B2 (fr)
EP (1) EP4004159A1 (fr)
KR (1) KR20220035392A (fr)
CN (1) CN114127235B (fr)
BR (1) BR112021024801A2 (fr)
FR (1) FR3099173B1 (fr)
WO (1) WO2021013526A1 (fr)

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2230793C (fr) * 1995-08-28 2007-05-29 Chemical Research & Licensing Company Processus de desulfuration d'essence
US6231754B1 (en) 1996-02-02 2001-05-15 Exxon Research And Engineering Company High temperature naphtha desulfurization using a low metal and partially deactivated catalyst
US6409913B1 (en) 1996-02-02 2002-06-25 Exxonmobil Research And Engineering Company Naphtha desulfurization with reduced mercaptan formation
FR2797639B1 (fr) 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
US6387249B1 (en) * 1999-12-22 2002-05-14 Exxonmobil Research And Engineering Company High temperature depressurization for naphtha mercaptan removal
EP1285047A4 (fr) 2000-04-18 2003-07-23 Exxonmobil Res & Eng Co Hydrocraquage et elimination selectifs de mercaptans
FR2811328B1 (fr) 2000-07-06 2002-08-23 Inst Francais Du Petrole Procede comprenant deux etapes d'hydrodesulfuration d'essence et une elimination intermediaire de l'h2s forme au cours de la premiere etape
US6736962B1 (en) 2000-09-29 2004-05-18 Exxonmobil Research And Engineering Company Catalytic stripping for mercaptan removal (ECB-0004)
US6960291B2 (en) 2001-06-19 2005-11-01 Exxonmobil Research And Engineering Company Naphtha desulfurization method
US7799210B2 (en) 2004-05-14 2010-09-21 Exxonmobil Research And Engineering Company Process for removing sulfur from naphtha
US20070114156A1 (en) 2005-11-23 2007-05-24 Greeley John P Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition
CN101993725B (zh) * 2009-08-27 2013-06-26 中国石油化工股份有限公司 一种生产低硫汽油的方法
ITTO20120525A1 (it) 2012-06-15 2013-12-16 Sabelt Spa Fibbia di collegamento per cinture di sicurezza, in particolare per veicoli da competizione
FR2993570B1 (fr) * 2012-07-17 2015-12-04 IFP Energies Nouvelles Procede de production d'une essence legere basse teneur en soufre
FR2993569B1 (fr) * 2012-07-17 2015-12-04 IFP Energies Nouvelles Procede de desulfuration d'une essence
EP2816094B1 (fr) * 2013-06-19 2020-04-29 IFP Energies nouvelles Procédé de production d'une essence à basse teneur en soufre et en mercaptans
WO2018096063A1 (fr) 2016-11-23 2018-05-31 Haldor Topsøe A/S Procédé de désulfurisation d'hydrocarbures

Also Published As

Publication number Publication date
CN114127235A (zh) 2022-03-01
EP4004159A1 (fr) 2022-06-01
KR20220035392A (ko) 2022-03-22
US20220275291A1 (en) 2022-09-01
BR112021024801A2 (pt) 2022-04-26
FR3099173A1 (fr) 2021-01-29
CN114127235B (zh) 2024-02-27
US11866656B2 (en) 2024-01-09
WO2021013526A1 (fr) 2021-01-28

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