FR3096900B1 - Procédé et unité de purification d’hélium - Google Patents

Procédé et unité de purification d’hélium Download PDF

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Publication number
FR3096900B1
FR3096900B1 FR1906005A FR1906005A FR3096900B1 FR 3096900 B1 FR3096900 B1 FR 3096900B1 FR 1906005 A FR1906005 A FR 1906005A FR 1906005 A FR1906005 A FR 1906005A FR 3096900 B1 FR3096900 B1 FR 3096900B1
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Prior art keywords
helium
flow
purification process
enriched
unit
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FR1906005A
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FR3096900A1 (fr
Inventor
Guludec Erwan Le
Antoine Hernandez
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Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR1906005A priority Critical patent/FR3096900B1/fr
Priority to AU2020203540A priority patent/AU2020203540A1/en
Priority to RU2020118384A priority patent/RU2768434C2/ru
Priority to US16/894,205 priority patent/US11021366B2/en
Publication of FR3096900A1 publication Critical patent/FR3096900A1/fr
Priority to US17/306,655 priority patent/US20210354987A1/en
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    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/30—Helium
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30—Compression of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00—Processes or apparatus involving steps for recycling of process streams
    • F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2260/00—Coupling of processes or apparatus to other units; Integrated schemes
    • F25J2260/60—Integration in an installation using hydrocarbons, e.g. for fuel purposes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y02P20/156—Methane [CH4]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

Titre : Procédé et unité de purification d’hélium Dans un procédé de purification d’hélium, un débit (1) contenant au moins 10% d’hélium, au moins 10% d’azote, de l’hydrogène et du méthane est séparé pour former un débit (3) enrichi en hélium et contenant de l’hydrogène, un premier débit (9) enrichi en azote et en méthane et un deuxième débit (11) enrichi en azote et en méthane, le débit enrichi en hélium est traité pour produire un produit riche en hélium (7) et un gaz résiduaire (15) contenant de l’eau, le gaz résiduaire est traité par adsorption (TSA) pour enlever l’eau et le gaz de régénération (13) de l’adsorption est envoyé à une unité de combustion (O). Figure de l’abrégé : Fig. 1
FR1906005A 2019-06-06 2019-06-06 Procédé et unité de purification d’hélium Active FR3096900B1 (fr)

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FR1906005A FR3096900B1 (fr) 2019-06-06 2019-06-06 Procédé et unité de purification d’hélium
AU2020203540A AU2020203540A1 (en) 2019-06-06 2020-05-29 Helium purification process and unit
RU2020118384A RU2768434C2 (ru) 2019-06-06 2020-06-04 Способ и устройство для очистки гелия
US16/894,205 US11021366B2 (en) 2019-06-06 2020-06-05 Helium purification process and unit
US17/306,655 US20210354987A1 (en) 2019-06-06 2021-05-03 Helium purification process and unit

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FR1906005 2019-06-06
FR1906005A FR3096900B1 (fr) 2019-06-06 2019-06-06 Procédé et unité de purification d’hélium

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FR3096900B1 (fr) * 2019-06-06 2021-10-01 Air Liquide Procédé et unité de purification d’hélium
CN113144821A (zh) * 2021-04-27 2021-07-23 大连理工大学 一种富氦天然气液化尾气生产高纯氦气的多技术集成分离工艺
CN114314534B (zh) * 2022-01-14 2023-03-21 鄂尔多斯市星星能源有限公司 一种天然气提氦工艺
CN114669164B (zh) * 2022-03-24 2023-03-28 浙江大学 一种天然气bog制取高纯氦气的系统和方法
CN114674115B (zh) * 2022-04-02 2023-05-16 珠海森铂低温能源装备有限公司 一种液化天然气bog闪蒸气提取高纯氦的系统与方法
CN117945368A (zh) * 2024-03-18 2024-04-30 北京石油化工工程有限公司 一种液化天然气闪蒸气无氧脱氢的氦气回收方法与系统

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US5085674A (en) * 1990-10-25 1992-02-04 Union Carbide Industrial Gases Technology Corporation Duplex adsorption process
US5224350A (en) * 1992-05-11 1993-07-06 Advanced Extraction Technologies, Inc. Process for recovering helium from a gas stream
DE102005006408A1 (de) * 2005-02-11 2006-08-24 Linde Ag Verfahren zum Abtrennen von Spurenkomponenten aus einem Stickstoff-reichen Strom
DE102012000147A1 (de) * 2012-01-05 2013-07-11 Linde Aktiengesellschaft Verfahren zum Gewinnen einer Helium-Reinfraktion
US10036590B2 (en) * 2012-08-02 2018-07-31 Air Products And Chemicals, Inc. Helium recovery from streams containing helium, carbon dioxide, and at least one of nitrogen and methane
RU2605593C2 (ru) * 2014-10-27 2016-12-20 Юоп Ллк Способ извлечения гелия и устройство для его осуществления
DE102015001664A1 (de) * 2015-02-10 2016-08-11 Linde Aktiengesellschaft Verfahren zur Heliumgewinnung
FR3035656B1 (fr) * 2015-04-30 2019-03-22 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Production d'helium a partir d'un courant gazeux contenant de l'hydrogene
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AU2020203540A1 (en) 2020-12-24
RU2020118384A3 (fr) 2022-01-19
US20210354987A1 (en) 2021-11-18
US11021366B2 (en) 2021-06-01
RU2020118384A (ru) 2021-12-06
FR3096900A1 (fr) 2020-12-11
RU2768434C2 (ru) 2022-03-24

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