FR3089133B1 - Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique - Google Patents

Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique Download PDF

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Publication number
FR3089133B1
FR3089133B1 FR1872176A FR1872176A FR3089133B1 FR 3089133 B1 FR3089133 B1 FR 3089133B1 FR 1872176 A FR1872176 A FR 1872176A FR 1872176 A FR1872176 A FR 1872176A FR 3089133 B1 FR3089133 B1 FR 3089133B1
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Prior art keywords
preparing
reduction reactions
electrochemical reduction
electrode layer
active electrode
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FR1872176A
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English (en)
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FR3089133A1 (fr
Inventor
Audrey Bonduelle-Skrzypczak
Sofiane Belaid
Philibert Leflaive
Gerhard Pirngruber
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1872176A priority Critical patent/FR3089133B1/fr
Priority to US17/295,206 priority patent/US20220010439A1/en
Priority to CN201980078558.2A priority patent/CN113366155A/zh
Priority to EP19806189.7A priority patent/EP3887573A1/fr
Priority to PCT/EP2019/081708 priority patent/WO2020109065A1/fr
Publication of FR3089133A1 publication Critical patent/FR3089133A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/081—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the element being a noble metal
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/27—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/061—Metal or alloy
    • C25B11/063—Valve metal, e.g. titanium
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/065—Carbon
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/077—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C25B3/26—Reduction of carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8828—Coating with slurry or ink
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8842—Coating using a catalyst salt precursor in solution followed by evaporation and reduction of the precursor
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9041—Metals or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
    • H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33—Electric or magnetic properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Catalysts (AREA)
  • Inert Electrodes (AREA)

Abstract

Procédé de préparation d’un matériau catalytique d’une électrode pour des réactions de réduction électrochimique, ledit matériau comprenant une phase active à base d’au moins un métal du groupe VIB et un support électro-conducteur, lequel procédé est réalisé selon au moins les étapes suivantes : - une étape de mise en contact dudit support par au moins une solution contenant au moins un précurseur d’au moins un métal du groupe VIB ; - une étape de séchage à une température inférieure à 250°C, sans étape de calcination ultérieure ; - une étape de sulfuration à une température comprise entre 100°C et 600°C.
FR1872176A 2018-11-30 2018-11-30 Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique Active FR3089133B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1872176A FR3089133B1 (fr) 2018-11-30 2018-11-30 Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique
US17/295,206 US20220010439A1 (en) 2018-11-30 2019-11-19 Method for producing an active layer of an electrode for electrochemical reduction reactions
CN201980078558.2A CN113366155A (zh) 2018-11-30 2019-11-19 生产用于电化学还原反应的电极的活性层的方法
EP19806189.7A EP3887573A1 (fr) 2018-11-30 2019-11-19 Procede de preparation d'une couche active d'electrode pour des reactions de reduction electrochimique
PCT/EP2019/081708 WO2020109065A1 (fr) 2018-11-30 2019-11-19 Procede de preparation d'une couche active d'electrode pour des reactions de reduction electrochimique

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1872176A FR3089133B1 (fr) 2018-11-30 2018-11-30 Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique

Publications (2)

Publication Number Publication Date
FR3089133A1 FR3089133A1 (fr) 2020-06-05
FR3089133B1 true FR3089133B1 (fr) 2024-04-19

Family

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FR1872176A Active FR3089133B1 (fr) 2018-11-30 2018-11-30 Procédé de préparation d’une couche active d’électrode pour des réactions de réduction électrochimique

Country Status (5)

Country Link
US (1) US20220010439A1 (fr)
EP (1) EP3887573A1 (fr)
CN (1) CN113366155A (fr)
FR (1) FR3089133B1 (fr)
WO (1) WO2020109065A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113403629A (zh) * 2021-06-07 2021-09-17 嘉寓氢能源科技(辽宁)有限公司 一种电解水制氢系统用催化剂及其制备方法
CN114602483B (zh) * 2022-03-10 2023-08-18 福州大学 一种催化裂化汽油加氢脱硫催化剂及其制备方法
FR3133544B1 (fr) 2022-03-18 2024-03-08 Ifp Energies Now Matériau catalytique à base d’un élément du groupe VIB et d’un élément du groupe IVB pour la production d’hydrogène par électrolyse de l’eau
CN114855180B (zh) * 2022-03-23 2024-01-19 中国石油大学(华东) 一种多酸衍生低铂载量析氢电催化剂的制备方法
CN114703488A (zh) * 2022-05-13 2022-07-05 天津市大陆制氢设备有限公司 一种采用析氢析氧促进剂的电解水方法
WO2024089259A1 (fr) * 2022-10-27 2024-05-02 Totalenergies Onetech Catalyseur modifié pour faire fonctionner une réduction électrochimique de dioxyde de carbone dans un milieu acide non alcalin et techniques associées
CN115821294B (zh) * 2022-11-17 2025-03-11 河南省高新技术实业有限公司 一种碳材催化电极材料及其制备方法和应用
CN116397261A (zh) * 2023-03-01 2023-07-07 河北科技大学 一种磷化镍-钼磷硫氧化物复合材料及其制备方法和应用
CN117305892B (zh) * 2023-09-22 2025-01-21 重庆万凯新材料科技有限公司 一种泡沫镍负载铁钨磷掺杂硫化镍催化剂的制备方法及其应用
CN117802526B (zh) * 2024-02-29 2024-05-31 华电重工股份有限公司 一种pem电解水的非贵金属阴极析氢催化剂及其应用
FR3162052A1 (fr) 2024-05-13 2025-11-14 IFP Energies Nouvelles Procédé de préparation d’une électrode activée électrochimiquement à base de MoS2 fluoré pour des réactions de réduction électrochimique
FR3162008A1 (fr) 2024-05-13 2025-11-14 IFP Energies Nouvelles Procédé de préparation d’une couche active d’électrode à base de MoS2 fluoré pour des réactions de réduction électrochimique
FR3162053A1 (fr) 2024-05-13 2025-11-14 IFP Energies Nouvelles Procédé de préparation d’une électrode activée électrochimiquement à base de MoS2 supporté pour des réactions de réduction électrochimique

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US2547380A (en) 1945-10-01 1951-04-03 Union Oil Co Catalyst for hydrocarbon conversion
IT1127303B (it) * 1979-12-20 1986-05-21 Oronzio De Nora Impianti Tprocedimento per la preparazione di ossidi misti catalitici
US5851382A (en) * 1995-12-18 1998-12-22 Texaco Inc. Selective hydrodesulfurization of cracked naphtha using hydrotalcite-supported catalysts
GB0214383D0 (en) * 2002-06-21 2002-07-31 Isis Innovation Catalyst
CN102933298B (zh) * 2009-12-16 2016-08-03 Ifp新能源公司 可用于加氢处理的包含viii和vib族金属的催化剂以及使用乙酸和琥珀酸c1-c4二烷基酯的制备方法
FR2984763B1 (fr) * 2011-12-22 2013-12-20 IFP Energies Nouvelles Procede de preparation d'un catalyseur utilisable en hydroconversion comprenant au moins une zeolithe nu-86
FR3004968B1 (fr) * 2013-04-30 2016-02-05 IFP Energies Nouvelles Procede de preparation d'un catalyseur a base de tungstene utilisable en hydrotraitement ou en hydrocraquage
FR3004967B1 (fr) * 2013-04-30 2016-12-30 Ifp Energies Now Procede de preparation d'un catalyseur a base de molybdene utilisable en hydrotraitement ou en hydrocraquage
FR3007427B1 (fr) 2013-06-20 2016-07-01 Ifp Energies Now Couche active a base de particules metalliques sur support conducteur poreux, methode de fabrication et utilisation en tant que cathode pour l'electroreduction de dioxyde de carbone.
WO2019016852A1 (fr) * 2017-07-18 2019-01-24 国立大学法人弘前大学 Procédé de production de catalyseur d'électrode et procédé de production d'hydrogène
CN107999108B (zh) * 2017-12-13 2019-01-18 中国石油大学(华东) 一种氮磷共掺杂碳负载的碳化钼或碳化钨催化剂及其制备方法和应用
CN108855146B (zh) * 2018-06-27 2020-05-05 北京师范大学 NiFeMoS复合体及其制备方法

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Publication number Publication date
FR3089133A1 (fr) 2020-06-05
WO2020109065A1 (fr) 2020-06-04
US20220010439A1 (en) 2022-01-13
CN113366155A (zh) 2021-09-07
EP3887573A1 (fr) 2021-10-06

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