FR3067353B1 - Copolymere fonctionnel d'un 1,3-diene et d'une olefine - Google Patents

Copolymere fonctionnel d'un 1,3-diene et d'une olefine Download PDF

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Publication number
FR3067353B1
FR3067353B1 FR1755108A FR1755108A FR3067353B1 FR 3067353 B1 FR3067353 B1 FR 3067353B1 FR 1755108 A FR1755108 A FR 1755108A FR 1755108 A FR1755108 A FR 1755108A FR 3067353 B1 FR3067353 B1 FR 3067353B1
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FR
France
Prior art keywords
diene
copolymer
olefin
functional copolymer
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1755108A
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English (en)
French (fr)
Other versions
FR3067353A1 (fr
Inventor
Julien Thuilliez
Vincent Lafaquiere
Leyla Pehlivan
Benoît MACQUERON
Christophe Boisson
Franck D'agosto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique
Compagnie Generale des Etablissements Michelin SCA
École d'Ingénieurs en Chimie et Sciences du Numérique
Université Claude Bernard Lyon 1
Original Assignee
Centre National de la Recherche Scientifique
Compagnie Generale des Etablissements Michelin SCA
École d'Ingénieurs en Chimie et Sciences du Numérique
Université Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1755108A priority Critical patent/FR3067353B1/fr
Application filed by Centre National de la Recherche Scientifique, Compagnie Generale des Etablissements Michelin SCA, École d'Ingénieurs en Chimie et Sciences du Numérique, Université Claude Bernard Lyon 1 filed Critical Centre National de la Recherche Scientifique
Priority to PCT/FR2018/051306 priority patent/WO2018224775A1/fr
Priority to SG11201910181QA priority patent/SG11201910181QA/en
Priority to JP2019567247A priority patent/JP7204684B2/ja
Priority to CN201880037929.8A priority patent/CN110709463B/zh
Priority to US16/619,370 priority patent/US11104755B2/en
Priority to EP18737663.7A priority patent/EP3635052B1/fr
Publication of FR3067353A1 publication Critical patent/FR3067353A1/fr
Application granted granted Critical
Publication of FR3067353B1 publication Critical patent/FR3067353B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
FR1755108A 2017-06-08 2017-06-08 Copolymere fonctionnel d'un 1,3-diene et d'une olefine Expired - Fee Related FR3067353B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1755108A FR3067353B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'un 1,3-diene et d'une olefine
SG11201910181QA SG11201910181QA (en) 2017-06-08 2018-06-06 Functional copolymer consisting of a 1,3-diene and an olefine
JP2019567247A JP7204684B2 (ja) 2017-06-08 2018-06-06 １，３－ジエンとオレフィンとからなる官能性コポリマー
CN201880037929.8A CN110709463B (zh) 2017-06-08 2018-06-06 由1,3-二烯和烯烃组成的官能化共聚物
PCT/FR2018/051306 WO2018224775A1 (fr) 2017-06-08 2018-06-06 Copolymere fonctionnel d'un 1,3-diene et d'une olefine
US16/619,370 US11104755B2 (en) 2017-06-08 2018-06-06 Functional copolymer consisting of a 1,3-diene and an olefine
EP18737663.7A EP3635052B1 (fr) 2017-06-08 2018-06-06 Copolymere fonctionnel d'un 1,3-diene et d'une olefine

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1755108A FR3067353B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'un 1,3-diene et d'une olefine
FR1755108 2017-06-08

Publications (2)

Publication Number Publication Date
FR3067353A1 FR3067353A1 (fr) 2018-12-14
FR3067353B1 true FR3067353B1 (fr) 2020-10-23

Family

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Family Applications (1)

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FR1755108A Expired - Fee Related FR3067353B1 (fr) 2017-06-08 2017-06-08 Copolymere fonctionnel d'un 1,3-diene et d'une olefine

Country Status (7)

Country Link
US (1) US11104755B2 (cg-RX-API-DMAC10.html)
EP (1) EP3635052B1 (cg-RX-API-DMAC10.html)
JP (1) JP7204684B2 (cg-RX-API-DMAC10.html)
CN (1) CN110709463B (cg-RX-API-DMAC10.html)
FR (1) FR3067353B1 (cg-RX-API-DMAC10.html)
SG (1) SG11201910181QA (cg-RX-API-DMAC10.html)
WO (1) WO2018224775A1 (cg-RX-API-DMAC10.html)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3848428A4 (en) * 2018-09-06 2022-06-22 Riken Technos Corporation HOT ADHESIVE, REINFORCEMENT TAPE AND FLEXIBLE FLAT CABLE REINFORCED AT CONDUCTIVE END WITH REINFORCEMENT TAPE
FR3090639A3 (fr) 2018-12-20 2020-06-26 Michelin & Cie Terpolymères d’éthylène, de 1,3-butadiène et d’une α-monooléfine aromatique.
FR3104584B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique
FR3104585B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
FR3116277A1 (fr) * 2020-11-19 2022-05-20 Compagnie Generale Des Etablissements Michelin Copolymères fonctionnels amine à blocs éthyléniques et diéniques

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
DE60041550D1 (de) 1999-11-12 2009-03-26 Bridgestone Corp Modifizierte polymere hergestellt mit katalysator auf basys von lanthaniden
CN100523023C (zh) 2002-10-16 2009-08-05 米其林技术公司 乙烯/丁二烯共聚物,用于合成其的催化体系和方法
JP2005200503A (ja) 2004-01-14 2005-07-28 National Institute Of Advanced Industrial & Technology プロピレンと共役ジエンとの共重合体及びその製造方法
FR2893029B1 (fr) 2005-11-09 2009-01-16 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
FR2893028B1 (fr) * 2005-11-09 2008-02-15 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
EP1954706B1 (en) 2005-11-30 2012-03-28 Epicentre Technologies Corporation Method using reversibly blocked tagging oligonucleotides
JP5217378B2 (ja) 2007-11-16 2013-06-19 Ｊｓｒ株式会社 変性共役ジエン系重合体の製造方法
CN103154059B (zh) 2010-07-30 2014-12-24 株式会社普利司通 共轭二烯化合物与非共轭烯烃的共聚物、橡胶组合物、交联橡胶组合物和轮胎
FR2984904B1 (fr) * 2011-12-22 2014-01-03 Michelin Soc Tech Composition de caoutchouc
JP6204646B2 (ja) 2012-09-19 2017-09-27 旭化成株式会社 変性共役ジエン系重合体の製造方法及び変性共役ジエン系重合体、並びに変性共役ジエン系重合体組成物
FR3044241A1 (fr) * 2015-12-01 2017-06-02 Michelin & Cie Systeme catalytique comprenant un metallocene de terre rare

Also Published As

Publication number Publication date
CN110709463A (zh) 2020-01-17
US11104755B2 (en) 2021-08-31
JP7204684B2 (ja) 2023-01-16
FR3067353A1 (fr) 2018-12-14
EP3635052B1 (fr) 2021-11-17
US20200157268A1 (en) 2020-05-21
CN110709463B (zh) 2022-04-15
SG11201910181QA (en) 2020-01-30
JP2020522594A (ja) 2020-07-30
WO2018224775A1 (fr) 2018-12-13
EP3635052A1 (fr) 2020-04-15

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