FR3045211B1 - Materiau de cathode pour batteries li-ion - Google Patents

Materiau de cathode pour batteries li-ion Download PDF

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Publication number
FR3045211B1
FR3045211B1 FR1562097A FR1562097A FR3045211B1 FR 3045211 B1 FR3045211 B1 FR 3045211B1 FR 1562097 A FR1562097 A FR 1562097A FR 1562097 A FR1562097 A FR 1562097A FR 3045211 B1 FR3045211 B1 FR 3045211B1
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FR
France
Prior art keywords
cathode material
ion batteries
cathode
relates
present
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Active
Application number
FR1562097A
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English (en)
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FR3045211A1 (fr
Inventor
Jean-Francois COLIN
Carole Bourbon
Quentin JACQUET
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Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
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Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1562097A priority Critical patent/FR3045211B1/fr
Priority to JP2018526069A priority patent/JP6861208B2/ja
Priority to EP16819337.3A priority patent/EP3386921A1/fr
Priority to US15/774,713 priority patent/US10644313B2/en
Priority to PCT/FR2016/053133 priority patent/WO2017098113A1/fr
Publication of FR3045211A1 publication Critical patent/FR3045211A1/fr
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Publication of FR3045211B1 publication Critical patent/FR3045211B1/fr
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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/76—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by a space-group or by other symmetry indications
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La présente invention concerne un matériau d'électrode de formule Li2+xNiuTivNbwO4 dans laquelle : 0 <x< 0.3, u>0 et w>0, x + u + v + w = 2, x + 2u + 4v + 5w = 6. La présente invention concerne également la cathode ayant pour matériau électroniquement actif ce matériau, mais aussi la batterie lithium-ion contenant cette cathode.
FR1562097A 2015-12-09 2015-12-09 Materiau de cathode pour batteries li-ion Active FR3045211B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1562097A FR3045211B1 (fr) 2015-12-09 2015-12-09 Materiau de cathode pour batteries li-ion
JP2018526069A JP6861208B2 (ja) 2015-12-09 2016-11-29 リチウムイオン電池のためのカソード材料
EP16819337.3A EP3386921A1 (fr) 2015-12-09 2016-11-29 Materiau de cathode pour batteries li-ion
US15/774,713 US10644313B2 (en) 2015-12-09 2016-11-29 Cathode material for Li-ion batteries
PCT/FR2016/053133 WO2017098113A1 (fr) 2015-12-09 2016-11-29 Materiau de cathode pour batteries li-ion

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1562097A FR3045211B1 (fr) 2015-12-09 2015-12-09 Materiau de cathode pour batteries li-ion
FR1562097 2015-12-09

Publications (2)

Publication Number Publication Date
FR3045211A1 FR3045211A1 (fr) 2017-06-16
FR3045211B1 true FR3045211B1 (fr) 2020-06-05

Family

ID=55236746

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1562097A Active FR3045211B1 (fr) 2015-12-09 2015-12-09 Materiau de cathode pour batteries li-ion

Country Status (5)

Country Link
US (1) US10644313B2 (fr)
EP (1) EP3386921A1 (fr)
JP (1) JP6861208B2 (fr)
FR (1) FR3045211B1 (fr)
WO (1) WO2017098113A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110247049A (zh) * 2019-04-30 2019-09-17 上海德朗能动力电池有限公司 一种锂电池金属氧化物负极材料及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SI22771A (sl) 2008-03-27 2009-10-31 Kemijski inštitut Titanati prehodnih kovin kot materiali za katodo v litijevih akumulatorjih
JP5670105B2 (ja) * 2009-09-29 2015-02-18 日本碍子株式会社 正極活物質及びリチウム二次電池
JP2012033279A (ja) * 2010-07-28 2012-02-16 Nec Energy Devices Ltd リチウムイオン二次電池
JP5909131B2 (ja) 2012-03-28 2016-04-26 株式会社Ｇｓユアサ リチウム二次電池用活物質、それを用いたリチウム二次電池用電極及びリチウム二次電池
JP5964729B2 (ja) 2012-11-12 2016-08-03 国立大学法人九州大学 リチウム電池用正極活物質、及び当該リチウム電池用正極活物質を含有するリチウム電池
PT2946246T (pt) * 2013-01-21 2019-07-11 Kinestral Tech Inc Dispositivo eletrocrómico multicamada com ânodo à base de óxido de lítio e níquel
TW201439371A (zh) * 2013-01-21 2014-10-16 Kinestral Technologies Inc 多層電致變色結構之製備方法
CN104269520A (zh) 2014-09-24 2015-01-07 南京工业大学 以石墨烯为载体的Li2FeTiO4-G复合正极材料及其制备方法

Also Published As

Publication number Publication date
US20180331359A1 (en) 2018-11-15
FR3045211A1 (fr) 2017-06-16
JP6861208B2 (ja) 2021-04-21
US10644313B2 (en) 2020-05-05
EP3386921A1 (fr) 2018-10-17
JP2019504437A (ja) 2019-02-14
WO2017098113A1 (fr) 2017-06-15

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