FR3044241A1 - Systeme catalytique comprenant un metallocene de terre rare - Google Patents

Systeme catalytique comprenant un metallocene de terre rare Download PDF

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Publication number
FR3044241A1
FR3044241A1 FR1561629A FR1561629A FR3044241A1 FR 3044241 A1 FR3044241 A1 FR 3044241A1 FR 1561629 A FR1561629 A FR 1561629A FR 1561629 A FR1561629 A FR 1561629A FR 3044241 A1 FR3044241 A1 FR 3044241A1
Authority
FR
France
Prior art keywords
group
catalyst system
substituted
groups
butadiene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR1561629A
Other languages
English (en)
French (fr)
Inventor
Julien Thuilliez
Christophe Boisson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michelin Recherche et Technique SA Switzerland
Centre National de la Recherche Scientifique
Compagnie Generale des Etablissements Michelin SCA
École d'Ingénieurs en Chimie et Sciences du Numérique
Original Assignee
Michelin Recherche et Technique SA Switzerland
Centre National de la Recherche Scientifique
Compagnie Generale des Etablissements Michelin SCA
École d'Ingénieurs en Chimie et Sciences du Numérique
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michelin Recherche et Technique SA Switzerland, Centre National de la Recherche Scientifique, Compagnie Generale des Etablissements Michelin SCA, École d'Ingénieurs en Chimie et Sciences du Numérique filed Critical Michelin Recherche et Technique SA Switzerland
Priority to FR1561629A priority Critical patent/FR3044241A1/fr
Priority to EP16806025.9A priority patent/EP3383530B1/fr
Priority to PCT/EP2016/079200 priority patent/WO2017093278A1/fr
Priority to RU2018122240A priority patent/RU2729076C2/ru
Priority to JP2018548279A priority patent/JP6946322B2/ja
Publication of FR3044241A1 publication Critical patent/FR3044241A1/fr
Priority to SA518391691A priority patent/SA518391691B1/ar
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/37—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
FR1561629A 2015-12-01 2015-12-01 Systeme catalytique comprenant un metallocene de terre rare Withdrawn FR3044241A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1561629A FR3044241A1 (fr) 2015-12-01 2015-12-01 Systeme catalytique comprenant un metallocene de terre rare
EP16806025.9A EP3383530B1 (fr) 2015-12-01 2016-11-30 Systeme catalytique comprenant un metallocene de terre rare
PCT/EP2016/079200 WO2017093278A1 (fr) 2015-12-01 2016-11-30 Systeme catalytique comprenant un metallocene de terre rare
RU2018122240A RU2729076C2 (ru) 2015-12-01 2016-11-30 Каталитическая система, содержащая редкоземельный металлоцен
JP2018548279A JP6946322B2 (ja) 2015-12-01 2016-11-30 希土類メタロセンを含む触媒系
SA518391691A SA518391691B1 (ar) 2015-12-01 2018-05-29 نظام حفزي يشتمل على ميتالوسين أرضي نادر

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1561629A FR3044241A1 (fr) 2015-12-01 2015-12-01 Systeme catalytique comprenant un metallocene de terre rare

Publications (1)

Publication Number Publication Date
FR3044241A1 true FR3044241A1 (fr) 2017-06-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1561629A Withdrawn FR3044241A1 (fr) 2015-12-01 2015-12-01 Systeme catalytique comprenant un metallocene de terre rare

Country Status (6)

Country Link
EP (1) EP3383530B1 (enExample)
JP (1) JP6946322B2 (enExample)
FR (1) FR3044241A1 (enExample)
RU (1) RU2729076C2 (enExample)
SA (1) SA518391691B1 (enExample)
WO (1) WO2017093278A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018224774A1 (fr) * 2017-06-08 2018-12-13 Compagnie Generale Des Etablissements Michelin Copolymere fonctionnel d'ethylene et de 1,3-butadiene
WO2018224775A1 (fr) * 2017-06-08 2018-12-13 Compagnie Generale Des Etablissements Michelin Copolymere fonctionnel d'un 1,3-diene et d'une olefine

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3078972B1 (fr) * 2018-03-19 2020-04-03 Compagnie Generale Des Etablissements Michelin Copolymere d’ethylene et de myrcene
CN113683716B (zh) * 2020-05-18 2022-08-05 中国石油天然气股份有限公司 一种乙烯聚合催化剂及其制备方法以及乙烯-异丁烯共聚物的制备方法
FR3118039B1 (fr) 2020-12-21 2024-03-29 Michelin & Cie procédé de copolymérisation de l’éthylène et d’une α-oléfine linéaire ayant 3 à 8 atomes de carbone en phase gazeuse
FR3118038B1 (fr) 2020-12-21 2024-03-29 Michelin & Cie procédé de polymérisation de l’éthylène en phase gazeuse
FR3118042B1 (fr) 2020-12-21 2023-07-21 Michelin & Cie systèmes catalytiques supportés pour la synthèse de polyoléfines semi-cristallines

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001072852A1 (de) * 2000-03-07 2001-10-04 Röhm GmbH & Co. KG Verfahren zur herstellung von polymerisaten und copolymerisaten alpha-substituierter acrylverbindungen sowie die erhaltenen polymerisate
WO2004035639A1 (fr) * 2002-10-16 2004-04-29 Societe De Technologie Michelin Copolymères éthylène/ butadiène, system catalytique et les produires et production desdits polymers
WO2007054223A2 (fr) * 2005-11-09 2007-05-18 Societe De Technologie Michelin Complexe metallocene borohydrure d’un lanthanide, systeme catalytique l’incorporant, procede de polymerisation l’utilisant et copolymere ethylene/butadiene obtenu par ce procede
EP1829901A2 (fr) * 1999-10-12 2007-09-05 Societe de Technologie Michelin Systéme catalytique et son procédé de préparation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10010511A1 (de) * 2000-03-07 2001-09-13 Roehm Gmbh Verfahren zur Herstellung von Polymerisaten und Copolymerisaten alpha-substituierter Acrylverbindungen
CN1146569C (zh) * 2000-09-15 2004-04-21 中国科学院上海有机化学研究所 一种二烃基亚甲基桥联芴基环戊二烯基稀土配合物、合成方法及用途
FR2893028B1 (fr) * 2005-11-09 2008-02-15 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1829901A2 (fr) * 1999-10-12 2007-09-05 Societe de Technologie Michelin Systéme catalytique et son procédé de préparation
WO2001072852A1 (de) * 2000-03-07 2001-10-04 Röhm GmbH & Co. KG Verfahren zur herstellung von polymerisaten und copolymerisaten alpha-substituierter acrylverbindungen sowie die erhaltenen polymerisate
WO2004035639A1 (fr) * 2002-10-16 2004-04-29 Societe De Technologie Michelin Copolymères éthylène/ butadiène, system catalytique et les produires et production desdits polymers
WO2007054223A2 (fr) * 2005-11-09 2007-05-18 Societe De Technologie Michelin Complexe metallocene borohydrure d’un lanthanide, systeme catalytique l’incorporant, procede de polymerisation l’utilisant et copolymere ethylene/butadiene obtenu par ce procede

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JAE-SANG RYU ET AL: "Organolathanide-Catalyzed Regioselective Intermolecular Hydroamination of Alkenes, Alkynes, Vinylarenes, Di- and Trivinylarenes, and Methylenecyclopropanes. Scope and Mechanistic Comparison to Intramolecular Cyclohydroaminations", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 125, no. 41, 1 October 2003 (2003-10-01), US, pages 12584 - 12605, XP055280082, ISSN: 0002-7863, DOI: 10.1021/ja035867m *
MIN HYUNG LEE ET AL: "The First Fluorenyl ansa -Yttrocene Complexes: Synthesis, Structures, and Polymerization of Methyl Methacrylate", ORGANOMETALLICS, vol. 18, no. 24, 1 November 1999 (1999-11-01), US, pages 5124 - 5129, XP055280251, ISSN: 0276-7333, DOI: 10.1021/om990471y *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018224774A1 (fr) * 2017-06-08 2018-12-13 Compagnie Generale Des Etablissements Michelin Copolymere fonctionnel d'ethylene et de 1,3-butadiene
WO2018224775A1 (fr) * 2017-06-08 2018-12-13 Compagnie Generale Des Etablissements Michelin Copolymere fonctionnel d'un 1,3-diene et d'une olefine
FR3067353A1 (fr) * 2017-06-08 2018-12-14 Compagnie Generale Des Etablissements Michelin Copolymere fonctionnel d'un 1,3-diene et d'une olefine
FR3067354A1 (fr) * 2017-06-08 2018-12-14 Compagnie Generale Des Etablissements Michelin Copolymere fonctionnel d'ethylene et de 1,3-butadiene
US11104755B2 (en) 2017-06-08 2021-08-31 Compagnie Generale Des Etablissements Michelin Functional copolymer consisting of a 1,3-diene and an olefine
US11155656B2 (en) 2017-06-08 2021-10-26 Compagnie Generale Des Etablissements Michelin Functional ethylene and 1,3-butadiene copolymer

Also Published As

Publication number Publication date
EP3383530A1 (fr) 2018-10-10
EP3383530B1 (fr) 2020-05-13
JP2018536759A (ja) 2018-12-13
RU2729076C2 (ru) 2020-08-04
WO2017093278A1 (fr) 2017-06-08
RU2018122240A (ru) 2020-01-10
RU2018122240A3 (enExample) 2020-03-02
SA518391691B1 (ar) 2021-10-26
JP6946322B2 (ja) 2021-10-06

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