RU2729076C2 - Каталитическая система, содержащая редкоземельный металлоцен - Google Patents

Каталитическая система, содержащая редкоземельный металлоцен Download PDF

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Publication number
RU2729076C2
RU2729076C2 RU2018122240A RU2018122240A RU2729076C2 RU 2729076 C2 RU2729076 C2 RU 2729076C2 RU 2018122240 A RU2018122240 A RU 2018122240A RU 2018122240 A RU2018122240 A RU 2018122240A RU 2729076 C2 RU2729076 C2 RU 2729076C2
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Russia
Prior art keywords
group
catalytic system
substituted
butadiene
groups
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RU2018122240A
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English (en)
Russian (ru)
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RU2018122240A (ru
RU2018122240A3 (enExample
Inventor
Жюльен Тюйие
Кристоф Буассон
Original Assignee
Компани Женераль Дэз Этаблиссман Мишлен
Сантр Насьональ Де Ла Решерш Сьентифик
Спе Лион Формасьон Континю Э Решерш
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Application filed by Компани Женераль Дэз Этаблиссман Мишлен, Сантр Насьональ Де Ла Решерш Сьентифик, Спе Лион Формасьон Континю Э Решерш filed Critical Компани Женераль Дэз Этаблиссман Мишлен
Publication of RU2018122240A publication Critical patent/RU2018122240A/ru
Publication of RU2018122240A3 publication Critical patent/RU2018122240A3/ru
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/37—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
RU2018122240A 2015-12-01 2016-11-30 Каталитическая система, содержащая редкоземельный металлоцен RU2729076C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1561629 2015-12-01
FR1561629A FR3044241A1 (fr) 2015-12-01 2015-12-01 Systeme catalytique comprenant un metallocene de terre rare
PCT/EP2016/079200 WO2017093278A1 (fr) 2015-12-01 2016-11-30 Systeme catalytique comprenant un metallocene de terre rare

Publications (3)

Publication Number Publication Date
RU2018122240A RU2018122240A (ru) 2020-01-10
RU2018122240A3 RU2018122240A3 (enExample) 2020-03-02
RU2729076C2 true RU2729076C2 (ru) 2020-08-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2018122240A RU2729076C2 (ru) 2015-12-01 2016-11-30 Каталитическая система, содержащая редкоземельный металлоцен

Country Status (6)

Country Link
EP (1) EP3383530B1 (enExample)
JP (1) JP6946322B2 (enExample)
FR (1) FR3044241A1 (enExample)
RU (1) RU2729076C2 (enExample)
SA (1) SA518391691B1 (enExample)
WO (1) WO2017093278A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3067353B1 (fr) * 2017-06-08 2020-10-23 Centre Nat Rech Scient Copolymere fonctionnel d'un 1,3-diene et d'une olefine
FR3067354B1 (fr) * 2017-06-08 2020-10-23 Centre Nat Rech Scient Copolymere fonctionnel d'ethylene et de 1,3-butadiene
FR3078972B1 (fr) * 2018-03-19 2020-04-03 Compagnie Generale Des Etablissements Michelin Copolymere d’ethylene et de myrcene
CN113683716B (zh) * 2020-05-18 2022-08-05 中国石油天然气股份有限公司 一种乙烯聚合催化剂及其制备方法以及乙烯-异丁烯共聚物的制备方法
FR3118039B1 (fr) 2020-12-21 2024-03-29 Michelin & Cie procédé de copolymérisation de l’éthylène et d’une α-oléfine linéaire ayant 3 à 8 atomes de carbone en phase gazeuse
FR3118038B1 (fr) 2020-12-21 2024-03-29 Michelin & Cie procédé de polymérisation de l’éthylène en phase gazeuse
FR3118042B1 (fr) 2020-12-21 2023-07-21 Michelin & Cie systèmes catalytiques supportés pour la synthèse de polyoléfines semi-cristallines

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1286256A (zh) * 2000-09-15 2001-03-07 中国科学院上海有机化学研究所 一种二烃基亚甲基桥联芴基环戊二烯基稀土配合物、合成方法及用途
WO2001072852A1 (de) * 2000-03-07 2001-10-04 Röhm GmbH & Co. KG Verfahren zur herstellung von polymerisaten und copolymerisaten alpha-substituierter acrylverbindungen sowie die erhaltenen polymerisate
WO2004035639A1 (fr) * 2002-10-16 2004-04-29 Societe De Technologie Michelin Copolymères éthylène/ butadiène, system catalytique et les produires et production desdits polymers
RU2437891C2 (ru) * 2005-11-09 2011-12-27 Сосьете Де Текноложи Мишлен Металлоценовый комплекс боргидрида лантаноида, каталитическая система, содержащая этот комплекс, способ полимеризации с его использованием и сополимер этилена с бутадиеном, полученный этим способом

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2799468B1 (fr) * 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
DE10010511A1 (de) * 2000-03-07 2001-09-13 Roehm Gmbh Verfahren zur Herstellung von Polymerisaten und Copolymerisaten alpha-substituierter Acrylverbindungen
FR2893029B1 (fr) * 2005-11-09 2009-01-16 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001072852A1 (de) * 2000-03-07 2001-10-04 Röhm GmbH & Co. KG Verfahren zur herstellung von polymerisaten und copolymerisaten alpha-substituierter acrylverbindungen sowie die erhaltenen polymerisate
CN1286256A (zh) * 2000-09-15 2001-03-07 中国科学院上海有机化学研究所 一种二烃基亚甲基桥联芴基环戊二烯基稀土配合物、合成方法及用途
WO2004035639A1 (fr) * 2002-10-16 2004-04-29 Societe De Technologie Michelin Copolymères éthylène/ butadiène, system catalytique et les produires et production desdits polymers
RU2437891C2 (ru) * 2005-11-09 2011-12-27 Сосьете Де Текноложи Мишлен Металлоценовый комплекс боргидрида лантаноида, каталитическая система, содержащая этот комплекс, способ полимеризации с его использованием и сополимер этилена с бутадиеном, полученный этим способом

Non-Patent Citations (3)

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Title
Jae-Sang Ryu et al. "Organolathanide-Catalyzed Regioselective Intermolecular Hydroamination of Alkenes, Alkynes, Vinylarenes, Di- and Trivinylarenes, and Methylenecyclopropanes. Scope and Mechanistic Comparison to Intramolecular Cyclohydroaminations", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, Vol. 125, No. 41, P. 12584-12605. *
Jae-Sang Ryu et al. "Organolathanide-Catalyzed Regioselective Intermolecular Hydroamination of Alkenes, Alkynes, Vinylarenes, Di- and Trivinylarenes, and Methylenecyclopropanes. Scope and Mechanistic Comparison to Intramolecular Cyclohydroaminations", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, Vol. 125, No. 41, P. 12584-12605. MIN HYUNG LEE et al. "The First Fluorenyl ansa-Yttrocene Complexes: Synthesis, Structures, and polymerization of Methyl Methacrylate", ORGANOMETALLICS, 1999, Vol. 18, No. 24, P. 5124-5129. *
MIN HYUNG LEE et al. "The First Fluorenyl ansa-Yttrocene Complexes: Synthesis, Structures, and polymerization of Methyl Methacrylate", ORGANOMETALLICS, 1999, Vol. 18, No. 24, P. 5124-5129. *

Also Published As

Publication number Publication date
EP3383530A1 (fr) 2018-10-10
EP3383530B1 (fr) 2020-05-13
JP2018536759A (ja) 2018-12-13
WO2017093278A1 (fr) 2017-06-08
FR3044241A1 (fr) 2017-06-02
RU2018122240A (ru) 2020-01-10
RU2018122240A3 (enExample) 2020-03-02
SA518391691B1 (ar) 2021-10-26
JP6946322B2 (ja) 2021-10-06

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