FR3007973A1 - NON-COLORING CAPILLARY COMPOSITION COMPRISING AN ANIONIC OR NON-IONIC ASSOCIATIVE POLYMER AND A PARTICULAR ORGANIC SILICON COMPOUND - Google Patents

Abstract

The invention relates to a non-dyeing hair composition comprising: 2-60% by weight, relative to the total weight of the composition, of one or more anionic or nonionic associative polymers, and one or more organic compounds of the silicon of formula R1 Si (OR2) z (R3) x (OH) y and / or their oligomers, in which R1 is a linear or branched, saturated or unsaturated C1-C22 hydrocarbon-based chain which may be substituted with an amine group NH2 or NHR with R = C1-C20 alkyl, C3-C40 cycloalkyl or C6-C30 aromatic group; or by a hydroxyl group, a thiol group, a substituted or unsubstituted aryl group; R1 may be interrupted by a heteroatom or a carbonyl group; R 2 and R 3, which may be identical or different, represent a linear or branched C 1 -C 6 alkyl group, y and z = 0 to 3, x = 0 to 2, with z + x + y = 3. It also relates to its use for the cleaning and / or conditioning of human hair.

Description

The present invention relates to a non-dyestuff capillary composition comprising at least 2% by weight relative to the total weight of the non-dyestuff capillary composition. , at least one anionic or nonionic associative polymer and at least one organic silicon compound as described below. It also relates to its use for the cleaning and / or conditioning of human hair. It is known to clean the hair with shampoos which are aqueous compositions containing high levels of surfactants. These surfactants are generally anionic surfactants alone or in combination with amphoteric or nonionic surfactants. The concentrations of surfactants used generally exceed 10% by weight, expressed as active ingredients.

These surfactants are mostly aggressive towards the scalp and frequently lead to irritation phenomena resulting in redness or feeling of discomfort. These surfactants are also aggressive vis-à-vis the eyes. In addition, the rinsing of the compositions with these high levels of surfactants is often long. Moreover, these surfactants degrade the cosmetic properties of the hair, which leads to the need for additions of conditioning ingredients such as cationic polymers, silicones or non-silicone oils.

Finally, to avoid application dripping and especially eye drops, shampoos must be thickened. Thickening of compositions containing high levels of surfactants is difficult and frequently poses stability problems. There is therefore a need to have compositions for cleaning the hair while reducing or even eliminating conventional surfactants causing these disadvantages. Associative polymers are known in cosmetics. These are polymers that, by their structure, have portions or groups that have the property of associating with each other or with the molecules or portions of molecules of other compounds. These association phenomena generally result in significant increases in viscosity. These associative polymers are therefore used as thickeners or viscosifiers or as suspending agents. Such polymers capable of associating reversibly with one another or with other molecules are called associative polymers. The interaction forces involved can be very different in nature, for example of electrostatic nature, hydrogen bonding type or hydrophobic interactions. The use of these associative polymers above a certain concentration leads to obtaining sufficient detergency to allow the cleaning of the hair in the presence of very small amounts of surfactants, or even in the absence of these surfactants. . This is described in French Patent Application No. 2 935 267. However, the compositions thus obtained, even if they allow a detergency similar to that obtained with a conventional shampoo, still have insufficient foaming; in addition, the cosmetic properties conferred on the hair are not yet completely satisfactory, especially on dry hair. The Applicant has surprisingly and unexpectedly discovered that the combination of 2 to 60% by weight, relative to the total weight of the cosmetic composition, of one or more anionic or nonionic associative polymers, with one or more organic compounds particular silicon as described below, overcomes the disadvantages mentioned above, and were particularly likely to generate adequate foam, in terms of quality and quantity, and providing hair with satisfactory cosmetic properties, such as the softness, shine, smoothing, detangling and suppleness, especially on dry hair. The subject of the invention is therefore a non-dyeing hair composition comprising: from 2 to 60% by weight, relative to the total weight of the composition, of one or more anionic or nonionic associative polymers, and one or several organic compounds of silicon of formula (I) below and / or their oligomers: R 1 Si (OR 2), (R 2) '(OH) y (I) in which: R 1 is a linear or branched C 1 -C 22 hydrocarbon-based chain, saturated or unsaturated, which may be substituted with: an amine group NH 2 or NHR, R representing a C 1 -C 20, preferably C 1 -C 6 alkyl, C 3 -C 4 cycloalkyl or C 6 -C 30 aromatic alkyl group; a thiol group, or an aryl group, such as benzyl, substituted or unsubstituted; R 1 which may be interrupted by a heteroatom such as O, S, NH or by a carbonyl group (CO), R 2 and R 3, which may be identical or different, represent a linear or branched alkyl group comprising from 1 to 6 carbon atoms, y denotes an integer from 0 to 3, and z denotes an integer from 0 to 3, and x denotes an integer from 0 to 2, with z + x + y = 3. The compositions according to the invention rinse faster than conventional shampoos. They are intrinsically more curing and bring more lightness to hair, especially wet hair. They do not necessarily require the addition of viscosifiers and allow to have varied textures. They are better tolerated by the scalp and the eyes. The present invention also relates to the use of a composition according to the invention for cleaning and / or conditioning human hair. Another object of the invention is a method for cleaning and / or conditioning human hair, comprising the use of the non-coloring hair composition as described below.

Other objects, features, aspects and advantages of the invention will emerge even more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field, especially in the expressions "between" and "from ... to". Moreover, the expression "at least one" used in the present description is equivalent to the expression "one or more". According to the invention, the non-coloring hair composition comprises: from 2 to 60% by weight, relative to the total weight of the non-coloring hair composition, of one or more anionic or nonionic associative polymers, and one or more organic compounds of silicon of formula (I) below and / or their oligomers: RIS i (OR2), (R3) '(OH) y (I) in which: Ri is a linear C1-C22 hydrocarbon chain, or branched, saturated or unsaturated, which may be substituted with: - an amine group NH 2 or NHR, R representing a C 1 -C 20 alkyl, preferably C 1 -C 6 alkyl, C 3 -C 4 cycloalkyl or C 6 -C 30 aromatic group; a hydroxyl group, a thiol group, or an aryl group, such as benzyl, which may or may not be substituted; R 1 which may be interrupted by a heteroatom such as O, S or NH, or by a carbonyl group (CO), R 2 and R 3, which may be identical or different, represent a linear or branched alkyl group comprising from 1 to 6 carbon atoms, y denotes an integer from 0 to 3, and z denotes an integer from 0 to 3, and x denotes an integer from 0 to 2, with z + x + y = 3.

The composition according to the invention is non-coloring. According to the present invention, the term "non-coloring composition" is intended to mean a composition which does not contain a dye for keratin fibers, such as direct dyes or oxidation dye precursors (bases and / or couplers). If they are present, their content does not exceed 0.005% by weight relative to the total weight of the composition. Indeed, at such a content, only the composition would be tinted, that is to say, one would not observe staining effect of keratin fibers. For the purposes of the present invention, the term "polymer" means any compound resulting from the polymerization by polycondensation or the radical polymerization of monomers, at least one of which is different from an alkylene oxide and a monofunctional compound of formula RX, R denoting a C 1 -C 30 alkyl or alkenyl group, optionally hydroxyl, and X denoting a carboxylic acid, amine, amide, hydroxyl or ester group. In particular, all compounds derived solely from the simple condensation of an alkylene oxide with a fatty alcohol, a fatty ester, a fatty acid, a fatty amide and a fatty amine are excluded. Unless otherwise stated, the term "fatty" compound, for example a fatty alcohol, a fatty acid or a fatty amide, a compound comprising in its main chain at least one hydrocarbon chain, saturated or unsaturated, such as alkyl or alkenyl. comprising at least 8 carbon atoms, preferably 8 to 30 carbon atoms, and more preferably 10 to 22 carbon atoms.

For the purposes of the present invention, the term "associative polymer" means an amphiphilic polymer capable, in an aqueous medium, of reversibly associating with itself or with other molecules. It generally comprises in its chemical structure, at least one zone or group, hydrophilic and at least one zone or group, hydrophobic. By "hydrophobic group" is meant a group or a hydrocarbon-based polymer, saturated or unsaturated, linear or branched. When it refers to a hydrocarbon group, the hydrophobic group comprises at least 10 carbon atoms, preferably from 10 to 30 carbon atoms, in particular from 12 to 30 carbon atoms and preferably from 18 to 30 carbon atoms. Preferably, the hydrophobic hydrocarbon group comes from a monofunctional compound. By way of example, the hydrophobic group may be derived from a fatty alcohol such as stearyl alcohol, dodecyl alcohol, decyl alcohol or a polyalkylene fatty alcohol such as steareth-100. It can also denote a hydrocarbon polymer such as for example polybutadiene. Among the associative polymers of the anionic type, mention may be made of: (1) those comprising at least one hydrophilic unit, and at least one fatty-chain allyl ether unit, more particularly those whose hydrophilic unit consists of an unsaturated anionic monomer; ethylenic, more particularly by a vinyl carboxylic acid, and more particularly by an acrylic acid or methacrylic acid or mixtures thereof, and whose fatty-chain allyl ether unit corresponds to the following monomer of formula (II) In which R 'denotes H or CH3, B denotes the ethyleneoxy group, n denotes an integer ranging from 1 to 100, R denotes a hydrocarbon group selected from alkyl groups; , arylalkyl, aryl, alkylaryl, cycloalkyl, comprising from 8 to 30 carbon atoms, preferably 10 to 24, and more particularly from 12 to 18 carbon atoms. For the purposes of the present invention, the term "fatty chain" is intended to mean a linear or branched alkyl or alkenyl chain containing at least 8 carbon atoms, preferably 8 to 30 carbon atoms, and more preferably 10 to 22 atoms. of carbon. A more particularly preferred unit of formula (II) is a unit in which R 'denotes H, n is equal to 10, and R denotes a stearyl (C18) group.

Anionic associative polymers of this type are described and prepared, according to an emulsion polymerization process, in patent EP-0 216 479. Among these anionic associative polymers, polymers formed from 20 to 20 are particularly preferred according to the invention. 60% by weight of acrylic acid and / or methacrylic acid, 5 to 60% by weight of C 1 -C 4 alkyl (meth) acrylates, 2 to 50% by weight of allyl ether fatty chain of formula (I), and from 0 to 1% by weight of a crosslinking agent which is a well-known copolymerizable polyethylenic unsaturated monomer, such as diallyl phthalate, allyl (meth) acrylate, divinylbenzene, (poly) ethylene glycol dimethacrylate, and methylene-bisacrylamide. Of these, the crosslinked terpolymers of methacrylic acid, ethyl acrylate, polyethylene glycol (10 moles of alkylene oxide (OE)), stearyl alcohol ether (Steareth-10), are especially preferred. those sold by CIBA under the names SALCARE SC 80 and SALCARE SC90 which are aqueous emulsions containing 30% by weight of a crosslinked terpolymer of methacrylic acid, ethyl acrylate and steareth-10-allyl ether ( 40/50/10). (2) those comprising at least one hydrophilic unit of unsaturated olefinic carboxylic acid type, and at least one hydrophobic unit of unsaturated carboxylic acid (C 10 -C 30) alkyl ester type.

Preferably, these polymers are chosen from those whose hydrophilic unit of olefinic unsaturated carboxylic acid type corresponds to the monomer of formula (III) below: ## STR1 ## in which R 1 denotes H or CH 3 or C 2 H 5 which corresponds to acrylic acid, methacrylic acid or ethacrylic acid units, and whose hydrophobic unit of unsaturated carboxylic acid (C 10 -C 30) alkyl ester type corresponds to the following monomer of formula (IV): H 2 C = CR1-COOR3 (IV) wherein R1 is H or CH3 or C2H5, which corresponds to acrylic acid, methacrylic acid or ethacrylic acid units, and preferably H (acrylate units) or CH3 (methacrylate units), R3 is a C 10 -C 30 alkyl group, and preferably a C 12 -C 22 alkyl group. Alkyl esters (Clo-C30) of unsaturated carboxylic acids according to the invention include, for example, lauryl acrylate, stearyl acrylate, decyl acrylate, isodecyl acrylate, dodecyl acrylate, and corresponding methacrylates, lauryl methacrylate, stearyl methacrylate, decyl methacrylate, isodecyl methacrylate, and dodecyl methacrylate. Anionic polymers of this type are for example described and prepared according to US Pat. Nos. 3,915,921 and 4,509,949. Among this type of anionic associative polymers, polymers formed from a monomer mixture will be used more particularly. comprising: (i) essentially acrylic acid, (ii) an ester of formula (IV) described above and wherein R1 is H or CH3, R3 is an alkyl group having 12 to 22 carbon atoms, H2C5 (iii) and a crosslinking agent, which is a well-known copolymerizable polyethylenic unsaturated monomer, such as diallyl phthalate, allyl (meth) acrylate, divinylbenzene, (poly) ethylene glycol dimethacrylate, and methylene-bisacrylamide .

Among this type of anionic associative polymers, use will more particularly be made of 95 to 60% by weight of acrylic acid (hydrophilic unit), 4 to 40% by weight of C10-C30 alkyl acrylate (hydrophobic unit) and 0 to 6% by weight of crosslinking polymerizable monomer, or those consisting of 98 to 96% by weight of acrylic acid (hydrophilic unit), 1 to 4% by weight of C 10 -C 30 alkyl acrylate ( hydrophobic pattern), and 0.1 to 0.6% by weight of crosslinking polymerizable monomer such as those described above. Among the above-mentioned polymers, the products sold by the company LUBRIZOL under the trade names PEMULEN TR1, PEMULEN TR2, CARBOPOL 1382, CARBOPOL ETD 2020, CARBOPOL ULTREZ 20 and CARBOPOL ULTREZ 21 of the INCI designation are particularly preferred according to the present invention. Acrylates / C10-30 alkyl acrylate crosspolymer, and even more preferentially PEMULEN TR1, and CARBOPOL 1382. (3) terpolymers of maleic anhydride / C30-C38 alpha-olefin / alkyl maleate such as the maleic anhydride / C30-C38 alpha-olefin copolymer / isopropyl maleate sold under the name PERFORMA V 1608 by the company NEWPHASE TECHNOLOGIES. (4) acrylic terpolymers comprising: (a) about 20% to 70% by weight of an unsaturated carboxylic acid (1,13-monoethylenic, (b) about 20 to 80% by weight of an unsaturated monomer; , (3-monoethylenic non-surfactant other than (a), (c) about 0.5 to 60% by weight of a nonionic mono-urethane which is the reaction product of a monohydric surfactant with a monoethylenically unsaturated monoisocyanate, such as those described in the patent application EP-A-0173109 and more particularly that described in Example 3, namely, a terpolymer methacrylic acid / methyl acrylate / dimethyl metaisopropenyl benzyl isocyanate ethoxylated behenyl alcohol (40%) in aqueous dispersion at 25% by weight As an example of this type of compound, mention may be made of the VISCOPHOBE DB 1000 sold by the company AMERCHOL (DOW CHEMICAL) INCI name Polyacrylate-3. (5) copolymers comprising among their monomers an acid α, β-monoethylenically unsaturated carboxylic acid and an α, β-monoethylenically unsaturated carboxylic acid ester and an oxyalkylenated fatty alcohol. Preferably, these compounds also comprise, as monomer, an unsaturated carboxylic acid ester (1,13-monoethylenic acid and (C1-C4) alcohol.) Examples of anionic associative polymers as defined above are those sold under the trade names Aculyn 88 (cross-linked oxyethylenated stearyl acrylate / methacrylate polymer) sold by the company Rohm and Haas, Novethix L-10 Polymer (acrylate polymer / cross-linked oxyethylenated behenyl methacrylate) sold by Lubrizol, Synthalen W2000 (acrylate / oxyethylenated palmityl acrylate copolymer) ) sold by the company 3V Sigma, and Rheomer 33 (Polyacrylate-33) sold by the company Rhodia In one embodiment, the anionic associative polymers defined above also comprise a carboxylic acid ester with unsaturated a, (3 mono-ethylenic and C 1 -C 4 alcohol as additional monomer As examples of this type of compound mention may be made of Aculyn 22 sold by Rohm and Haas, which is an acrylic acid / ethyl acrylate / stearyl methacrylate oxyalkylenated terpolymer, and Aculyn 28 sold by the company Rohm and Haas, which is an acidic terpolymer. acrylic / ethyl acrylate / oxyalkylenated behenyl methacrylate.

The nonionic associative polymers that can be used in the invention are preferably chosen from: (1) celluloses modified with groups comprising at least one fatty chain. By way of example, mention may be made of: hydroxyethylcelluloses modified with groups comprising at least one fatty chain, such as alkyl, arylalkyl or alkylaryl groups, or mixtures thereof, and in which the alkyl groups are preferably C8-C22, as the products NATROSOL PLUS GRADE 330 CS (alkyls in C16) or POLYSURF 67 CS sold by the company ASHLAND, or the product BERMOCOLL EHM 100 sold by the company BEROL NOBEL, - those modified by polyalkylene glycol ether alkyl phenol groups, such as the product AMERCELL POLYMER HM-1500 (polyethylene glycol (15) nonylphenol ether) sold by the company Amerchol. (2) hydroxypropyl guars modified with groups comprising at least one fatty chain such as the product ESAFLOR HM 22 (C22 alkyl chain) sold by LAMBERTI, the products RE210-18 (C14 alkyl chain) and RE205-1 ( C20 alkyl chain) sold by Rhodia Chimie. (3) inulins modified with groups comprising at least one fatty chain, such as the alkyl carbamate inulins and in particular the lauryl carbamate inulin sold by the company Orafti under the name INUTEC SPI. (4) copolymers of vinylpyrrolidone and hydrophobic fatty-chain monomers which may be mentioned by way of example: the products ANTARON V216 or GANEX V216 (vinylpyrrolidone / hexadecene copolymer) sold by the company I.S.P. products ANTARON V220 or GANEX V220 (vinylpyrrolidone / eicosene copolymer) sold by the company I.S.P. (5) copolymers of methacrylates or of C 1 -C 6 alkyl acrylates and of amphiphilic monomers comprising at least one fatty chain, such as, for example, the methyl acrylate / oxyethylenated stearyl acrylate copolymer sold by the company GOLDSCHMIDT under the name ANTIL 208. (6) copolymers of hydrophilic methacrylates or acrylates and of hydrophobic monomers comprising at least one fatty chain, such as, for example, polyethylene glycol methacrylate / lauryl methacrylate copolymer. (7) polyether polyurethanes comprising in their chain, both hydrophilic sequences most often polyoxyethylenated nature and hydrophobic sequences which may be aliphatic sequences alone and / or cycloaliphatic and / or aromatic sequences. (8) polymers having an aminoplast ether skeleton having at least one fatty chain, such as the PURE THIX compounds proposed by the company SUD-CHEMIE. The at least one nonionic associative polymer is preferably chosen from polyether polyurethanes. Preferably, the associative nonionic polyurethane polyethers according to the invention comprise at least two hydrocarbon-based lipophilic chains having from 6 to 30 carbon atoms, separated by a hydrophilic sequence, the hydrocarbon chains possibly being pendant chains or end chains. hydrophilic sequence. In particular, it is possible that one or more pendant chains are provided. In addition, the polymer may comprise a hydrocarbon chain at one end or at both ends of a hydrophilic block. The polyether polyurethanes may be multiblocked, in particular in the form of a triblock. The hydrophobic sequences may be at each end of the chain (for example: hydrophilic central block triblock copolymer) or distributed at both the ends and in the chain (multiblock copolymer for example). These same polymers may also be graft or star. The nonionic polyurethane polyethers with a fatty chain may be triblock copolymers whose hydrophilic sequence is a polyoxyethylenated chain containing from 50 to 1000 oxyethylenated groups. Nonionic polyurethane polyethers have a urethane bond between the hydrophilic blocks, hence the origin of the name.

By extension are also included among the nonionic fatty-chain polyurethane polyethers, those whose hydrophilic sequences are linked to the lipophilic blocks by other chemical bonds. As examples of fatty-chain nonionic polyurethane polyethers that may be used in the invention, mention may also be made of the urea-functional Rheolate 205 sold by the company ELEMENTIS or else the Rheolates 208, 204 or 212, as well as the Acrysol RM 184. Mention may also be made of the product ELFACOS T210 with a C12-C14 alkyl chain and the product ELFACOS T212 with a C18 alkyl chain from AKZO. The product DW 1206B from Rohm & Haas containing a C20 alkyl chain and a urethane linkage, proposed at 20% solids content in water, may also be used. It is also possible to use solutions or dispersions of these polymers, especially in water or in an aqueous-alcoholic medium. By way of example of such polymers, mention may be made of RHEOLATE 255, RHEOLATE 278 and RHEOLATE 244 sold by the company ELEMENTIS. It is also possible to use the product DW 1206F and the DW 1206J proposed by the company Rohm & Haas.

The polyether polyurethanes that can be used according to the invention are in particular those described in the article by G. Fonnum, J. Bakke and Fk. Hansen - Colloid Polym. Sci 271, 380, 389 (1993). In a variant, an associative nonionic polyurethane polyether is used which can be obtained by polycondensation of at least three compounds comprising (i) at least one polyethylene glycol comprising from 100 to 180 moles of ethylene oxide, (ii) a polyoxyethylene stearyl alcohol comprising 100 moles of ethylene oxide and (iii) a diisocyanate. Such a polymer is in particular proposed by the company ELEMENTIS under the name RHEOLATE FX 1100 ® which is a polyethylene glycol polycondensate containing 136 moles of ethylene oxide, of stearyl alcohol polyoxyethylenated with 100 moles of ethylene oxide and of hexamethylene diisocyanate (HDI) having a weight average molecular weight (Mw) of 30000 (INCI name: PEG-136 / STEARETH-100 / HDI COPOLYMER). In another variant, it is also possible to use a polyether polyurethane obtainable by polycondensation of at least three compounds comprising (i) at least one polyethylene glycol comprising from 150 to 180 moles of ethylene oxide, (ii) stearyl alcohol or decyl alcohol and (iii) at least one diisocyanate. Such polyether polyurethanes are sold in particular by the company ROHM & HAAS under the names ACULYN 46, ACULYN 44 [ACULYN 46 is a polycondensate of polyethylene glycol with 150 or 180 moles of ethylene oxide, stearyl alcohol and methylene bis (4-cyclohexyl-isocyanate) (SMDI), 15% by weight in a matrix of maltodextrin (4%) and water (81%); ACULYN 44 is a polycondensate of polyethylene glycol with 150 or 180 moles of ethylene oxide, decyl alcohol and methylene bis (4-cyclohexylisocyanate) (SMDI), at 35% by weight in a propylene glycol mixture (39 %) and water (26%)]. Preferably, the associative polymers as described above, have a number-average molecular weight of less than 500,000 and even more preferentially less than 100,000, preferably ranging from 5,000 to 80,000, which can be measured by methods such as cryoscopy, osmotic pressure, ebullioscopy, titration of terminal groups. Preferably, the anionic and / or nonionic associative polymer (s) used in the invention is or are chosen from the anionic associative polymers of the families. (2), and (5) and nonionic associative polymers. Even more particularly, the anionic and / or nonionic associative polymer (s) used in the invention is or are chosen from the products sold by the LUBRIZOL company under the trade names PEMULEN TR1, PEMULEN TR2, the oxyethylenated crosslinked stearyl acrylates / methacrylate polymer sold under the name Aculyn 88 by the company Rohm and Haas, the crosslinked oxyethylenated behenyl acrylates / methacrylate polymer sold under the name Novethix L- Polymer by the company Lubrizol, the acrylates / palmityl acrylate copolymer sold under the name Synthalen W2000 by the company 3V Sigma, an acrylic acid / ethyl acrylate / stearyl methacrylate oxyalkylenated terpolymer sold under the name ACULYN 22 by the company ROHM and HAAS, the acrylic acid / ethyl acrylate / oxyalkylenated behenyl methacrylate terpolymer sold under the name Aculyn 28 by the company Rohm et al. HAAS, polyethylene glycol polycondensate containing 150 or 180 moles of ethylene oxide, decyl alcohol and methylene bis (4-cyclohexylisocyanate) (SMDI) sold under the name Aculyn 44, polyethylene glycol polycondensate at 150 or 180 ° C. moles of ethylene oxide, stearyl alcohol and methylene bis (4-cyclohexyl-isocyanate) (SMDI) sold under the name ACULYN 46, the hexamethyl diisocyanate / polyethylene glycol copolymer terminated with alpha-omega stearyl polyoxyethylene sold under the name RHEOLATE FX1100, and mixtures thereof. Even more preferably, the associative polymer according to the invention is a nonionic associative polymer chosen from nonionic polyurethane associative polyethers (family (7)), in particular those capable of being obtained by polycondensation of at least three compounds comprising (i) at least one polyethylene glycol comprising from 100 to 180 moles of ethylene oxide, (ii) a polyoxyethylenated stearyl alcohol comprising 100 moles of ethylene oxide and (iii) a diisocyanate such as hexamethyl copolymer diisocyanate / polyethylene glycol terminated alpha-omega stearyl polyoxyethylene sold under the name RHEOLATE FX1100. The anionic and / or nonionic associative polymer (s) used in the composition of the invention are present in an amount ranging from 2 to 60% by weight, preferably ranging from 2.5 to 40% by weight and better still from 2 to , 7 to 20% by weight, or even 2.75 to 15% by weight of the total weight of the composition.

The compositions of the invention comprise one or more organic compounds of silicon of formula (I) below and / or their oligomers: R1Si (OR2), (R3) '(OH) y (I) in which: Ri is a hydrocarbon chain saturated or unsaturated, linear or branched C1-C22, which may be substituted with: an amine group NH2 or NHR, R representing a C1-C20 alkyl group, preferably a C1-C6 alkyl or a C3-C40 cycloalkyl group; or a C 6 -C 30 aromatic group, a hydroxy group, a thiol group, or an aryl group, such as benzyl, substituted or unsubstituted; which can be interrupted by a heteroatom such as O, S, NH or by a carbonyl group (CO), R 2 and R 3, which are identical or different, represent a linear or branched alkyl group comprising from 1 to 6 carbon atoms, denotes an integer from 0 to 3, and z denotes an integer from 0 to 3, and x denotes an integer from 0 to 2, with z + x + y = 3. By oligomer is meant the polymerization products of compounds of formula (I) having from 2 to 10 silicon atoms. Preferably, R2 represents an alkyl group comprising from 1 to 4 carbon atoms, more preferably a linear alkyl group comprising from 1 to 4 carbon atoms, and preferably the ethyl group. Preferably, z varies from 1 to 3. Even more preferably z is equal to 3. Preferably, the composition comprises at least one organic silicon compound chosen from octyltriethoxysilane, dodecyltriethoxysilane, octadecyltriethoxysilane and hexadecyltriethoxysilane. and γ-aminopropyltriethoxysilane.

More particularly, the composition comprises at least one organic silicon compound chosen from octyltriethoxysilane (OTES) and γ-aminopropyltriethoxysilane (APTES). In a variant, R 1 represents an alkyl group, and even more preferably a linear alkyl group comprising from 7 to 18 carbon atoms, and more particularly from 7 to 12 carbon atoms, or a C 1 -C 6 aminoalkyl group, preferably in C2-C4. More particularly, R 1 represents an octyl group. Even more preferably, in this variant, the composition comprises octyltriethoxysilane (OTES). In another variant, R 1 is a linear or branched, saturated or unsaturated C 1 -C 22 hydrocarbon-based chain substituted by an NH 2 or NHR amine group with R = C 1 -C 20 alkyl, in particular C 1 -C 6 alkyl or C 3 -C 40 cycloalkyl. or aromatic C6-C30. In this variant, R 1 preferably represents a C 1 -C 6, preferably C 2 -C 4, aminoalkyl group. Even more preferentially, in this variant, the composition comprises γ-aminopropyl triethoxysilane (APTES). The organic silicon compounds used in the composition of the invention, in particular those comprising a basic function, may be neutralized, partially or totally, in order to improve their solubility in water. In particular, the neutralizing agent is preferably chosen from organic or inorganic acids, such as citric acid, tartaric acid, lactic acid and hydrochloric acid. Preferably, the organosilicon compounds according to the invention, optionally neutralized, are soluble in water and in particular soluble at the concentration of 2% by weight, better at the concentration of 5% by weight and even better at the concentration of 10% by weight in water at 25 ° C ± 5 ° C and at atmospheric pressure. By soluble is meant the formation of a single macroscopic phase. The organic silicon compound (s) may be present in the composition according to the invention in an amount ranging preferably from 0.1 to 20% by weight, better still from 0.2 to 10% by weight, and more preferably from 0.3 to 5% by weight relative to the total weight of the composition. The compositions of the invention may further comprise one or more surfactants chosen from anionic, nonionic, amphoteric and cationic surfactants. The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups -CO2H, -O2-, -803H, -803 -0803H, -0803-, -H2PO3, -HPO3-, -PO32, -H2PO2, -HPO2-, -PO2, - POH, -P0-. As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates, alkyl aryl sulphonates, alpha-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, monoesters salts of alkyl and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether carboxylic acid salts, alkyl acid salts amidoether carboxylic acids; and the corresponding non-salified forms of all these compounds; the alkyl and acyl groups of all these compounds having from 6 to 40 carbon atoms, and preferably from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units. The salts of C 6 -C 24 alkyl monoesters and of polyglycoside-polycarboxylic acids may be chosen from C 6 -C 24 alkyl polyglycoside-citrates, C 6 -C 24 alkyl polyglycoside-tartrates and polyglycoside-sulphosuccinates. C6-C24 alkyl. When the anionic surfactants are in the form of salts, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, the salts of ammonium, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salt.

By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine, the salts of 2-amino-2-methyl-1- propanol, and 2-amino-2-methyl-1,3-propanediol methane.

The tri (hydroxymethyl) amino salts are preferably alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts. In a first variant, the additional anionic surfactants are chosen from (C6-C24) alkyl sulphates, (C6-C24) alkyl ether sulphates comprising from 2 to 50 ethylene oxide units, in particular in the form of alkali metal salts, d ammonium, aminoalcohols, and alkaline earth metals, or a mixture of these compounds. Even better, in this variant, the alkyl (C 12 -C 20) sulphates, the (C 12 -C 20) alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metal salts, ammonium salts, d aminoalcohols, and alkaline earth metals, or a mixture of these compounds. More preferably, sodium lauryl ether sulfate is preferred to 2.2 moles of ethylene oxide. In a second variant, the additional anionic surfactants are chosen from surfactants with anionic groups chosen from -C (O) OH, -C (O) O-, -SO3H, -S (O) 20-, such as alkylsulfonates, alkylamidesulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, acyllactylates, N-acyl glycinates, alkyl and acyl groups; of all these compounds having from 6 to 40 carbon atoms, preferably from 6 to 24 carbon atoms.

Very particularly, C6-40 acyl glutamates, more preferably C6-24 acyl glutamates, such as, for example, the disodium cocoyl glutamate sold under the trade name PLANTAPON ACG LC by BASF, or C6-40 acyls can be used. ) isethionates, better (C 6-24 acyl) isethionates such as, for example, sodium lauroyl methyl isethionate marketed by INNOSPEC under the trade name ISELUX LQCLR-SB. Examples of nonionic surfactants which can be used in the non-dyeing hair composition according to the invention are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178. They are chosen in particular from alcohols, alpha-diols and (CiC20) alkyl phenols, these compounds being polyethoxylated, polypropoxylated and / or polyglycerolated, and having at least one fatty chain comprising, for example, from 8 to 18 carbon atoms. the number of ethylene oxide groups and / or propylene oxide groups that can range from 2 to 50 and the number of glycerol groups that can range from 2 to 30. It is also possible to mention the ethylene oxide and ethylene oxide condensates. propylene oxide on fatty alcohols, the polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, the polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4 ethoxylated sorbitan fatty acid esters having 2 to 30 ethylene oxide units, sucrose fatty acid esters, polyethylene glycol fatty acid esters, C6-C24 alkyls; mono- or polyglycosides, the N- (C6-C24alkyl) glucamine, amine oxides such as (C10-C14) alkyl amine oxides or N- (C10-C14 acyl) aminopropylmorpholine oxides.

Particularly preferred nonionic surfactants are (C 6 -C 24) alkyl mono- or polyglycosides. The amphoteric or zwitterionic surfactants that may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, containing at least one anionic group such as, for example, a carboxylate, sulphonate, sulphate, phosphate or phosphonate, and wherein the aliphatic group or at least one of the aliphatic groups is a linear or branched chain having from 8 to 22 carbon atoms. Mention may in particular be made of (C 8 -C 20) alkyl betaines, sulfobetaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines such as cocoamidopropylbetaine and (C 8 -C 20) alkylamido (C 1 -C 6) alkyl- sulfobetaines.

Among the optionally quaternized secondary or tertiary aliphatic amine derivatives that may be used, mention may also be made of the following products of structures (V) and (VI): Ra-CONHCH 2 CH 2 -N + (Rb) (Rc) (CH 2 COO) ) (V) in which: coconut derivative Ra represents a C10-C30 alkyl or alkenyl group of a Ra-COOH acid preferably present in the hydrolyzed oil, a heptyl, nonyl or undecyl group, Rb represents a beta group hydroxyethyl, and R, represents a carboxymethyl group; Ra-CONHCH2CH2-N (B) (B ') (VI) wherein: B represents -CH2CH2OX', X 'represents the group -CH2-COOH, CH2-COOZ', -CH2CH2-COOH, -CH2CH2-COOZ ', or a hydrogen atom, B 'represents - (CH2) z-Y', with z = 1 or 2, Y 'represents -COOH, -COOZ', the group -CH2-CHOH-SO3H or -CH2-CHOH- SO3Z ', Z' represents an ion derived from an alkali metal or alkaline earth metal, such as sodium, potassium or magnesium; an ammonium ion; or an ion derived from an organic amine and especially an aminoalcohol, such as mono-, di- and triethanolamine, mono-, di- or triisopropanolamine, 2-amino-2-methyl-1 propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. Ra, represents a C10-C30 alkyl or alkenyl group of an Ra-COOH acid preferably present in coconut oil or in hydrolyzed linseed oil, an alkyl group, in particular a C17 group and its iso form, a unsaturated C17 group. These compounds are also classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, lauroamphodipropionic acid, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate. It is also possible to use compounds of formula (VIa): Ra-NH-CH (Y ") - (CH 2) .-C (O) -NH- (CH 2) n -N (Rd) (Re) (VIa) formula wherein: Y "is -C (O) OH, -C (O) OZ", -CH2-CH (OH) -SO3H or -CH2-CH (OH) -SO3-Z "; Rd and Re, independently of one another, represent a C1-C4 alkyl or hydroxyalkyl group; Z "represents a cationic counterion derived from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra- represents a C 10 -C 30 alkyl or alkenyl group of an acid Ra-C (O) OH preferably present in coconut oil or in hydrolyzed linseed oil, n and n ', independently of each other, denote an integer ranging from 1 to 3. the compounds of formula (VIa), there may be mentioned the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by CHIMEX under the name CHIMEXANE HB.

Preferably, the amphoteric or zwitterionic surfactants are chosen from (C 8 -C 20) alkyl betaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines and (C 8 -C 20) alkyl amphodiacetates, the sodium salt of lauryl. diethylaminopropyl amino succinamate and mixtures thereof.

Preferably, the amphoteric or zwitterionic surfactants are chosen from, alone or as a mixture, cocoylamidopropylbetaine, cocoylbetaine and cocoamphodiacetate. The cationic surfactant or surfactants that can be used in the composition according to the invention comprise, in particular, the optionally polyoxyalkylenated primary, secondary or tertiary fatty amine salts, the quaternary ammonium salts, and mixtures thereof. As quaternary ammonium salts, mention may be made, for example: - those corresponding to the following general formula (VII): R8 \ XR (R11 (VII) in which the groups R8 to R11, which may be identical or different, represent a linear or branched aliphatic group containing from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups R8 to R11 containing from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms The aliphatic groups may comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens.

The aliphatic groups are, for example, chosen from C1-C30 alkyl, C1-C30 alkoxy, (C2-C6) polyoxyalkylene, C1-C30 alkylamide, (C12-C22) alkylamido (C2-C6) alkyl, ( C12-C22) acetate, and C1-C30 hydroxyalkyl, X- is an anion selected from the group of halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, (C1-C4) alkyl- or alkyl (Ci C4) arylsulphonates. Of the quaternary ammonium salts of formula (VII), tetraalkylammonium chlorides, for example dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group comprises from about 12 to 22 carbon atoms, are preferred. carbon, in particular behenyltrimethylammonium, di stearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium chlorides or else palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl (myristylacetate) ammonium chloride sold under the name CERAPHYL® 70 by VAN DYK. the quaternary ammonium salts of imidazoline, such as, for example, those of formula (VIII) below: wherein R12 represents an alkenyl or alkyl group, wherein R12 represents an alkenyl or alkyl group; from 8 to 30 carbon atoms, for example derived from tallow fatty acids, X R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group containing from 8 to 30 carbon atoms, R14 represents a C1-C4 alkyl group, R15 represents a hydrogen atom, a C1-C4 alkyl group, X- is an anion chosen from the group of halides, phosphates, acetates, lactates, (C1-C4) alkyl sulphates, (C1-C4) alkyl or (C1-C4) alkylsulfonates. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl group, R15 denotes a hydrogen atom. Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO. the quaternary di- or triammonium salts, in particular of formula (IX) below: R17 R19 R16-N- (C1-12) N-R21 R18 R20 (IX) in which R16 denotes an alkyl group comprising from about 16 to 30 carbon atoms optionally hydroxylated and / or interrupted by one or more oxygen atoms, R17 is selected from hydrogen or an alkyl group having from 1 to 4 carbon atoms or a group - (CH2) 3-NP (Ri6a ) (R17a) (R18a), R16a, R17a, R18a, R18, R19, R20 and R21, which are identical or different, are chosen from hydrogen or an alkyl group containing from 1 to 4 carbon atoms, and 2+ 2X- X- is an anion chosen from the group of halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylsulphonates, in particular methylsulphate and ethylsulphate. Such compounds are, for example, the Finquat CT-P proposed by Finetex (Quaternium 89), the Finquat CT proposed by Finetex (Quaternium 75). quaternary ammonium salts containing one or more ester functions, such as, for example, those of the following formula (X): ## STR2 ## Wherein R22 is selected from C1-C6 alkyl groups and C1-C6 hydroxyalkyl or dihydroxyalkyl groups, wherein R22 is selected from C1-C6 alkyl groups and C1-C6 hydroxyalkyl or dihydroxyalkyl groups; R23 is chosen from: o - the linear R26 C group or - the R27 hydrocarbon groups containing 1 to 22 CC, branched, saturated or unsaturated, - the hydrogen atom, R 25 is chosen from: o R2c - the group the linear or branched, saturated or unsaturated C 1 -C 6 hydrocarbon-based R 29 groups, the identical or different hydrogen atom, R 24, R 26 and R 28, are chosen from linear or branched C 7 -C 21 hydrocarbon-based groups; , saturated or unsaturated, r, s and t, identical or different, are integers ranging from 2 to 6, r 1 and t 1, which may be identical or different, are equal to 0 or 1, r 2 + r 1 = 2 r and t 1 + t 2 = 2 t , y is an integer from 1 to 10 , x and z, which may be identical or different, are integers ranging from 0 to 10, X- is a simple or complex anion, organic or inorganic, provided that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and when z is 0 then R25 is R29. The alkyl groups R22 may be linear or branched and more particularly linear. Preferably, R 22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group. Advantageously, the sum x + y + z is from 1 to 10. When R 23 is a hydrocarbon R 27 group, it may be long and have 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms. When R 25 is a hydrocarbon R 29 group, it preferably has 1 to 3 carbon atoms. Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C11-C21 hydrocarbon groups, and more particularly from linear or branched, saturated C11-C21 alkyl and alkenyl groups. or unsaturated. Preferably, x and z, identical or different, are 0 or 1. Advantageously, y is equal to 1.

Preferably, r, s and t, which are identical or different, are equal to 2 or 3, and even more particularly are equal to 2. The anion X- is preferably a halide, preferably chloride, bromide or iodide, an alkyl (Ci -C4) sulfate, (C1-C4) alkyl- or (C1-C4) alkyl aryl sulfonate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function. The anion X- is even more particularly chloride, methylsulfate or ethylsulfate. In the composition according to the invention, the ammonium salts of formula (X) are used more particularly in which: R 22 denotes a methyl or ethyl group, x and y are equal to 1, z is equal to 0 or 1, - r, s and t are equal to 2, - R23 is chosen from: 0 -the group R26 C15 - the methyl, ethyl or C14-C22 hydrocarbon groups, - the hydrogen atom, - R25 is chosen among: - the group R2C - the hydrogen atom, - R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C13-C17 hydrocarbon groups, and preferably from linear or branched, saturated or unsaturated C13-C17 alkyl and alkenyl groups. Advantageously, the hydrocarbon groups are linear. Examples of the compounds of formula (X) include salts, especially diacyloxyethyldimethylammonium chloride, diacyloxyethylhydroxyethylmethylammonium chloride, monoacyloxyethyldihydroxyethylmethylammonium chloride, triacyloxyethylmethylammonium chloride, monoacyloxyethylhydroxyethyldimethylammonium chloride, and mixtures thereof. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different. These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine optionally oxyalkylenated on fatty acids or mixtures of fatty acids of plant or animal origin, or by transesterification. of their methyl esters. This esterification is followed by quaternization using an alkylating agent, such as an alkyl halide, preferably methyl or ethyl, a dialkyl sulphate, preferably methyl or ethyl sulfate. ethyl, methyl methanesulfonate, methyl para-toluenesulfonate, chlorohydrin glycol or glycerol. Such compounds are, for example, sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. By way of examples of such compounds, mention may be made of distearoylethylhydroxyethylmethylammonium or dipalmitoylethylhydroxyethylmethylammonium salts, and in particular the methosulphates. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180. It is also possible to use behenoylhydroxypropyltrimethylammonium chloride, for example, proposed by KAO under Quartamin BTC 131. Preferably, the ammonium salts containing at least one ester function contain two ester functions. Among the cationic surfactants, it is more particularly preferred to choose the salts of cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethyl-hydroxyethylmethylammonium, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride and dipalmitoylethylhydroxyethylammonium methosulfate. , and their mixtures.

In one embodiment of the invention, the composition comprises one or more surfactants chosen from anionic, nonionic, amphoteric and cationic surfactants, in particular from nonionic surfactants such as (C 6 -C 24) alkyl mono - or polyglycosides, and anionic surfactants, in particular (C6-C40 acyl) glutamates or (C6-C40 acyl) isethionates. The composition according to the invention preferably has a total content of surfactants of less than or equal to 10% by weight, better still less than 8% by weight and better still less than 7.5% by weight relative to the total weight of the composition.

More particularly, the total content of surfactant (s) can range from 0.1 to 10% by weight, better still from 1 to 8% by weight, and still more preferably from 1.5 to 7.5% by weight relative to total weight of the composition. When at least one surfactant is present, the weight ratio of the total amount of surfactant (s) to the total amount of associative anionic and / or nonionic polymer (s) is preferably less than 3, more preferably 0.01 to 2.8, and more preferably 0.1 to 2.5. The composition according to the invention may also comprise one or more polymers, different from the nonionic or anionic associative polymers according to the invention, and especially chosen from cationic or amphoteric polymers, as well as their mixtures. The term "cationic polymer" means any polymer comprising cationic groups and / or ionizable groups into cationic groups. Preferably, the cationic polymer is hydrophilic or amphiphilic. The preferred cationic polymers are chosen from those containing units containing primary, secondary, tertiary and / or quaternary amine groups that may either be part of the main polymer chain or may be carried by a lateral substituent directly connected thereto. The cationic polymers that may be used preferably have a weight average molecular weight (Mw) of between about 500 and 5 × 10 6, preferably between about 103 and 3 × 10 6.

Among the cationic polymers, mention may be made more particularly of: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units: I3 R 13 CI-1 C- I - CHF? - 0 = C 0 = CII 0 0 IA IA X-I / N R4 N + -R6 \ 1 R2 R1 R5 I3 I3 CI-1 C- -CI-1 C- II 0 = C 0 = CI NH NH XIIAA In which: R3, which may be identical or different, denote a hydrogen atom or a CH3 group; A, which may be identical or different, represent a divalent alkyl group, linear or branched, of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; - R4, R5, R6, identical or different, represent an alkyl group having 1 to 18 carbon atoms or a benzyl group; preferably an alkyl group having 1 to 6 carbon atoms; - R1 and R2, identical or different, represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, preferably methyl or ethyl; X denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide. The copolymers of the family (1) may further contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetones acrylamides, acrylamides and methacrylamides substituted on the nitrogen by C1-C4 alkyls, acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Among these copolymers of family (1), mention may be made of: copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC by Hercules, copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride, such as those sold under the name BINA QUAT P 100 by Ciba Geigy; copolymer of acrylamide and of methacryloyloxyethyltrimethylammonium methosulphate, such as that sold under the name RETEN by the company HERCULES, - vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers, quaternized or otherwise, such as the products sold under the name "GAFQUAT" by the company ISP, for example "GAFQUAT 734" or "GAFQUAT 755" or else the products referred to as "COPOLYMER 845, 958 and 937". These polymers are described in detail in the French patents 2,077,143 and 2,393,573, the terpolymers of dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone, such as the product sold under the name GAFFIX VC 713 by the company ISP, the vinylpyrrolidone / methacrylamidopropyldimethylamine copolymers. , such as those marketed under the name STYLEZE CC 10 by ISP; quaternized vinylpyrrolidone / dimethylaminopropylmethacrylamide copolymers, such as the product sold under the name "GAFQUAT HS 100" by ISP, - polymers, preferably crosslinked, of methacryloyloxyalkyl (C 1 -C 4) trialkyl (C 1 -C 4) salts; such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with methyl chloride, the homo- or copolymerization being followed by a crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion comprising 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name "SALCARE® SC 92" by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride comprising about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are sold under the names "SALCARE® SC 95" and "SALCARE® SC 96" by the company CIBA. (2) cationic polysaccharides, especially cationic celluloses and galactomannan gums. Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives containing quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums. The cellulose ether derivatives containing quaternary ammonium groups are especially described in FR1492597, and mention may be made of the polymers sold under the name "UCARE POLYMER JR" (JR 400 LT, JR 125, JR 30M) or "LR" (LR). 400, LR 30M) by the company AMERCHOL. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose reacted with an epoxide substituted by a trimethylammonium group. The cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, are described in particular in the US4131576 patent, and mention may be made of hydroxyalkylcelluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl cellulose grafted in particular with a salt methacryloylethyl trimethylammonium, methacrylamidopropyl trimethylammonium, dimethyl diallylammonium. The marketed products corresponding to this definition are more particularly the products sold under the name "Celquat L 200" and "Celquat H 100" by the company National Starch. The cationic galactomannan gums are described more particularly in the patents US Pat. No. 3,098,578 and US Pat. No. 4,031,307, and mention may be made of guar gums comprising cationic trialkylammonium groups. For example, guar gums modified with a salt (for example a chloride) of 2,3-epoxypropyltrimethylammonium are used. Such products are marketed in particular under the names Jaguar C13 S, Jaguar C 15, Jaguar C 17 or Jaguar C162 by Rhodia. (3) polymers consisting of piperazinyl units and linear or branched chain alkylene or hydroxyalkylene divalent groups, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. (4) water-soluble polyaminoamides, prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide or else by an oligomer resulting from the reaction of a bifunctional compound which is reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halogenide, epilhalohydrin, diepoxide or bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 moles per amine group of the polyaminoamide; these polyaminoamides can be alkylated or if they comprise one or more tertiary amine functional groups, quaternized. (5) polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid-dialkylaminohydroxyalkyldialkylenetriamine polymers in which the alkyl group contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl or propyl. Among these derivatives, mention may be made more particularly of the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz. (6) polymers obtained by reacting a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms; the molar ratio between the polyalkylene polyamine and the dicarboxylic acid being preferably between 0.8: 1 and 1.4: 1; the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide preferably between 0.5: 1 and 1.8: 1. Polymers of this type are in particular sold under the name "Hercosett 57" by the company Hercules Inc. or under the name "PD 170" or "Delsette 101" by the company Hercules in the case of the adipic acid copolymer / epoxypropyl / diethylenetriamine. (7) cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (PI) or (PII): - (CH2) t- - CR12 C (R12) -CH2- (PI) N + Y- (PII) H2CCH II \ 2 (CH2) k - (CH2) t- - CR12 C (R12) -CH2-H2CN / CH2 / \ (CH2) k N 1 p in which: k and t are equal to 0 or 1, the sum k + t being equal to 1; - R12 denotes a hydrogen atom or a methyl group; R 10 and R 11, independently of each other, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group has 1 to 5 carbon atoms, an amidoalkyl group containing C4; or R10 and R11 may together with the nitrogen atom to which they are attached designate heterocyclic groups, such as piperidinyl or morpholinyl; R 10 and R 11, independently of one another, preferably denote an alkyl group having 1 to 4 carbon atoms. - Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. Mention may be made more particularly of the homopolymer of dimethyldiallylammonium salts (for example chloride) for example sold under the name "Merquat 100" by the company NALCO (and their homologues of low average molecular weight by weight) and the salt copolymers ( for example chloride) of diallyldimethylammonium and acrylamide sold in particular under the name "MERQUAT 550" or "MERQUAT 7SPR". (8) quaternary diammonium polymers comprising recurring units of formula: ## STR2 ## in which: R13, R14, R15 and R16, which are identical, R13 R13 R15 1 1 N + -A1-N + -B1 (PIII) II R14 X-R16 X- or different, represent aliphatic, alicyclic, or arylaliphatic groups comprising from 1 to 20 carbon atoms or hydroxyalkylaliphatic groups Ci-C4, or R13, R14, R15 and R16, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally comprising a second heteroatom other than nitrogen or R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl group substituted with a nitrile, ester, acyl, amide or - CO-O-R17-D or -CO-NH-R17-D where R17 is an alkylene and D is a quaternary ammonium group; Al and B1 represent divalent polymethylenic groups comprising from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and which may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and - X- denotes an anion derived from a mineral or organic acid; it being understood that A1, R13 and R15 can form with the two nitrogen atoms to which they are attached, a piperazine ring. In addition, if Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene group, B1 can also denote a - (CH2) .- CO-D-OC- (CH2) .- group in which D denotes: a) a glycol residue of formula -O-Z-O-, where Z denotes a linear or branched hydrocarbon group or a group corresponding to one of the following formulas: - (CH 2 -CH 2 -O) '- CH 2 -CH 2 - and - [CH2-CH (CH3) -O] y-CH2-CH (CH3) - where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing a average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon group, or the divalent group -CH 2 -CH 2 -S-S-CH 2 -CH 2 -; d) a ureylene group of formula: -NH-CO-NH-. Preferably, X- is an anion such as chloride or bromide. These polymers have a number-average molecular weight (Mn) generally of between 1000 and 100000. Mention may be made more particularly of polymers which consist of repeating units corresponding to the formula: R 1 R 3 1 + 1 + - N - (CH 2) n Wherein R1, R2, R3 and R4, which may be identical or different, denote an alkyl or hydroxyalkyl group having from 1 to about 4 carbon atoms, n and p are integers ranging from about 2 to about 20 and X- is an anion derived from a mineral or organic acid. A particularly preferred compound of formula (PIV) is that for which R1, R2, R3 and R4 represent a methyl group, n = 3, p = 6 and X = Cl, called Hexadimethrine chloride according to the INCI nomenclature (CTFA). (9) quaternary polyammonium polymers comprising units of formula (PV): R 18 R 2, I - N + - (Cl - 12) r - NEI - CO - (Cl - 12) q - CO - NEI - (CH 2) s In which: R18, R19, R20 and R21, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl or P-hydroxyethyl group; 13-hydroxypropyl or -CH2CH2 (OCH2CH2) pOH, where p is 0 or an integer of 1 to 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom, - and s, which may be identical or different, are integers between 1 and 6, q is 0 or an integer from 1 to 34, X represents an anion such as a halide, - A denotes a radical of a dihalide or is preferably -CH2-CH2-O-CH2-CH2-. It is possible, for example, to mention the products "Mirapol® A 15", "Mirapol® AD1", "Mirapol® AZ1" and "Mirapol® 175" sold by Miranol. (10) Quaternary polymers of vinylpyrrolidone and of vinylimidazole such as, for example, the products sold under the names Luviquat® FC 905, FC 550 and FC 370 by the company B.A.S.F. (11) Polyamines such as Polyquart® H sold by COGNIS, referenced under the name "POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE" in the CTFA dictionary. (12) polymers comprising in their structure: (a) one or more units corresponding to the following formula (A): NI-12 (A) (b) optionally one or more units corresponding to the following formula (B): In other words, these polymers may in particular be chosen from homo- or copolymers comprising one or more units derived from vinylamine and optionally one or more units derived from vinylformamide.

Preferably, these cationic polymers are chosen from polymers comprising, in their structure, from 5 to 100 mol% of units corresponding to formula (A) and from 0 to 95 mol% of units corresponding to formula (B) , preferably from 10 to 100 mol% of units corresponding to formula (A) and from 0 to 90 mol% of units corresponding to formula (B). These polymers can be obtained for example by partial hydrolysis of polyvinylformamide. This hydrolysis can be done in acidic or basic medium.

The weight average molecular weight of said polymer, measured by diffraction of light, can vary from 1000 to 3,000,000 g / mol, preferably from 10,000 to 1,000,000 and more particularly from 100,000 to 500,000 g / mol. The cationic charge density of these polymers can vary from 2 to 20 meq / g, preferably from 2.5 to 15 meq / g, and more particularly from 3.5 to 10 meq / g. The polymers comprising units of formula (A) and optionally units of formula (B) are sold, for example, under the name LUPAMIN by BASF, such as, for example, and without limitation, the products sold under the name LUPAMIN 9095. , LUPAMIN 5095, LUPAMIN 1095, LUPAMIN 9030 (or LUVIQUAT 9030) and LUPAMIN 9010. Other cationic polymers that can be used in the context of the invention are cationic proteins or hydrolysates of cationic proteins, polyalkyleneimines, in particular polyethyleneimines, polymers comprising vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives. Preferably, the cationic polymers are chosen from those of families (1), (2), (7) and (10) mentioned above. Among the cationic polymers mentioned above, it is preferable to use cationic polysaccharides, in particular cationic celluloses and galactomannan gums, and in particular quaternary cellulose ether derivatives such as the products sold under the name "JR 400. "By the company AMERCHOL, cationic cyclopolymers, in particular homopolymers or copolymers of salts (for example chloride) of dimethyldiallylammonium, sold under the names MERQUAT 100, MERQUAT 550 and MERQUAT S by the company NALCO and their homologues of low molecular weight in weight, vinylpyrrolidone and vinylimidazole quaternary polymers, optionally crosslinked homopolymers or copolymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts; and their mixtures. It is also possible to use amphoteric polymers, which may preferably be chosen from amphoteric polymers comprising the repetition of: (i) one or more units derived from a monomer of the (meth) acrylamide type, (ii) one or several units derived from a monomer of the (meth) acrylamidoalkyl-trialkylammonium type, and (iii) one or more units derived from an acid monomer of (meth) acrylic acid type.

Preferably, the units derived from a monomer of (i) (meth) acrylamide type are units of the following structure (Ia): ## STR2 ## in which R 1 denotes H or CH 3, and R 2 is chosen from an amino, dimethylamino group. , tert-butylamino, dodecylamino, or -NH-CH2OH.

Preferably, said amphoteric polymer comprises the repetition of only one unit of formula (Ia). The unit derived from a monomer of (meth) acrylamide type of formula (Ia) in which R1 denotes H and R2 is an amino group (NH2) is particularly preferred. It corresponds to the acrylamide monomer itself. Preferably, the units derived from a monomer of (ii) CI-12 (1a) (meth) acrylamidoalkyltrialkylammonium type are units of the following structure (IIa): R 3 CH 2 O NH Y (11 a) 4 R 5 N -R R 6 7 wherein: - R3 denotes H or CH3, - R4 denotes a group (CH2) k with k an integer ranging from 1 to 6, and preferably from 2 to 4; - R5, R6 and R7, identical or different, each denote an alkyl group having 1 to 4 carbon atoms; - Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. Preferably, said amphoteric polymer comprises the repetition of only one unit of formula (IIa). Among these units resulting from a (meth) acrylamidoalkyltrialkylammonium type monomer of formula (IIa), those derived from methacrylamidopropyltrimethylammonium chloride monomer, for which R3 denotes a methyl group, k is 3, R5, R6 and R7 denote a methyl group, and Y- denotes a chloride anion. Preferably, the units derived from a monomer of (iii) (meth) acrylic acid type are units of formula (IIIa): R 8 CH 2 (111a) 0 R 9 in which R 8 denotes H or CH 3, and R 9 denotes a hydroxyl group or -NH-C (CH3) 2-CH2-SO3H.

The preferred units of formulas (IIIa) correspond to the monomers acrylic acid, methacrylic acid and 2-acrylamino-2-methyl propane sulfonic acid. Preferably, the unit derived from a (meth) acrylic acid monomer of formula (Ma) is that derived from acrylic acid, for which R 8 denotes a hydrogen atom and R 9 denotes a hydroxyl group. The acid monomer (s) of the (meth) acrylic acid type may be unneutralized, or partially or completely neutralized with an organic or inorganic base. Preferably, said amphoteric polymer comprises the repetition of only one unit of formula (Ma). According to a preferred embodiment of the invention, the amphoteric polymer or polymers of this type comprise at least 30 mol% of units derived from a monomer of (i) (meth) acrylamide type. Preferably, they comprise from 30 to 70 mol% of units derived from a (meth) acrylamide type monomer, more preferably from 40 to 60 mol%. The content of units derived from a monomer of the type (ii) (meth) acrylamido alkyltrialkylammonium may advantageously be from 10 to 60%, preferably from 20 to 55% by moles. The content of units derived from an acidic monomer of (iii) (meth) acrylic acid type may advantageously be from 1 to 20%, preferably from 5 to 15% by mole.

According to a particularly preferred embodiment of the invention, the amphoteric polymer of this type comprises: from 30 to 70 mol% of units derived from a monomer of (i) (meth) acrylamide type, more preferably from From 40 to 60 mol%, from 10 to 60 mol%, preferably from 20 to 55 mol%, of units derived from a monomer of (ii) (meth) acrylamidoalkyltrialkylammonium type, and from 1 to 20% by weight; moles, preferably from 5 to 15 mol%, of units derived from a monomer of (iii) (meth) acrylic acid type.

This type of amphoteric polymers may also comprise additional units, different from the units derived from a monomer of (meth) acrylamide type, of (meth) acrylamidoalkyltrialkylammonium type and (meth) acrylic acid type as described above.

However, according to a preferred embodiment of the invention, said amphoteric polymers consist solely of units derived from monomers of (i) (meth) acrylamide type, (ii) (meth) acrylamidoalkyltrialkylammonium type and (iii) acid type. (meth) acrylic acid.

As examples of particularly preferred amphoteric polymers, mention may be made of acrylamide / methacrylamidopropyltrimethylammonium chloride / acrylic acid terpolymers. Such polymers are listed in the C.T.F.A. International Cosmetic Ingredient Dictionary, 10th edition 2004, under the name "Polyquaternium 53". Corresponding products are in particular sold under the names MERQUAT 2003 and MERQUAT 2003 PR by the company NALCO. As another type of amphoteric polymer that may be used, mention may also be made of copolymers based on (meth) acrylic acid and on a dialkyldiallylammonium salt, such as copolymers of (meth) acrylic acid and sodium chloride. dimethyldiallyl ammonium. We can cite for example the Merquat 280 proposed by the company NALCO. The composition according to the invention may comprise cationic and / or amphoteric, preferably cationic, polymers in an amount ranging from 0.01 to 5% by weight, in particular from 0.05 to 3% by weight, preferably 0.1 at 2% by weight, relative to the total weight of the composition. The cosmetic composition according to the invention may be in any of the galenical forms conventionally used, and especially in the form of an aqueous, alcoholic or aqueous-alcoholic solution or suspension, or an oily solution; a solution or dispersion of the lotion or serum type; an emulsion, in particular of liquid or semi-liquid consistency, of the oil-in-water (O / W), water-in-oil (W / O) or multiple type; a suspension or emulsion of soft consistency of cream (O / W) or (W / O) type; an aqueous or anhydrous gel, or any other cosmetic form. The composition according to the invention is preferably aqueous and then comprises water at a concentration preferably ranging from 5 to 98% by weight, in particular from 20 to 95% by weight, better still from 50 to 95% by weight, by weight. relative to the total weight of the composition. The composition may also comprise one or more organic solvents liquid at 25 ° C., especially water-soluble, such as C 1 -C 7 alcohols, and especially C 1 -C 7 aliphatic or aromatic monoalcohols, polyols and polyethers. C3-C7 polyols, which can be used alone or mixed with water. Advantageously, the organic solvent may be chosen from ethanol, isopropanol and mixtures thereof.

The pH of the composition, if it is aqueous, is preferably between 3 and 9, especially between 3 and 7. The composition according to the invention may further contain one or more additives chosen from fatty substances such as fatty alcohols. C12-C30, fatty esters such as isopropyl myristate, mineral, vegetable or synthetic oils such as α-olefins; silicones, ceramides, thickeners or viscosity regulators, natural or synthetic, different from the associative polymers described above; anti-dandruff active ingredients, vitamins or provitamins; pearling agents; pH stabilizers, preservatives; dyes; and their mixtures. These additives may be present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition. Those skilled in the art will take care to choose these optional additives and their amounts so that they do not adversely affect the properties of the compositions of the present invention. The compositions according to the invention may be present, in a nonlimiting manner, in the form of human hair washing products, in particular shampoos, conditioning products such as conditioners, or both. The composition may be in the form of already formed foam, aerated cream or not. It can also be in the form of an aerosol, in combination with a propellant gas. The invention further relates to the use of the composition as defined above for the cleaning and / or conditioning of human hair. The present invention also relates to a method of washing / cleaning and / or conditioning human hair, which comprises applying to human hair an effective amount of a composition as described above and rinsing. The invention is illustrated by the following examples.

Examples The compositions according to the invention are prepared from the ingredients indicated in the table below. The amounts indicated are expressed in% by weight of product as is relative to the total weight of the composition. Example 1 Example 2 Example 3 PEG-136 / STEARETH-100 / HDI Copolymer (Elementis RHEOLATE FX1100) 3 3 2.91 Cocoglucoside at 52% by weight of active ingredient (PLANTACARE 818 UP BASF) 9 9 8.73 Disodium cocoyl glutamate at 31.3% by weight of active ingredient (PLANTAPON ACG LC BASF) 5 5 4.85 Polyquaternium -10 (UCARE POLYMER JR400 LT from DOW CHEMICAL) 0.22 0.22 0.21 Aminopropyl triethoxysilane (KBE-903 from SHIN ETSU) 0.5 - 0.485 Octyltriethoxysilane (DYNASYLAN OCTEO from DEGUSSA) - 2 - Isopentane / isobutane mixture ( 75/25) (NOVASPRAY IP / IBU from INVENTEC) - - 3 Water Qs 100% 100% 100% Foaming detergent compositions are obtained which can be used for cleaning the hair and leading to good cosmetic properties on the skin. dry hair.

Claims (15)

REVENDICATIONS1. Non-coloring hair composition comprising: from 2 to 60% by weight, relative to the total weight of the composition, of one or more anionic or nonionic associative polymers, and one or more organic compounds of the formula ( I) and / or their oligomers: R1Si (OR2), (R2) '(OH) y (I) in which: R1 is a linear or branched, saturated or unsaturated, C1-C22 hydrocarbon chain which may be substituted by an amine group NH 2 or NHR, R representing a C 1 -C 20 alkyl, preferably C 1 -C 6 alkyl, C 3 -C 40 cycloalkyl or C 6 -C 30 aromatic group, a hydroxyl group, a thiol group, or an aryl group, such as benzyl, substituted or otherwise; R 1 which may be interrupted by a heteroatom such as O, S, NH or by a carbonyl group (CO), R 2 and R 3, which may be identical or different, represent a linear or branched alkyl group comprising from 1 to 6 carbon atoms, y denotes an integer from 0 to 3, and z denotes an integer from 0 to 3, and x denotes an integer from 0 to 2, with z + x + y = 3. 2. Composition according to claim 1, characterized in that the (s) associative polymer (s) is or are anionic (s), in particular chosen (s) from: (1) those comprising at least one hydrophilic unit , and at least one fatty-chain allyl ether unit, more particularly those whose hydrophilic unit is constituted by an ethylenic unsaturated anionic monomer, (2) those comprising at least one hydrophilic unit of unsaturated olefinic carboxylic acid type, and at least one a hydrophobic unit of unsaturated carboxylic acid (C10-C30) alkyl ester type, (3) maleic anhydride / C30-C38 alpha-olefin / alkyl maleate terpolymers, (4) acrylic terpolymers comprising (a) about 20% to 70% by weight of an unsaturated carboxylic acid (1,13-monoethylenic, (b) about 20 to 80% by weight of an α, (-monoethylenically unsaturated monomer; surfactant other than (a), (c) about 0.5 to 60% by weight of a nonionic mono-urethane which is the reaction product of a monohydric surfactant with a monoethylenically unsaturated monoisocyanate, and (5) copolymers having among their monomers an α, β-monoethylenically unsaturated carboxylic acid and an unsaturated carboxylic acid ester. , 3-monoethylenic and an oxyalkylenated fatty alcohol. 3. Composition according to claim 1, characterized in that the (s) associative polymer (s) is or are nonionic (s), in particular chosen (s) from: (1) celluloses modified by groups comprising at least one fatty chain, (2) hydroxypropyl guars modified with groups containing at least one fatty chain, (3) inulins modified with groups comprising at least one fatty chain, (4) copolymers of vinylpyrrolidone and of monomers hydrophobic fatty-chain compounds, (5) copolymers of C 1 -C 6 alkyl methacrylates or acrylates and amphiphilic monomers having at least one fatty chain, (6) copolymers of hydrophilic methacrylates or acrylates and hydrophobic monomers comprising at least one fatty chain, (7) polyether polyurethanes comprising in their chain, both hydrophilic sequences most often of polyoxyethylenated nature and hydrophobic sequences which may be aliphatic linkages alone and / or cycloaliphatic and / or aromatic linkages, and (8) aminoplast ether backbone polymers having at least one fatty chain. 4. Composition according to claim 1 or 3, characterized in that the (s) nonionic associative polymer (s) is (are) chosen from polyether polyurethanes having in their chain, at the both hydrophilic sequences most often polyoxyethylenated nature and hydrophobic sequences which may be aliphatic sequences alone and / or cycloaliphatic and / or aromatic sequences. 5. Composition according to any one of the preceding claims, characterized in that the (s) associative polymer (s) anionic (s) and / or nonionic (s) is or are present (s) in a amount ranging from 2.5 to 40% by weight, preferably ranging from 2.7 to 20% by weight and better still from 2.75 to 15% by weight relative to the total weight of the composition. 6. Composition according to any one of the preceding claims, characterized in that the (s) compound (s) organic (s) silicon are selected from the compounds of formula (I) and / or their oligomers, wherein R2 represents an alkyl group comprising from 1 to 4 carbon atoms, more preferably a linear alkyl group comprising from 1 to 4 carbon atoms, and preferably the ethyl group; R 1 represents an alkyl group, and even more preferably a linear alkyl group, comprising from 7 to 18 carbon atoms and more particularly from 7 to 12 carbon atoms; and z varies from 1 to 3, even more preferably z is equal to 3. 7. Composition according to any one of the preceding claims, characterized in that the (s) compound (s) organic (s) silicon are selected from the compounds of formula (I) and / or oligomers, wherein R2 represents a an alkyl group comprising 1 to 4 carbon atoms, more preferably a linear alkyl group comprising 1 to 4 carbon atoms, and preferably the ethyl group; R 1 is a linear or branched, saturated or unsaturated C 1 -C 22 hydrocarbon-based chain substituted by an NH 2 or NHR amine group with R = C 1 -C 20 alkyl, especially C 1 -C 6 alkyl, C 3 -C 40 cycloalkyl or C 6 -C aromatic ring; C30, and preferably R1 represents a C1-C6 aminoalkyl group, preferably a C2-C4 aminoalkyl group; and z varies from 1 to 3, even more preferably z is equal to 3. 8. Composition according to any one of the preceding claims, characterized in that the (s) organic compound (s) of silicon are selected from octyltriethoxysilane, 3-aminopropyltriethoxysilane and mixtures thereof. 9. Composition according to any one of the preceding claims, characterized in that the organic compound (s) of the silicon of formula (I) and / or their oligomers is or are present in a quantity ranging from 0.1 to 20% by weight, preferably from 0.2 to 10% by weight, and more preferably from 0.3 to 5% by weight relative to the total weight of the composition. 10. Composition according to any one of the preceding claims, characterized in that it comprises one or more anionic, nonionic, amphoteric and / or cationic surfactants, preferably anionic and / or nonionic surfactants. 11. Composition according to any one of the preceding claims, characterized in that the (s) surfactant (s) anionic (s), nonionic (s), amphoteric (s) and / or cationic (s) is or are present in an amount of less than or equal to 10% by weight, more preferably ranging from 0.1 to 10% by weight, preferably 1 to 8% by weight, or even 1.5 to 7.5% by weight per relative to the total weight of the composition. 12. Composition according to claim 11, characterized in that the weight ratio of the total amount of anionic surfactant (s), nonionic (s), amphoteric (s) and / or cationic (s) on the total amount. The anionic and / or nonionic associative polymer (s) is less than 3, preferably from 0.01 to 2.8, more preferably from 0.1 to 2.5. 13. Composition according to any one of the preceding claims, characterized in that it comprises one or more cationic polymers, preferably in an amount ranging from 0.01 to 5% by weight, especially from 0.05 to 3% by weight. preferably from 0.1 to 2% by weight relative to the total weight of the composition 14. Use of the composition according to any one of the preceding claims, for cleaning and / or conditioning human hair. A method of washing human hair, comprising applying a non-coloring hair composition according to any one of claims 1 to 13 to human hair, and rinsing it.