FR2984155A1 - Cosmetic composition, useful for washing/cleaning body or conditioning hair, comprises hydrophobically modified celluloses that have hydrophobic groups and comprise main chain constituted by nonionic cellulose ether, and vegetable oil - Google Patents

Abstract

Cosmetic composition comprises hydrophobically modified celluloses having hydrophobic groups (greater than 0.6 wt.%), and vegetable oil, where: the celluloses comprise a main chain constituted by a nonionic cellulose ether on which hydrophobic groups are provided; and the hydrophobic groups comprise (1) 3-alkoxy-2-hydroxy group (3-6C alkyl) in which the fragment alkoxy is linear or branched and comprises 5-30C, preferably 3-alkoxy-2-hydroxypropyl group and/or (2) 9-30C (preferably 12-18C) alkyl and 6-30C aryl, arylalkyl and alkylaryl groups. Cosmetic composition comprises hydrophobically modified celluloses having hydrophobic groups (greater than 0.6 wt.%), and vegetable oil, where: the celluloses comprise a main chain constituted by a nonionic cellulose ether on which hydrophobic groups are provided; the hydrophobic groups comprise (1) 3-alkoxy-2-hydroxy group (3-6C alkyl) in which the fragment alkoxy is linear or branched and comprises 5-30C, preferably 3-alkoxy-2-hydroxypropyl group and/or (2) 9-30C (preferably 12-18C) alkyl and 6-30C aryl, arylalkyl and alkylaryl groups; and the hydrophobically modified celluloses does not comprise 3-8C non alkoxylated alkyl group. An independent claim is included for conditioning hair or washing/cleaning body, comprising applying the composition on the keratinous material and then rinsing.

Description

B11-2832EN 1 Cosmetic composition comprising a hydrophobically modified cellulose and a vegetable oil.

The present invention relates to a composition for the cosmetic treatment of keratinous substances, in particular human keratinous fibers such as the hair, comprising one or more particular hydrophobically modified celluloses, and one or more vegetable oils. The present invention also relates to a process for the cosmetic treatment of keratin materials using such a composition as well as a cosmetic use of said composition.

In the hair cosmetic field, it is sought to treat keratin fibers subjected to various external aggressions. Indeed, these fibers can undergo assaults of various origins, such as mechanical aggression, for example related to disentangling or blow drying, or chemical aggression, for example following a coloring or a permanent. These attacks have repercussions on the qualities of the keratinous fiber and can induce a difficult disentangling at the time of the washing of the hair, on dry hair and / or wet hair as well as a degradation of the surface properties of the fibers, which become on the surface not smooth and irregular, especially when the hair is dry. There are care products for washing the hair while conditioning, known as conditioning shampoos, or only conditioning, which can limit these phenomena. These products generally contain one or more keratin fiber conditioning agents, such as cationic polymers and / or cationic surfactants. These compounds are deposited on the keratin fibers and make it possible to improve the state of the fibers and thus their cosmetic properties.

However, while improving the cosmetic properties of the hair, these compounds, used in skincare products, are not totally environmentally friendly. There is therefore a need to develop cosmetic compositions that are less ecotoxic or non-ecotoxic, to condition the hair satisfactorily or even higher than the compositions of the state of the art. The Applicant has now discovered that, surprisingly, the combination of a particular hydrophobically modified cellulose with at least one vegetable oil, made it possible to achieve the objectives set out above. These particular celluloses are described in particular in international patent application WO 2006/065848. The subject of the present invention is therefore a cosmetic composition for cleaning the body or for conditioning the hair, comprising one or more hydrophobically modified celluloses having a content of hydrophobic group (s) (hydrophobization rate) greater than 0.6. % by weight, based on the total weight of the hydrophobically modified cellulose, as described below, and one or more vegetable oils. This particular combination has proved particularly suitable for the care of dry or wet hair, and has made it possible to improve their cosmetic properties, and in particular to provide greater ease of shaping and more volume, soft and regular touch, very good properties of flexibility and shine, and good ease of disentangling. In addition, this cosmetic composition is more eco-friendly, that is to say less ecotoxic with respect to the environment. The present invention also relates to a method of conditioning the hair or washing / cleaning the body, comprising applying to the keratin materials a composition according to the invention.

In particular, the composition according to the invention may be rinsed or not, applied under the effect of heat or not, and associated or not with chemical and / or mechanical treatments of the hair. Preferably, the compositions according to the invention are used for conditioning the hair or washing / cleaning the body. Other objects, features, aspects and advantages of the invention will emerge even more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field, especially in the expressions "between" and "from ... to". In addition, the expression "at least one" is equivalent to the expression "one or more".

According to the invention, the cosmetic composition comprises one or more hydrophobically modified celluloses having a content of hydrophobic group (s) greater than 0.6% by weight, relative to the total weight of the hydrophobically modified cellulose, and one or more a plurality of vegetable oils, said one or more hydrophobically modified celluloses comprising a main chain consisting of a non-ionic cellulose ether on which is attached to one or more hydrophobic groups chosen from: 1) 3-alkoxy-2-hydroxy groups (C 3 -C 6) alkyl in which the alkoxy moiety is branched or linear and has 5 to 30 carbon atoms, preferably 3-alkoxy-2-hydroxypropyl, 2) C 9 -C 30 alkyl, preferably in C 10 -C 22, better still in C 12 -C 18, and aryl, arylalkyl and C 6 -C 30 alkylaryl groups. The aryl, arylalkyl and alkylaryl groups preferably contain 7, more preferably 8, and even more preferably 10 carbon atoms, up to 22, even more preferably up to 18, and even more preferably up to 16 carbon atoms. , 3) and mixtures thereof, said hydrophobically modified cellulose or celluloses not having a non-alkoxylated C3-8 alkyl group. Examples of alkoxy groups in the 3-alkoxy-2-hydroxy (C 3 -C 6) alkyl group are hexyloxy, 2-ethylhexyloxy, octyloxy, cetyloxy and octadecyloxy. Examples of the hydrophobic group of family 2) are especially the decyl, undecyl, dodecyl (or lauryl), tridecyl, tetradecyl (or myristyl), pentadecyl, cetyl, octadecyl and methylphenyl groups, better still the dodecyl (or lauryl), tridecyl, tetradecyl (or myristyl), pentadecyl and cetyl groups; . The hydrophobic group (s) may or may be attached to the cellulose ether chain via an ether, ester or urethane bond, the ether bond being particularly preferred. In a particularly preferred manner, the hydrophobic group or groups are chosen from: 1 ') 3-alkoxy-2-hydroxypropyl groups in which the alkoxy moiety is branched or linear and comprises from 5 to 30 carbon atoms, preferably from to 20 carbon atoms, 2 ') C 9 -C 30, preferably C 10 -C 22, better still C 12 -C 18, and even more preferably C 12 -C 16, 3') and mixtures thereof, and more preferably those of the family 2 '). As examples of nonionic cellulose ethers constituting the main chain, there may be mentioned hydroxyethylcellulose (HEC), hydroxypropylcellulose (HPC), methylcellulose (MC), hydroxypropylmethylcellulose (HPMC), ethylhydroxyethylcellulose (EHEC), and methylhydroxyethylcellulose (MHEC). Hydroxyethylcellulose is particularly preferred. In the hydrophobically modified cellulose of the invention, all or part of the hydroxyl -OH groups of the cellulose have become -OR groups with R denoting in particular a methyl, ethyl, hydroxyethyl or hydroxypropyl group, or a hydrophobic group as defined herein. -above.

The content of the hydrophobic group (s) (hydrophobization rate) of the hydrophobically modified celluloses of the invention corresponds to the ratio of the total weight of the hydrophobic groups to the total weight of the hydrophobically modified cellulose, multiplied by 100. This content is greater than 0.6% by weight, preferably greater than 0.8% by weight, and better still greater than 1% by weight, relative to the total weight of hydrophobically modified cellulose. This content is preferably less than 5% by weight, relative to the total weight of hydrophobically modified cellulose. The hydrophobically modified cellulose (s) used in the invention has a weight average molecular weight of preferably from 100,000 to 2,000,000, more preferably from 200,000 to 1,500,000. and more preferably from 250 000 to 1 000 000. Preferably, the hydrophobically modified cellulose or celluloses used in the invention are chosen from cetyl hydroxyethylcelluloses having a content of hydrophobic group (s) greater than 0.6%. in weight.

As examples of hydrophobically modified cellulose, mention may be made of the following compounds listed in Table 1, commercially available from HERCULES: Table 1 cellulose (Mw) Hydrophobic groups degree of content in hydrophobic groups (% by weight) substitution in hydroxyethyl (in mole) Cellulose 1 HEC- 300,000 Cetyl (C16) 3.9 to 4.5 (ie 1.1 - 1.2% Regular 4.2 average) Cellulose 2 HEC- Regular 1,000,000 cetyl (C16) 3.9 1.8% Cellulose 3 HEC Block 1 000 000 Cetyl (C16) 3.4 2% Cellulose 4 HEC Block 300 000 Mix C12 and C14 4.1 2.7% Cellulose 5 HEC Block 300,000 cetyl (C16) 3.6 2.8-3.3% The compound Cellulose 1 is prepared according to the method described in Examples 1 to 10 of US4228,277, using a cetyl halide as reagent, and a hydroxyethylcellulose (HEC) having a suitable molar degree of hydroxyethyl substitution. The compound Cellulose 2 is prepared according to the method described in Examples 1 to 10 of US4228,277, using a hydroxyethylcellulose (HEC) having a suitable degree of molar substitution to hydroxyethyl.

The Cellulose 3 compound is prepared according to a method similar to that described in Example 27 of EP1858970, using a cetyl halide in place of the epoxide. The compound Cellulose 4 is prepared according to a method similar to that described in Example 27 of EP1858970, using a mixture of epoxide derivatives of dodecane and tetradecane. The Cellulose 5 compound is prepared by a method similar to that described in Example 27 of EP1858970, using a cetyl halide instead of the epoxide. The hydrophobically modified cellulose or celluloses are present in the composition according to the invention in preferred amounts ranging from 0.01% to 10% by weight, more preferably from 0.1% to 5% by weight, and preferably from 0.2% to 2% by weight. relative to the total weight of the composition.

The composition according to the invention comprises one or more vegetable oils. Examples of vegetable oils that can be used in the invention include triglyceride oils of vegetable origin, for example sunflower, corn, soybean, squash, grape seed, sesame and hazelnut oils. , apricot, macadamia, arara, avocado, argan, rice bran, olive, rapeseed, copra, wheat germ, flax, sweet almond, safflower , of bancoulier nut, passionflower, muscat rose, shea butter, palm, cotton, jojoba, alfalfa, poppy, pumpkin, blackcurrant, evening primrose, millet, barley, quinoa, rye, camelina, tamanu, lemon, babassu, pracaxi and their mixtures. In a preferred variant of the invention, the vegetable oil consists of triglycerides whose total content of C18 fatty acids comprising unsaturation and of C18 fatty acids comprising two unsaturations (called C18: 1 + C18: 2 according to the nomenclature biochemical or physiological fatty acid) represents more than 20% by weight of the total fatty acid content. Particularly preferred vegetable oil (s) include apricot oil, camelina oil, avocado oil, argan oil, rice bran, olive oil and their mixtures. In a variant of the invention, the composition comprises two or more vegetable oils.

The vegetable oil content of the composition of the invention may vary from 0.001 to 20%, better still from 0.001 to 10% by weight relative to the total weight of the composition. The vegetable oil or the vegetable oils is or are preferably present in an amount of less than 5% by weight, more particularly less than 4% by weight, more preferably ranging from 0.001% to 3% by weight, more preferably 0% by weight. , 01 to 2% by weight, more preferably from 0.01 to 1.5% by weight by weight relative to the total weight of the composition.

The composition according to the invention may also contain one or more surfactants chosen from anionic, amphoteric or zwitterionic, nonionic surfactants and mixtures thereof.

The term "anionic surfactant" means a surfactant having, as ionic or ionizable groups, only anionic groups. These anionic groups are preferably chosen from the groups -CO2H, -SO3H, -SO3, -OSO3H, -SO3-, -H2PO3, -HPO3-, -PO32-, -H2PO2, -HPO2-, -PO2, -POH, -P0-. As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates and alkyl aryl sulphonates. , alpha-olefin-sulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, monoesters salts of alkyl and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether carboxylic acid salts, alkyl acid salts amidoether carboxylic acids; and the corresponding non-salified forms of all these compounds; the alkyl and acyl groups of all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units.

The salts of C 6 -C 24 alkyl monoesters and of polyglycoside-polycarboxylic acids may be chosen from C 6 -C 24 alkyl polyglycoside-citrates, C 6 -C 24 alkyl polyglycoside-tartrates and polyglycoside-sulphosuccinates. C6-C24 alkyl.

When the agent or the anionic surfactants are in the salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salt. By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine, the salts of 2-amino-2-methyl-1- propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used. The optionally present anionic surfactants may be mild anionic surfactants, that is to say without sulfate function. As regards the mild anionic surfactants, mention may in particular be made of the following compounds and their salts, as well as their mixtures: polyoxyalkylenated alkyl ether carboxylic acids, polyoxyalkylenated alkylaryl ether carboxylic acids, polyoxyalkylenated alkylamido ether carboxylic acids, in particular those comprising 2 to 50 ethylene oxide groups, alkyl D galactoside uronic acids, acylsarcosinates, acylglutamates, and alkylpolyglycoside carboxylic esters. In particular, it is possible to use polyoxyalkylenated alkyl ether carboxylic acids, such as, for example, lauryl ether carboxylic acid (4.5%) sold, for example, under the name AKYPO RLM 45 CA from KAO. The anionic surfactant (s) may be present in the composition according to the invention in a content ranging from 1 to 25% by weight, preferably from 3 to 20% by weight, and still more preferably from 4 to 15% by weight. relative to the total weight of the composition. The amphoteric or zwitterionic surfactant (s) that may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. In particular, mention may be made of (C 8 -C 20) betaines, (C 8 -C 20) alkylsulfobetaines, (C 8 -C 20) alkylamido (C 3 -C 8) -betaines and (C 8 -C 20) alkylamidoyl (C 6 -C 8) alkyls. C8) sulphobetaines. Among the optionally used quaternized secondary or tertiary aliphatic amine derivatives, as defined above, there may also be mentioned the following compounds of structures (A1) and (A2): RaCONHCH2CH2N + (Rb) (R1) (CH2C00- ) (A1) in which: coconut derivative Ra represents a C10-C30 alkyl or alkenyl group of a RaCOOH acid preferably present in the hydrolyzed oil, a heptyl, nonyl or undecyl group, Rb represents a beta-hydroxyethyl group; and R, represents a carboxymethyl group; and Ra'CONHCH2CH2N (B) (B ') (A2) wherein: B represents the group -CH2CH2OX', B 'represents the group - (CH2) zY', with z = 1 or 2, X 'represents the group - CH2COOH, CH2COOZ ', -CH2CH2COOH, -CH2CH2COOZ', or a hydrogen atom, Y 'represents the group -COOH, -COOZ', the group -CH2CHOHSO3H or the group -CH2CHOHSO3Z ', Z' represents an ion derived from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, Ra, represents a C10-C30 alkyl or alkenyl group of a Ra'COOH acid preferably present in the oil of coconut or in hydrolyzed linseed oil, an alkyl group, especially C17 and its iso form, an unsaturated C17 group. These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium, acid lauroamphodipropionic, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOL® C2M concentrate.

Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of alkyl (C 8 -C 20) betaines such as cocobetaine, (C 8 -C 20) alkylamido (C 3 -C 8) alkyl betaines such as cocamidopropylbetaine, and their mixtures. More preferably, the amphoteric or zwitterionic surfactant (s) is (are) chosen from cocamidopropylbetaine and cocobetaine. When present, the amount of the amphoteric or zwitterionic surfactant or agents preferably ranges from 0.1 to 15% by weight, more preferably from 0.5 to 10% by weight, more preferably better from 1 to 8% by weight, relative to the total weight of the composition. Examples of nonionic surfactants useful in the composition used according to the invention are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178. They are chosen in particular from alcohols, alpha-diols and (CiC20) alkyl phenols, these compounds being polyethoxylated, polypropoxylated and / or polyglycerolated, and having at least one fatty chain comprising, for example, from 8 to 18 carbon atoms. the number of ethylene oxide groups and / or propylene oxide groups that can range from 2 to 50 and the number of glycerol groups that can range from 2 to 30. It is also possible to mention the ethylene oxide and ethylene oxide condensates. propylene oxide on fatty alcohols, the polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, the polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4 ethoxylated sorbitan fatty acid esters having 2 to 30 ethylene oxide units, sucrose fatty acid esters, polyethylene glycol fatty acid esters, C6-C24 alkyl polyglycosides , derivatives of N- (C6-C24 alkyl) glucamine, amine oxides such as (C1-C14) alkyl amine oxides or N- (C10-C14 acyl) aminopropylmorpholine oxides.

Unless otherwise stated, the term "fatty" compound is used, for example a fatty acid, a compound comprising in its main chain at least one hydrocarbon chain, saturated or unsaturated, such as alkyl or alkenyl having at least 8 carbon atoms. carbon, preferably 8 to 30 carbon atoms, and more preferably 10 to 22 carbon atoms. When present, the amount of the nonionic surfactant or agents preferably ranges from 0.01 to 20% by weight, more preferably from 0.1 to 10% by weight relative to the total weight of the composition. .

According to a first particularly preferred embodiment, the composition according to the invention comprises one or more anionic surfactants, and optionally one or more amphoteric or zwitterionic surfactants.

The composition according to the invention may further comprise one or more cationic surfactants. The cationic surfactant (s) that may be used in the composition according to the invention comprise, for example, primary, secondary or tertiary fatty amine salts, optionally polyoxyalkylenated, quaternary ammonium salts, and mixtures thereof. As quaternary ammonium salts, mention may be made, for example: - those corresponding to the following general formula (I): Ro \ / Rio XR (R11 (I) in which the groups R8 to R11, which may be identical or different, represent a linear or branched aliphatic group containing from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups R8 to R11 comprising from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms The aliphatic groups may comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens, the aliphatic groups are, for example, chosen from C1-C30 alkyl and alkoxy groups. C1-C30, polyoxyalkylene (C2-C6), alkyl (C1-C22) alkylamido (C2-C6) alkyl, (C1-2-C22) alkyl, and C1-C30 hydroxyalkyl, X- is an anion selected from group of halides, phosphates, acetates, lactates, alkyl (Ci-C4) sulphates, alkyl (Ci-C4) or - (C1-C4) alkylsulphonates. Of the quaternary ammonium salts of the formula (I), tetraalkylammonium chlorides, such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group comprises from about 12 to about 22 are preferred. carbon atoms, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium chlorides, or palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl (myristyl acetate) ammonium chloride sold under the name CERAPHYL® 70 by VAN DYK. the quaternary ammonium salts of imidazoline, for example those of the following formula (II): embedded image in which R 12 represents an alkenyl or alkyl group containing from 8 to 8 30 carbon atoms, for example fatty acid derivatives of tallow, R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group having from 8 to 30 carbon atoms, R14 represents an alkyl group C1-C4, R15 is hydrogen, C1-C4 alkyl, X- is an anion selected from the group of halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, alkyl ( C 1 -C 4) - or (C 1 -C 4) alkylarylsulfonates. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl group, R15 denotes a hydrogen atom. Such a product is for example sold under the name REWOQUAT® W 75 by the company REWO, - quaternary di- or triammonium salts, in particular of formula (III): X R17 R19 1 1 R16-N- (CH2) ) Wherein R 16 denotes an alkyl group having from about 16 to 30 carbon atoms optionally hydroxylated and / or interrupted by one or more oxygen atoms, R 17 is chosen from hydrogen or an alkyl group comprising from 1 to 4 carbon atoms or a group - (CH 2) 3 -N + (R 16a) (R 17a) (R 1sa), R 16a, Rua, R 18a, R 18, R 19, R 20 and R 21, which may be identical or different, are chosen from 1 hydrogen or an alkyl group having 1 to 4 carbon atoms, and X- is an anion selected from the group of halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl- or alkyl (C 1 -C 4) aryl sulfonates, in particular methylsulfate and ethylsulfate. Such compounds are, for example, Finquat CT-P proposed by Finetex (Quaternium 89), Finquat CT proposed by Finetex (Quaternium 75), and quaternary ammonium salts containing one or more ester functions, such as for example, those of the following formula (IV): ## STR1 ## wherein R 2 Wherein R22 is selected from C1-C6 alkyl groups and hydroxyalkyl or C1-C6 dihydroxyalkyl groups, R23 is selected from: o - the group R '- the groups R27 hydrocarbon C1-C22, linear or branched, saturated or unsaturated, and - the hydrogen atom, R25 is selected from: o - the group R28 - R29 hydrocarbon groups Ci-C6, linear or branched, saturated or unsaturated, and - the hydrogen atom, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C7-C21 hydrocarbon groups, r, s and t, i identical or different, are integers from 2 to 6, r1 and t1, identical or different, are 0 or 1, r2 + r1 = 2 r and t1 + t2 = 2 t, y is an integer of 1 to 10, x and z, which are identical or different, are integers ranging from 0 to 10, and X- is a simple or complex anion, organic or inorganic, provided that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and when z is 0 then R25 is R29. The alkyl groups R22 may be linear or branched and more particularly linear. Preferably, R 22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group. Advantageously, the sum x + y + z is from 1 to 10. When R 23 is a hydrocarbon R 27 group, it may be long and have 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms. When R 25 is a hydrocarbon R 29 group, it preferably has 1 to 3 carbon atoms. Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C 1 -C 21 hydrocarbon-based groups, and more particularly from linear or branched, saturated or saturated C 11 -C 21 alkyl and alkenyl groups. or unsaturated. Preferably, x and z, identical or different, are 0 or 1.

Advantageously, y is equal to 1. Preferably, r, s and t, identical or different, are 2 or 3, and even more particularly are equal to 2. The anion X- is preferably a halide, preferably chloride, bromide or iodide, (C1-C4) alkyl sulphate, (C1-C4) alkyl or (C1-C4) alkyl aryl sulphonate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function. The anion X- is even more particularly chloride, methylsulfate or ethylsulfate. In the composition according to the invention, the ammonium salts of formula (IV) are used more particularly in which: R 22 denotes a methyl or ethyl group, x and y are equal to 1, z is equal to 0 or 1, - r, s and t are equal to 2, - R23 is chosen from: o - the group, - methyl, ethyl or C14-C22 hydrocarbon groups, and - the hydrogen atom, - R25 is chosen from: o - the group R28 c- - the hydrogen atom, - R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated C13-C17 hydrocarbon groups, and preferably from linear or branched, saturated or unsaturated C13-C17 alkyl and alkenyl groups.

Advantageously, the hydrocarbon groups are linear. Examples of compounds of formula (IV) that may be mentioned include salts, especially diacyloxyethyldimethylammonium chloride, diacyloxyethyl hydroxyethylmethylammonium chloride, monoacyloxyethyldihydroxyethylmethylammonium chloride, triacyloxyethylmethylammonium chloride, monoacyloxyethylhydroxyethyldimethylammonium chloride, and mixtures thereof. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different. These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine optionally oxyalkylenated on fatty acids or mixtures of fatty acids of plant or animal origin, or by transesterification. of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide, preferably methyl or ethyl, a dialkyl sulphate, preferably methyl or ethyl sulphate. methyl methanesulfonate, methyl para-toluenesulfonate, glycol or glycerol chlorohydrin. Such compounds are, for example, sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts.

By way of examples of such compounds, mention may be made of distearoylethylhydroxyethylmethylammonium or dipalmitoylethylhydroxyethylmethylammonium salts, in particular the methosulphates.

It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180. It is also possible to use behenoylhydroxypropyltrimethylammonium chloride, for example, proposed by the company KAO under the name Quartamin BTC 131. Preferably, the ammonium salts containing at least one ester function contain two ester functions. Among the cationic surfactants which may be present in the composition according to the invention, cetyltrimethylammonium is more particularly preferred, and the methylammonium behenyltrimethylammonium salts, and mixtures thereof, of distearoylethylhydroxyethyl, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, distearoylethylhydroxyethylammonium methosulfate, and mixtures thereof. When the composition contains one or more cationic surfactants, their content preferably varies from 0.05 to 10% by weight, more preferably from 0.1 to 5% by weight, better still from 0.5 to 5% by weight, by weight. relative to the total weight of the composition. The composition according to the invention may further comprise one or more fatty alcohols. These fatty alcohols are non-oxyalkylenated and non-glycerolated. They can be solid or liquid.

The fatty alcohols that can be used in the invention preferably comprise from 8 to 40 carbon atoms, better still from 10 to 30 carbon atoms, and even more preferably from 12 to 25 carbon atoms. The fatty alcohols that can be used in the invention can be saturated or unsaturated. Saturated fatty alcohols are linear or branched. They may optionally comprise in their structure at least one aromatic cycle or not. Preferably, they are acyclic.

By way of examples, mention may be made of cetyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyl-1-dodecanol, 2-butyloctanol, 2-hexyl-1-decanol, 2- tetradecyl-1-cetanol, and mixtures thereof, and more particularly cetyl alcohol, stearyl alcohol, 2-octyl-1-dodecanol and mixtures thereof. The unsaturated fatty alcohols have in their structure at least one double or triple bond, and preferably one or more double bonds. When more than one double bond is present, it is preferably 2 or 3 and may or may not be conjugated. These unsaturated fatty alcohols can be linear or branched. They may optionally comprise in their structure at least one aromatic cycle or not. Preferably, they are acyclic. More particularly, the unsaturated fatty alcohols of the invention are chosen from oleic (or oleyl) alcohol, linoleic (or linoleyl) alcohol, linolenic (or linolenyl) alcohol, undecylenic alcohol, and mixtures thereof. Oleyl alcohol is particularly preferred. The fatty alcohols that can be used in the invention are preferably chosen from saturated and unsaturated fatty alcohols as described above, and mixtures thereof. In one variant of the invention, the fatty alcohols are liquid. By liquid fatty alcohol is meant a non-glycerolated and non-oxyalkylenated fatty alcohol, liquid at ordinary temperature (25 ° C.) and at atmospheric pressure (760 mmHg, ie 1.013 × 10 5 Pa). The preferred liquid fatty alcohols are oleic alcohol and 2-octyld-1-dodecanol. Even more preferentially, the liquid fatty alcohol is 2-octyl-1-dodecanol. When the fatty alcohol (s) are present in the composition according to the invention, their preferential amount ranges from 0.01 to 20% by weight, more preferably from 0.1 to 10% by weight, better still from 0.5 to 5% by weight. by weight, relative to the total weight of the composition. The composition may also comprise one or more cationic polymers.

By cationic polymer is meant any polymer containing cationic groups and / or ionizable groups into cationic groups, preferably non-siliceous. The cationic polymers that may be used in accordance with the present invention may be chosen from all those already known per se as improving the cosmetic properties of the hair treated with detergent compositions, namely in particular those described in the patent application EP-A-0 337 354 and in the French patent applications FR-A-2,270,846, 2,383,660, 2,598,611, 2,470,596 and 2,519,863. The preferred cationic polymers are chosen from those containing units containing primary, secondary amine groups, tertiary and / or quaternary may be part of the main polymer chain, or be carried by a lateral substituent directly connected thereto. The cationic polymers used have a weight average molecular weight greater than 105, preferably greater than 106, and more preferably between 106 and 108. Among the cationic polymers, mention may be made more particularly of the polyamine, polyaminoamide and quaternary polyammonium type polymers. These are known products. The polymers of the polyamine, polyaminoamide or quaternary polyammonium type that can be used in the composition of the present invention are those described in French Patents 2,505,348 and 2,542,997. Among these polymers, mention may be made of: ) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units of formulas (V), (VI), (VII) and (VIII): R5 -CI-12-C - 0- 0 X- 1 A 1 + N / \ R6 N - R8 R3 R4 (V) R7 R5 R5 1 -CEIC- -C1-12- C - 0 H OH NH NH I 1 AA X- 1 1+ N Wherein R3 and R4, which may be identical or different, represent a hydrogen atom or a group; alkyl having 1 to 6 carbon atoms, and preferably a methyl or ethyl group, R5, which may be identical or different, denote a hydrogen atom or a CH3 group, A, which may be identical or different, represent a linear or branched alkyl group; , from 1 to 6 carbon atoms, preferably of 2 or 3 carbon atoms or a hydroxyalkyl group having from 1 to 4 carbon atoms, R6, R7, R8, identical or different, represent an alkyl group having 1 to 18 carbon atoms or a benzyl group, and preferably an alkyl group having 1 to 6 carbon atoms, X- denotes an anion derived from a mineral or organic acid such as a methosulphate anion, or a halide such as chloride or bromide. The copolymers of the family (1) may further contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, acrylamide diacetones, acrylamides and methacrylamides substituted on the nitrogen atom by lower alkyls (Ci -C4), acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Thus, among these copolymers of the family (1), mention may be made of: copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide such as that sold under the name HERCOFLOC by the company HERCULES copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride described, for example, in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY, the copolymer of acrylamide and methosulphate of methacryloyloxyethyltrimethylammonium sold under the name RETEN by the company HERCULES, vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate quaternized or otherwise, such as the products sold under the name "GAFQUAT" by the company ISP such as "GAFQUAT 734" or "GAFQUAT 755 "or the products referred to as" COPOLYMER 845, 958 and 937 ". These polymers are described in detail in French Pat. Nos. 2,077,143 and 2,393,573, dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, such as the product sold under the name GAFFIX VC 713 by the company ISP, vinylpyrrolidone / methacrylamidopropyl copolymers. dimethylamine sold in particular under the name STYLEZE CC 10 by ISP, quaternized vinylpyrrolidone / dimethylaminopropyl methacrylamide copolymers such as the product sold under the name "GAFQUAT HS 100" by the company ISP, and - crosslinked polymers of methacryloyloxyalkyl salts (Ci -C4) trialkyl (Ci-C4) ammonium such as polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized by methyl chloride, or copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized by methyl chloride, homo or the copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name "SALCARE® SC 92" by the company CIBA. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride (INCI name Polyquaternium-37), for example, in dispersion in mineral oil or in a liquid ester. These dispersions are sold under the names "SALCARE® SC 95" and "SALCARE® SC 96" by the company CIBA. (2) polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. Such polymers are described in particular in French Patents 2 162 025 and 2 280 361. (3) water-soluble polyaminoamides, prepared in particular by polycondensation of an acidic compound with a polyamine. These polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide, or by an oligomer resulting from the reaction of a bifunctional compound which is reactive with a bis-halohydrin, a bis-azetidinium, a bishaloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or a bis-unsaturated derivative, the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mole per amine group of the polymaoamide. These polyaminoamides can be alkylated or if they contain one or more tertiary amine functions, quaternized. Such polymers are described in particular in French Patents 2,252,840 and 2,368,508. (4) polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid / dialkylaminohydroxyalkyldialkylene triamine polymers in which the alkyl group contains from 1 to 4 carbon atoms and preferably denotes a methyl, ethyl or propyl group. Such polymers are described in particular in French Patent 1,583,363. Among these derivatives, mention may be made more particularly of the adipic acid / dimethylaminohydroxypropyl-diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by SANDOZ. (5) polymers obtained by reacting a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. The molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1, the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the grouping. secondary amine of the polyaminoamide between 0.5: 1 and 1.8: 1. Such polymers are described in particular in US Patents 3,227,615 and 2,961,347.

Polymers of this type are in particular sold under the name "Hercosett 57" by Hercules Inc. or under the name "PD 170" or "Delsette 101" by the company Hercules in the case of the adipic acid copolymer epoxypropyl diethylene triamine. (6) cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium, such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (IX) or (X): (CH 2) t CR 12 (CH 2) C (R12) -CH2 CH2 CH2 NR1-10. In which k and t are equal to 0 or 1, the sum k + t being equal to 1, R12 denotes a hydrogen atom or a hydrogen atom, or methyl group, R10 and R11, independently of each other, denote an alkyl group having 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, an amidoalkyl group; lower (C1-C4), or R10 and R11 may designate together with the nitrogen atom to which they are attached, (IX) (X) heterocyclic groups, such as piperidinyl or morpholinyl, Y- is an anion such as bromide , chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are in particular described in French patent 2,080,759 and in its certificate of addition 2,190,406. R10 and R11, independently of one another, preferably denote an alkyl group having from 1 to 4 carbon atoms. . Among the polymers defined above, mention may be made more particularly of the homopolymer of dimethyldiallylammonium chloride sold under the name "Merquat 100" by the company NALCO, its counterparts of low molecular weight average, and the copolymers of diallyldimethylammonium chloride and acrylamide sold under the name "MERQUAT 550". (7) the quaternary diammonium polymer containing, in particular, recurring units corresponding to the formula (XI): wherein R13, R14, R15 and R16, which are identical, are identical to one another in which R13, R14, R15 and R16 are identical; or different, represent aliphatic, alicyclic or arylaliphatic groups containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or R13, R14, R15 and R16, together or separately, together with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen, or R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl group substituted with a nitrile, ester, acyl, amide or -CO- O-R17-D or -CO-NH-R17-D where R17 is an alkylene and D is a quaternary ammonium group, Al and B1 represent polymethylene groups containing from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated res, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more oxygen atoms, sulfur or sulfoxide groups, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester, and X- denotes an anion derived from a mineral or organic acid, A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring. In addition, if Al denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 may also denote a (CH2) nCO-D-OC- (CH2) p- group, n and p are integers ranging from About 2 to about 20, wherein D is: a) a glycol residue of formula: -O-Z-O-, where Z is a linear or branched hydrocarbon radical, or a group corresponding to one of the following formulas: - (CH 2 -CH 2 -O) x-CH 2 -CH 2 -, - [CH 2 -CH (CH 3) -O] y -CH 2 -CH (CH 3) -, where x and y denote an integer of 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization, b) a bis-secondary diamine residue such as a piperazine derivative, c) a bis-primary diamine residue of formula -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or the divalent radical -CH2-CH2-SS-CH2-CH2-, d) a ureylene group of formula -NH-CO-NH- .

Preferably, X- is an anion such as chloride or bromide. These polymers have a number average molecular weight generally between 1,000 and 100,000.

Polymers of this type are described in particular in French Patents 2,330,330, 2,270,846, 2,316,271, 2,336,434 and 2,413,907 and US Patents 2,273,780, 2,375,853, 2,388,614 and 2,454,547. , 3,206,462, 2,261,002, 2,271,378, 3,874,870, 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945 and 027 020. It is more particularly possible to use polymers which consist of repeating units corresponding to formula (XII): ## STR5 ## wherein R18, R19, R20 and R21, which may be identical or different, denote an alkyl or hydroxyalkyl group having from 1 to 4 carbon atoms, r and s are integers ranging from 2 to approximately 20 and X- is an anion derived from a mineral or organic acid. A particularly preferred compound of formula (XII) is that for which R18, R19, R20 and R21 represent a methyl radical, r = 3, s = 6 and X = Cl, called Hexadimethrine chloride according to the INCI nomenclature (CTFA). (8) quaternary polyammonium polymers consisting in particular of units of formula (XIII): R22 R24 + -N- (CH2) NH-O- (CH2) CO-NH- (CH2) N + R23 X R25 X (XIII) in which: R22, R23, R24 and R25, identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, 13-hydroxyethyl, 13-hydroxypropyl or -CH2CH2 (OCH2CH2) pOH group, where p is 0 or to an integer between 1 and 6, with the proviso that R22, R23, R24 and R25 do not simultaneously represent a hydrogen atom, t and u, which may be identical or different, are integers between 1 and 6, v is 0 or an integer from 1 to 34, X- is an anion such as a halide, A is a radical of a dihalide or is preferably -CH2-CH2-O-CH2-CH2-. Such compounds are described in particular in patent application EP-A-122 324.

One can, for example, mention among these, the products "Mirapol® A 15", "Mirapol® AD1", "Mirapol® AZ1" and "Mirapol® 175" sold by MIRANOL. (9) quaternary polymers of vinylpyrrolidone and / or vinylimidazole, such as, for example, the products sold under the names Luviquat® FC 905, FC 550, FC 370 and Luviquat Excellence by the company BASF. (10) cationic polysaccharides, especially cationic celluloses and galactomannan gums. Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives containing quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.

The cellulose ether derivatives containing quaternary ammonium groups described in French Patent 1,492,597. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose having reacted with an epoxide substituted with a trimethylammonium group.

Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, are described in particular in US Pat. No. 4 131 576, such as hydroxyalkyl celluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl-grafted celluloses in particular. with a salt of methacryloylethyl trimethylammonium, methacrylmidopropyltrimethylammonium, dimethyldiallylammonium. The cationic galactomannan gums are described more particularly in US Pat. Nos. 3,589,578 and 4,031,307, in particular guar gums containing cationic trialkylammonium groups. For example, salt-modified guar gums such as 2,3-epoxypropyltrimethylammonium chloride are used. (11) cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives. The proteins or hydrolysates of cationic proteins are in particular chemically modified polypeptides carrying at the end of the chain, or grafted onto it, quaternary ammonium groups. Their molecular weight may vary, for example, from 1,500 to 10,000, and in particular from 2,000 to 5,000. Among these compounds, there may be mentioned in particular: collagen hydrolysates bearing triethylammonium groups, such as the products sold under the name Quat-Pro E by the company MAYBROOK and referred to in the CTFA dictionary as "Triethonium Hydrolyzed Collagen Ethosulfate", collagen hydrolysates bearing trimethylammonium chloride and trimethylstearylammonium groups, sold under the name "Quat-Pro S" by the company MAYBROOOK and referred to in the CTFA dictionary "Steartrimonium Hydrolyzed Collagen", - hydrolysates of animal proteins carrying trimethylbenzylammonium groups, such as the products sold under the name "Crotein BTA" by the company CRODA and referred to in the CTFA dictionary as "Benzyltrimonium hydrolyzed animal protein", - the protein hydrolysates bearing on the polypeptide chain of the quaternary ammonium groups comprising at least one alk radical having from 1 to 18 carbon atoms. Among these protein hydrolysates, mention may be made inter alia of: - "Croquat L" whose quaternary ammonium groups contain a C 12 alkyl group, - "Croquat M" whose quaternary ammonium groups contain C 10 -C 18 alkyl groups, the "Croquat S" whose quaternary ammonium groups comprise a C 1 -C 4 alkyl group, the "Crotein Q" whose quaternary ammonium groups contain at least one alkyl group having from 1 to 18 carbon atoms. These different products are sold by CRODA. Other quaternized proteins or hydrolysates are, for example, those corresponding to the formula (XIV): ## STR2 ## wherein X is an anion of an organic or inorganic acid, denotes a residue of protein derived from collagen protein hydrolysates, R29 denotes a lipophilic group having up to 30 carbon atoms, R30 represents an alkylene group having 1 to 6 carbon atoms. There may be mentioned, for example, the products sold by the company INOLEX, under the name "Lexein QX 3000", called in the CTFA dictionary "Cocotrimonium Collagent Hydrolysate". Mention may also be made of quaternized vegetable proteins such as wheat, corn or soya proteins, such as quaternized wheat proteins. Mention may be made of those marketed by the company CRODA under the names "Hydrotriticum WQ or QM" referred to in the CTFA dictionary "Cocodimonium Hydrolysed wheat protein", "Hydrotriticum QL" referred to in the CTFA dictionary "Laurdimonium hydrolysed wheat protein" or "Hydrotriticum QS" Called in the CTFA dictionary "Steardimonium hydrolysed wheat protein". Preferably, the cationic polymer (s) are chosen from those of families (1), (6), (9) and (10).

Among these preferred cationic polymers which can be used in the context of the present invention, it is more particularly preferred to use cationic cyclopolymers, in particular homopolymers or copolymers of dimethyldiallylammonium chloride, sold under the names "Merquat 100", " MERQUAT 550 "and" MERQUAT S "by the company NALCO, the quaternary vinylpyrrolidone and vinylimidazole polymers such as the copolymer of vinylpyrrolidone and of methyl vinyl imidazolinium chloride sold under the name Luviquat Excellence sold by BASF, cationic polysaccharides, more particularly guar gums modified with 2,3-epoxypropyltrimethylammonium chloride, sold for example under the name "Jaguar Cl3S" by Rhodia or cellulose ether derivatives containing quaternary ammonium groups, such as cellulose ethers sold by for example, under the name "UCARE POLYMER JR400 LT" by the company AMERCHOL (DOW CHEMICAL), the crosslinked polymers of methacryloyloxyalkyl (C 1 -C 4) trialkyl (C 1 -C 4) ammonium salts, such as the crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride sold under the name Salcare SC95 by the company CIBA, and mixtures thereof. When they are present or are present, the cationic polymer (s) is (are) present in the composition according to the invention in amounts preferably ranging from 0.01 to 10% by weight, more preferably from 0.05 to 15% by weight, better still from 0.1 to 2% by weight, relative to the total weight of the composition. The composition may also comprise one or more silicones.

The silicones that may be used in the composition according to the invention are, in particular, polyorganosiloxanes which may be in the form of aqueous solutions, that is to say solutions which are solubilized, or optionally in the form of dispersions or microdispersions, or of aqueous emulsions. . The polyorganosiloxanes may also be in the form of oils, waxes, resins or gums. Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968) Academie Press. Silicones can be volatile or non-volatile.

When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic silicones containing from 3 to 7 silicon atoms and preferably 4 to 5.

It is, for example, octamethylcyclotetrasiloxane marketed in particular under the name "VOLATILE SILICONE 7207" by the company UNION CARBIDE or "SILBIONE 70045 V 2" by Rhodia, the decamethylcyclopentasiloxane marketed under the name "VOLATILE SILICONE 7158 "by the company UNION CARBIDE," SILBIONE 70045 V 5 "by RHODIA, and mixtures thereof. Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the "VOLATILE SILICONE FZ 3109" marketed by UNION CARBIDE, of chemical structure: D "D 'D" D' -1 1 CH3 CH3 with D ": - Si-O- with D ': Si -0-CH3 C8H17 Mention may also be made of mixtures of cyclic silicones with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture octamethylcyclotetrasiloxane and oxy1,1 '(hexa-2,2,2', 2 ', 3,3'-trimethylsilyloxy) bis-neopentane (ii) linear volatile silicones having 2 to 9 silicon atoms and having a viscosity less than or equal to 5.10-6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" by Toray Silicone, silicones falling into this class are also described. in the article published in s Cosmetics and toiletries, Vol 91, Jan. 76, p 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". When the silicones are nonvolatile, polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, polyorganosiloxanes modified with organofunctional groups and their mixtures are preferably used. These silicones are more particularly chosen from polyalkylsiloxanes, among which, for example, polydimethylsiloxanes containing trimethylsilyl end groups (dimethicone according to the CTFA name) having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. and preferably 1 × 10 -5 to 1 m2 / s. The viscosity of the silicones is for example measured at 25 ° C. according to ASTM standard 445 Appendix C.

Among these polyalkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE oils of series 47 and 70,047 or MIRASIL oils marketed by RHODIA, such as, for example, 70,047 V 500,000 oil, the oils of the MIRASIL series marketed by RHODIA, the oils of the 200 series of DOW CORNING, such as, more particularly, the DC200 with a viscosity of 60 000 Cst, the VISCASIL oils of the company GENERAL ELECTRIC and certain oils of the series. SF (SF 96, SF 18) of the company GENERAL ELECTRIC. Mention may also be made of polydimethylsiloxane end groups dimethylsilanol (dimethiconol according to the CTFA name) such as the oils of the 48 series from Rhodia. Mention may also be made of polydimethylsiloxane aminoethyl, aminopropyl and alpha-omega silanol groups. In this class of polyalkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX 9800 and 9801" by GOLDSCHMIDT, which are poly (C1-C20) alkylsiloxanes. The polyalkylarylsiloxanes are particularly chosen from polydimethyl methylphenylsiloxanes and linear and / or branched polydimethyl diphenylsiloxanes with a viscosity of from 1 × 10 -5 to 5 × 10 -2 m 2 / s at 25 ° C. Among these polyalkylarylsiloxanes, mention may be made, by way of example, of the products sold under the following names: SILBIONE oils of the 70 641 series from RHODIA; oils of RHODORSIL 70 633 and 763 series from RHODIA - DOW CORNING 556 COSMETIC GRAD FLUID oil from Dow Corning, - Silicones from the PK series from Bayer as the PK20 product, - Silicones from the PN, PH series from the Bayer company, such as PN1000 products and PH1000, certain oils of SF series of the company GENERAL ELECTRIC such as SF 1023, SF 1154, SF 1250, SF 1265. The silicone gums that may be present in the composition according to the invention are especially polydiorganosiloxanes having average molecular weights in large numbers between 200 000 and 1 000 000, used alone or mixed in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecanes or their mixtures. Mention may be made more particularly of the following products: polydimethylsiloxane gums, polydimethylsiloxane / methylvinylsiloxane gums, polydimethylsiloxane / diphenylsiloxane gums, polydimethylsiloxane / phenylmethylsiloxane gums, polydimethylsiloxane / diphenylsiloxane / methylvinylsiloxane gums.

More particularly useful products are the following mixtures: - mixtures formed from a hydroxylated polydimethylsiloxane at the end of the chain (called dimethiconol according to the CTFA dictionary nomenclature) and a cyclic polydimethylsiloxane (called cyclomethicone according to the CTFA dictionary nomenclature ) such as the product Q2 1401 sold by the company Dow Corning, the mixtures formed from a polydimethylsiloxane gum with a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number-average molecular weight of 500,000, solubilized in SF 1202 Silicone Fluid oil corresponding to decamethylcyclopentasiloxane, - blends of two PDMSs of different viscosities, and more particularly of a PDMS gum and of a PDMS oil, such as the product SF 1236 from the company GENERAL ELECTRIC. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s.

This product preferably comprises 15% of SE gum and 85% of an SF 96 oil. The organopolysiloxane resins optionally present in the composition according to the invention are crosslinked siloxane systems containing the units: R 2 SiO 2, R 3 SiO 1/2, RSiO3 / 2 and SiO412 in which R represents a hydrocarbon group having 1 to 16 carbon atoms or a phenyl group. Among these products, those that are particularly preferred are those in which R denotes a C 1 -C 4 alkyl group, more particularly methyl, or a phenyl group.

Among these resins may be mentioned the product sold under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure.

Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shinet Su. The organomodified silicones optionally present in the composition according to the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon group.

Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally comprising C 6 -C 24 alkyl groups such as the products called dimethicone copolyol marketed by the company Dow Corning under the name DC 1248 or the oils SILWET L 722, L 7500, L 77, L 711 of the company UNION CARBIDE and the alkyl (C12) methylic copolyol marketed by the company Dow Corning under the name Q2 5200, thiol groups such as the products sold under the names " GP 72 A "and" GP 71 "from the company GENESEE, - alkoxylated groups such as the product sold under the name" SILICONE COPOLYMER F-755 "by SWS SILICONES and ABIL WAX 2428, 2434 and 2440 by the company GOLDSCHMIDT, - hydroxyl groups such as the hydroxyalkyl-functional polyorganosiloxanes described in the French patent application FR 2 589 476, acyloxyalkyl elements such as, for example, the polyorganosiloxanes described in US-A-4957732, - anionic groups of the carboxylic type, for example, in the products described in the patent EP 186 507 of the company CHISSO CORPORATION, or alkylcarboxylic type such as those present in the product X-22-3701E from the company Shin-Etsu, 2-hydroxyalkylsulphonate, 2-hydroxyalkylthiosulphate, such as the products marketed by GOLDSCHMIDT under the names "ABIL 5201" and "ABIL S255", - hydroxyacylamino groups, such as the polyorganosiloxanes described in application EP 342 834. There may be mentioned for example the product Q2-8413 from the company Dow Corning. Among the organomodified silicones, mention may also be made of amino silicones.

By "amino silicone" is meant any silicone comprising at least one primary, secondary, tertiary amine or a quaternary ammonium group. The aminated silicones optionally used in the cosmetic composition according to the present invention are chosen from: (a) the compounds corresponding to the following formula (XV): (R 1) a (T) 3 -Si [O Si (T) 21. - [0 Si (T) b (R 1) 2 -b] m -O Si (T) 3-a- (R 1) a (XV) in which: T is a hydrogen atom, or a phenyl group, hydroxyl (- OH), or C1-C8 alkyl, and preferably methyl, or C1-C8 alkoxy, preferably methoxy, a denotes the number 0 or an integer of 1 to 3, and preferably 0, b is 0 or 1 , and in particular 1, m and n are numbers such that the sum (n + m) may vary in particular from 1 to 2,000 and in particular from 50 to 150, n being able to designate a number from 0 to 1,999 and in particular from 49 to 149 and m being able to designate a number from 1 to 2,000, and in particular from 1 to 10, R 1 is a monovalent group of formula -CqH 2 qL in which q is a number from 2 to 8 and L is an optionally quaternized amino group chosen among the groups: -N (R 2) -CH 2 -CH 2 -N (R 2) 2, -N (R 2) 2, -N + (R 2) 3 Q-, -N + (R 2) (H) 2 Q-, -N + (R 2) 2HQ, -N (R 2) -CH 2 -CH 2 -NOP (R 2) (H) 2 Q-, wherein R 2 may denote a hydrogen atom, a phenyl group, a benzyl group, or a monovalent saturated hydrocarbon group, for example an alkyl group in C 1 -C 20, and Q- represents a halide ion such as, for example, fluoride, chloride, bromide or iodide. In particular, the amino silicones corresponding to the definition of formula (XV) are chosen from compounds corresponding to the following formula (XVI): ## STR2 ## Wherein R, R ', R ", which may be identical or different, denote a C1-C4 alkyl group, preferably a CH3 group or a C1-C4 alkoxy group; , preferably methoxy, or OH, A represents a linear or branched C3-C8, preferably C3-C6, alkylene group, m and n are integers dependent on the molecular weight and whose sum is between 1 and 2000.

According to a first possibility, R, R 'and R ", which may be identical or different, each represent a C1-C4 alkyl or hydroxyl group, A represents a C3 alkylene group and m and n are such that the weight average molecular weight of the The compounds of this type are referred to in the CTFA dictionary as "amodimethicone." According to a second possibility, R, R 'and R ", which may be identical or different, each represent a lower alkoxy group. C1-C4 or hydroxyl, at least one of the groups R or R "is an alkoxy group and A represents a C3 alkylene group The molar ratio of hydroxy / alkoxy is preferably between 0.2 / 1 and 0.4 / 1 and advantageously equal to 0.3 / 1. Moreover, m and n are such that the weight average molecular weight of the compound is between 2000 and 106. More particularly, n is between 0 and 999 and m is included. between 1 and 1000, the sum of n and m being between 1 and 1000. In this This class of compounds includes, among others, the Belsil®ADM 652 product marketed by Wacker. According to a third possibility, R and R ", different, each represent a C1-C4 alkoxy or hydroxyl group, at least one of the groups R and R" being an alkoxy group, R 'representing a methyl group and A representing a C3 alkylene group. The molar ratio of hydroxy / alkoxy is preferably between 1 / 0.8 and 1 / 1.1, and advantageously is equal to 1 / 0.95. Furthermore, m and n are such that the weight average molecular weight of the compound is between 2000 and 200000. More particularly, n is between 0 and 999 and m is between 1 and 1000, the sum of n and m being between 1 and 1000. More particularly, mention may be made of FluidWRe 1300, marketed by WACKER. It should be noted that the molecular mass of these silicones is determined by gel permeation chromatography (room temperature, polystyrene standard, columns for styragem, THF eluent, flow rate of 1 mm / m, 200 μl of a 0.5 solution are injected % by weight of silicone in THF and the detection is carried out by refractometry and UV-metry). A product corresponding to the definition of formula (XV) is in particular the polymer referred to in the CTFA dictionary "trimethylsilylamodimethicone", corresponding to the following formula (XVII): ## STR2 ## SiO CH 3 CH Si (CH 3) 3 SiO CH 3 Embedded image in which n and m have the meanings given above according to formula (XV). ## STR2 ## in which n and m have the meanings given above according to formula (XV).

Such compounds are described, for example, in EP 95238. A compound of formula (XVII) is, for example, sold under the name Q2-8220 by the company OSI. (b) the compounds corresponding to the following formula (XVIII): ## STR3 ## wherein Cis, and in particular a C 1 -C 18 alkyl group, or C 1 -C 4 alkenyl for example methyl, R 4 represents a divalent hydrocarbon group, in particular a C 1 -C 18 alkylene group or a divalent C 1 -C 18 alkyleneoxy group, for example in Ci -C8, R4-CH2-CHOH -CH2-NE (R3) 3 Q Q- is a halide ion, in particular chloride, r represents an average statistical value of 2 to 20 and in particular 2 to 8, s represents a statistical value from 20 to 200 and in particular from 20 to 50. Such compounds are described more particularly in patent US 4185087. A compound in this class is that sold by UNION CARBIDE under the name "Ucar Silicone ALE 56". c) the quaternary ammonium silicones, in particular of formula (XIX): ## STR2 ## in which R 1 is embedded in the formula (C 1 -C 6) -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 Wherein R7, R7, R7, R7, R7, R7 and R7, which may be identical or different, represent a monovalent hydrocarbon group having from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl group or a C2 alkenyl group; -C18 or a ring comprising 5 or 6 carbon atoms, for example methyl, R6 represents a divalent hydrocarbon group, in particular a C1-C18 alkylene group or a divalent C1-C18, for example C1-C8, alkyleneoxy group connected to the If, by an Si-C bond, R8, which may be identical or different, each represents a hydrogen atom, a monovalent hydrocarbon group having from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl group, an alkenyl group containing C2-C18, a group -R6-NHCOR7, X- is an anion such as a halide ion, in particular chloride or an organic acid salt (acetate, ...), r represents an average statistical value of 2 to 200 and in particular 5 to 100.

These silicones are for example described in the application EP-A-0530974. D) the amino silicones of formula (XX): R 3 SiO 2 R 2 Si R 5 Si O (511-1211) NH I-1 (Cm 2m) In which: R1, R2, R3 and R4, which may be identical or different, each denote a C1-C4 alkyl group or a phenyl group; R5 denotes a C1-C4 alkyl group or a group; hydroxyl, n is an integer ranging from 1 to 5, m is an integer ranging from 1 to 5, and - x is chosen so that the amine number is between 0.01 and 1 meq / g. .

When these compounds are used, a particularly interesting embodiment is their use together with cationic and / or nonionic surfactants. For example, it is possible to use the product sold under the name "Cationic Emulsion DC 939" by the company Dow Corning, which comprises, in addition to amodimethicone, a cationic surfactant which is trimethylketylammonium chloride and a non-surface-active agent. ionic acid, of formula C13H27- (OC2H4) 12-OH, known under the name CTFA "trideceth-12". Another commercial product that can be used according to the invention is the product sold under the name "Dow Corning Q2 7224" by the company Dow Corning, comprising in combination the trimethylsilyl amodimethicone of formula (XVII) described above, a non-surfactant ionic compound of the formula: C8H17-C6H4- (OCH2CH2) 40-OH, known under the name CTFA "octoxynol-40", a second nonionic surfactant of the formula: C12H25- (OCH2-CH2) 6-OH, known under the name CTFA name "isolaureth-6", and propylene glycol. Another commercial product that can be used according to the invention is the product sold under the name Wacker-Belsil ADM LOG 1 marketed by the company Wacker, comprising, in the form of a microemulsion combination, an amodimethicone of formula (XVI) with trideceth-5 and the trideceth-10. The silicones which are particularly preferred are polydimethylsiloxanes containing trimethylsilyl or dimethicone end groups, with dimethylsilanol or dimethiconol end groups, and quaternized or non-quaternized amino silicones, such as amodimethicones or silicones with a quaternary ammonium group, and polyoxyethylenated silicones. Even more preferentially, the silicones of the invention are chosen from polydimethylsiloxanes containing trimethylsilyl end groups and preferably non-quaternized amino silicones. Among these particularly preferred silicones, the product marketed under the name Wacker-Belsil ADM LOG1 by WACKER is more particularly preferred. When the silicone or silicones are present in the composition according to the invention, their preferential amount is at least 0.001% by weight, preferably from 0.001 to 10% by weight, more preferably from 0.05 to 8% by weight, more preferably from 0.1 to 7% by weight, relative to the total weight of the composition.

The composition according to the invention may be aqueous or anhydrous. By "anhydrous" is meant a composition without added water, that is to say a composition whose water possibly present comes only from the water of crystallization or adsorption of the raw materials. In any case, an anhydrous composition contains less than 5% by weight of water and better still less than 1% by weight of water, relative to the total weight of the composition. Preferably, the composition according to the invention is aqueous, and comprises at least 30% by weight of water, and preferably at least 45% by weight of water, relative to the total weight of the composition. When the composition of the invention is aqueous, its pH is generally between 2 and 9, and in particular between 3 and 8. Preferably, the pH is less than 7. Even more preferentially, it ranges from 3 to 6.

It can be adjusted to the desired value by means of acidifying or alkalizing agents usually used in cosmetics for this type of application or even using conventional buffer systems. Among the acidifying agents, there may be mentioned, for example, the organic acids already mentioned above or the mineral acids. By "mineral acid" is meant any acid derived from a mineral compound. Among the mineral acids, mention may be made of hydrochloric acid, orthophosphoric acid, sulfuric acid, sulphonic acids and nitric acid. It will be possible to use inorganic or organic acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids such as acetic acid, tartaric acid, citric acid, lactic acid, sulfonic acids. Among the alkalinizing agents, mention may be made, for example, of ammonia, alkaline carbonates, alkanolamines such as mono-, di- and triethanolamines and their derivatives, sodium or potassium hydroxides and compounds of the following formula: Ra, Rb NWN 'Re Rd in which W is a propylene residue optionally substituted by a hydroxyl group or a C1-C4 alkyl group, Ra, Rb, R, and Rd, which may be identical or different, represent an atom of hydrogen, C1-C4 alkyl or C1-C4 hydroxyalkyl. Preferably, the pH adjusting agents may be chosen from alkaline agents such as ammonia, monoethanolamine, diethanolamine, triethanolamine, 1,3-propanediamine, an alkaline hydroxide, such as 2-amino 2-methyl-1-propanol or the acidifying agents such as phosphoric acid or hydrochloric acid. The compositions according to the invention may also contain one or more additives chosen from ceramides, pseudo-ceramides, vitamins and pro-vitamins, including panthenol, water-soluble and fat-soluble sunscreens, pearlescent and opacifying agents and sequestering agents. solubilizing agents, anti-oxidizing agents, anti-dandruff agents, antiseborrhoeic agents, hair loss and / or regrowing agents, penetrating agents, perfumes, peptizers and preservatives, or any other additive conventionally used in the cosmetic field. These additives may be present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition. Those skilled in the art will take care to choose these optional additives and their amounts so that they do not adversely affect the properties of the compositions of the present invention. The compositions according to the invention may be present, in a nonlimiting manner, in the form of conditioners shampoos and conditioners, body washings, in particular shower gel. The present invention also relates to a method of conditioning the hair or washing / cleaning the body, which comprises applying to the hair an effective amount of a composition as described above. This application may or may not be followed by rinsing. When the application of the composition is followed by rinsing, the exposure time of the composition on the keratin materials ranges from a few seconds to 60 minutes, better from 5 seconds to 30 minutes, even better from 10 seconds to 10 minutes. Whether rinsed or non-rinsed mode, the application of the composition can be done with or without heat. The heater may be a hair dryer, a helmet, a round or flat iron. The heating temperature can be between 40 and 220 ° C. The present invention also relates to the use of the cosmetic composition according to the invention for conditioning the hair or washing / cleaning the body, for example, as a conditioner. The following examples serve to illustrate the invention without being limiting in nature.

EXAMPLES In the following examples, all the amounts are indicated in percentage by weight relative to the total weight of the composition. Example 1 The rinsed conditioner composition according to the following invention was prepared from the ingredients indicated in the table below.

Ingredients Quantity in% by weight Cellulose 1 (1) 0.5 Apricot oil (2) 0.5 Camelina oil (3) 0.5 Distearoylethyl hydroxyethylmethylammonium methosulfate (4) 2.8 MA Cetearyl alcohol 3,5 Tocopherols / Soybean oil (50/50 by weight) (5) 0.5 Caprylyl glycol 0.2 Benzoic acid 0.15 Perfume 0.4 Water qs 100 MA: Active material (1) as defined in Table 1 (2 ) Sold under the name Apricot Kernel Oil by the company Desert Whale (3) sold under the name Refined Gold of Pleasure Oil by the company Aharushkar SHAMN (4) sold under the name Dehyquart F 175 by the company Cognis, 70% by weight active ingredient. (5) sold under the name COVI OX T 50 C by the company COGNIS Example 2 Another rinsed conditioner composition according to the invention was prepared from the ingredients indicated in the table below.

Ingredients Quantity in% by weight Cellulose 1 (1) 0.5 Avocado oil (2) 0.5 Cetyl alcohol 3 Behenyltrimethylammonium chloride (3) 1.44 MA Amodimethicone (4) 0.92 MA PEG-180 2 Esters cetyl (5) 0.25 Bis-diglyceryl polyacyladipate-2 (6) 0.15 Chlorhexidine dihydrochloride 0.02 Benzoic acid 0.15 Perfume 0.4 Water qs 100 MA: Active material (1) as defined in the table 1 (2) sold under the name Avocado oil RDB STAB RE3 by the company Jan Dekker (3) sold under the name GENAMIN KDMP by the company Clariant, 80% by weight of active ingredient. (4) sold under the trade name DOW CORNING 2-8299 CATIONIC EMULSION by the company Dow Corning to 57.5% by weight of active ingredient. (5) myristate / palmitate / myristyl stearate / cetyl / stearyl mixture sold under the trade name CRODAMOL MS PA by the company CRODA (6) sold under the trade name SOFTISAN 649 by the company SASOL An expert found that the compositions of the examples 1 and 2 are stable and have a satisfactory viscosity to be applied to hair.

The compositions of Examples 1 and 2 were applied to locks of hair. They have good qualities of use. The cosmetic properties of the treated hair are very good. We obtain a very easy disentangling, a volume effect, and easy formatting. Example 3 A shampoo composition according to the invention was prepared from the ingredients indicated in the table below.

Ingredients Quantity in% by weight Ammonium Lauryl Sulfate ") 11.2 MA Disodium Cocoamphodiacetate (2) 1.5 MA Cocobetaine (3) 0.6 MA Cellulose 1 (4) 0.5 Camelina Oil (5) 0.01 Argan oil (6) 0.01 Hydroxypropyl guar-0.5 hydroxypropyltrimonium chloride (7) 2-octyl-1-dodecanol 1 Glycol distearate 2 Sodium benzoate 0.5 Salicylic acid 0.2 Sodium chloride 1 Polysorbate 20 0.6 Perfume 0.5 Water qs 100 MA: Active material (1) sold under the trade name Empicol AL 30 by Huntsman, containing 26.8% by weight of active ingredient (2) sold under the name Miranol C2M concentrated by the company RHODIA, 31.5% by weight of active ingredient (3) sold under the trade name Dehyton AB 30 by the company COGNIS, 30% by weight of active ingredient (4). defined in Table 1 (5) sold under the trade name Refined Gold of Pleasure Oil by AARHUSKARL SHAMN (6) sold under the name as LIPOFRUCTYL ARGAN BE LS 9779 by the company BASF (7) sold under the trade name Jaguar 162 by the company RHODIA 10 EXAMPLE 4 Another shampoo composition according to the invention was prepared from the ingredients indicated in the table below. below. Ingredients Amount in% by Weight Ammonium Lauryl Sulfate ") 11.2 MA Disodium Cocoamphodiacetate (2) 1.51 MA Cocobetaine (3) 0.6 MA Cellulose 1 (4) 0.5 Apricot Oil (5) 0, 01 Rice bran oil (6) 0.01 Olive oil (7) 0.01 Hydroxypropyl guar-0.5 hydroxypropyltrimonium chloride (8) 2-octyl-1-dodecanol 1 Glycol distearate 2 Sodium benzoate 0.5 Salicylic acid 0.2 Polysorbate 20 0.6 Sodium chloride 1 Perfume 0.5 Water qs 100 MA: Active material (1) sold under the trade name Empicol AL 30 by Huntsman, in aqueous solution of 26, 8% by weight of active material (2) sold under the trade name Miranol C2M concentrated by Rhodia, in aqueous solution containing 31.5% by weight of active ingredient (3) sold under the trade name Dehyton AB 30 by the company COGNIS, in aqueous solution at 30% by weight of active ingredient (4) as defined in Table 1 (5) sold under the trade name Apricot Ker nel Oil by the company DESERT WHALE (6) sold under the trade name RICE BRAN OIL by the company TSUNO RICE FINE CHEMICALS (7) sold under the trade name OLIVE OLIVE OIL by the company OLVEA (8) sold under the trade name Jaguar 162 by RHODIA Example 5 Another shampoo composition according to the invention was prepared from the ingredients indicated in the table below.

Ingredients Quantity in% by Weight Sodium Laureth Sulfate ") 12.34 MA Cocobetaine (2) 1.8 MA Cellulose 1 (3) 0.5 Olive Oil (4) 0.01 Dimethicone (5) 1.875 Glycol Distearate 1 , 6 Sodium benzoate 0.5 Salicylic acid 0.2 Sodium chloride 0.736 Carbomer (6) 0.147 MA Hexylene glycol 0.5 Fragrance 0.5 Water qs 100 MA: Active material (1) sold under the trade name Texapon AOS 225 UP by the company COGNIS, containing 70% by weight of active material (2) sold under the trade name Dehyton AB 30 by the company Cognis, in aqueous solution containing 30% by weight of active ingredient (3) as defined in Table 1 (4) sold under the trade name OIL OF VIRGIN OLIVES by the company OLVEA (5) sold under the trade name XIAMETER PMX-200 SILICON FLUID 60000 CS by the company Dow Corning (6) sold under the trade name Carbopol 980 by the company LUBRIZOL to 98% by weight of active ingredient An expert found that the The compositions of Examples 3 to 5 are stable and have a satisfactory viscosity to be applied to hair.

The compositions of Examples 3 to 5 were applied to the hair and then rinsed. After drying, the hair is easy to disentangle, soft and shiny.

Claims (18)

REVENDICATIONS1. A cosmetic composition for cleaning the body or for conditioning hair comprising one or more hydrophobically modified celluloses having a content of hydrophobic group (s) greater than 0.6% by weight, relative to the total weight of the hydrophobically modified cellulose, and one or more vegetable oils, said one or more hydrophobically modified celluloses comprising a main chain consisting of a non-ionic cellulose ether on which is attached to one or more hydrophobic groups selected from: 1) 3-alkoxy-groups; 2-hydroxy (C 3 -C 6) alkyl in which the alkoxy moiety is branched or linear and has 5 to 30 carbon atoms, preferably 3-alkoxy-2-hydroxypropyl, 2) C 9 -C 30 alkyl groups, preferably C 10 -C 22 alkyl groups, and C 6 -C 30 aryl, arylalkyl and alkylaryl groups, 3) and mixtures thereof, said one or more hydrophobically modified celluloses not having a non-alkoxylated C 3 -C 8 alkyl group. 2. Composition according to Claim 1, characterized in that the hydrophobically modified cellulose or celluloses having a content of hydrophobic group (s) greater than 0.6% by weight have a hydrophobic group (s) content (s). greater than 0.8% by weight, more preferably greater than 1% by weight, and preferably less than 5% by weight, relative to the total weight of the hydrophobically modified cellulose. 3. Composition according to claim 1 or 2, characterized in that the hydrophobic group or groups are chosen from: 1 ') 3-alkoxy-2-hydroxypropyl groups in which the alkoxy moiety is branched or linear and comprises from 5 to 30 carbon atoms, preferably from 5 to 20 carbon atoms, 2 ') C 9 -C 30, preferably C 10 -C 22, better still C 12 -C 18, and even more preferentially C 12 -C 16 alkyl groups; ) and their mixtures. 4. Composition according to any one of the preceding claims, characterized in that the hydrophobically modified cellulose or celluloses having a content of hydrophobic group (s) greater than 0.6% by weight have a weight average molecular weight of from 100,000 to 2,000,000, better from 200,000 to 1,500,000, and even more preferably from 250,000 to 1,000,000. 5. Composition according to any one of the preceding claims, characterized in that the hydrophobically modified cellulose or celluloses are chosen from cetyl hydroxyethylcelluloses having a content of hydrophobic group (s) greater than 0.6% by weight. 6. Composition according to any one of the preceding claims, characterized in that the hydrophobically modified cellulose or celluloses are present in amounts of 0.01 to 10% by weight, more preferably 0.1 to 5% by weight, better from 0.2 to 2% by weight, relative to the total weight of the composition. 7. Composition according to any one of the preceding claims, characterized in that the vegetable oil (s) are (are) chosen from sunflower, corn, soybean, squash, grape seed and sesame oils. , hazelnut, apricot, macadamia, arara, avocado, argan, rice bran, olive, rapeseed, copra, wheat germ, flax, sweet almond , safflower, bancoulier nut, passionflower, muscat rose, shea butter, palm, cotton, jojoba, alfalfa, poppy, pumpkin, blackcurrant, evening primrose, millet, barley, quinoa, rye, camelina, tamanu, lemon, babassu, pracaxi and their mixtures. 8. Composition according to any one of the preceding claims, characterized in that the vegetable oil (s) is (are) constituted by triglycerides whose content of C18: 1 + C18: 2 fatty acids represents more 20% of the total fatty acid content. 9. Composition according to any one of the preceding claims, characterized in that the vegetable oil (s) is (are) chosen from apricot oil, camelina oil, avocado, argan oil, rice bran oil, olive oil and their blends. 10. Composition according to any one of the preceding claims, characterized in that the vegetable oil (s) are present in an amount ranging from 0.001 to 20%, better still from 0.001 to 10% by weight relative to the weight. total of the composition. 11. Composition according to any one of the preceding claims, characterized in that the vegetable oil or oils (s) are present in an amount of less than 5% by weight, more preferably ranging from 0.001 to 3% by weight, better from 0.01 to 2% by weight, more preferably from 0.01 to 1.5% by weight, relative to the total weight of the composition. 12. Composition according to any one of the preceding claims, characterized in that it comprises one or more surfactants chosen from anionic surfactants, amphoteric or zwitterionic, nonionic and mixtures thereof. 13. Composition according to any one of the preceding claims, characterized in that it comprises one or more cationic surfactants. 14. Composition according to any one of the preceding claims, characterized in that it comprises one or more fatty alcohols comprising from 8 to 40 carbon atoms, better still from 10 to 30 carbon atoms, and even more preferably from 12 to 25 carbon atoms. carbon atoms. 15. Composition according to any one of the preceding claims, characterized in that it comprises one or more cationic polymers. 16. Composition according to any one of the preceding claims, characterized in that it comprises one or more silicones. 17. A method of conditioning the hair or washing / cleaning the body, characterized in that it consists in applying to the keratin materials a composition according to any one of claims 1 to 16, and then to perform or not rinse after a possible exposure time, with or without heat. 18. Use of the cosmetic composition according to one of claims 1 to 16 for conditioning the hair, or washing / cleaning the body.