FR2802086A1 - COSMETIC COMPOSITIONS CONTAINING QUATERNIZED SILICONE AND CATIONIC POLYMER AND USES THEREOF - Google Patents

Abstract

The invention concerns novel cosmetic compositions comprising in a cosmetically acceptable medium at least a cationic polymer and at least a type (AB)n silicone, A being a polysiloxane block and B being a block comprising at least two quaternary ammonium groups. Said combination provides improved cosmetic properties (lightness, easy combing, volume). Said compositions are used in particular for washing and /or conditioning keratinous materials such as hair or skin.

Description

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COSMETIC COMPOSITIONS CONTAINING QUATERNIZED SILICONE AND
CATIONIC POLYMER AND USES THEREOF

The present invention relates to novel cosmetic compositions comprising, in a cosmetically acceptable medium, at least one cationic polymer and at least one quaternary polyammonium silicone of (AB) n type, A being a polysiloxane block and B being a block comprising at least two quaternary ammonium groups. .

It is well known that hair which has been sensitized (ie damaged and / or embrittled) to varying degrees under the action of atmospheric agents or under the action of mechanical or chemical treatments, such as colorations, discolorations and / or perms, are often difficult to disentangle and comb, and lack softness.

It has already been advocated in the compositions for washing or caring for keratin materials such as the hair the use of conditioning agents, in particular cationic polymers or silicones, to facilitate disentangling of the hair and to impart softness and suppleness to it. However, the cosmetic benefits mentioned above are unfortunately also accompanied, on dried hair, certain cosmetic effects deemed undesirable, namely a heavier hair (lack of lightness of the hair), a lack of smoothing (non-homogeneous hair of root to tip).

In addition, the use of cationic polymers for this purpose has various disadvantages. Because of their high affinity for the hair, some of these polymers deposit significantly during repeated use, and lead to undesirable effects such as unpleasant, loaded, stiffening of the hair, and interfiber adhesion affecting styling. These disadvantages are accentuated in the case of fine hair, which lack of nervousness and volume.

It has also been recommended to improve the conditioning properties of hair products, to use cosmetic compositions for the treatment of hair containing the combination of a conditioner and a polyoxyalkylenated silicone type (AB) n comprising at least one group primary, secondary or tertiary amine, A being a polysiloxane block and B being a polyoxyalkylenated block comprising at least one primary, secondary or tertiary amine group. However, these compositions do not yet give complete satisfaction as regards the properties of smoothing and

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 softness imparted to the hair. In addition, the hair is weighed down after repeated applications.

It has also been recommended, for improving the conditioning properties of hair products, to use cosmetic compositions for the treatment of hair containing a type (AB) n silicone, where A is a polysiloxane block and B is a block comprising at least two quaternary ammonium groups. . These compositions, however, do not yet give complete satisfaction with regard to the lightness properties imparted to the hair.

In summary, it turns out that the current cosmetic compositions containing conditioning agents, are not completely satisfactory.

The Applicant has now discovered that the combination of a silicone comprising at least two quaternary ammonium groups with cationic polymers overcomes these disadvantages.

Thus, following important research conducted on the subject, it has now been found by the Applicant that by introducing a particular silicone described below in the compositions in particular capillaries of the prior art based on cationic polymers, it is possible to limit or even eliminate the problems generally related to the use of such compositions, namely in particular the increase in weight, the lack of smoothing and softness, the hair, while retaining the other advantageous cosmetic properties which are attached to compositions containing a cationic polymer.

Furthermore, the compositions of the invention applied to the skin, especially in the form of a bubble bath or a shower gel, provide an improvement in the softness of the skin.

Thus, according to the present invention, it is now proposed new cosmetic compositions, comprising, in a cosmetically acceptable medium, at least one quaternary polyammonium silicone type (AB) n, A being a polysiloxane block and B being a block comprising at least two quaternary ammonium groups and at least one cationic polymer.

Another subject of the invention relates to the use of a quaternary polyammonium silicone of (AB) n type, where A is a polysiloxane block and B is a block comprising at least one

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 minus two quaternary ammonium groups in, or for the manufacture of a cosmetic composition comprising a cationic polymer.

The different objects of the invention will now be detailed. All the meanings and definitions of the compounds used in the present invention given below are valid for all the objects of the invention.

dans laquelle : R1, R2, R3, R4, identiques ou différents, représentent un radical alkyle en C1-C4, de préférence méthyle. The quaternary polyammonium silicones of type (AB) n, A being a polysiloxane block and B being a block comprising at least two quaternary ammonium groups may consist of repeating units of the following general formula:

in which: R1, R2, R3, R4, which may be identical or different, represent a C1-C4 alkyl radical, preferably methyl.

Plus particulièrement, X et X', identiques ou différents, sont choisis parmi : -CH2CH2CH20 CH2CH (OH)CH2-, -CH2CH(OH)CH2 OCH2CH2CH2- X and X ', which are identical or different, represent a divalent organic group which is bonded to the adjacent silicon atom by a carbon-silicon bond and to a nitrogen atom, and which comprises at least 4 carbon atoms and a hydroxyl group; X and X ', which are identical or different, are preferably a C4-C12 hydrocarbon radical optionally comprising one or more heteroatoms such as oxygen. More particularly, X and X ', which may be identical or different, denote a linear or branched butylene radical, linear or branched hexylene, -CH 2 CH 2 CH 2 OCH (OH) CH 2 -, -CH 2 CH 2 CH 2 O CH 2 CH (OH) CH 2 -, -CH 2 CH 2 CH 2 O CH 2 CH (CH 2 OH) -, -CH2CH (OH) CH2 OCH2CH2CH2-

More particularly, X and X ', which are identical or different, are chosen from: -CH 2 CH 2 CH 2 O CH 2 CH (OH) CH 2 -, -CH 2 CH (OH) CH 2 OCH 2 CH 2 CH 2

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 Y represents a divalent organic group comprising at least two carbon atoms, Y is preferably a C2-C12 hydrocarbon radical optionally comprising one or more heteroatoms such as oxygen. More particularly, Y denotes an ethylene radical, linear or branched propylene, linear or branched butylene, linear or branched hexylene or -CH 2 CH 2 CH 2 OCH (OH) CH 2 -, -CH 2 CH 2 OCH 2 CH 2 -, -CH 2 OCH 2 -, -CH 2 CH 2 N (CH 3) CH 2 CH 2 -.

More particularly, Y is selected from -CH2CH2OCH2CH2-, - (CH2) 6- and - (CH2) 3-.

A- denotes an organic or inorganic anion, such as, for example, bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulphite, methosulphate, sulphate, phosphate. n defines the number of dimethylsiloxane units and is generally a number between 5 and 200 and preferably between 15 and 100. m defines the number of AB blocks and is greater than or equal to 1 and preferably between 1 and 10.

The weight average molecular weight of the silicone is preferably between 2,000 and 1,000,000 and even more particularly between 3,500 and 200,000.

These quaternary polyammonium silicones are especially described in patent application EP-A-282720. The quaternary polyammonium silicone is preferably used in an amount of between 0.01% and 20% by weight relative to the total weight of the composition. More preferably, this amount is between 0.1 and 15% by weight and even more particularly between 0.5 and 10% by weight.

Even more generally, within the meaning of the present invention, the expression "cationic polymer" denotes any polymer containing cationic groups and / or ionizable groups in cationic groups.

The cationic polymers that may be used in accordance with the present invention may be chosen from all those already known per se as improving the properties

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 hair cosmetics treated with detergent compositions, namely in particular those described in the patent application EP-A-0 337 354 and in the French patent applications FR-A-2 270 846.2 383 660.2 598 611, 2 470,596 and 2,519,863.

The preferred cationic polymers are chosen from those containing units containing primary, secondary, tertiary and / or quaternary amine groups that may either be part of the main polymer chain or may be carried by a lateral substituent directly connected thereto.

The cationic polymers used generally have a number-average molecular weight of between about 500 and 5 × 10 6, and preferably between about 103 and 3 × 10 6.

Among the cationic polymers, mention may be made more particularly of the polyamine, polyaminoamide and quaternary polyammonium type polymers. These are known products.

The polymers of the polyamine, polyamidoamide or quaternary polyammonium type which can be used in accordance with the present invention, which may be mentioned in particular, are those described in French patents Nos. 2,505,348 or 2,542,997. Among these polymers, mention may be made of: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the following units of formulas:

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dans lesquelles: R3 , identiques ou différents, désignent un atome d'hydrogène ou un radical CH3; A, identiques ou différents, représentent un groupe alkyle, linéaire ou ramifié, de 1 à 6 atomes de carbone, de préférence 2 ou 3 atomes de carbone ou un groupe hydroxyalkyle de 1 à 4 atomes de carbone ; R4, R5, R6, identiques ou différents, représentent un groupe alkyle ayant de 1 à 18 atomes de carbone ou un radical benzyle et de préférence un groupe alkyle ayant de 1 à 6 atomes de carbone; R1 et R2 , identiques ou différents, représentent hydrogène ou un groupe alkyle ayant de 1 à 6 atomes de carbone et de préférence méthyle ou éthyle; X désigne un anion dérivé d'un acide minéral ou organique tel que un anion méthosulfate ou un halogénure tel que chlorure ou bromure.

in which: R3, which may be identical or different, denote a hydrogen atom or a CH3 radical; A, which may be identical or different, represent a linear or branched alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical and preferably an alkyl group having from 1 to 6 carbon atoms; R1 and R2, identical or different, represent hydrogen or an alkyl group having 1 to 6 carbon atoms and preferably methyl or ethyl; X denotes an anion derived from a mineral or organic acid such as a methosulphate anion or a halide such as chloride or bromide.

The copolymers of the family (1) may further contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetones acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyls (C1-C4) , acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters.

Thus, among these copolymers of the family (1), mention may be made of: the copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulphate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company Hercules,

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 the copolymers of acrylamide and of methacryloyloxyethyltrimethylammonium chloride described, for example, in the patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY, the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulphate sold under the name RETEN by the company HERCULES, - vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers quaternized or otherwise, such as the products sold under the name "GAFQUAT" by the company ISP such as "GAFQUAT 734" or "GAFQUAT 755 "or the products referred to as" COPOLYMER 845,958 and 937 ". These polymers are described in detail in French patents Nos. 2,077,143 and 2,393,573, dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, such as the product sold under the name GAFFIX VC 713 by the company ISP, vinylpyrrolidone copolymers. / methacrylamidopropyl dimethylamine marketed in particular under the name STYLEZE CC 10 by ISP.

and the quaternized vinylpyrrolidone / dimethylaminopropyl methacrylamide copolymers such as the product sold under the name "GAFQUAT HS 100" by the company ISP.

(2) The cellulose ether derivatives containing quaternary ammonium groups described in French Patent 1,492,597, and in particular the polymers sold under the names "JR" (JR 400, JR 125, JR 30M) or "LR" (LR 400, LR 30M) by Union Carbide Corporation. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose reacted with an epoxide substituted by a trimethylammonium group.

(3) Cationic cellulose derivatives such as cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, and described in particular in US Pat. No. 4,131,576, such as hydroxyalkyl celluloses, such as hydroxymethyl- hydroxyethyl or hydroxypropyl cellulose grafted in particular with a salt of methacryloylethyl trimethylammonium, methacrylmidopropyl trimethylammonium, dimethyl-diallylammonium.

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The marketed products corresponding to this definition are more particularly the products sold under the name "Celquat L 200" and "Celquat H 100" by the company National Starch.

(4) The cationic polysaccharides described more particularly in US Pat. Nos. 3,589,578 and 4,031,307, such as guar gums containing cationic trialkylammonium groups. For example, guar gums modified with a salt (eg chloride) of 2,3-epoxypropyltrimethylammonium are used.

Such products are marketed in particular under the trade names JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17 or JAGUAR C162 by the company MEYHALL.

(5) polymers consisting of piperazinyl units and straight or branched chain alkylene or hydroxyalkylene divalent radicals, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as oxidation and / or quaternization of these polymers. Such polymers are described in particular in French Patents 2 162,025 and 2,280,361; (6) water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide or else with an oligomer resulting from the reaction of a bifunctional compound which is reactive with a bis-halohydrin, a bisazetidinium, a bis-haloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 moles per amine group of the polymaoamide; these polyaminoamides can be alkylated or if they contain one or more tertiary amine functional groups, quaternized. Such polymers are in particular described in French Patents 2,252,840 and 2,368,508; (7) polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. For example, the adipic acid polymers may be

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 diacoylaminohydroxyalkyldialoylene triamine wherein the alkyl radical has 1 to 4 carbon atoms and preferably denotes methyl, ethyl, propyl. Such polymers are described in particular in French Patent 1,583,363.

 Among these derivatives, mention may be made more particularly of the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz.

(8) polymers obtained by reacting a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. The molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: and 1.4: 1, the polyaminoamide resulting therefrom being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the amine group. secondary polyaminoamide between 0.5: and 1.8: Such polymers are described in particular in US Patents 3,227,615 and 2,961,347.

 Polymers of this type are in particular sold under the name "Hercosett 57" by the company Hercules Inc. or under the name "PD 170" or "Delsette 101" by the company Hercules in the case of the adipic acid copolymer / epoxypropyl / diethylenetriamine.

formules dans lesquelles k et t sont égaux à 0 ou 1, la somme k + t étant égale à 1 ; R12 désigne un atome d'hydrogène ou un radical méthyle ; R10 et R11, indépendamment l'un (9) cyclopolymers of alkyl diallyl amine or of dialkyl diallyl ammonium, such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (VI) or (VI '):

formulas in which k and t are 0 or 1, the sum k + t being equal to 1; R12 denotes a hydrogen atom or a methyl radical; R10 and R11, independently one

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 on the other, denote an alkyl group having 1 to 22 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (C1-C4) or R10 and R11 may designate, together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. These polymers are described in particular in French patent 2,080,759 and in its certificate of addition 2,190,406.

R10 and R11, independently of one another, preferably denote an alkyl group having 1 to 4 carbon atoms.

 Among the polymers defined above, mention may be made more particularly of the homopolymer of dimethyldiallylammonium chloride sold under the name "Merquat 100" by the company Calgon (and its homologues of low molecular weight average) and the copolymers of sodium chloride. diallyldimethylammonium and acrylamide sold under the name "MERQUAT 550".

formule (VII) dans laquelle :
R13, R14, R15 et R16, identiques ou différents, représentent des radicaux aliphatiques, alicycliques, ou arylaliphatiques contenant de 1 à 20 atomes de carbone ou des radicaux hydroxyalkylaliphatiques inférieurs, ou bien R13, R14, R15 et R16, ensemble ou séparément, constituent avec les atomes d'azote auxquels ils sont rattachés des hétérocycles contenant éventuellement un second hétéroatome autre que l'azote ou bien R13, R14, R15 et R16 représentent un radical alkyle en C1-C6 linéaire ou ramifié substitué par un groupement nitrile, ester, acyle, amide ou -CO-O-R17-D ou-CO- NH-R17-D où R17 est un alkylène et D un groupement ammonium quaternaire ; (10) the quaternary diammonium polymer containing repeating units corresponding to the formula:

formula (VII) in which:
R13, R14, R15 and R16, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic radicals containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or R13, R14, R15 and R16, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen or R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl radical substituted with a nitrile group, ester, acyl, amide or -CO-O-R17-D or -CO-NH-R17-D wherein R17 is alkylene and D is a quaternary ammonium group;

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-[CH2 -CH (CH3 )-O]y-C H2 -CH (C H3)- où x et y désignent un nombre entier de 1 à 4, représentant un degré de polymérisation défini et unique ou un nombre quelconque de 1 à 4 représentant un degré de polymérisation moyen ; b) un reste de diamine bis-secondaire tel qu'un dérivé de pipérazine ; c) un reste de diamine bis-primaire de formule : -NH-Y-NH-, où Y désigne un radical hydrocarboné linéaire ou ramifié, ou bien le radical bivalent -CH2-CH2-S-S-CH2-CH2- ; d) un groupement uréylène de formule : -NH-CO-NH- ;
De préférence, X- est un anion tel que le chlorure ou le bromure. A1 and B1 represent polymethylene groups containing from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more carbon atoms; oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
X- denotes an anion derived from a mineral or organic acid;
A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; furthermore, if A1 denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 may also denote a (CH2) n -CO-D-OC- (CH2) n- group in which D denotes: a) a residue of glycol of formula: -OZO-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: - (CH2-CH2-O) x-CH2-CH2-

- [CH 2 -CH (CH 3) -O] y C H 2 -CH (C H 3) - where x and y denote an integer of 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing a degree of average polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or the divalent radical -CH2-CH2-SS-CH2-CH2-; d) a ureylene group of formula: -NH-CO-NH-;
Preferably, X- is an anion such as chloride or bromide.

 These polymers have a number average molecular weight generally between 1000 and 100000.

 Polymers of this type are described in French patents 2, 320,330, 2,270,846, 2,316,271, 2,336,434 and 2,413,907 and US Patents 2,273,780, 2,375,853, 2,388,614 and 2,454,547. , 206.462, 2. 261.002, 2.271.378, 3. 874.870,

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 4,001,432, 3,929,990, 3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945 and 4,027,020.

dans laquelle R1, R2, R3 et R4, identiques ou différents, désignent un radical alkyle ou hydroxyalkyle ayant de 1 à 4 atomes de carbone environ, n et p sont des nombres entiers variant de 2 à 20 environ et, X- est un anion dérivé d'un acide minéral ou organique. It is more particularly possible to use polymers which consist of recurring units corresponding to the formula:

in which R1, R2, R3 and R4, which are identical or different, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, n and p are integers ranging from 2 to approximately 20 and, X- is an anion derived from a mineral or organic acid.

A compound of formula (a) which is particularly preferred is that for which R 1, R 2, R 3 and R 4 represent a methyl radical and n = 3, p = 6 and X = Cl, referred to as Hexadimethrine chloride according to the INCI nomenclature (CTFA).

formule dans laquelle : R18, R19, R20 et R21, identiques ou différents, représentent un atome

d'hydrogène ou un radical méthyle, éthyle, propyle, (3-hydroxyéthyle, p-hydroxypropyle ou -CH2CH2 (OCH2CH2)pOH, où p est égal à 0 ou à un nombre entier compris entre 1 et 6, sous réserve que R18, R19, R20 et R21 ne représentent pas simultanément un atome d'hydrogène, r et s, identiques ou différents, sont des nombres entiers compris entre 1 et 6, q est égal à 0 ou à un nombre entier compris entre 1 et 34,
X- désigne un anion tel qu'un halogènure, (11) quaternary polyammonium polymers consisting of units of formula (VIII):

formula in which: R18, R19, R20 and R21, identical or different, represent an atom

hydrogen, methyl, ethyl, propyl, (3-hydroxyethyl, p-hydroxypropyl or -CH2CH2 (OCH2CH2) pOH, where p is 0 or an integer of 1 to 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom, r and s, identical or different, are integers between 1 and 6, q is 0 or an integer between 1 and 34,
X- denotes an anion such as a halogenide,

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A denotes a radical of a dihalide or is preferably -CH 2 -CH 2 -O-CH 2 -CH 2 -.

Such compounds are described in particular in patent application EP-A-122 324.

For example, the products "Mirapol A 15", "Mirapol AD1", "Mirapol AZ1" and "Mirapol 175" sold by the company Miranol can be mentioned among them.

(12) Quaternary vinylpyrrolidone and vinylimidazole polymers such as, for example, the products sold under the names Luviquat @ FC 905, FC 550 and FC 370 by the company B.A.S.F.

(13) Polyamines such as Polyquart H sold by HENKEL, referenced under the name POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE in the CTFA dictionary.

(14) Crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts such as polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized by the methyl chloride, homo or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylenebisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of said copolymer in mineral oil. This dispersion is sold under the name SALCARE SC 92 by the company ALLIED COLLOIDS. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing about 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are sold under the names SALCARE SC 95 and SALCARE SC 96 by the company ALLIED COLLOIDS.

Other cationic polymers which may be used in the context of the invention are cationic proteins or hydrolysates of cationic proteins, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine units or

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 vinylpyridinium, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives.

Among all the cationic polymers that may be used in the context of the present invention, it is preferred to use quaternary cellulose ether derivatives such as the products sold under the name JR 400 by the company Union Carbide Corporation, polysaccharides. cationic cyclopolymers, in particular the homopolymers or copolymers of dimethyldiallylammonium chloride, sold under the names Merquat 100, Merquat 550 and Merquat S by the company Calgon, the quaternary vinylpyrrolidone and vinylimidazole polymers, and mixtures thereof.

According to a particularly preferred embodiment, the compositions according to the invention further comprise at least one other silicone.

The silicones that can be used in accordance with the invention are in particular polyorganosiloxanes that are insoluble in the composition and can be in the form of oils, waxes, resins or gums.

Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968) Academie Press. They can be volatile or nonvolatile.

When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic silicones containing from 3 to 7 carbon atoms and from preferably 4 to 5.

It is, for example, octamethylcyclotetrasiloxane marketed in particular under the name "VOLATILE SILICONE 7207" by UNION CARBIDE or "SILBIONE 70045 V 2" by RHONE POULENC, decamethylcyclopentasiloxane marketed under the name "VOLATILE SILICONE 7158" by CARBIDE UNION, "SILBIONE 70045 V 5" by RHONE POULENC, as well as their mixtures.

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On peut également citer les mélanges de silicones cycliques avec des composés organiques dérivés du silicium, tels que le mélange d'octaméthylcyclotétrasiloxane et de tétratriméthylsilylpentaérythritol (50/50) et le mélange d'octaméthylcyclotétrasiloxane et d'oxy-1,1'(hexa-2,2,2',2',3,3'-triméthylsilyloxy) bis-néopentane ; (ii) les silicones volatiles linéaires ayant 2 à 9 atomes de silicium et possédant une viscosité inférieure ou égale à 5.10-6m2/s à 25 C. Il s'agit, par exemple, du décaméthyltétrasiloxane commercialisé notamment sous la dénomination "SH 200" par la société TORAY SILICONE. Des silicones entrant dans cette classe sont également décrites dans l'article publié dans Cosmetics and toiletries, Vol. 91, Jan. 76, P. 27-32 TODD & BYERS "Volatile Silicone fluids for cosmetics". Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylakylsiloxane type, such as the "VOLATILE SILICONE FZ 3109" marketed by UNION CARBIDE, of chemical structure:

Mention may also be made of cyclic silicone mixtures with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '(hexamethylcyclotetrasiloxane). 2,2,2 ', 2', 3,3'-trimethylsilyloxy) bis-neopentane; (ii) linear volatile silicones having 2 to 9 silicon atoms and having a viscosity of less than or equal to 5 × 10 -6 m 2 / s at 25 ° C. This is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" by the company TORAY SILICONE. Silicones included in this class are also described in the article published in Cosmetics and toiletries, Vol. 91, Jan. 76, p. 27-32 TODD & BYERS "Volatile Silicone fluids for cosmetics".

Non-volatile silicones and more particularly polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, polyorganosiloxanes modified with organofunctional groups and their mixtures are preferably used.

These silicones are more particularly chosen from polyalkylsiloxanes, among which, for example, polydimethylsiloxanes containing trimethylsilyl end groups having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. and preferably 1 × 10 -5 to 1 m 2 / s may be mentioned. The viscosity of the silicones is for example measured at 25 ° C. according to ASTM 445 Appendix C.

Among these polyalkylsiloxanes, mention may be made, without limitation, of the following commercial products:

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 the SILBIONE oils of the 47 and 70 047 series or the MIRASIL oils marketed by RHONE POULENC, such as, for example, the 70 047 V 500 000 oil; oils of the MIRASIL series marketed by RHONE POULENC; the oils of the 200 series of Dow Corning, such as, more particularly, the DC200 with a viscosity of 60,000 Cst; - VISCASIL oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC.

Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups (Dimethiconol according to the CTFA name), such as the oils of the 48 series of the company Rhone-Poulenc.

In this class of polyalkylsiloxanes, mention may also be made of the products sold under the names "ABIL WAX 9800 and 9801" by GOLDSCHMIDT, which are poly (C1-C20) alkylsiloxanes.

The polyalkylarylsiloxanes are especially chosen from polydimethyl methylphenylsiloxanes and linear and / or branched polydimethyl diphenylsiloxanes with a viscosity of from 1.10-5 to 5.10-2m2 / s at 25 C.

Among these polyalkylarylsiloxanes include by way of example the products sold under the following names: the SILBIONE oils of the 70 641 series from RHONE POULENC; . RHODORSIL 70 633 and 763 series oils from RHONE POULENC; . DOW CORNING 556 COSMETIC GRAD FLUID oil from DOW CORNING; . silicones of the PK series from BAYER, such as the product PK20; . silicones of the PN and PH series of BAYER, such as the PN1000 and PH1000 products; . some oils from the SF series of GENERAL ELECTRIC such as SF 1023,
SF 1154, SF 1250, SF 1265.

The silicone gums that can be used in accordance with the invention are in particular polydiorganosiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones and polydimethylsiloxane oils.

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 (PDMS), polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecanes or mixtures thereof.

The following products may more particularly be mentioned: polydimethylsiloxane polydimethylsiloxane / methylvinylsiloxane, polydimethylsiloxane / diphenylsiloxane, polydimethylsiloxane / phenylmethylsiloxane, polydimethylsiloxane / diphenylsiloxane / methylvinylsiloxane.

More particularly useful products according to the invention are mixtures such as: mixtures formed from a hydroxylated polydimethylsiloxane at the end of the chain (called dimethiconol according to the CTFA dictionary nomenclature) and a cyclic polydimethylsiloxane (called cyclomethicone according to the CTFA dictionary nomenclature), such as the product Q2 1401 marketed by the company Dow Corning; . mixtures formed from a polydimethylsiloxane gum with a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500,000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; . mixtures of two PDMS of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s. This product preferably comprises 15% of SE 30 gum and 85% of an SF 96 oil.

The organopolysiloxane resins used in accordance with the invention are crosslinked siloxane systems containing the units: R 2 SiO 2/2, R 3 SiO 1/2, RSiO 3, 2 and SiO 4/2 in which R represents a hydrocarbon group having 1 to 16 carbon atoms or a phenyl group. Among

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 these products, those particularly preferred are those in which R denotes a lower alkyl radical C1-C4, more particularly methyl, or a phenyl radical.

Among these resins may be mentioned the product marketed under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure.

Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shin-Etsu.

The organomodified silicones that may be used in accordance with the invention are silicones as defined above and comprising in their structure one or more organofunctional groups attached via a hydrocarbon radical.

Among the organomodified silicones, mention may be made of polyorganosiloxanes comprising: polyethyleneoxy and / or polypropyleneoxy groups optionally comprising C 6 -C 24 alkyl groups such as the products called dimethicone copolyol marketed by the company Dow Corning under the name DC 1248 or the oils SILWET L 722, L 7500, L 77, L 711 of the company UNION CARBIDE and the alkyl (C12) methicone copolyol marketed by the company Dow Corning under the name Q2 5200; substituted or unsubstituted amine groups such as the products sold under the name GP 4 Silicone Fluid and GP 7100 by the company Genesee or the products sold under the names Q2 8220 and Dow Corning 929 or 939 by the company Dow Corning. The substituted amino groups are, in particular, C1-C4 aminoalkyl groups; thiol groups such as the products sold under the names "GP 72 A" and "GP 71" from GENESEE;

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dans laquelle les radicaux R3 identiques ou différents sont choisis parmi les radicaux méthyle et phényle ; au moins 60 % en mole des radicaux R3 désignant méthyle ; le radical R'3 est un chaînon alkylène divalent hydrocarboné en C2-C18 ; p est compris entre 1 et 30 inclus ; q est compris entre 1 et 150 inclus ; - des groupements acyloxyalkyle tels que par exemple les polyorganosiloxanes décrits dans le brevet US-A-4957732 et répondant à la formule (X) :

dans laquelle : R4 désigne un groupement méthyle, phényle, -OCOR5, hydroxyle, un seul des radicaux R4 par atome de silicium pouvant être OH ; R'4 désigne méthyle, phényle ; au moins 60 % en proportion molaire de l'ensemble des radicaux R4 et R'4 désignant méthyle ; R5 désigne alkyle ou alcényle en C8-C20 ; R" désigne un radical alkylène hydrocarboné divalent, linéaire ou ramifié en C2-C18 ; r est compris entre 1 et 120 inclus ; p est compris entre 1 et 30 ; alkoxylated groups, such as the product marketed under the name "Silicone Copolymer F-755" by SWS Silicones and Abil Wax 2428, 2434 and 2440 by the company GOLDSCHMIDT; hydroxyl groups such as the hydroxyalkyl-functional polyorganosiloxanes described in the French patent application FR-A-85 16334 corresponding to the formula (IX):

in which the radicals R3 which are identical or different are chosen from methyl and phenyl radicals; at least 60 mol% of the radicals R3 denoting methyl; the radical R '3 is a C2-C18 hydrocarbon divalent alkylene chain; p is between 1 and 30 inclusive; q is from 1 to 150 inclusive; acyloxyalkyl groups such as, for example, the polyorganosiloxanes described in US Pat. No. 4,957,732 and corresponding to formula (X):

wherein: R4 denotes a methyl, phenyl, -OCOR5, hydroxyl group, only one of the radicals R4 per silicon atom may be OH; R'4 is methyl, phenyl; at least 60% in molar proportion of all the radicals R4 and R'4 denoting methyl; R5 is C8-C20 alkyl or alkenyl; R "denotes a linear or branched C2-C18 divalent hydrocarbon alkylene radical, r is between 1 and 120 inclusive, p is between 1 and 30;

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dans des proportions ne dépassant pas 15 % de la somme p + q + r. q is 0 or less than 0.5 p, p + q being 1 to 30; the polyorganosiloxanes of formula (VI) may contain groups:

in proportions not exceeding 15% of the sum p + q + r.

 anionic groups of the carboxylic type, for example in the products described in patent EP 186 507 of the company Chisso Corporation, or of alkylcarboxylic type, such as those present in the product X-22-3701 E of the company Shin-Etsu; 2-hydroxyalkylsulfonate; 2-hydroxyalkylthiosulphate such as the products marketed by GOLDSCHMIDT under the names "ABIL S201" and "ABIL S255".

 hydroxyacylamino groups, such as the polyorganosiloxanes described in patent application EP 342 834. Mention may be made, for example, of the product Q2-8413 from Dow Corning.

According to the invention, it is also possible to use silicones comprising a polysiloxane portion and a portion consisting of a non-silicone organic chain, one of the two portions constituting the main chain of the polymer, the other being grafted onto the said main chain. . These polymers are for example described in patent applications EP-A-412 704, EP-A-412 707, EP-A-640 105 and WO 95/00578, EP-A-582 152 and WO 93/23009 and the US Patents 4,693,935, US 4,728,571 and US 4,972,037. These polymers are preferably anionic or nonionic.

Such polymers are, for example, the copolymers that can be obtained by radical polymerization from the monomer mixture consisting of: a) 50 to 90% by weight of tert-butyl acrylate; b) 0 to 40% by weight of acrylic acid; c) 5 to 40% by weight of silicone macromer of formula:

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 with v being a number from 5 to 700; the percentages by weight being calculated with respect to the total weight of the monomers.

Other examples of grafted silicone polymers are in particular polydimethylsiloxanes (PDMS) on which are grafted, via a thiopropylene type connection link, mixed polymeric units of the poly (meth) acrylic acid and poly type. alkyl (meth) acrylate and polydimethylsiloxanes (PDMS) on which are grafted, via a thiopropylene type connecting link, polymeric units of the poly (meth) acrylate isobutyl type.

According to the invention, all the silicones can also be used in the form of emulsions, nanoemulsions or microemulsions.

The polyorganosiloxanes that are particularly preferred according to the invention are: non-volatile silicones chosen from the family of polyalkylsiloxanes with trimethylsilyl end groups, such as oils having a viscosity of between 0.2 and 2.5 m 2 / s at 25 ° C., such as the oils of the DC200 series of DOW CORNING, in particular that of viscosity 60 000 Cst, the SILBIONE 70047 and 47 series and more particularly the 70 047 V 500 000 oil marketed by the company RHONE POULENC, the polyalkylsiloxanes with dimethylsilanol end groups, such as dimethiconol or polyalkylarylsiloxanes such as the oil SILBIONE 70641 V 200 sold by the company RHONE POULENC; the organopolysiloxane resin sold under the name Dow Corning 593; polysiloxanes containing amino groups, such as amodimethicones or trimethylsilylamodimethicone; According to the invention, the cationic polymer or polymers may represent from 0.001% to 20% by weight, preferably from 0.01% to 10% by weight and more particularly from 0.1% to 3% by weight relative to the total weight of the final composition.

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According to the invention, the additional silicone or silicones may represent from 0.001% to 20% by weight, preferably from 0.01% to 10% by weight and more particularly from 0.1% to 3% by weight relative to the total weight of the final composition.

The compositions of the invention advantageously also contain at least one surfactant which is generally present in an amount of between approximately 0.1% and 60% by weight, preferably between 3% and 40% and even more preferentially between 5%. and 30%, based on the total weight of the composition.

This surfactant may be chosen from anionic, amphoteric, nonionic or cationic surfactants or mixtures thereof.

The surfactants that are suitable for the implementation of the present invention are notably the following: (i) Anionic surfactant (s): Their nature is not, in the context of the present invention, of a truly critical nature.

Thus, by way of example of anionic surfactants which may be used, alone or as mixtures, in the context of the present invention, mention may be made in particular (nonlimiting list) of the salts (in particular alkaline salts, in particular sodium salts, ammonium salts, amine salts, aminoalcohol salts or magnesium salts) of the following compounds: alkyl sulphates, alkyl ether sulphates, alkyl amido ether sulphates, alkyl aryl polyether sulphates, monoglyceride sulphates; alkylsulfonates, alkylphosphates, alkylamidesulfonates, alkylarylsulfonates, α-olefin-sulfonates, paraffin-sulfonates; alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates; alkylsulfosuccinamates; alkylsulfoacetates; alkyl ether phosphates; acylsarcosinates; acylisethionates and N-acyltaurates, the alkyl or acyl radical of all these various compounds preferably containing from 8 to 24 carbon atoms, and the aryl radical preferably denoting a phenyl or benzyl group. Among the anionic surfactants that can still be used, mention may also be made of fatty acid salts such as the salts of oleic, ricinoleic, palmitic and stearic acids, coconut oil acid or hydrogenated coconut oil acid; acyl lactylates whose acyl radical has 8 to 20 carbon atoms. It is also possible to use weakly anionic surfactants, such as alkyl D galactoside uronic acids and their salts, as well as alkyl (Ce-C24) acids.

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 polyoxyalkylenated carboxylic ether, polyoxyalkylenated (C6-C24) aryl ether carboxylic acids, polyoxyalkylenated (C6-C24) alkyl carboxylic amido ether acids and their salts, in particular those containing from 2 to 50 ethylene oxide groups, and mixtures thereof .

Among the anionic surfactants, it is preferred to use, according to the invention, the alkyl sulphate and alkyl ether sulfate salts and their mixtures.

 (ii) Nonionic surfactant (s): Nonionic surfactants are also well-known compounds per se (see in particular in this connection "Handbook of Surfactants" by MR PORTER, Blackie & Son editions ( Glasgow and London), 1991, pp. 116-178) and their nature does not, in the context of the present invention, of a critical nature. Thus, they may be chosen in particular from (non-limiting list) alcohols, alpha-diols, alkylphenols or polyethoxylated, polypropoxylated or polyglycerolated fatty acids, having a fatty chain comprising for example 8 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups that can range from 2 to 50 and the number of glycerol groups that can range from 2 to 30. Mention may also be made of copolymers of ethylene oxide and propylene oxide, the condensates of ethylene oxide and propylene oxide on fatty alcohols; polyethoxylated fatty amides preferably having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups and in particular 1.5 to 4; polyethoxylated fatty amines preferably having 2 to 30 moles of ethylene oxide; oxyethylenated sorbitan fatty acid esters having from 2 to 30 moles of ethylene oxide; sucrose fatty acid esters, polyethylene glycol fatty acid esters, alkylpolyglycosides, N-alkylglucosamine derivatives, amine oxides such as (C10-C14) alkyl oxides or oxides N-acylaminopropylmorpholine. It will be noted that alkylpolyglycosides constitute nonionic surfactants that fall particularly well within the scope of the present invention.

 (iii) Amphoteric surfactant (s): The amphoteric surface-active agents, the nature of which does not take part in the context of the present invention of a critical nature, may especially be (non-limiting list) derivatives of secondary or tertiary amines aliphatic radicals, in which the aliphatic radical is a linear or branched chain containing 8 to 22 carbon atoms and

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 containing at least one water-soluble anionic group (for example carboxylate, sulphonate, sulphate, phosphate or phosphonate); mention may also be made of (C 8 -C 20) alkyl betaines, sulphobetaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkyl betaines or (C 8 -C 20) alkylamido (C 1 -C 6) alkyl sulfobetaines.

Among the amine derivatives, mention may be made of the products sold under the name MIRANOL, as described in US Pat. No. 2,528,378 and US Pat. No. 2,781,354, and of structures: ## STR2 ## (CH2COO-) (2) in which: R2 denotes an alkyl radical derived from a R2-COOH acid present in the hydrolysed coconut oil, a heptyl, nonyl or undecyl radical, R3 denotes a beta-hydroxyethyl group and R4 a carboxymethyl group; and R5-CONHCH2CH2-N (B) (C) (3) wherein: B represents -CH2CH2OX ', C represents - (CHz) z -Y', with z = 1 or 2, X 'denotes the group -CH2CH2- COOH or a hydrogen atom Y 'denotes -COOH or the radical -CH2-CHOH-S03H R5 denotes an alkyl radical of an R9 -COOH acid present in the coconut oil or in the hydrolysed linseed oil, a alkyl radical, especially R7, R9, C11 or C13, a C17 alkyl radical and its iso form, an unsaturated C17 radical.

These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names Disodium Cocoamphodiacetate, Disodium Lauroamphodiacetate, Disodium Caprylamphodiacetate, Disodium Capryloamphodiacetate, Disodium Cocoamphodipropionate, Disodium Lauroamphodipropionate, Disodium Caprylamphodipropionate, Disodium Capryloamphodipropionate, Lauroamphodipropionic Acid, Cocoamphodipropionic Acid.

By way of example, mention may be made of cocoamphodiacetate sold under the trade name MIRANOL C2M concentrated by the company RHONE POULENC.

 (iv) Cationic surfactant (s): The cationic surfactants may be chosen from: A) quaternary ammonium salts of the following general formula (IV):

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dans laquelle X est un anion choisi dans le groupe des halogénures (chlorure, bromure ou iodure) ou alkyl(C2-C6)sulfates plus particulièrement méthylsulfate, des phosphates, des alkyl-ou-alkylarylsulfonates, des anions dérivés d'acide organique tel que l'acétate ou le lactate.

wherein X is an anion selected from the group of halides (chloride, bromide or iodide) or (C2-C6) alkyl sulfates more particularly methylsulfate, phosphates, alkyl-or-alkylarylsulfonates, anions derived from organic acid such as acetate or lactate.

and i) the radicals R 1 to R 3, which may be identical or different, represent a linear or branched aliphatic radical containing from 1 to 4 carbon atoms, or an aromatic radical such as aryl or alkylaryl. The aliphatic radicals can comprise heteroatoms such as in particular oxygen, nitrogen, sulfur, halogens. The aliphatic radicals are, for example, chosen from alkyl, alkoxy and alkylamide radicals. R4 denotes a linear or branched alkyl radical containing from 16 to 30 carbon atoms.

Preferably, the cationic surfactant is a salt (for example chloride) of behenyltrimethylammonium. ii) the radicals R 1 and R 2, which may be identical or different, represent a linear or branched aliphatic radical containing from 1 to 4 carbon atoms, or an aromatic radical such as aryl or alkylaryl. The aliphatic radicals can comprise heteroatoms such as in particular oxygen, nitrogen, sulfur, halogens. The aliphatic radicals are, for example, chosen from alkyl, alkoxy, alkylamide and hydroxyalkyl radicals, comprising approximately from 1 to 4 carbon atoms; R3 and R4, which may be identical or different, denote a linear or branched alkyl radical containing from 12 to 30 carbon atoms, said radical comprising at least one ester or amide function.

R3 and R4 are in particular chosen from (C12-C22) alkyl radicals (C2-C6) alkyl amido, (C12-C22) alkyl acetate; Preferably, the cationic surfactant is a salt (for example chloride) of staramidopropyl dimethyl (methyl acrylate) ammonium.

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dans laquelle R5 représente un radical alcényle ou alkyle comportant de 8 à 30 atomes de carbone par exemple dérivés des acides gras du suif, R6 représente un atome d'hydrogène, un radical alkyle en C,-C4 ou un radical alcényle ou alkyle comportant de 8 à 30 atomes de carbone, R7 représente un radical alkyle en C1-C4, R6 représente un atome d'hydrogène, un radical alkyle en C1-C4, X est un anion choisi dans le groupe des halogénures, phosphates, acétates, lactates, alkylsulfates, alkyl-ou-alkylarylsulfonates. B) - quaternary ammonium salts of imidazolinium, such as for example that of formula (V) below:

in which R 5 represents an alkenyl or alkyl radical containing from 8 to 30 carbon atoms, for example derived from tallow fatty acids, R 6 represents a hydrogen atom, a C 1 -C 4 alkyl radical or an alkenyl or alkyl radical containing 8 to 30 carbon atoms, R7 represents a C1-C4 alkyl radical, R6 represents a hydrogen atom, a C1-C4 alkyl radical, X is an anion chosen from the group of halides, phosphates, acetates, lactates, alkylsulfates, alkyl-or-alkylarylsulfonates.

dans laquelle R9 désigne un radical aliphatique comportant environ de 16 à 30 atomes de carbone, R10, R11, R12, R13 et R14 , identiques ou différents sont choisis parmi l'hydrogène ou un radical alkyle comportant de 1 à 4 atomes de carbone, et X est un anion choisi dans le groupe des halogénures, acétates, phosphates, nitrates et méthylsulfates. De tels sels de diammonium quaternaire comprennent notamment le dichlorure de propanesuif diammonium. Preferably, R 5 and R 6 denote a mixture of alkenyl or alkyl radicals containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R 7 denotes methyl and R 6 denotes hydrogen. Such a product is for example Quaternium-27 (CTFA 1997) or Quaternium-83 (CTFA 1997) sold under the names "REWOQUAT" W 75, W90, W75PG, W75HPG by WITCO, C) - diammonium salts quaternary formula (VI):

in which R 9 denotes an aliphatic radical containing about 16 to 30 carbon atoms, R 10, R 11, R 12, R 13 and R 14, which are identical or different, are chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms, and X is an anion selected from the group of halides, acetates, phosphates, nitrates and methylsulfates. Such diammonium quaternary salts include in particular propane dichloride diammonium.

D) - quaternary ammonium salts containing at least one ester function of formula (VII) below:

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dans laquelle : - R15 est choisi parmi les radicaux alkyles en C1-C6 et les radicaux hydroxyalkyles ou dihydroxyalkyles en C-Cg ; - R16 est choisi parmi :

0 - le radical R9 C- - les radicaux R20 hydrocarbonés en C1-C22 linéaires ou ramifiés, saturés ou insaturés, - l'atome d'hydrogène, - R18 est choisi parmi :

0 il - le radical R2 C- - les radicaux R22 hydrocarbonés en C1-C6 linéaires ou ramifiés, saturés ou insaturés, - l'atome d'hydrogène, - R17, R19 et R21, identiques ou différents, sont choisis parmi les radicaux hydrocarbonés en C7-C21, linéaires ou ramifiés, saturés ou insaturés ; - n, p et r, identiques ou différents, sont des entiers valant de 2 à 6 ; - y est un entier valant de 1 à 10 ; - x et z, identiques ou différents, sont des entiers valant de 0 à 10 ; - X- est un anion simple ou complexe, organique ou inorganique ; sous réserve que la somme x + y + z vaut de 1 à 15 , que lorsque x vaut 0 alors R16 désigne R20 et que lorsque z vaut 0 alors R18 désigne R22.

in which: R 15 is chosen from C 1 -C 6 alkyl radicals and C 1 -C 6 hydroxyalkyl or dihydroxyalkyl radicals; - R16 is chosen from:

The radical R9 C- - the linear or branched, saturated or unsaturated C1-C22 hydrocarbon radicals R20, - the hydrogen atom, - R18 is chosen from:

C 1 -C 2 - the linear or branched, saturated or unsaturated C 1 -C 6 hydrocarbon radicals R 22, R 17, R 19 and R 21, which are identical or different, are chosen from hydrocarbon radicals; C7-C21, linear or branched, saturated or unsaturated; n, p and r, which may be identical or different, are integers ranging from 2 to 6; y is an integer from 1 to 10; x and z, identical or different, are integers ranging from 0 to 10; - X- is a simple or complex anion, organic or inorganic; with the proviso that the sum x + y + z is from 1 to 15, that when x is 0 then R16 is R20 and that when z is 0 then R18 is R22.

More particularly, the ammonium salts of formula (VII) in which: R15 denotes a methyl or ethyl radical, - x and y are equal to 1; z is 0 or 1;

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0 il - le radical Rie C- - les radicaux méthyle, éthyle ou hydrocarbonés en C14-C22 - l'atome d'hydrogène ; - R17, R19 et R21, identiques ou différents, sont choisis parmi les radicaux hydrocarbonés en C7-C21, linéaires ou ramifiés, saturés ou insaturés ; - R18 est choisi parmi :

0 Il -le radical R-C# - l'atome d'hydrogène ; De tels composés sont par exemple commercialisés sous les dénominations DEHYQUART par la société HENKEL, STEPANQUAT par la société STEPAN, NOXAMIUM par la société CECA, REWOQUAT WE 18 par la société REWO-WITCO. n, p and r are 2; - R16 is chosen from:

There is - the radical Rie C- - methyl, ethyl or C14-C22 hydrocarbon radicals - the hydrogen atom; - R17, R19 and R21, which are identical or different, are chosen from linear or branched, saturated or unsaturated C7-C21 hydrocarbon radicals; R18 is chosen from:

It is the radical RC # - the hydrogen atom; Such compounds are for example sold under the names DEHYQUART by Henkel, STEPANQUAT by STEPAN, NOXAMIUM by CECA, REWOQUAT WE 18 by REWO-WITCO.

Of the quaternary ammonium salts, behenyltrimethylammonium chloride is preferred, or stearamidopropyldimethyl (myristyl acetate) ammonium chloride sold under the name CERAPHYL 70 by the company VAN DYK, Quaternium-27 or Quaternium-83 marketed by the company WITCO company.

In the compositions according to the invention, use is preferably made of surfactant mixtures and in particular mixtures of anionic surfactants and mixtures of anionic surfactants and amphoteric or nonionic surfactants. A particularly preferred mixture is a mixture of at least one anionic surfactant and at least one amphoteric surfactant.

Preferably, an anionic surfactant chosen from sodium (C12-C14) alkyl sulphates, triethanolamine or ammonium alkyls, (C2-C14) alkyl ethersulfates of sodium, triethanolamine or ammonium oxyethylenated with 2,2 moles of ethylene oxide, sodium cocoyl isethionate and sodium (C14-C16) alpha-olefin sulfonate and mixtures thereof with:

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 or an amphoteric surfactant such as the amine derivatives known as disodiumcocoamphodipropionate or sodiumcocoamphopropionate marketed in particular by the company Rhone-Poulenc under the trade name "MIRANOL C2M CONC" in aqueous solution containing 38% active ingredient or under the name MIRANOL C32; or an amphoteric surfactant of zwitterionic type such as alkylbetaines, in particular cocobetaine sold under the name "Dehyton AB 30" in aqueous solution containing 32% of MA by Henkel.

The composition of the invention may also contain at least one additive chosen from thickeners, anti-dandruff or anti-seborrhoeic agents, perfumes, pearlescent agents, hydroxy acids, electrolytes, thickeners, fatty acid esters, preservatives, silicone or non-silicone sunscreens, vitamins, provitamins, anionic or nonionic polymers, proteins, protein hydrolysates, methyl-18 eicosanoic acid, hydroxy acids, panthenol, vegetable oils, animal oils, mineral or synthetic, fluorinated or perfluorinated oils, natural or synthetic waxes, ceramide-type compounds, cationic surfactants, fatty amines, fatty acids and their derivatives, fatty alcohols and their derivatives and mixtures thereof different compounds and any other additive conventionally used in the cosmetic field which does not affect the properties of the compositions according to the invention.

These additives are present in the composition according to the invention in proportions ranging from 0 to 20% by weight relative to the total weight of the composition. The precise amount of each additive is readily determined by those skilled in the art according to its nature and function.

The compositions in accordance with the invention may be used more particularly for washing or treating keratin materials such as the hair, the skin, the eyelashes, the eyebrows, the nails, the lips, the scalp and more particularly the hair.

In particular, the compositions according to the invention are detergent compositions such as shampoos, shower gels and bubble baths. In this mode of

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 embodiment of the invention, the compositions comprise a washing base, which is generally aqueous.

The surfactant or surfactants forming the washing base can be indifferently chosen, alone or in mixtures, from anionic, amphoteric and nonionic surfactants as defined above.

The quantity and the quality of the washing base are those sufficient to give the final composition a satisfactory foaming and / or detergent power.

Thus, according to the invention, the washing base can represent from 4% to 50% by weight, preferably from 6% to 35% by weight, and still more preferably from 8% to 25% by weight, of the total weight of the final composition.

The subject of the invention is also a process for treating keratin materials such as the skin or the hair, characterized in that it consists in applying to the keratin materials a cosmetic composition as defined above, then optionally performing a rinsing with the water.

Thus, this method according to the invention allows the maintenance of the hairstyle, the treatment, care or washing or removing make-up of the skin, hair or any other keratin material.

The compositions of the invention may also be in the form of after-shampoo to be rinsed or not, compositions for permanent, straightening, coloring or bleaching, or in the form of compositions to be rinsed, to be applied before or after a coloration, a discoloration , a perm or a straightening or between the two stages of a perm or straightening.

When the composition is in the form of an optionally rinsing conditioner, it advantageously contains at least one cationic surfactant, its concentration generally between 0.1 and 10% by weight and preferably from 0.5 to 5% by weight. weight relative to the total weight of the composition.

<Desc / Clms Page number 31>

The compositions of the invention may also be in the form of washing compositions for the skin, and in particular in the form of solutions or gels for bathing or showering or makeup removers.

The compositions according to the invention may also be in the form of aqueous or aqueous-alcoholic lotions for the care of the skin and / or the hair.

The cosmetic compositions according to the invention may be in the form of a gel, a milk, a cream, an emulsion, a thickened lotion or a mousse and may be used for the skin, the nails, the eyelashes, the lips and more particularly the hair.

The compositions may be packaged in various forms, in particular in vaporizers, pump bottles or in aerosol containers in order to ensure application of the composition in vaporized form or in foam form. Such forms of packaging are indicated, for example, when it is desired to obtain a spray, a lacquer or a mousse for the treatment of the hair.

In all that follows or the above, the percentages expressed are by weight.

The invention will now be more fully illustrated by the following examples which can not be considered as limiting the described embodiments.

In the examples, MA means active ingredient.

EXAMPLE 1 Two shampoo compositions, one in accordance with the invention (composition A) and the other comparative (compositions B), were produced:

<Tb>
<tb> Invention <SEP> Example
<tb> A <SEP> comparative <SEP> B
<tb> according to <SEP> EP <SEP> 282720
<tb> Lauryl ether sulfate <SEP> of <SEP> sodium <SEP> (C12 / C14 <SEP> to
<tb> 70/30) <SEP> to <SEP> 2. <SEP> 2 <SEP> moles <SEP> of oxide <SEP> of ethylene <SEP> to <SEP> 10. <SEP> 0 <SEP> g <SEP> MA <SEP> 10. <SEP> 0 <SEP> g <SEP> MA
<Tb>

70% AM
<Tb>

Claims (29)

<Tb> <Tb> <Tb> Cocoyl <SEP> amidopropyl <SEP> betaine <SEP> 2. <SEP> 0 <SEP> g <SEP> M.A. <SEP> 2. <SEP> 0 <SEP> g <SEP> M.A. <Tb> <tb> Preservatives <SEP> q.s. <SEP> q. <SEP> s. <tb> Chloride <SEP> of <SEP> sodium <SEP> 3. <SEP> 5 <SEP> g <SEP> 3. <SEP> 5 <SEP> g <tb> GOODRICH <SEP> 0. <SEP> 2 <SEP> g <SEP> 0. <SEP> 2 <SEP> g <tb> under <SEP> the <SEP> denomination <SEP> Carbopol <SEP> 980 <SEP> by <tb> <SEP> Polyacrylic acid <SEP> crosslinked <SEP> marketed <Tb> <tb> by <SEP> the <SEP> company <SEP> GOLDSCHMIDT <SEP> 3. <SEP> 0 <SEP> g <SEP> 3. <SEP> 0 <SEP> g <tb> sold <SEP> under <SEP> <SEP> name <SEP> Antil <SEP> 141 <SEP> Liquid <tb> propylene glycol <SEP> in <SEP> solution <SEP> hydroglycolic, <tb> Dioleate <SEP> of <SEP> Polyethylene Glycol <SEP> 55 <SEP> OE <SEP> and <SEP> from <tb> company <SEP> RHODIA <SEP> CHEMISTRY <SEP> 0. <SEP> 2 <SEP> g <tb> under <SEP> the <SEP> denomination <SEP> Jaguar <SEP> C13S <SEP> by <SEP> <tb> 2,3-epoxypropyl <SEP> trimethylammonium <SEP> sold <tb> Gum <SEP> of <SEP> modified <SEP> guar <SEP> by <SEP> of <SEP> chloride <SEP> of <tb> epoxide <SEP> / <SEP> diacetate <SEP> of <SEP> bis- (2dimethylaminoethyl) ether <SEP> 2. <SEP> 0 <SEP> g <SEP> 2. <SEP> 0 <SEP> g <tb> Block <SEP> polymer <SEP> polydimethylsiloxane <SEP> bis Propylene <SEP> Glycol <SEP> 4. <SEP> 0 <SEP> g <SEP> 4. <SEP> 0 <SEP> g  Shampooing is performed by applying about 12 g of composition A to previously wet hair. The shampoo is lathered and rinsed thoroughly with water. <Tb> Demineralized water <SEP> q. <SEP> s.p. <SEP> 100. <SEP> 0 <SEP> g <SEP> 100. <SEP> 0 <SEP> g The same procedure is carried out as above with the comparative composition B. A panel of experts evaluated the properties of wet hair. Comparative tests carried out on models with sensitized hair, have shown that the composition according to the invention provides, in 80% of cases, more lightness to wet hair than the reference composition. In addition, with the composition according to the invention, the wet hair disentangles more easily and the roots are more loose. <Desc / Clms Page number 33>  1. Cosmetic composition, characterized in that it comprises, in a cosmetically acceptable medium, at least one cationic polymer and at least one quaternary polyammonium silicone type (AB) n, A being a polysiloxane block and B being a block comprising at least two quaternary ammonium groups. 2- Composition according to Claim 1, characterized in that the said polyammonium quaternary silicone consists of repeating units of the following general formula:

 in which: R1, R2, R3, R4, which may be identical or different, represent a C1-C4 alkyl radical, preferably methyl. X and X ', which are identical or different, represent a divalent organic group which is bonded to the adjacent silicon atom by a carbon-silicon bond and to a nitrogen atom, and which comprises at least 4 carbon atoms and a hydroxyl group; - Y represents a divalent organic group comprising at least two carbon atoms, A- denotes an organic or inorganic anion, n is a number between 5 and 200, m is greater than or equal to 1 and preferably between 1 and 10. 3. Composition according to claim 2, characterized in that X and X ', which are identical or different, denote a C4-C12 hydrocarbon radical optionally comprising one or more heteroatoms such as oxygen. 4- Composition according to claim 3, characterized in that X and X ', identical or different, denote a linear or branched butylene radical, linear or branched hexylene, -CH2CH2CH20CH (OH) CH2-, -CH2CH2CH20 CH2CH (OH) CH2 -, -CH2CH2CH20 CH2CH (CH20H) -, -CH2CH (OH) CH2 OCH2CH2CH2- <Desc / Clms Page number 34>

 5. Composition according to claim 4, characterized in that X and X ', which are identical or different, are chosen from: -CH 2 CH 2 CH 2 O CH 2 CH (OH) CH 2 -, -CH 2 CH (OH) CH 2 OCH 2 CH 2 CH 2 -. 6. Composition according to any one of claims 2 to 5, characterized in that Y is a C2-C12 hydrocarbon radical optionally comprising one or more heteroatoms such as oxygen. 7- Composition according to any one of claims 2 to 6, characterized in that Y denotes an ethylene radical, linear or branched propylene, butylene linear or branched, linear or branched hexylene or -CH2CH2CH20CH (OH) CH2-, -CH2CH20CH2CH2 -, -CH2OCH2-, -CH2CH2N (CH3) CH2CH2-. 8- Composition according to the preceding claim, characterized in that Y is selected from the radicals -CH2CH2OCH2CH2- - (CH2) 6- and - (CH2) 3-. 9- Composition according to any one of claims 2 to 8, characterized in that A- denotes an anion bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, methosulfate, sulfate, phosphate. 10- Composition according to any one of claims 1 to 9, characterized in that the cationic polymers are chosen from those containing units having primary, secondary, tertiary and / or quaternary amine groups that can be part of the chain. main polymer, to be carried by a lateral substituent directly connected thereto. 11- Composition according to any one of the preceding claims, characterized in that said cationic polymer is chosen from: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of following formulas: <Desc / Clms Page number 35>  in which: R3, which may be identical or different, denote a hydrogen atom or a CH3 radical; A, which may be identical or different, represent a linear or branched alkyl group of 1 to 6 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; R4, R5, R6, which may be identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical; R1 and R2, which may be identical or different, represent hydrogen or an alkyl group having from 1 to 6 carbon atoms; X denotes an anion derived from a mineral or organic acid.

(2) cellulose ether derivatives containing quaternary ammonium groups, <Desc / Clms Page number 36>  (3) Cationic cellulose derivatives such as cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, (4) Cationic polysaccharides, (5) polymers consisting of piperazinyl units and divalent alkylene radicals or straight-chain or branched-chain hydroxyalkylene, optionally interrupted by oxygen, sulfur, nitrogen or aromatic or heterocyclic rings, as well as the oxidation and / or quaternization products of these polymers, (6) water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide or else with an oligomer resulting from the reaction of a bifunctional compound which is reactive with a bis-halohydrin, a bisazetidinium, a bis-haloacyldiamine, an alkyl bis-halide, a epilhalohydrin, a diepoxide or bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 moles per amine group of the polymaoamide; these polyaminoamides can be alkylated or if they contain one or more tertiary amine functional groups, quaternized. (7) polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents, (8) polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid selected from diglycolic acid and saturated aliphatic dicarboxylic acids having 3 to 8 carbon atoms, (9) cyclopolymers of alkyl diallyl amine or dialkyl diallyl ammonium (10) diammonium polymer quaternary containing repeating units corresponding to the formula: <Desc / Clms Page number 37> A1, R13 and R15 can form with the two nitrogen atoms to which they are attached a piperazine ring; furthermore, if A1 denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B1 may also denote a (CH2) n -CO-D-OC- (CH2) n- group in which D denotes: a) a residue of glycol of formula: -OZO-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulas: - (CH 2 -CH 2 -O) x -CH 2 -CH 2 - - [CH 2 -CH (CH 3 Where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; X- denotes an anion derived from a mineral or organic acid; A1 and B1 represent polymethylene groups containing from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and may contain, bound to or intercalated in the main chain, one or more aromatic rings, or one or more atoms oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and R13, R14, R15 and R16, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic radicals containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or R13, R14, R15 and R16, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen or R13, R14, R15 and R16 represent a linear or branched C1-C6 alkyl radical substituted with a nitrile group, ester, acyl, amide or -CO-O-R17-D or-CONH-R17-D wherein R17 is alkylene and D is a quaternary ammonium group;  formula (VII) in which:

<Desc / Clms Page number 38> Preferably, X- is an anion.  c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or alternatively the divalent radical -CH 2 -CH 2 -S-S-CH 2 -CH 2 -; d) a ureylene group of formula: -NH-CO-NH-; A denotes a radical of a dihalide or is preferably -CH2-CH2-OCH2-CH2-. X denotes a halogen atom, R18, R19, R20 and R21, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, hydroxyethyl or ss-hydroxypropyl radical or -CH2CH2 (OCH2CH2) pOH, where p is equal to 0 or an integer between 1 and 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent a hydrogen atom, r and s, which may be identical or different, are integers between 1 and 6, q is equal to 0 or to an integer between 1 and 34,  formula in which:

(11) quaternary polyammonium polymers consisting of units of formula (VIII): (12) The quaternary polymers of vinylpyrrolidone and of vinylimidazole, (13) The polyamines referenced under the name Polyethylene glycol (15) tallow polyamine in the CTFA dictionary. (14) Crosslinked polymers of methacryloyloxyalkyl (C1-C4) trialkyl (C1-C4) ammonium salts, <Desc / Clms Page number 39>  (15) polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives. 12- Composition according to the preceding claim, characterized in that said cationic polymer is selected from quaternary cellulose ether derivatives, cationic cyclopolymers, cationic polysaccharides, vinylpyrrolidone and vinylimidazole quaternary polymers and mixtures thereof. 13- Composition according to claim 12, characterized in that said cyclopolymer is chosen from homopolymers of diallyldimethylammonium chloride and copolymers of diallyldimethylammonium chloride and acrylamide. 14- Composition according to claim 12, characterized in that said quaternary cellulose ether derivatives are chosen from hydroxyethylcelluloses having reacted with an epoxide substituted with a trimethylammonium group. 15. Composition according to claim 12, characterized in that the said cationic polysaccharides are chosen from guar gums modified with a 2,3-epoxypropyltrimethylammonium salt. 16. Composition according to any one of claims 1 to 15, characterized in that it further comprises at least one silicone. 17- Composition according to claim 16, characterized in that the silicones are chosen from polyorganosiloxanes insoluble in the composition. 18- Composition according to any one of claims 16 and 17, characterized in that the silicones are non-volatile polyorganosiloxanes selected from polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, polyorganosiloxanes modified by groups organofunctional compounds and their mixtures. 19- Composition according to Claim 18, characterized in that: <Desc / Clms Page number 40>  (a) the polyalkylsiloxanes are chosen from: - polydimethylsiloxanes with trimethylsilyl end groups; polydimethylsiloxanes with dimethylsilanol end groups; polyalkyl (C1-C20) siloxanes; (b) the polyalkylarylsiloxanes are chosen from: - polydimethylmethylphenylsiloxanes, linear and / or branched polydimethyldiphenyl siloxanes with a viscosity of between 1.10-5 and 5.10-2m2 / s at 25 ° C; (c) the silicone gums are selected from polydiorganosiloxanes having number average molecular weights between 200,000 and 1,000,000 used alone or as a mixture in a solvent; (d) the resins are chosen from resins consisting of: R 3 Si 0112, R 2 Si O 2/2, R Si O 3/2, Si O 4/2 in which R represents a hydrocarbon group having from 1 to 16 carbon atoms; or a phenyl group (e) the organo-modified silicones are chosen from silicones comprising in their structure one or more organofunctional groups attached via a hydrocarbon radical. 20- Composition according to any one of claims 16 to 19, characterized in that the silicones are chosen from polyalkylsiloxanes trimethylsilyl end groups, polyalkylsiloxanes end groups dimethylsilanol, polyalkylarylsiloxanes, mixtures of two PDMS consisting of gum and an oil of different viscosities, mixtures of organosiloxanes and cyclic silicones, organopolysiloxane resins. 21- Composition according to any one of the preceding claims, characterized in that said polyammonium quaternary silicone is present at a concentration of between 0.01 and 20% by weight relative to the total weight of the composition, preferably between 0.1 and 15% by weight and even more particularly between 0.5 and 10% by weight. 22. Composition according to any one of the preceding claims, characterized in that the cationic polymer is present in a concentration of between 0.001% and 20% by weight relative to the total weight of the composition, preferably between 0.01% and 10% by weight. <Desc / Clms Page number 41> 23- Composition according to any one of claims 16 to 22, characterized in that said silicone is present at a concentration of between 0.001% and 20% by weight relative to the total weight of the composition, preferably between 0.01% and 10% by weight. 24. Composition according to any one of the preceding claims, characterized in that it further comprises at least one surfactant chosen from anionic, nonionic, amphoteric and cationic surfactants and mixtures thereof. 25- Composition according to Claim 24, characterized in that the surfactant (s) are present at a concentration of between 0.1% and 60% by weight, preferably between 3% and 40% by weight, and even more preferably between 5% and 30% by weight, relative to the total weight of the composition. 26- Composition according to any one of claims 1 to 25, characterized in that the composition contain at least one additive selected from thickeners, anti-dandruff or anti-seborrhoeic agents, perfumes, pearlescent agents, hydroxy acids, electrolytes , thickeners, fatty acid esters, preservatives, silicone or non-silicone sunscreens, vitamins, provitamines, anionic or nonionic polymers, proteins, protein hydrolysates, methyl-18 eicosanoic acid, hydroxyacids, panthenol, vegetable, animal, mineral or synthetic oils, fluorinated or perfluorinated oils, natural or synthetic waxes, ceramide-type compounds, fatty amines, fatty acids and their derivatives, fatty alcohols and their derivatives as well as mixtures of these different compounds. 27- Composition according to any one of the preceding claims, characterized in that it is in the form of shampoo, conditioner, composition for the permanent, straightening, coloring or bleaching of the hair, rinse composition to be applied between the two steps of a permanent or straightening, washing composition for the body. 28. Use of a composition as defined in any one of the preceding claims for washing or for the care of keratin materials. <Desc / Clms Page number 42> 29- Process for treating keratin materials, such as the hair, characterized in that it consists in applying to said materials a cosmetic composition according to one of claims 1 to 27, then optionally to perform a rinsing with water.