FR3004941A1 - COMPOSITION BASED ON HENNE OR INDIGO POWDER WITH OIL PRE-DISPERSION, HAIR COLORING METHOD USING THE SAME - Google Patents

Abstract

The subject of the invention is a composition for dyeing keratin fibers, comprising: i) at least 1%, preferably at least 5%, of red henna powder (Lawsonia inermis, alba) and / or plant powder (s) indigo (s), (ii) at least one oil, (iii) optionally at least one surfactant, and (iv) water or an aqueous phase, preferably water with the understanding that ingredients (ii), (iii) and (iv) ) are pre-dispersed together to form a pre-dispersion and then mixed the ingredient (s) i) in said predispersion or said pre-dispersion is mixed with (ux) ingredient (s) i); it also relates to a composition comprising said composition and a complement of water or aqueous phase, the method of dyeing keratinous fibers implementing said compositions, and the use of said compositions for dyeing keratinous fibers. The compositions and the poultice according to the invention make it possible to color the keratinous fibers with results of powerful coloring, chromatic, resistant to washes, perspiration, sebum and light and more durable without alteration of said fibers. In addition, the use of the compositions or the poultice does not release dust of raw materials ("dust-free"). These compositions are easy to use, safely and without risk of staining. In addition, the composition and the coloring active agent (s) remain storage stable. The treated keratin fibers have a very pleasant cosmetic, their integrity is respected.

Description

The invention relates to a composition for coloring keratinous fibers, comprising i) at least 1%. preferably at least 5%, red henna powder (Lawsonia inermis, alba) and / or indigo-producing plant powder (s), ii) at least one oil, iii) optionally at least one surfactant, and iv) water or an aqueous phase, preferably water, with the proviso that ingredients ii), iii) and iv) are pre-dispersed together and then mixing the ingredient (s) i) and said meadow. -dispersion ; it also relates to a composition comprising said composition and a complement of water or aqueous phase, the method of dyeing keratin fibers using said compositions, and the use of said compositions for dyeing keratinous fibers. Two major modes of staining human keratinous fibers, and in particular the hair, are known. The first, called oxidation or permanent staining, consists in using one or more oxidation dye precursors, more particularly one or more oxidation bases possibly associated with one or more couplers. Usually, oxidation bases are selected from ortho- or para-phenylenediamines, ortho- or para-aminophenols as well as heterocyclic compounds. These oxidation bases are colorless or weakly colored compounds which, combined with oxidizing products, make it possible to access, by a process of oxidative condensation, colored species which remain trapped inside the fiber. Very often, the shades obtained with these oxidation bases are varied by combining them with one or more couplers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols, meta-diphenols and certain heterocyclic compounds. such as indole compounds. The variety of molecules involved in the oxidation bases and couplers allows a rich palette of colors to be obtained. The second mode of staining, referred to as direct or semi-permanent staining, comprises the application of direct dyes which are colored and coloring molecules, having an affinity for the fibers. Given the nature of the molecules used, these remain rather on the surface of the fiber and penetrate relatively little inside the fiber, compared to the small molecules of precursors of oxidation dyes. The main advantages of this type of coloration is that it does not require an oxidizing agent which limits the degradation of the fibers and does not use dyes having a certain reactivity, thus limiting the risks of intolerance. The first hair dyes were semi-permanent. One of the best-known natural dyes is that derived from the henna plant. Henna continues to be used to beautify women by coloring hair, nails, or to color leather, silk and wool, etc. It is also used traditionally for important events, celebrations and various beliefs. The red henna is made up of shrub leaves of the genus Lawsonia from the Lythraceae family which is based on the principle of Lawsone active staining: 2-hydroxy-1,4-naphthoquinone. The lawsone [83-72-7] (Cl Natural Orange 6; Cl 75420) also known as isojuglone, can be found in Henna shrubs (Lawsonia alba, Lawsonia inermis) ("Dyes, Naturel", Kirk- Othmer Encyclopedia of Chemical Technology, "Henna" Encyclopedia Brittanica). This dye provides a red-orange color with white hair, and a "warm" color that is to say, coppered red with brown hair. The coloring process from henna is complicated to implement. It is first made a kind of "dough", often called "poultice", from mash or powder of henna leaves that is then diluted at the time of use with hot water and said paste is then applied to the keratinous fibers.

However, this process from said paste has drawbacks. During the preparation and application of the composition on the keratin fibers, it is not possible to always obtain a satisfactory impregnation because of the poor consistency of the composition obtained from the coarsely ground powder. In addition, it is very difficult to hope to reproduce exactly the colors because the Lawsone content very often varies from one batch to another, and different shreds. Another well-known natural dye is indigo (see Ullmann's Encyclopedia of Industrial Chemistry, "hair preparation", section 5.2.3, 2006 VViley-VCH Verlag GmbH & Co.KGA, VVeinheim, 10.1002 / 14356007.a12 571.pub2). . Indigo continues to be used to beautify women by coloring hair, nails, or to color leather, silk and wool fabrics, etc. Indigo [482-89-3] is a natural dye, especially from the indigo plant of the empirical formula: C16H10N2O2; it has the following structure: - -H The Indigo is derived from the indican can be prepared from different plants called indigofera such as indigo tinctoria, Indigo suffraticosa, Isatis tinctoria etc (see KirkOthmer Encyclopedia of Chemical Technology, updated to 17/04/2009, D01: 10.1002 / 0471238961.0425051903150618.a01.pub2). Indigestible plants are usually cut and soaked in hot, heated, fermented and air-oxidized water to release the purple-blue indigo (see Rev. 2011, 111, 2537-2561). 2537-2561). Indigo is the result of fermentation and oxidation of indican (glycosylated precursor). Indigo as a molecule is insoluble in water.

The problem is that staining from indigo leaf is difficult because the rise in color in the keratin fibers is very low. This dye gives a blue color to white hair, and a "cold" color of ash-gray to brown-haired type. The dyeing process from the indigo leaves is complicated to implement. It is first made a kind of "dough" (often called poultice) from crushed stone or indigo leaf powder (indigo indigo or indigo dyers) or pastel dyers (or wadi or Isatis tinctoria ) that it must be fermented, that is then diluted at the time of use with hot water and said paste is then applied to the keratinous fibers. However, this process from said paste has drawbacks. During the preparation and application of the composition on the keratin fibers, it is not possible to always obtain a satisfactory impregnation because of the poor consistency of the composition obtained from the coarsely ground powder. In addition, it is very difficult to hope to reproduce exactly the colors because the indigo content varies very often from one batch to another, and different crushed.

As much as the color obtained on brown hair has a natural effect, as much the white hair is colored in an orange color with henna or blue with indigo, unsightly and unnatural ("Hair preparations", Kirk-Othmer Encyclopedia of Chemical Technology , John VViley & Sons, Inc.). In addition, the colorations obtained are not homogeneous between the root and the tip or from one fiber to another (The Science of Hair Care, C. Bouillon, J. V Volkinson, Ed. 2d, CRC Press, Taylor & Francis Group Boca Raton, London, pp. 236-241 (2005)). Added to this is the risk of tachage clothing and skin with henna or indigo during the preparation of the "dough" and also during the application thereof on keratinous fibers, the consistency being very irregular. In addition, the break time is long with henna or indigo. It can vary from several tens of minutes to several hours (one night) depending on the desired intensity, without being able to master the result. The result varies according to the fibers to be colored and the raw material of indigo or henna used.

It is known to use metal salts as a mordant for improving henna coloring (Ullmann's Encyclopedia, 2006 VViley-VCH Verlag GmbH & Co. KGaA, V Veinheim 10.1002 / 14356007.a12 571.pub2 and US 2010/03133362). It is also known to use metal salts to improve the coloration of indigo (Vat Dyes - see Chem Rev. 2011, 111, 2537-2561, pp. 2537-2561). The use of these requires a great deal of know-how, multiplies the steps of the process, does not always respect the integrity of the fiber (cosmetic not respected) and can disrupt subsequent cosmetic treatments. Another solution is to use dye powder, optionally in the presence of excipients in the form of a fine powder (DE 195 48 291). Generally these powders are packaged in sachet or blister (DE 101 31 385). If it happens that the packaging of said powder is no longer hermetic, a large part of raw material is lost in the air and can not be recovered. In addition to the problem of loss of raw material, is added that related to the fineness of the particles for users or users. Indeed, suspended particles in the atmosphere can cause respiratory problems or rhinitis-type allergies, for users, sellers of extracts or natural color professionals (Allergy, J. Scibilia, E. Galdi, G. Biscaldi G. Moscato, 52, 231-232, (1997)). Another solution for improving the coloration from these natural dyes is to use leaf powder, for example finely ground henna, optionally in the presence of excipients in powder form (DE 299 02 432). Generally these powders are packaged in sachet or blister. If it happens that the conditioning of the dye powder is no longer hermetic, a large part of raw material is lost in the air and can not be recovered. In addition to the problem of loss of raw material, is added that related to the powder for users or users as indicated above. Indeed in the form of fine particles, henna or indigo is suspended in the atmosphere and can cause respiratory problems or rhinitis-type allergies, for users, sellers of extracts or natural color professionals (Allergy , J. Scibilia, E. Galdi, G. Biscaldi, G. Moscato, 52, 231-232, (1997)).

To remedy the problem of low dyeing efficiency of natural dyes, it is known to "dope" the coloring by adding direct dyes generally used in direct dyeing such as nitrobenzene, anthraquinone, nitropyridine, azo, methine, azomethine, xanthene acridinic, azine or triarylmethane (DE 199 05 707, EP 0 806 199, JP 2010-0001278). This option has the disadvantage for users of natural products, or supporters of "natural / organic", that the color is partly made from synthetic dyes. International Patent Application (VVO 97/39724) discloses compositions for treating hair, in solid form, and compounds whose viscosity does not exceed 500 mPas. The proposed compositions do not make it possible to obtain rapid or satisfactory colorations. Moreover, the solid compositions do not always break easily in water. In addition the poultices from the compositions of the prior art are not always creamy and / or easy to apply. There is therefore a real need to develop coloring processes that make it possible to obtain powerful colorations from henna and / or indigo, while respecting the cosmetics of keratin fibers. In particular, there is a need to provide a henna and / or indigo coloring product which does not have the drawbacks mentioned above, especially a non-dusting product ("dust-free") which is easy to remove. store, easily miscible (rapid disintegration) in water, and which allows in particular to obtain colorings less aggressive to the hair and at the same time resistant to external agents (light, bad weather, shampoo), which are stubborn and homogeneous while remaining powerful and chromatic. This object is achieved by the present invention which relates to a composition comprising: i) at least 1% by weight, preferably at least 5% of red henna powder and / or indigestible plant (s), by relative to the total weight of the composition; ii) at least one oil, preferably of plant origin; iii) optionally at least one surfactant, preferably nonionic and / or anionic surfactant; and iv) water or an aqueous phase, preferably water; it being understood that ingredients ii), iii) and iv) are pre-dispersed together to form a pre-dispersion, and then the ingredient (s) i) is (are) dispersed in said pre-dispersion or said pre-dispersion is dispersed in the said ingredient (s) i). Preferably the pre-dispersion comprising ingredients ii), iii) and iv) is a water-in-oil emulsion. More particularly, the pre-dispersion is a microemulsion or even a nanoemulsion, preferably of water-in-oil type. According to a particular embodiment of the invention, the above composition is a ready-to-use composition, that is to say that can be used as such at the time of use, without the need for addition of d complementary water. It can be advantageously in the form of poultice. The composition of the invention may according to a particular embodiment, be used later, possibly after storage with or without subsequent addition of water.

The invention also relates to a process for preparing the preceding composition consisting in carrying out a pre-dispersion comprising ingredients ii), iii) and iv) of the composition and then mixing the ingredient (s) i) with said pre-dispersion . The subject of the invention is also a method for dyeing keratinous fibers, in particular hair, using the composition as defined above. The compositions and the process using the composition according to the invention have the advantage of coloring the keratinous fibers, especially human fibers, with results of powerful, chromatic, wash-resistant, transpiration, sebum and light-colored stains. more durable without altering said fibers. In addition, the colorations obtained from the composition and the process give homogeneous colors from the root to the tip of a fiber (low color selectivity). In addition, the application of the composition does not release dust from raw materials ("dustfree"). The composition is easy to use, safe and without risk of staining. In addition, the composition and the active ingredient (natural dyes Henné and / or Indigo) remain storage stable. The treated keratin fibers have a very pleasant cosmetic, their integrity is respected. In addition, the composition or the poultice resulting from the composition as defined hereinafter of the invention is particularly creamy, and / or has excellent adhesion to the hair.

Unless otherwise indicated in the invention, "at least ..." is understood to be "one or more ..."; the ranges of values of the invention include inclusively the terminals indicated in said ranges. i) Powdered red henna and / or indigo According to a particular embodiment of the invention, the composition comprises as first ingredient i) red henna in powder form, preferably in fine particles. The henna powder can be sieved to obtain upper size particle sizes corresponding to the sieve mesh orifices or mesh sizes especially between 35 and 80 mesh (US). According to one particular embodiment of the invention, the particle size of the henna powder is fine. According to the invention, is more particularly meant a particle size of less than or equal to 500 lm. Preferably, the powder consists of fine particles of size 20 inclusive of between 50 and 300 μm and more particularly between 10 and 200 μm. It is understood that said henna particles preferentially have a moisture content of between 0 and 10% by weight, relative to the total weight of the powders. Where appropriate, the composition according to the invention comprises red henna powder in an amount ranging from 1 to 85% by weight, relative to the total weight of the composition, more particularly ranging from 5 to 80% by weight, more particularly from 10 to 75% relative to the total weight of the composition. In case of additional addition of water, the final composition comprises red henna powder in an amount ranging from 1 to 80% by weight, relative to the total weight of the composition, more particularly ranging from 1 to 75% by weight. preferably from 2 to 70% by weight, preferably from 10 to 70% by weight relative to the total weight of the final composition. According to another particular embodiment of the invention, the composition comprises as first ingredient i) indigestible plant powder (s), preferably in fine particles. As indigo plant we can cite many species of the genera: - Indigo will make such as Indigo will make tinctoria, Indigo suffraticosa, Indigo will articulata Indigo will affecta, Indigo will make gerardiana, Indigo will make argenta, Indigo will make indica, Indigo will make longiracemosa; 40 - Isatis such as Isatis tinctoria; - Polygonum or Persicaria such as Polygonum tinctorium (Persicaria tinctoria); Wrightia such as Wrightia tinctoria; - Calanthus such as Calanthe veratrifolia; and - Baphicacanthus such as Baphicacanthus cusia.

Preferably the indigo plant is of the kind Indigo will do and more particularly is Indigo will make tinctoria. One can use all or part (especially the leaves especially for Indigo will make tinctoria) of the indigo plant.

The indigestible plant powder can be sieved to obtain particles of upper limit sizes corresponding to the orifices or mesh sizes of the sieve particularly between 35 and 80 mesh (US). According to a particular embodiment of the invention, the particle size of the indigestible plant powder. is fine. According to the invention, is more particularly meant a particle size of less than or equal to 500 lm. Preferably, the powder consists of fine particles having a size of between 50 and 300 μm and more particularly between 10 and 200. It is understood that said particles of indigestible plant (s) preferably have a moisture content of between 0 and 10 μm. % by weight, based on the total weight of the powders. Where appropriate, the composition according to the invention comprises indigestible plant powder (s) in an amount ranging from 1 to 85% by weight, relative to the total weight of the composition, more particularly ranging from 5 to 80% by weight, preferably ranging from 10 to 75% by weight relative to the total weight of the composition. In case of additional addition of water, the final composition comprises indigestible plant powder (s) in an amount ranging from 1 to 80% by weight, relative to the total weight of the composition, more particularly from 1 to 75% by weight, preferably ranging from 2 to 70% by weight, better still from 10 to 70% by weight relative to the total weight of the final composition. According to another advantageous embodiment of the invention, the composition comprises as first ingredient i) a mixture of red henna powder as defined above and indigestible plant powder (s), preferably in fine particles such as previously defined. Where appropriate, the composition according to the invention comprises the mixture of powders in an amount ranging from 1 to 85% by weight, relative to the total weight of the composition, more particularly ranging from 5 to 80% by weight, preferably ranging from 10 to 75% by weight relative to the total weight of the composition.

In the case of additional addition of water, the final composition comprises the mixture of powders in an amount ranging from 1% to 80% by weight, relative to the total weight of the composition, more particularly ranging from 1% to 75% by weight. preferably from 2 to 7 by weight, better still from 10 to 70% by weight relative to the total weight of the final composition.

Pre-dispersion, emulsion, microemulsion and nanoemulsion The pre-dispersion of the invention uses the ingredients ii) and iv), and optionally iii), as defined below, which are thus pre-dispersed. The term "predispersed" means that the ingredients ii), iv) and optionally iii) are mixed with iv) the water or the aqueous phase of the composition of the invention so as to obtain a "dispersion", preferably stable at at room temperature and at atmospheric pressure, before being mixed with ingredient i), and any residue of water, said pre-dispersion may contain optional ingredients as described below. When the pre-dispersion comprises at least one surfactant, it will be referred to as a pre-emulsion.

By "dispersed" in the sense of the present invention is meant that the solid ingredient (such as ingredient i)) is distributed in the mixture of ingredients ii), iv) and optionally iii) without being solubilized.

For the purposes of the invention, the term "emulsion" means the mixing of a liquid (such as the oils: ingredient ii) with another immiscible liquid (such as water: ingredient iv) or an aqueous phase). preferably in the presence of an emulsifier (such as surfactants, ingredient iii)), one of which is finely distributed in the other as a droplet (see "Emulsions", Kirk-Othmer Encyclopedia of Chemical Technology, Edward Kostansek, published Online on 13/07/2012, D01: 10.1002 / 0471238961.0513211206180902.a01.pub3). The average size of the droplets of the emulsion according to the invention is preferably between 10 nm and 100 μm and preferably between 20 nm and 50 μm. This is the average diameter D (3.2) measurable, in particular using a laser granulometer. When the size of the emulsion droplets is less than or equal to 200 nm, we will speak of nanoemulsions or microemulsions, the former being thermodynamically unstable and the second being thermodynamically stable. The emulsion can be direct ie of oil-in-water type (Oil in VVater or 0 / VV), the emulsion is then in the form of an aqueous continuous phase (or external phase) in which a discontinuous fatty phase is distributed. (or internal phase: oil + possibly solid fatty substances). According to another preferred embodiment of the invention, the emulsion is of average size greater than 200 nm. and is reversed ie of water-in-oil type (VVater in Oil or VV / O), the emulsion is then in the form of a continuous fatty phase (or external phase: oil + possibly solid fatty substances) in which is distributed a discontinuous aqueous phase (or internal phase). The emulsion of the invention is prepared by conventional methods of preparing emulsions and dispersions, well known to those skilled in the art (see for example see "Emulsions", Kirk-Othmer Encyclopedia of Chemical Technology, Edward Kostansek, published online on 13/07/2012, D01: 10.1002 / 0471238961.0513211206180902.a01.pub3, bullet 3 "Preparation"). Microemulsions can be obtained simply by mixing hot and cold water, oils and surfactants from the moment when one is in the right zone of the phase diagrams; Nanoemulsions are obtained by conventional methods known to those skilled in the art (see for example J. Phys .: Condens Matter, "Nanoemulsions: formation, structure, and physical properties", TG Mason et al., 18, 635-666 ( 2006)).

The nanoemulsions can be obtained by placing themselves in the appropriate zones of the phase diagrams and using powerful stirring devices such as high pressure homogenizers. It can also be achieved by phase inversion techniques well known to those skilled in the art.

Preferably, the pre-emulsion according to the invention is a pre-emulsion of water or of aqueous phase in the VV / O type i.e. According to a particular embodiment, the pre-dispersion of the invention is free of any surfactant. By surfactant-free is meant in the sense of the present invention, free of any nonpolymeric compound having a H LB greater than or equal to 1.

According to another advantageous embodiment of the invention, the pre-dispersion comprises at least one surfactant, i.e. ingredient iii) as defined above. We then speak of pre-emulsion as indicated above. According to another variant, the pre-dispersion comprises at least one stabilizing polymeric compound, preferably sylated, such as those based on polydimethylsiloxane PDMS, and / or SMDI and polyalkylene glycol, in particular polyethylene glycol and polypropylene glycol. This or these polymeric stabilizing compounds may represent from 0.1 to 20% by weight, preferably from 0.5 to 15% by weight, better still from 1 to 10% by weight relative to the total weight of said pre-dispersion. Preferably, the ready-to-use composition applied to the keratinous fibers is not a compact solid. the oil or oils The composition of the invention, the final composition in the case of additional water addition, the pre-dispersion comprise one or more oils, preferably of plant origin. By "oil" is meant a "fat" which is liquid at room temperature (25 ° C), and at atmospheric pressure (760 mm Hg). The viscosity at 25 ° C. is preferably less than 1200 cps better than less than 500 cps (defined for example from the Newtonian plateau determined using a TA Instruments ARG2 rheometer equipped with a mobile phone of plane geometrical geometry. a diameter of 60 mm and an angle of 2 degrees over a range of shear stress ranging from 0.1 Pa to 100 Pa. By "fatty substance" is meant an organic compound that is insoluble in water at a temperature of standard (25 ° C.) and at atmospheric pressure (760 mmHg) (solubility less than 5% and preferably 1%, even more preferentially 0.1%). They have in their structure at least one hydrocarbon chain containing at least 6 carbon atoms or a chain of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same conditions of temperature and pressure, such as, for example, chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran ( THF), petrolatum oil or decamethylcyclopentasiloxane. More particularly, the oils are chosen from non-silicone oils and in particular hydrocarbons and C6-C16 or more than 16 carbon atoms and in particular alkanes; oils of animal origin; triglyceride oils of vegetable origin; essential oils ; glycerides or fluorinated oils of synthetic origin, fatty alcohols; fatty acid esters and / or fatty alcohol different from triglycerides, and silicone oils. Preferably, the oils do not comprise oxyalkylenated unit 02-03 or glycerolated unit.

Preferably, the oils are not fatty acids which in salified form give water-soluble soaps. The oils that can be used as the second ingredient ii) in the composition according to the invention can be silicones.

The silicones may be volatile or non-volatile, cyclic, linear or branched, modified or otherwise with organic groups, having a viscosity of 5 × 10 -6 to 2.5 m 2 / s at 25 ° C. and preferably 1 × 10 -5 to 1 m 2 / s. Preferably, the silicone is chosen from polydialkylsiloxanes, in particular polydimethylsiloxanes (PDMS), and organomodified polysiloxanes comprising at least one functional group chosen from poly (oxyalkylene) groups, amino groups and alkoxy groups. Organopolysiloxanes are further defined in Walter Noll's "Chemistry and Technology of Silicones" (1968), Academie Press. They can be volatile or nonvolatile.

When they are volatile, the silicones are more particularly chosen from those having a boiling point of between 60 ° C. and 260 ° C., and even more particularly from: (i) cyclic polydialkylsiloxanes containing from 3 to 7, preferably from 4 to 5 silicon atoms. It is, for example, octamethylcyclotetrasiloxane sold in particular under the name VOLATILE SILICONE® 7207 by UNION CARBIDE or SILBIONE® 70045 V2 by RHODIA, decamethylcyclopentasiloxane marketed under the name VOLATILE SILICONE® 7158 by UNION CARBIDE, and SILBIONE ® 70045 V5 by RHODIA, as well as their mixtures. Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as the VOLATILE® SILICONE FZ 3109 marketed by UNION CARBIDE, of formula: ## STR2 ## with D "- Si - Si - - II CH3 C8H17 with D ': Cyclic polydialkylsiloxane mixtures can also be mentioned with organic compounds derived from silicon, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1 '- (hexa-2,2,2', 2 ', 3,3'-trimethylsilyloxy) bis-neopentane (ii) linear volatile polydialkylsiloxanes having 2 to 9 silicon atoms and having a viscosity less than or equal to 5.10-6 m 2 / s at 25 ° C. It is, for example, decamethyltetrasiloxane marketed in particular under the name "SH 200" by Toray Silicone, silicones falling into this class are also described inthe article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, p. 27-32 - TODD & BYERS "Volatile Silicone fluids for cosmetics". Non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above organofunctional groups and mixtures thereof are preferably used. These silicones are more particularly chosen from polydialkylsiloxanes, among which may be mentioned mainly polydimethylsiloxanes with trimethylsilyl end groups. The viscosity of the silicones is measured at 25 ° C. according to the ASTM 445 Appendix C standard. Among these polydialkylsiloxanes, mention may be made, without limitation, of the following commercial products: SILBIONE® oils of the 47 and 70 047 series or the MIRASIL® oils marketed by RHODIA, such as, for example, 70 047 V 500 000; the oils of the MIRASIL® series marketed by RHODIA; the oils of the 200 series of Dow Corning, such as DC200 having a viscosity of 60,000 mm 2 / s; - VISCASIL® oils from GENERAL ELECTRIC and some oils from SF series (SF 96, SF 18) from GENERAL ELECTRIC. Mention may also be made of polydimethylsiloxanes with dimethylsilanol end groups known under the name of dimethiconol (CTFA), such as the oils of the 48 series from the company RHODIA. The alcohols, fatty acids and amides and fatty acid esters which can be used as the second ingredient ii) in the composition according to the invention are in the form of oils. It is recalled that within the meaning of the invention, the alcohols, amides, fatty acid esters, and fatty acids, liquids (oils) more particularly have at least one hydrocarbon group, linear or branched, saturated or unsaturated comprising 6 to 30 carbon atoms, optionally substituted, in particular with one or more hydroxyl groups (in particular 1 to 4). If unsaturated, these compounds may comprise one to three carbon-carbon double bonds, conjugated or otherwise. More specifically, ingredient ii) can represent a C 1 -C 10 alcohol ester and a fatty acid at 06-030 such that RC (O) -O-R 'with R representing a C 6 -C 30 alkyl group, linear or branched chain, linear or branched C 6 -C 30 alkenyl, comprising one or two unsaturations, and R representing a linear or branched C 1 -C 6 alkyl group. Preferentially, R represents a linear C10-C20 alkyl group and R 'represents a preferably branched C1-C6 alkyl group such as isopropyl myristate. According to another advantageous variant, ingredient ii) represents one or more 06-030 fatty acid amides and C 1 -C 10 primary or secondary amine, preferably primary amine, such as those of formula R "- C (O) -N (Ra) -R- with R "representing a linear or branched C 6 -C 30 alkyl group, linear or branched C 6 -C 30 alkenyl, comprising one or two unsaturations, which may be substituted by one or several hydroxy groups, or (di) (01-06) (alkyl) amino, and R "represents a linear or branched C1-C10 alkyl group, Ra represents a hydrogen atom or an alkyl group as defined for R ". Preferably R "represents an alkenyl group at 014-020, Ra represents a hydrogen atom and R" represents a C 1-6 alkyl group optionally substituted with (di) (C 1 -C 4) (alkyl) amino, such as oleyl amidopropyl dimethyl amine. As for the alkanes at 06-016, the latter are linear, branched, possibly cyclic. By way of example, mention may be made of hexane, dodecane and isoparaffins, such as isohexadecane and isodecane. The linear or branched hydrocarbons having more than 16 carbon atoms may be chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, polydecenes and hydrogenated polyisobutene such as Parleam®. Among the animal oils there may be mentioned perhydrosqualene. Among triglycerides of plant or synthetic origin, mention may be made of liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, for instance triglycerides of heptanoic or octanoic acids or else, for example, sunflower, corn, soya, squash, grape seed, sesame, hazelnut, apricot, macadamia, arara, sunflower, castor oil, avocado, caprylic / capric acid triglycerides as sold by the company Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil, shea butter oil. Among the fluorinated oils that may be mentioned perfluoromethylcyclopentane and perfluoro1,3 dimethylcyclohexane, sold under the names "FLUTEC® PC1" and "FLUTEC® P03" by BNFL Fluorochemicals; perfluoro-1,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names "PF 5050®" and "PF 5060®" by the company 3M, or the bromoperfluorooctyl sold under the name "Foralkyl" by the company Atochem; nonafluoro-methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives, such as 4-trifluoromethyl perfluoromorpholine sold under the name "PF 5052®" by the company 3M. Among the essential oils contained in the composition of the invention, or may include those mentioned in Ullmann's Encyclopedia of Industrial Chemistry ("Flavors and Fragrances", Karl-Georg Fahlbusch et al., Published Online: JAN 15, 2003, D01: 10.1002 / 14356007.a11_141). According to a preferred embodiment, the ingredient (s) ii) is (are) different (s) essential oils. According to a preferred variant of the invention, the one or more oils are chosen from 06-016 alkanes, polydecenes, liquid esters of fatty acids and / or fatty alcohol, liquid fatty alcohols or mixtures thereof. Better still, the fatty substance is chosen from petrolatum oil and alkanes at 06-016, polydecenes. In this variant preferably, the oil or oils are chosen from mineral oils such as petroleum jelly.

According to another particularly advantageous embodiment of the invention, the ingredient ii) the oils are chosen from oils of natural origin and particularly of plant origin such as jojoba, babassu, sunflower, olive, coconut, brazil nuts, marula, maize, argan, soya, squash, grape seed, flax, sesame, hazelnut, apricot, macadamia, arara , coriander, castor oil, avocado, shea butter oil and rapeseed oil. Preferably, the oil or oils, ingredient ii) of the invention are chosen from sunflower or avocado oil, sesame oil and jojoba oil, and more preferably are chosen from avocado and sunflower oils. According to a preferred embodiment of the invention, the oils of plant origin above are in admixture with one or more esters of alcohol Ci-Cio and fatty acid 06-030 such that R-O (0) - 0-R 'with R representing a linear or branched C 6 -C 30 alkyl group, linear or branched C 6 -C 30 alkenyl, comprising one or two unsaturations, and R representing a linear or branched C 1 -C 6 alkyl group, preferably, R represents a linear C10-C20 alkyl group and R 'represents a preferably branched C1-C6 alkyl group, such as isopropyl myristate.

According to another preferred embodiment of the invention, the oils of vegetable origin above are in admixture with one or more fatty acid amides of 0-6 0 0 0 and primary or secondary amines of I-0, preferably of primary amine, such as those of formula R "-C (O) -N (Ra) -R- with R" representing a linear or branched C 6 -C 30 alkyl group, linear or branched C 6 -C 30 alkenyl, comprising one or two unsaturations, which may be substituted by one or more hydroxyl groups, or (di) (01-06) (alkyl) amino, and R "represents a linear or branched C1-C10 alkyl group, Ra represents an atom of hydrogen or an alkyl group as defined for R-. Preferably R "represents a C14-C20 alkenyl group, R a represents a hydrogen atom and R- represents a C1-C6 alkyl group optionally substituted with (di) (C1-C4) (alkyl) amino such as oleylamidopropyl dimethylamine. Preferably, the oil or oils of the invention are non-silicone. The term "non-silicone oil" means an oil containing no silicon atom (Si) and a "silicone oil" an oil containing at least one silicon atom.

Preferably, the pre-dispersion of the invention before addition of the ingredient (s) i) comprises from 30 to 90% by weight of one or more oils, preferably 40 to 75% by weight relative to the total weight of said meadow. -dispersion. The composition according to the invention comprises from 10 to 85% by weight of one or more oils, preferably from 15 to 80% by weight, better still from 20 to 75% by weight relative to the total weight of said composition. In case of additional addition of water the composition comprises from 10 to 60% by weight of one or more oils, preferably from 15 to 50% by weight, better still from 20 to 40% by weight relative to the total weight of said final composition.

Fatty substance different from oils: butters, waxes or resins According to one particular embodiment of the invention, the composition of the invention, the final composition in the case of additional water addition, the pre-dispersion comprise in addition one or more different fatty substances of the oil or ii) as defined above.

According to a particular embodiment of the invention, the composition comprises as one or more butters, preferably of vegetable origin. For the purposes of the present invention, the term "butter" (also referred to as "pasty fatty substance") is understood to mean a lipophilic fatty compound with a reversible solid / liquid state change and comprising at the temperature of 25 ° C. a liquid fraction and a fraction. solid, and at atmospheric pressure (760 mm Hg). In other words, the starting melting temperature of the pasty compound may be less than 25 ° C. The liquid fraction of the pasty compound measured at 25 ° C. can represent 9 to 97% by weight of the compound. This liquid fraction at 25 ° C is preferably between 15 and 85%, more preferably between 40 and 85% by weight. Preferably, the one or more butters have an end-of-melting temperature of less than 60 ° C. Preferably, the one or more butters have a hardness less than or equal to 6 MPa.

Preferably, the pasty fatty substances have in the solid state an anisotropic crystalline organization, visible by X-ray observations. For the purposes of the invention, the melting temperature corresponds to the temperature of the most endothermic peak observed in thermal analysis ( DSC) as described in ISO 11357-3; 1999. The melting point of a paste or a wax can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name "DSC Q2000" by the company TA Instruments . As regards the measurement of the melting temperature and the determination of the end-of-melting temperature, the sample preparation and measurement protocols are as follows: A sample of 5 mg of pasty fatty substance preheated to 80 ° C. and taken from below Magnetic stirring using an equally heated spatula is placed in an airtight aluminum capsule, or crucible. Two tests are carried out to ensure the reproducibility of the results. The measurements are carried out on the calorimeter mentioned above. The oven is subjected to a nitrogen sweep. The cooling is ensured by the RCS 90 heat exchanger. The sample is then subjected to the following protocol, first being brought to a temperature of 20 ° C and then subjected to a first temperature rise ranging from 20 ° C to 80 ° C. ° C, at the heating rate of 5 ° C / minute, then cooled from 80 ° C to -80 ° C at a cooling rate of 5 ° C / minute and finally subjected to a second temperature rise from - 80 ° C to 80 ° C at a heating rate of 5 ° C / minute. During the second rise in temperature, the variation of the power difference absorbed by the empty crucible and the crucible containing the butter sample is measured as a function of temperature. The melting point of the compound is the value of the temperature corresponding to the peak apex of the curve representing the variation of the difference in power absorbed as a function of the temperature. The end of melting temperature corresponds to the temperature at which 95% of the sample melted. The liquid fraction by weight of the butter at 25 ° C. is equal to the ratio of the enthalpy of fusion consumed at 25 ° C. on the enthalpy of melting of the butter. The heat of fusion of the pasty compound is the enthalpy consumed by the compound to pass from the solid state to the liquid state. The butter is said to be in the solid state when the entirety of its mass is in crystalline solid form. The butter is said to be in the liquid state when the entirety of its mass is in liquid form. The melting enthalpy of the butter is equal to the integral of the whole of the melting curve obtained with the aid of the calorimeter evoked, with a rise in temperature of 5 or 10 ° C. per minute, according to the ISO 11357 standard. -3: 1999. The melting enthalpy of the butter is the amount of energy required to pass the compound from the solid state to the liquid state. It is expressed in J / g. The enthalpy of fusion consumed at 25 ° C is the amount of energy absorbed by the sample to change from the solid state to the state it has at 25 ° C consisting of a liquid fraction and a solid fraction.

The liquid fraction of the butter measured at 32 ° C preferably represents from 30 to 100% by weight of the compound, preferably from 50 to 100 (%), more preferably from 60 to 100% by weight of the compound. When the liquid fraction of the butter measured at 32 ° C is 100%, the temperature of the end of the melting range of the pasty compound is less than or equal to 32 ° C.

The liquid fraction of the butter, measured at 32 ° C., is equal to the ratio of the enthalpy of fusion consumed at 32 ° C. to the heat of fusion of the pasty compound. The enthalpy of fusion consumed at 32 ° C. is calculated in the same way as the heat of fusion consumed at 23 ° C. Regarding the measurement of the hardness, the sample preparation and measurement protocols are as follows: The composition according to the invention or the butter is placed in a mold 75 mm in diameter which is filled to about 75% of its height. In order to overcome the thermal past and control the crystallization, the mold is placed in the Vôtsch VC0018 programmable oven where it is first heated to 80 ° C for 60 minutes, then cooled from 80 ° C to 0 ° C at a cooling rate of 5 ° C / minute, then left at the stabilized temperature of 0 ° C for 60 minutes, then subjected to a temperature rise from 0 ° C to 20 ° C, at a rate of heat of 5 ° C / minute, then left at the stabilized temperature of 20 ° C for 180 minutes. The compression force measurement is performed with Swantech TA / TX2i texturometer. The mobile used is chosen according to the texture: - mobile cylindrical steel 2 mm in diameter for very rigid raw materials; - Cylindrical 12 mm diameter steel mobile for inferior raw materials; The measurement comprises 3 steps: a first step after automatic detection of the surface of the sample where the mobile moves at the measurement speed of 0.1 mm / s, and enters the composition according to the invention or the butter at a penetration depth of 0.3 mm, the software records the value of the maximum force reached; a second so-called relaxation stage where the mobile stays at this position for one second and where the force is noted after 1 second of relaxation; finally - a third step called withdrawal or the mobile returns to its initial position at the speed of 1 mm / s and note the energy withdrawal of the probe (negative force).

The value of the hardness measured in the first step corresponds to the maximum compression force measured in Newton divided by the surface of the texturometer cylinder expressed in mm 2 in contact with the butter or the composition according to the invention. The value of hardness obtained is expressed in mega-pascals or MPa.

According to a preferred embodiment of the invention, the particular butter or butters are of plant origin, such as those described in Ullmann's Encyclopedia of Industrial Chemistry ("Fats and Fatty Oils", A. Thomas, published online: 15/06/2000, D01: 10.1002 / 14356007.a10_173, item 13.2.2.2 Shea Butter, Borneo Tallow, and Related Fats (Vegetable Butters).

Shea butter, Shea butter Nilotica (Butyrospermum parkii), Galam butter (Butyrospermum parkii), Borneo butter or fat or Tengkawang tallow (Shorea stenoptera), Shorea butter, butter may be mentioned more particularly. of Illipé, Madhuca butter or Bassia Madhuca longifolia, mowrah butter (Madhuca Latifolia), Katiau butter (Madhuca mottleyana), Phulwara butter (M. butyracea), mango butter (Mangifera indica), butter Murumuru (Astrocaryum murumuru), Kokum butter (Garcinia Indica), Ucuuba butter (Virola sebifera), Tucuma butter, Painya butter (Kpangnan) (Pentadesma butyracea), Coffee butter (Coffea arabica) , apricot butter (Prunus Armeniaca), Macadamia butter (Macadamia Temifolia), grape seed butter (Vitis vinifera), avocado butter (Persea gratissima), olive butter (Olea europaea) , sweet almond butter (Prunus amygdalus dulcis), cocoa butter (Theobroma c acao) and sunflower butter.

According to one preferred embodiment of the invention, the weight content of the butter or butters according to the invention, in the form of triglyceride fatty acids, expressed relative to the total fatty acids of the triglycerides, is less than 23%. In a preferred variant of the invention, the weight content of fatty acids 016 of the triglycerides expressed relative to the total fatty acid triglycerides varies from 0 to 22%, better from 0 to 15%, more preferably from 2 to 12%. Preferably, the butter or butters according to the invention are chosen from Murumuru butter, Ucuuba butter, Shorea butter, Illipé butter, Shea butter, Cupuaçu butter and even more preferably from butter. Murumuru and Ucuuba butter. The waxes can be solid fatty alcohols or solid fatty esters at room temperature and at atmospheric pressure.

According to a particular embodiment of the invention, the composition comprises, as third component, one or more solid fatty alcohols). The fatty alcohols that are suitable for carrying out the invention are more particularly chosen from linear, saturated alcohols containing from 6 to 30 carbon atoms, preferably from 8 to 30 carbon atoms. There may be mentioned, for example, cetyl alcohol, stearyl alcohol and their mixture (cetylstearyl alcohol). As regards the fatty esters of fatty acids and / or solid fatty alcohols, mention may be made preferably of linear and saturated fatty acid esters and of linear and saturated fatty alcohols such as cetyl palmitate, stearyl stearate, cetyl stearate. According to another particular embodiment of the invention, the composition comprises, as third component, one or more waxes, different from the fatty alcohols and fatty esters mentioned above, preferably of plant origin.

The wax or waxes (non-silicone) are chosen in particular from Carnauba wax, Candelila wax, and Alfa wax, paraffin wax, ozokerite, vegetable waxes such as olive wax, wax of rice, hydrogenated jojoba wax or absolute waxes of flowers such as the essential wax of blackcurrant flower sold by the company BERTIN (France), animal waxes such as beeswax, or modified beeswax ( cerabellina); other waxes or waxy raw materials that can be used according to the invention are, in particular, marine waxes, such as the one sold by SOPHIM under the reference M82, and polyethylene or polyolefin waxes in general. According to another particular embodiment of the invention, the composition comprises one or more waxes, resins or silicone gums.

In the class of polydialkylsiloxanes, mention may be made of the waxes sold under the names "ABIL WAX® 9800 and 9801" by GOLDSCHMIDT, which are polydialkyl (C1-020) siloxanes. The silicone gums that can be used in accordance with the invention are in particular polydialkylsiloxanes, preferably polydimethylsiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures. More particularly useful products according to the invention are mixtures such as: - mixtures formed from a hydroxyl end-of-the-chain polydimethylsiloxane, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such that the product Q2 1401 marketed by the company Dow Corning; mixtures of a polydimethylsiloxane gum and a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500,000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 -6 m 2 / s. This product preferably comprises 15% of SE 30 gum and 85% of an SF 96 oil. The organopolysiloxane resins used in accordance with the invention are crosslinked siloxane systems containing the units: R25iO2 / 2, R35iO1 / 2, R5iO3 Wherein R represents an alkyl having 1 to 16 carbon atoms. Among these products, those that are particularly preferred are those in which R denotes a C1-C4 lower alkyl group, more particularly methyl. Among these resins may be mentioned the product sold under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shin40 ETSU. Preferably, the different fatty substance (s) of the oil (s) ii) do not comprise an oxyalkylenated unit at 02-03 or glycerol and are (are) different (s) fatty acids. Preferably, the different fatty substance (s) of the oils (ii) is (are) chosen from among the butters.

The pre-dispersion of the invention before addition of the ingredient (s) i) may comprise one or more different fatty substance (s) of the oil (s) ii) in an amount ranging from 0.1 to 50% by weight more particularly from 1 to 40% by weight, preferably from 2 to 30% by weight, and more preferably from 3 to 20% by weight relative to the weight of said pre-dispersion.

The composition according to the invention may comprise one or more different fatty substances of the oil (s) ii) in an amount ranging from 0.1 to 30% by weight, more particularly from 0.5 to 20% by weight. by weight, preferably from 1 to 10% by weight, relative to the weight of said composition. In case of additional addition of water, the final composition n may comprise one or more different fatty substances of the oil (s) ii) in an amount ranging from 0.1 to 20% by weight, more particularly from 0.5 to 10% by weight, preferably from 1 to 5% by weight, relative to the weight of said final composition, the surfactant (s) According to a preferred embodiment of the composition of the invention, the final composition of case of additional water addition, the pre-dispersion, comprise one or more surfactant (s) ie ingredient (s) iii). This surfactant (s) may be chosen from nonionic, anionic, cationic and amphoteric surfactants. According to a particular embodiment of the invention, ingredient iii) represents one or more amphoteric surfactants. The at least one amphoteric surfactant (s) that may be used in the present invention may be chosen from secondary or tertiary aliphatic amine derivatives, optionally quaternized, in which the aliphatic group is a chain. linear or branched having from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate group, sulfonate, sulfate, phosphate or phosphonate.

According to a particular embodiment of the invention, the ingredient (s) iii) is (are) in the pre-dispersion and / or the compositions of the invention and is (are) chosen from among the compounds of respective structures (B1) and (B2): Ra-C (O) -N (Z) -CH2- (CH2), -N + (Rb) (Ra-CH2-C (O) -O-, M +, X- (B1) (to be reported in PR231) Formula (B1) in which: - Ra represents a C10-C30 alkyl or alkenyl group derived from a carboxylic acid Ra-C (O) -OH, preferably present in the hydrolysed coconut oil, a heptyl, nonyl or undecyl group; Rb represents a beta-hydroxyethyl group; and - R, represents a carboxymethyl group; - W represents a cationic counterion derived from an alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and - X- represents an organic or inorganic anionic counterion, preferably selected from halides, acetates, phosphates, nitrates, alkyl (01-04) sulf ates, 04) - or alkyl (01-04) aryl sulfonates, in particular methylsulfate and ethylsulfate; m is equal to 0.1 or 2; Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group or else W and X- are absent; Ra'-C (O) -N (Z) -CH 2 - (CH 2) n (B) (B 1) (B2) Formula (B2) in which: B represents the group -CH 2 -CH 2 -O-X '; B 'represents the group - (CH2) z-Y', with z = 1 or 2; X 'represents the group -CH 2 -O (O) -OH, -CH 2 -O (O) -OZ', -CH 2 -CH 2 -O (O) -OH, -CH 2 -CH 2 -O (O) -OZ ', or a hydrogen atom; Y 'represents the group -O (O) -OH, -O (O) -OZ', -OH2-CH (OH) -SO3H or the group -OH2-CH (OH) -SO3-Z '; Z 'represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - Ra, represents an alkyl group in 0-10-030 or alkenyl in 010-030 of an acid Ra-C (O) -OH, preferably present in coconut oil or in hydrolyzed linseed oil, an alkyl group , especially 017 and its iso form, an unsaturated 017 group; m is equal to 0.1 or 2; Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group. Compounds of this type are classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacetate disodium, lauroamphodiacetate disodium, caprylamphodiacetate disodium, capryloamphodiacetate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, 35 caprylamphodipropionate disodium, disodium capryloamphodipropionate, lauroamphodipropionic acid, cocoamphodipropionic acid hydroxyethylcarboxymethylcocamidopropylamine. By way of example, mention may be made of cocoamphodiacetate sold by the company Rhodia under the trade name MIRANOLO 02M Concentrate or under the trade name MIRANOL ULTRA 0 32 and the product marketed by CHIMEX under the trade name CH IMEXANE HA (to According to another particular embodiment of the invention, the ingredient (s) iii) is (are) in the pre-dispersion and / or the compositions of the invention and is (are) chosen (s) among the following structural compounds (B'2); Ra "-N (H) -CH (Y") - (CH2), - C (O) -N (H) - (CH2) ', - N (Rd) (Re) (B'2) Formula (B) 2) in which: Y "represents the group -O (O) -OH, -O (O) -O-Z", -01-12-01-1 (01-1) -5031-1 or group -01-12-01-1 (01-1) -503-Z "- Rd and Re, independently of one another, represent a C1-C4 alkyl or hydroxyalkyl radical; cationic ion derived from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra "represents a C 10 -C 30 alkyl or alkenyl group of an acid Ra" -C (O) -OH, preferably present in coconut oil or in hydrolysed linseed oil; n and n ', independently of one another, denote an integer ranging from 1 to 3. Among the compounds of formula (B'2), mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by CHIMEX under the name CHIMEXANE HB. According to a particular embodiment of the invention, the ingredient iii) represents one or more surfactants chosen from the compounds of formula (B3) as well as their possible salts of organic or mineral acids or bases, their solvates such as the hydrates: R 2 + R 1 -N-R 4 - (Z) R 3 (B 3) Formula (B 3) in which: R 1 denotes a linear or branched, saturated or unsaturated hydrocarbon-based chain containing from 6 to 100 carbon atoms, 6 to 50 carbon atoms, which can be interrupted by one or more heteroatoms, divalent groups, or combinations thereof selected from -O-, -O (O) -, -N (R) with R denoting an atom of hydrogen or a C 1 -C 4 alkyl radical, and R 1 may be further interrupted by an arylene group or terminated by an aryl group; - R2 and R3, identical or different, in particular R2 and R3 are identical, denote a group (01-06) alkyl, preferably R2 and R3 represents a methyl group; G- - R4 denotes a divalent hydrocarbon radical, linear or branched, preferably linear, containing from 1 to 10, preferably from 1 to 5 carbon atoms optionally substituted in particular by one or more hydroxyl groups; Z denotes a heteroatom or a divalent group chosen from -O-, -N (R) - with R as defined above, n denotes a number equal to 1 or 2; m denotes an integer equal to 0 or 1; - G- denotes an anionic radical chosen from carboxylates, sulphates, sulphonates, phosphates and phosphonates (* -C (O) -O-, * -S (O) 2-0-, * -O-S (O) 2 -0-, * -P (0) 2-0-, * -P (O) -O-, -P (OH) -O-, ** = P (O) -O- and ** = P -0-, with "* -" designating the point of attachment of the anionic radical to the rest of the molecule via Z or R4 when n is 1, and "** =" representing the two points of attachment of the anionic radical via Z or R4 when n is 2); it being understood that: when n is 2, the radicals R 1 R 2 R 3 N + -R '- (Z), - are identical or different, preferably identical; and the surfactant of formula (B3) being electrically neutral, it may comprise anionic and / or cationic counterions to arrive at the electroneutrality of the molecule.

By "unsaturated" hydrocarbon chain is meant a hydrocarbon chain which comprises one or more double bonds and / or one or more triple bonds, said bonds possibly being conjugated or not; By "alkyl radical" is meant a saturated hydrocarbon radical, linear or branched, preferably C 1-8; By "alkenyl radical" is meant a hydrocarbon radical, linear or branched, preferably 02-08; unsaturated compound comprising one or more double bonds, conjugated or otherwise "Alkoxy radical" is understood to mean an alkyl-oxy radical for which the alkyl radical is a hydrocarbon radical, linear or branched, in Cl-016, preferentially in Cl-08; By radical "aryl" is meant a mono- or polycyclic carbon group, condensed or not, comprising from 6 to 22 carbon atoms, and of which at least one ring is aromatic; preferably the aryl radical is a phenyl, biphenyl, naphthyl, indenyl, anthracenyl, or tetrahydronaphthyl; By radical "atylene" is meant an aromatic radical divalent mono- or polycyclic, condensed or not, comprising from 6 to 22 carbon atoms, and of which at least one ring is aromatic, preferably phenylene, and more preferably 1.3 or 1,4-phenylene; By "optionally substituted" assigned to the radical in question is meant that said radical may be substituted with one or more radicals chosen from the radicals i) hydroxy, ii) alkoxy at Cl-04, iii) acylamino, iv) amino optionally substituted by a or two identical or different C 1 -C 4 alkyl radicals, said alkyl radicals being able to form, with the nitrogen atom carrying them, a 5- to 7-membered heterocyl, optionally comprising another heteroatom which may or may not be different from nitrogen; ; By "organic or mineral acid salt" is meant more particularly the salts selected from a salt derived i) hydrochloric acid HCl, ii) hydrobromic acid HBr, iii) sulfuric acid H2SO4, iv) acids alkylsulfonic: Alk-S (O) 20H such as methylsulfonic acid and ethylsulfonic acid; y) arylsulfonic acids: Ar-S (O) 20H such as benzene sulfonic acid and toluene sulfonic acid; (vi) citric acid; vii) succinic acid; viii) tartaric acid; ix) lactic acid, x) alkoxysulfinic acids: Alk-O-S (O) OH such as methoxysulfinic acid and ethoxysulfinic acid; xi) aryloxysulfinic acids such as tolueneoxysulfinic acid and phenoxysulfinic acid; xii) phosphoric acid H3PO4; xiii) acetic acid CH3C (O) OH; xiv) triflic acid CF3SO3H and xv) tetrafluoroboric acid HBF4; By "organic or inorganic base salt" is meant more particularly the salts selected from a salt derived from basifying agents as defined "Additional alkalizing agents:" hereinafter. By "anionic counterion" is meant an anion or an anionic group derived from organic or inorganic acid salt counterbalancing the cationic charge of the dye; more particularly the anionic counterion is selected from i) halides such as chloride, bromide; ii) nitrates; iii) sulfonates, including C1-C6 alkylsulphonates: Alk-S (O) 20- such as methylsulphonate or mesylate and ethylsulphonate; iv) arylsulfonates: Ar-S (O) 20- such as benzenesulphonate and toluenesulphonate or tosylate; y) citrate; vi) succinate; (vii) tartrate; viii) lactate; ix) alkyl sulphates: Alk-O-S (O) O- such as methysulphate and ethylsulphate; x) arylsulfates: Ar-O-S (O) O- such as benzenesulphate and toluenesulphate; xi) alkoxysulfates: Alk-O-S (O) 20- such as methoxy sulfate and ethoxysulfate; xii) aryloxysulfates: Ar-OS (O) 20-, xiii) the phosphates O = P (01-1) 2-0-, O = P (O) 2-OH, O = P (O-) 3, 1-10- [P (0) (0 -)], - P (0) (0-) 2 with w being an integer; (xiv) acetate; xv) triflate; and xvi) borates such as tetrafluoroborate, xvii) (0 =) 2S (O-) 2 or SO42- disulfate and HSO4- monosulfate; the anionic counterion, derived from organic or inorganic acid salt, ensures the electroneutrality of the molecule so it is understood that when the anion comprises several anionic charges then the same anion can be used for the electroneutrality of several cationic groups in the same molecule or else can be used for the electroneutrality of several molecules; for example a betainic surfactant which contains two positive charges may contain either two "monocharged" anionic ions or contains a "bicharged" anionic counterion such that (0 =) 2S (O) 2 or 0 = P (O-) 2 -01-1. In particular, the cationic counterion or ions are chosen from alkali metals such as Na, K, or alkaline earth metals such as Mg, Ca, or organic cations such as ammonium, mono / di / tri (C1-C6) alkylammonium, and / or the anionic counterion or ions are selected from halides such as chloride or alkylsulfonates such as mesylates. More preferably, the optional cationic counterion or ions are chosen from alkali metals such as Na, K, or alkaline earth metals such as Mg, Ca, and / or the anionic counterion or ions are chosen from halides such as chloride or alkylsulfonates such as mesylates. According to a preferred embodiment of the invention, the betainic surfactant or surfactants are chosen from surfactants of formula (B3) in which n is equal to 1 and G- denotes an anionic radical chosen from * -C (O) O- and * -S (O) 2-O-, According to an advantageous embodiment of the invention, the betainic surfactant (s) are chosen from surfactants of formula (B3) in which R4 denotes a divalent linear alkylene radical in Cl- 05, optionally substituted with a hydroxy group such as -CH2-CH2-CH2-, -CH2-CH (OH) -CH2-, or -CH2-CH2-. According to a preferred embodiment of the invention, the betaine surfactant or surfactants are chosen from surfactants of formula (B3) in which m is 1 and Z represents an oxygen atom or a group -N (R) - with R as defined above. More preferably, when m is 1, then Z represents an oxygen atom. According to another preferred embodiment of the invention, the betainic surfactant (s) are chosen from surfactants of formula (B3) in which m is 0.

According to another preferred embodiment of the invention, the betainic surfactant or surfactants are chosen from surfactants of formula (B3) in which R1 denotes a group chosen from: i) alkyl at 06-030; ii) alkenyl at 06-030, - (C6-C30) alkyl-amido- (C1-C4) alkyl or - (C6-C30) alkenyl-amido- (C1-C4) alkyl, with amido representing a group -C ( 0) -N (R) - and R being as defined above.

In particular, R denotes a hydrogen atom. More particularly, R 1 denotes an alkyl radical, linear or branched, preferably linear, at 06-030. Among the amphoteric surfactants mentioned above, use is preferably made of (C 8 -C 20) alkyl betaines such as cocoylbetaine, (C 8 -C 20) alkylamido (C 2 -C 20) alkyl betaines such as cocoylamidopropylbetaine, and mixtures thereof. More preferably, the amphoteric surfactant (s) are chosen from cocoylamidopropylbetaine and cocoylbétaine. According to another particular embodiment of the invention, ingredient iii) represents one or more anionic surfactants. The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups -C (O) OH, -C (O) O-, -SO3H, -S (O) 20-, -OS (O) 20H, -OS (O) 20- , -P (O) OH2, -P (O) 20-, -P (O) O2-, -P (OH) 2, = P (O) OH, -P (OH) O, = P (O) 0-, = POH, = PO-, the anionic parts comprising a cationic counterion such as an alkali metal, an alkaline earth metal, or an ammonium. As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates and alkyl aryl sulphonates. , alpha-olefinsulfonates, paraffin-sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, monoesters salts of alkyl and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether carboxylic acid salts, alkyl acid salts amidoether carboxylic acids, and the corresponding non-salified forms of all these compounds, alkyl and acyl groups. all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group.

These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units. The salts of Ⓒ monoesters and of polyglycoside-polycarboxylic acids may be chosen from Ⓒ polyglycoside-citrates, Ⓒ alkyl polyglycosidestartrates and olefin polyglycoside-sulfosuccinates. alkyl at 06-024.

When the agent or the anionic surfactants are in the salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salts.

By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or triisopropanolamine, the salts of 2-amino-2-methyl-1- propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used.

Among the anionic surfactants mentioned, it is preferred to use (C 6 -C 24) alkyl sulphates, alkyl (C 6 -C 24) ether sulphates comprising from 2 to 50 ethylene oxide units, in particular in the form of alkali metal or ammonium salts. , aminoalcohols, and alkaline earth metals, or a mixture of these compounds. In particular, it is preferred to use (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metal salts, ammonium salts, aminoalcohol , and alkaline earth metals, or a mixture of these compounds. More preferably, it is preferred to use sodium lauryl ether sulfate with 2.2 moles of ethylene oxide. According to another particular embodiment of the invention, the ingredient (s) iii) represent (s) one or more cationic surfactants. The cationic surfactant (s) which can be used in the composition according to the invention comprises, for example, the primary, secondary or tertiary fatty amine salts, optionally polyoxyalkylenated, ammonium salts. quaternary, and their mixtures.

Among the tertiary fatty amines, mention may be made more particularly of oleamidopropyl dimethylamine. As quaternary ammonium salts, there may be mentioned in particular: a) the quaternary ammonium salts of general formula (B4) below: - Formula (B4) in which: R8 to R11, identical or different, branched, saturated or initiated, aromatic such as aryl or R11 have from 8 to 30 carbon; and R8 / Rio X - X-, represents a counterion R (R1, (B4) represent having alkylaryl, being carbon atoms, an aliphatic group, linear or 1 to 30 carbon atoms, or a group understood that at least one of R8 and preferably from 12 to 24 organic or inorganic anionic atoms, such as that chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkylsulphates, O 4) or alkyl (C 1 -C 4) aryl sulfonates, in particular methylsulfate and ethylsulfate; the aliphatic groups of R8 to R11 may further comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens; the aliphatic groups of R8 to R11 are in particular chosen from C1-C30alkyl, C1-C30alkoxy, polyoxyalkylene (02-06), C1-C30alkylamide, (C12-C22alkyl) amidoalkyl (C2-C6) ), (C12-C22) alkyl, and (C1-C30) hydroxyalkyl, is an anionic counterion selected from halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, (C1-C4) alkyl or alkyl (C1-C4) aryl sulfonates; of the quaternary ammonium salts of the formula (B4), tetraalkylammonium chlorides, such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group comprises from about 12 to 22 carbon atoms, are preferred. carbon, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium chlorides or secondly distearoylethylhydroxyethylmethylammonium methosulphate, dipalmitoylethylhydroxyethylammonium methosulphate or distearoylethylhydroxyethylammonium methosulphate, or else finally palmitylamidopropyltrimethylammonium chloride; b) the quaternary ammonium salts of imidazoline, for example those of the following formula (B5): R13 XNN + (; 1-12CH2-N (R15) -C (O) -Ri2 V R14 Formula (B5 in which: R12 represents an alkenyl or alkyl group containing from 8 to 30 carbon atoms, for example fatty acid derivatives of tallow; R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl group; or alkyl having from 8 to 30 carbon atoms; - R14 represents a C1-C4 alkyl group; - R15 represents a hydrogen atom, a C1-C4 alkyl group; -X- represents an organic or inorganic anionic counterion. , such as that selected from halides, phosphates, acetates, lactates, alkyl (01-04) sulfates, 04) - or alkyl (01-04) aryl sulfonates; preferably, R12 and R13 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl group, R15 denotes a hydrogen atom; such a product is for example marketed under the name REVVOQUATO VV 75 by the company REVVO; c) the quaternary di- or triammonium salts, in particular of formula (B6) below: R17 R19 + + R16 N (CH2) 3 NR X-X 21 R18 R20 Formula (B6) in which: R16 denotes a group alkyl having from about 16 to 30 carbon atoms, optionally hydroxylated and / or interrupted by one or more oxygen atoms; R 17 is chosen from hydrogen, an alkyl group comprising from 1 to 4 carbon atoms or a - (CH 2) 3 -N + (R 16a) (R 17a) (R 18a), X group; R16a, R17a, R18a, R18, R19, R20 and R21, which are identical or different, are chosen from hydrogen and an alkyl group comprising from 1 to 4 carbon atoms; and (B5) (B6) -X-, which may be identical or different, represent an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, alkyl (Cl-C4) sulphates, alkyl (Cl- C4) - or (C1-C4) alkylarylsulfonates, in particular methylsulfate and ethylsulfate; such compounds are, for example, the Finquat CT-P proposed by Finetex (Quaternium 89), the Finquat CT proposed by Finetex (Quaternium 75); d) quaternary ammonium salts containing one or more ester functions, such as those of the following formula (B7): R24 (B7) Formula (B7) in which: R22 is chosen from C1-C6 alkyl groups; and the hydroxyalkyl or dihydroxyalkyl groups at Cl-06, -R23 is chosen from: the group R2C-the linear or branched, saturated or unsaturated C -C hydrocarbon groups at C-022, the hydrogen atom, R 25 is chosen from: O - the group R 2 -C 8 - the linear or branched, saturated or unsaturated hydrocarbon groups R-C 6, - the hydrogen atom, - R 24, R 26 and R 28, which may be identical or different are selected from linear or branched, saturated or unsaturated hydrocarbon groups of 07-021; r, s and t, which may be identical or different, are integers of from 2 to 6, r1 and t1 which are identical or different, equal to 0 or 1 with r2 + r1 = 2r and t1 + t2 = 2t - y is an integer from 1 to 10, - x and z, which may be identical or different, are integers ranging from 0 to 10, 30 - X- represents an anionic counterion, organic or inorganic, provided that the sum x + y + z is equal to 1 at 15, that when x is 0 then R23 is R27 and when z is 0 then R25 is R29; the alkyl groups R22 may be linear or branched, and more particularly linear; preferably, R22 denotes a methyl, ethyl, hydroxyethyl or X (Cs I-12s) R25 0 CrH r2 (0 H) r, 17 N + + CtHt2 (OH) t, 017 R23 1122 dihydroxypropyl group, and more particularly a group methyl or ethyl; advantageously, the sum x + y + z is from 1 to 10; When R 23 is a hydrocarbon R 27 group, it may be long and have 12 to 22 carbon atoms, or short and have 1 to 3 carbon atoms; When R 25 is a hydrocarbon R 29 group, it preferably has 1 to 3 carbon atoms; Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated Cil-021 hydrocarbon groups, and more particularly from linear or branched, saturated Cil-021 alkyl and alkenyl groups. or unsaturated; Preferably, x and z, identical or different, are 0 or 1; Advantageously, y is 1; Preferably, r, s and t, identical or different, are 2 or 3, and even more particularly are 2; The anionic counterion X- is preferably a halide, such as chloride, bromide or iodide; a (C1-C4) alkyl sulphate; (C1-C4) alkyl or (C1-C4) alkyl aryl sulfonate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function; The anionic counterion X- is even more particularly chloride, methylsulphate or ethylsulphate; In the composition according to the invention, the ammonium salts of formula (B7) are used more particularly in which: R 22 denotes a methyl or ethyl group, x and y are equal to 1, z is equal to 0 or 1, - r, s and t are equal to 2, - R23 is chosen from: o - the group R2C - the methyl, ethyl or hydrocarbon groups at 014-022, - the hydrogen atom, - R25 is chosen from The group R2 - - the hydrogen atom, - R24, R28 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated hydrocarbon groups in 013-017, and preferably from linear or branched, saturated or unsaturated 0-13-017 alkyl and alkenyl groups; Advantageously, the hydrocarbon radicals are linear; Examples of compounds of formula (B7) include salts, especially diacyloxyethyldimethylammonium, diacyloxyethylhydroxyethylmethylammonium, monoacyloxyethyldihydroxyethylmethylammonium, triacyloxyethylmethylammonium, monoacyloxyethylhydroxyethyldimethylammonium, and mixtures thereof, especially diacyloxyethyldimethylammonium chloride or methylsulfate. The acyl groups preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains more than one acyl group, the latter groups may be identical or different.

These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine optionally oxyalkylenated on fatty acids or mixtures of fatty acids of plant or animal origin, or by transesterification. of their methyl esters. This esterification is followed by quaternization using an alkylating agent such as an alkyl halide, preferably methyl or ethyl, a dialkyl sulphate, preferably methyl or ethyl sulphate. methyl methanesulfonate, methyl para-toluenesulfonate, glycol or glycerol chlorohydrin. Such compounds are, for example, sold under the names DEHYQUARTO by the company HENKEL, STEPANQUATO by the company STEPAN, 20 NO) AMIUM® by the company CECA, REVVOQUATO VVE 18 by the company REVVO-VVITCO. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180. Behenoylhydroxypropyltrimethylammonium chloride proposed by KAO can be used under the name Quatarmin BTC 131. Preferably, the ammonium salts containing at least one ester function contain two ester functions. Among the cationic surfactants which may be present in the composition according to the invention, it is more particularly preferred to choose the salts of cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethylhydroxyethylmethylammonium, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, chloride cetyltrimethylammonium, dipalmitoylethylhydroxyethylammonium methosulfate, oleamidopropyldimethylamine and mixtures thereof. According to another particular embodiment of the invention, ingredient iii) represents one or more nonionic surfactants. By "nonionic" surfactant is meant a surfactant which does not carry anionic or cationic charge. Examples of nonionic surfactants useful in the composition used according to the invention are described, for example, in "Handbook of Surfactants" by M. R. PORTER, Blackie & Son editions (Glasgow and London), 1991, pp. 116-178. They are chosen in particular from alcohols, alpha-diols and (C1-C20) alkyl phenols, these compounds being polyethoxylated, polypropoxylated and / or polyglycerolated, and having at least one fatty chain comprising, for example, from 8 to 18 atoms. carbon, the number of ethylene oxide groups and / or propylene oxide may range from 2 to 50 and the number of glycerol groups ranging from 2 to 30.

Mention may also be made of copolymers of ethylene oxide and of propylene oxide, esters of fatty acids and of sorbitan, optionally oxyethylenated, esters of fatty and sucrose acids, esters of polyoxyalkylenated fatty acids, alkylpolyglycosides, optionally oxyalkylenated. alkylglucoside esters, N-alkylglucamine and N-acyl-methylglucamine derivatives, aldobionamides and amine oxides.

The nonionic surfactants are more particularly chosen from mono or polyoxyalkylenated, mono- or polyglycerolated nonionic surfactants. The oxyalkylenated units are more particularly oxyethylenated units, oxypropylene, or their combination, preferably oxyethylenated. As examples of oxyalkylenated nonionic surfactants, mention may be made of: oxyalkylenated (C 8 -C 24) alkyl phenols; saturated or unsaturated, linear or branched, oxyalkylenated 08-030 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated amides 08-030; saturated or unsaturated, linear or branched, 08-030 acid esters of polyethylene glycols; 08-030 acid esters, saturated or unsaturated, linear or branched, and polyoxyethylenated sorbitol; vegetable oils oxyethylenated, saturated or not; condensates of ethylene oxide and / or propylene oxide, among others, alone or in mixtures. Oxyethylenated and / or oxypropylenated silicones. Surfactants having a number of moles of ethylene oxide and / or propylene of between 1 and 100, preferably between 2 and 50, preferably between 2 and 30. Advantageously, the nonionic surfactants do not comprise oxypropylene units. According to a preferred embodiment of the invention, the oxyalkylenated nonionic surfactants are chosen from oxyethylenated 08-030 alcohols comprising from 1 to 100 moles of ethylene oxide; 08-030 esters, saturated or unsaturated, linear or branched, and polyoxyethylenated sorbitol comprising from 1 to 100 moles of ethylene oxide. By way of example of mono- or poly-glycerolated nonionic surfactants, the mono-or poly-glycerolated 08-040 alcohols are preferably used.

In particular, mono- or poly-glycerolated 08-040 alcohols correspond to the following formula (B8): R290- [CH2-CH (CH2OH) -O] --H (B8) Formula (B8) in which: - R29 represents a linear or branched, alkyl or alkenyl radical, at 08-040, preferably at 08-030; and - m represents a number ranging from 1 to 30 and preferably from 1 to 10. By way of example of compounds of formula (B8) which are suitable within the scope of the invention, mention may be made of 4-lauryl alcohol. glycerol moles (INCI name: POLYGLYCERYL-4 LAURYL ETHER), lauric alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol to 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol to 2 moles of glycerol, cetearyl alcohol to 6 moles of glycerol, oleocetyl alcohol to 6 moles of glycerol, and octadecanol to 6 moles of glycerol.

The alcohol of formula (B8) can represent a mixture of alcohols in the same way that the value of m represents a statistical value, which means that in a commercial product several polyglycerolated fatty alcohol species can coexist in the form of a mixed. Among the mono- or poly-glycerolated alcohols, it is more particularly preferred to use the alcohol in 0/010 to one mole of glycerol, the alcohol in 010/012 to 1 mole of glycerol and the alcohol in 0 to 1.5 mole of glycerol. Of the saturated or unsaturated, linear or branched, 08-030 acid esters of polyoxyethylene sorbitol, those having a number of moles of ethylene oxide of less than or equal to 20 are particularly preferred. Particularly comprising from 8 to 24 carbon atoms. carbon and more particularly from 8 to 18 carbon atoms. The fatty acids are in particular chosen from lauric acid, palmitic acid, oleic acid and stearic acid, and preferably from lauric acid and stearic acid and even more particularly lauric acid. 08-024 fatty acid monoesters and oxyethylenated sorbitan are preferably used. The number of moles of ethylene oxide is preferably less than 10 and more particularly from 3 to 8 moles of ethylene oxide and in particular is equal to 4. The preferred sorbitan esters are mono-laurate. sorbitan oxyethylenated with 4 moles of ethylene oxide (40E) or polysorbate 21, sorbitan monostearate oxyethylenated with 4 moles of ethylene oxide (40E) or polysorbate 61, the oxyethylenated sorbitan mono-oleate to 5 moles of ethylene oxide (50E) or polysorbate 81.

Polysorbate 21 is particularly preferred and is sold especially under the name TWEEN 21 by the company UNIQEMA. According to the invention, the composition may advantageously comprise mixtures of oxyethylenated sorbitan esters and in particular polysorbate 21 with polysorbate 20 (oxyethylenated sorbitan monolaurate at 20 OE).

Preferably, the surfactant (s) iii) are chosen from cationic and anionic nonionic surfactants, particularly chosen from nonionic and anionic surfactants. More particularly, the surfactant (s) present in the composition are chosen from nonionic surfactants. Preferably, the nonionic surfactant or surfactants are mono or polyoxyalkylenated, especially mono- or polyoxyethylenated, mono or polyoxypropylenated, or a combination thereof, more particularly mono or polyoxyethylenated. More preferentially, the nonionic surfactants are chosen from polyoxyethylenated sorbitol esters and polyoxyethylenated fatty alcohols, and mixtures thereof.

According to one variant of the invention, the composition according to the invention, the final composition in the case of additional water addition, the pre-dispersion and the treatment method (coloring) of the keratin fibers use as ingredient iii) a or more surfactants chosen from nonionic surfactants, in particular mono- or polyoxyalkylenated nonionic surfactants, more particularly chosen from saturated or unsaturated, linear or branched, 08-030 acid esters of polyoxyethylenated sorbitol, such as previously defined; and / or one or more anionic surfactants, in particular of alkyl sulphate type as defined above, in particular alkaline or alkaline earth lauryl ether sulphate.

The pre-dispersion, or pre-emulsion, of the invention preferably contains from 1 to 60% by weight, preferably from 5 to 50% by weight, more preferably from 10 to 40% by weight of surfactant (s) relative to to the total weight of said pre-dispersion. The composition of the invention preferably contains 1 to 40% by weight, preferably 2 to 20% by weight, more preferably 5 to 20% by weight of surfactant (s) relative to the total weight of said composition. In case of additional addition of water to the composition of the invention, the final composition preferably contains from 0.1 to 30% by weight, preferably from 0.5 to 20% by weight, better still from 1 to 10% by weight. % by weight of surfactant (s) relative to the total weight of said final composition. iv) the water or the aqueous phase The composition according to the invention, and the final composition in the case of additional addition of water, as defined above comprise water. This water constitutes part or all of an aqueous phase. By "aqueous phase" is meant a phase that essentially comprises water, and further comprises other miscible ingredients, or soluble in water at room temperature and at atmospheric pressure. Mention may be made, as liquid or solid, which may be in the aqueous phase: the organic solvents as defined hereinafter, polar or polar protic, the acid or base salts, mineral or organic, or the soluble cosmetic active ingredients in the aqueous phase; the water. The pre-dispersion of the invention contains water preferably in an amount ranging from 5 to 50%, more preferably from 7 to 40%, particularly from 8 to 20% by weight relative to the total weight of said composition. The composition of the invention contains water preferably in an amount ranging from 3 to 40%, better still from 5 to 20%, particularly from 7 to 15% by weight relative to the total weight of said composition. In case of additional addition of water to the composition of the invention, the final composition contains water preferably in an amount ranging from 20 to 90%, better still from 30 to 80%, particularly from 50 to 70%. by weight relative to the total weight of said final composition. Organic Solvents: The ready-to-use composition and / or the pre-dispersion and / or optionally the intermediate composition of the invention may comprise one or more organic solvents. As organic solvent, there may be mentioned for example lower alkanols in Cl-04, such as ethanol and isopropanol; polyols and polyol ethers such as 2-butoxyethanol, propylene glycol, propylene glycol monomethyl ether, diethylene glycol monoethyl ether and monomethyl ether, hexylene glycol, and aromatic alcohols such as benzyl alcohol or phenoxyethanol. The organic solvents are present in proportions preferably of between 0.1 and 20% by weight approximately relative to the total weight of the composition in question, and still more preferably between 0.5 and 10% by weight approximately. Adjuvants: The composition according to the invention, the final composition in case of additional water addition, the pre-dispersion may also contain various adjuvants conventionally used in compositions for dyeing hair, such as anionic, cationic polymers , nonionic, amphoteric, zwitterionic or mixtures thereof, inorganic or organic thickeners, and in particular anionic, cationic, nonionic and amphoteric polymeric associative thickeners, antioxidants, penetrating agents, sequestering agents, perfumes , buffers, dispersing agents, conditioning agents other than the fatty substances of the invention such as, for example, ceramides, film-forming agents, preserving agents, opacifying agents and mineral or organic thickeners such as clays .

The adjuvants above are generally present in an amount for each of them between 0.01 and 40% by weight relative to the weight of the composition, preferably between 0.1 and 20% by weight relative to the weight of the composition considered.

Of course, one skilled in the art will take care to choose this or these optional additional compounds in such a way that the advantageous properties intrinsically attached to the composition, pre-emulsion or poultice useful in the coloring process according to the invention do not not, or not substantially, impaired by the addition or additions envisaged.

The additional dyes: The composition according to the invention, the final composition in case of additional addition of water, the pre-dispersion may also contain one or more additional direct dyes different from the ingredient i) as defined above. . These direct dyes are, for example, chosen from those conventionally used in direct dyeing, and among which may be mentioned all the aromatic and / or nonaromatic dyes of current use such as neutral, benzene neutral, acid or cationic direct dyes, direct dyes neutral azo, acidic or cationic, natural direct dyes other than henna or indigo, direct quinone dyes and in particular neutral, acidic or cationic anthraquinone dyes, direct dyes azine, triarylmethane, indoamine, methines, styril, porphyrins, metalloporphyrins, phthalocyanines, methine cyanines, and fluorescent dyes.

Preferably, the composition according to the invention, the final composition in case of additional addition of water, the pre-dispersion of the invention may comprise one or more natural dyes different from i) as defined above. Among the natural direct dyes that may be mentioned are juglone, isatin, curcumin, spinulosin, apigenidine, orceins in the form of a defined compound.

These natural dyes can in addition to their defined compound form can be added in the form of extracts, or parts of plants. Said defined compounds of extracts, or part of plants are preferably in the form of powders, especially fine whose particles have sizes identical to that of the red henna powder and / or indigo i) as defined previously.

The direct dye or dyes, natural or non-different from i), represent, in particular, from 0.001% to 10% by weight and even more preferably from 0.05% to 5% by weight, relative to the total weight of the composition of the composition. invention or, if appropriate, the final composition.

Preferably the compositions of the invention do not contain synthetic direct dyes, i.e. which have no natural occurrence. The composition according to the invention, the final composition in the case of additional water addition, the pre-dispersion may further comprise one or more oxidation bases and / or one or more couplers conventionally used for dyeing keratinous fibers. . Among the oxidation bases that may be mentioned are para-phenylenediamines, bisphenylalkylenediamines, para-aminophenols, bis-para-aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts. Among these couplers, mention may notably be made of meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalenic couplers, heterocyclic couplers and their addition salts. The oxidation base (s) present in the composition of the invention are generally present each in an amount of between 0.001% and 10% by weight relative to the total weight of the dyeing composition (s). Preferably the composition according to the invention, the final composition in case of additional addition of water, the pre-dispersion do not contain oxidation dyes. pH of the compositions and of the pre-dispersion According to one particular embodiment of the invention, the pH of the composition of the invention and / or, if appropriate, of the final composition is neutral ie of pH around 7. According to a particular embodiment of the invention the composition of the invention and / or optionally the final composition of the invention is (are) acid (s) and preferably pH has a pH ranging from 3 to 6.5. The pH of the composition may be adjusted to the desired value by means of acidifying or basifying agents usually used for dyeing keratinous fibers or else using conventional buffer systems or clays present in the composition, in the pre-emulsion or in the added aqueous phase to make the poultice as defined above. Among the acidifying agents of the compositions used in the invention, mention may be made, for example, of mineral or organic acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids such as acetic acid, tartaric acid, citric acid, lactic acid, sulfonic acids, preferably the acid is an organic acid such as citric acid. An advantageous variant is to add an alkalizing agent to the composition or poultice according to the invention. More particularly, this alkaline agent is chosen from ammonia, alkaline carbonates, alkanolamines such as mono-, di- and triethanolamines and their derivatives, sodium or potassium hydroxides and compounds of formula (II) below : Wherein R is a C1-C6 alkylene group such as propylene, optionally substituted by a hydroxy group or a C1-C4 alkyl group; Ra, Rb, R, and Rd, identical or different, represent a hydrogen atom, a C1-C4 alkyl or C1-C4 hydroxyalkyl radical. According to one particular embodiment of the invention, the ready-to-use composition of the invention does not contain "mordants" ie metal salts conventionally used in "etching" (see for example Ullmann's Encyclopedia of Industrial Chemistry ("Textile Dyeing, Herbert Leube et al., D01: 10.1002 / 14356007.a26_351, and in particular point 4.8.2, p.72, ibid, "Metal-complex dyes", Klaus Gryschtol et al., D01: 10.1002 / 14356007 According to another particular embodiment of the invention, the composition of the invention contains at least one "mordant" ie of metal salts conventionally used in "etching" as defined above. metal salts are selected from iron, copper, zinc, manganese ...). In addition, the metal salt or salts are preferably in the pre-dispersion as defined above. Composition after mixing i) + pre-dispersion The composition according to the invention is characterized by its method of preparation, which consists in mixing the ingredient (s) i) as defined above in a dispersion which has been previously prepared also called "pre-dispersion", preferably a "pre-emulsion", as defined above, and which comprises the ingredients i) to iv) as defined above. A supplement of water may be added to the composition of the invention in particular to make the composition of the invention more unctuous or more easily applicable. The mixture of the pre-dispersion with the ingredient (s) i) can be made at the time of use without the addition of water to give the composition of the invention. This composition can optionally be stored and used at the time of use with the addition of preferably hot water (s) (temperature between 30 ° C and 80 ° C). The mixture of the pre-dispersion with ingredient i) can be made at the time of use with addition of preferably hot water (s) (temperature between 30 ° C and 80 ° C) to give the final composition .

According to a preferred embodiment of the invention, the henna and / or indigo powder, ingredient i) of the invention, is mixed in a sparse, dispersed manner, within the pre-dispersion in an ingredient ratio. ) and in pre-dispersion ranging from 0.015 parts to 0.5 parts of ingredient i) by weight to 1 part by weight of pre-dispersion. According to another particular embodiment of the invention, the ratio of ingredient i) and the pre-dispersion is greater than 0.5 part by weight of ingredient i) per 1 part by weight of pre-dispersion, preferably the ratio is included inclusively between 0.6 and 3 parts by weight of ingredient i) for 1 part by weight of pre-dispersion, more preferably 2 parts by weight of i) for 1 part by weight of pre-dispersion. In this second advantageous option, the composition obtained is pasty and the ingredient i) is coated by the pre-dispersion.

In the case of addition of water complementary to the composition according to the invention, the weight ratio of the mixture of the pre-dispersion / the ingredient i) and the additional water preferably varies from 0.1 to 2 parts better from 0.5 to 1 part of mixture to 1 part of additional water. More preferably 1.5 parts of mixture will be used for 2.5 parts of additional water. The compositions of the invention are cosmetic, i.e. they are cosmetically acceptable therefore suitable for use for application to keratinous fibers.

According to a preferred embodiment of the invention of the invention or, where appropriate, the final composition is (are) in non-compact galenic forms, such as a lotion, a mousse, a cream, a gel or any other form suitable for dyeing keratinous fibers. Preferably these compositions are in the form of a poultice having a creamy and pleasant consistency. During the preparation of the composition of the invention, one or more clays, which may be identical or different, may be added.

According to a particular embodiment of the invention, the pre-dispersion is a pre-emulsion and is preferably in the form of a microemulsion or nanoemulsion and / or which contains the following ingredients: Ingredients Trade name Sorbitan monolaurate laurate 40E (surfactant not ionic) Tween 21 Isopropyl myristate CRODAMOL IPM-LQ- (MV) lsononyl isononanoate VVICKENOL 151 Helianthus annuus seed oil Refined sunflower oil Caprylyl glycol Dermosoft octiol water According to a particular embodiment of the invention the pre-dispersion is a pre-dispersion -emulsion which is in microemulsion or nanoemulsion form and / or which contains the following ingredients: Ingredients Trade name Polyethylene glycol monostearate PEG 8 isotrearate Behenyl trimethyl ammonium chloride (cationic surfactant) Behentrimonium chloride Protected avocado oil Persea gratissima oil Jojoba oil Simmondsia chinensis seed oil cyclopenta dimethylsiloxane Cyclopen tasiloxane Glycerol Glycerin Ethyl alcohol Alcohol COPOLYMER SMDI / POLYETHYLENE GLYCOL ALKYL TERMINATION (METHYLJC18) 15% IN MATT MALTODEXTRIN / WATER PEG-150 / STEARYL ALCOHOLSMDI COPOLYMER 1,3 butylene glycol Butylene glycol water According to a particular embodiment of the invention The pre-dispersion is a pre-emulsion which is in the form of microemulsion or nanoemulsion and / or which contains the following ingredients: Ingredients Trade name Glyceryl Stearate TEGIN 6070 Dipalmitoylethyl Methyl Hydroxyethyl Methyl Ether Dehyquart F30 Ammonium / Ceryl Alcohol Glycerol Glycerin Cetrimonium Dehydrogenation Dehyquart A OR Poly dimethylsiloxane with GRPTS alpha-omega acetate Abil Quat 3474 quaternary ammonium with coconut fatty chain in 95% solution in propylene glycol water According to a particular embodiment of the invention, the pre-dispersion is a pre-dispersion -emulsion which pre-emulsion which is in the form of microemuls ion or nanoemulsion and / or which contains the following ingredients: Ingredients Trade name Protected avocado oil Persea gratissima oil Sesame oil Sesamum indicum seed oil Texapon N62 Sodium lauryl ether sulfate Oleamidopropyl dimethylamine Mackine 501 V water Coloring process using the composition of the invention According to a particular embodiment P1 of the invention the dyeing process is carried out in several steps, - the first step consists in the preparation of the composition (la) of the invention that is ie obtained by mixing at the time of use of the ingredient i) as defined above with the pre-dispersion as defined above optionally with the addition of additional water to give the final composition (11a); in the second step, the composition (Ia) or (IIa) is applied to the keratinous fibers, and is left on the said fibers preferably for a minimum of 30 minutes, preferably a time ranging from 30 minutes to 24 hours, better ranging from 1 hour to 12 hours; during the third step, the keratinous fibers are rinsed with water until the poultice disappears, preferably without shampooing; the keratinous fibers may then be dried or allowed to dry naturally without a hair dryer.

According to another particular embodiment P2 of the invention, the dyeing process is carried out in several steps; the first step consists in the preparation of the composition (la) or (11a) as described above; in the second step, the composition (la) or (11a) is left standing for several hours, preferably 24 hours, and is then preferably applied in the form of a poultice and left on said fibers, preferably a minimum time of 30 minutes ( preferably from minutes to 24 hours, better hour to 12 hours); in the third step, the keratinous fibers are rinsed with water until the composition (la) or (11a) disappears, preferably without shampooing; the keratinous fibers can then be dried or allowed to dry naturally without a hair dryer.

According to a particularly advantageous method the keratinous fibers are after the third step of P1 or P2: a) are wiped mechanically with a towel, or absorbent paper, b) are dried by heat with a heat source (convection, conduction or radiation) in for example, sending a hot gas stream such as the air necessary for the evaporation of the solvent (s); as a thermal source are hair dryers, hair helmets, a hair straightener, an infrared dispenser and other conventional heaters. Whatever the mode of application, the application temperature of the composition (la) or (IIa) varies from room temperature (15 to 25 ° C) to 80 ° C and more particularly from 15 to 45 ° C. Thus, it is advantageous, after application of the composition ready for use according to the invention, to subject the hair to heat treatment by heating at a temperature ranging from 30 to 60 ° C. In practice, this operation can be carried out by means of a hairdressing helmet, a hair dryer, an infrared dispenser and other conventional heating devices. Both heating and smoothing of the hair can be used to heat a heating iron at a temperature ranging from 60 to 220 ° C and preferably from 120 to 200 ° C. A particular embodiment of the invention relates to a dyeing process which is carried out at room temperature (25 ° C).

Whatever the method of staining, in particular of P1 and P2 as defined above, if the ingredient i) used is henna powder, each of these processes may be followed by another P1 or P2 staining process comprising as an ingredient ) indigo; and vice versa ie to whatever the P1 or P2 staining process as defined above, if the ingredient i) used is indigo to each of these processes can be followed another P1 or P2 staining process comprising as an ingredient i) henna powder. More specifically, the dyeing process can be done, for example, in 3 different ways. Process 1: The Henna and / or indigo powder (1 part) is mixed with the pre-dispersion (0.5 part) with water at a temperature between 40 and 98 ° C. (2.5 parts) in a bowl and mix the time necessary to obtain a creamy poultice. Then the poultice is applied to the head for a minimum of 30 minutes (preferably between 30 minutes and 24 hours, better between 1 hour and 12 hours) before rinsing without shampooing and then drying the hair.

Method 2: The Henna and / or indigo powder (1 part) is mixed with the pre-dispersion (0.5 part) with water at a temperature of between 10 and 40 ° C. (2.5 parts) in a bowl and mix the time necessary to obtain a creamy poultice. Then the poultice is applied to the head for a minimum of 30 minutes (preferably between 30 minutes and 24 hours, better between 1 hour and 12 hours) before rinsing without shampooing and then drying the hair.

Method 3: The cream is applied directly (pre-emulsion in nanoemulsion or microemulsion or cationic emulsion ie comprising at least one cationic surfactant as defined above) mixed with the Henné powder and / or indigo on head for a minimum of 30 minutes (preferably between 30 minutes and 24 hours, better between 1 hour and 12 hours) before rinsing without shampooing and then drying the hair.

EXAMPLES OF COLORING The following compositions were prepared as follows: The percentages are given by weight relative to 100 g of composition.

Composition A: Ingredient Trade name Amount Natural henna powder (Lawsonia Natural henna powder 100g inermis) to 78% Henna Composition B: Ingredient Trade name Amount Sorbitan monolaurate 40E TWEEN 21 LQ 30 g% Isopropyl myristate RADIA 7730 30 g% SUNFLOWER OIL REFINED Refined Sunflower Oil 30g% Caprylyl Glycol MINACARE OCTIOL 0.5 g% Demineralized Water 9.5 g% Composition C: Ingredient Trade Name Amount Avocado Oil AVOCADO OIL RBD 70g% Sodium Lauryl Ether Sulfate TEXAPON N 702 15 g% Oleylamidopropyl dimethylamine MACKINE 501V 0.7 g% (10.5 g% MA) Demineralized water 14.3 g% MA: active ingredient Composition D: Ingredient Trade name quantity Avocado oil refined AVOCADO OIL RBD 70g% Lauryl Sodium ether sulfate TEXAPON N 702 15 g% Oleyl amidopropyl dimethyl amine MACKINE 501V 0.7 g% (10.5 g% MA) Indigo powder (Indigofera tinctoria) Natural indigo powder 5 g% Demineralized water 9.3 g% My subject active ingredient 1 part of the composition A is mixed with 0.5 parts of the composition B or C and with 2.5 parts of hot water at 37 ° C. in a bowl, or in cold water (10 ° C.) and 1.5 parts of composition D was mixed with 2.5 hot water at 37 ° C, or in cold water at 10 ° C. Mixing is easy even in cold water. The poultices obtained are very unctuous, apply easily on keratinous fibers, and this by completely impregnating the keratinous fibers from the root to the tip.

The poultice is applied to 90% white hair with a break time of 30 minutes. We rinse the hair thoroughly. We dry the hair. An intense copper-colored cosmetic coloration is obtained with the compositions B and C, blue-green with the composition D The hair is smooth and soft, the coloring is very homogeneous from one fiber to the other and from the root to the tip.

Claims (25)

REVENDICATIONS1. A composition comprising: i) at least 1% by weight, preferably at least 5% by weight, of red henna powder and / or indigo plant (s); ii) at least one oil; iii) optionally at least one surfactant; and iv) water; it being understood that ingredients ii), iii) and iv) are pre-dispersed together to form a pre-dispersion, and then the ingredient (s) i) is (are) dispersed in said pre-dispersion or said pre-dispersion is dispersed in the said ingredient (s) i). 2. Composition according to the preceding claim ready for use, which is preferably a poultice. 3. Composition according to any one of the preceding claims wherein the ingredient i) powder consists of fine particles less than or equal to 500 lm; preferably, the powder consists of fine particles of size included between 50 and 300 μm and more particularly between 10 and 200 μm. 4. A composition according to any preceding claim wherein ingredient i) is red henna powder. 5. A composition according to any one of the preceding claims wherein ingredient i) is indigestible plant powder (s). 6. Composition according to any one of the preceding claims wherein ingredient i) is in an amount ranging from 1 to 85% by weight, relative to the total weight of the composition, more particularly ranging from 5 to 80% by weight, more Especially from 10 to 75% by weight relative to the total weight of the composition. 7. A composition according to any one of the preceding claims wherein the pre-dispersion contains at least one surfactant iii) and is a pre-emulsion preferably of average size of droplets greater than 200 nm of water type in the oil VV / O particularly the ingredients ii), iii) and iv) are in microemulsion and more particularly in nanoemulsion. 8. Composition according to any one of the preceding claims wherein the one or more oils are chosen from non-silicone oils and in particular hydrocarbons and C6-C16 or more than 16 carbon atoms and in particular alkanes; Oils of animal origin; triglyceride oils of vegetable origin; essential oils ; glycerides or fluorinated oils of synthetic origin, fatty alcohols; fatty acid esters and / or fatty alcohol different from triglycerides, and silicone oils. 9. Composition according to any one of the preceding claims, in which the oil or oils ii) are chosen from oils of natural origin, particularly oils of vegetable origin and essential oils, preferentially oils of vegetable origin such as oils. jojoba, babassu, sunflower, olive, coconut, brazil nut, marula, corn, argan, soya, squash, grape seed, flax, sesame, hazelnut, apricot, macadamia, arara, coriander, almond, castor, avocado, shea butter oil as well as rapeseed oil, borage, evening primrose, pomegranate, mango , palm, cottonseed and coconut oil, more preferably the oil or oils, ingredient ii) of the invention are chosen from sunflower or avocado oil, sesame oil and jojoba oil, and even more preferably are chosen from avocado and sunflower oils. 10. Composition according to any one of the preceding claims wherein the oil content (s) varies from 10 to 85% by weight, preferably 15 to 80% by weight, better still from 20 to 75% by weight relative to the total weight of said composition. 11. Composition according to any one of the preceding claims wherein the pre-dispersion of the invention before addition of the ingredient (s) i) comprises from 30 to 90% by weight of one or more oils, preferably 40 to 75% by weight. relative to the total weight of said pre-dispersion. 12. A composition according to any of the preceding claims wherein the ratio of ingredient i) and the pre-dispersion is greater than 0.5 part by weight of ingredient i) to 1 part by weight of pre-dispersion, preferably the ratio is included inclusively between 0.6 and 3 parts by weight of ingredient i) for 1 part by weight of pre-dispersion, more preferably 2 parts by weight of i) for 1 part by weight of pre-dispersion. 13. Composition according to any one of the preceding claims, which additionally comprises one or more fatty substances different from i), the additional fatty substance or fats being chosen from butters, preferably of plant origin, and in particular are chosen from butter. shea butter, Nilotica shea butter (Butyrospermum parkii), Galam butter (Butyrospermum parkii), Borneo butter or fat or Tallow tengkawang (Shorea stenoptera), Shorea butter, Illipé butter, Madhuca butter or Bassia (Madhuca longifolia), Mowrah butter (Madhuca Latifolia), Katiau butter (Madhuca mottleyana), Phulwara butter (M. butyracea), Mango butter (Mangifera index) 'Murumuru butter (Astrocatyum murumuru), Kokum butter (Garcinia Indica), Ucuuba butter (Virola sebifera), Tucuma butter, Painya butter (Kpangnan) (Pentadesma butyracea), coffee butter (Coffea arabica), apricot butter ( Prunus Armeniaca), the Macadamia butter (Macadamia Temifolia), grape seed butter (Vitis vinifera), avocado butter (Persea gratissima), olive butter (Olea europaea), sweet almond butter (Prunus amygdalus dulcis) ), cocoa butter (Theobroma cacao) and sunflower butter. 14. Composition according to any one of the preceding claims which comprises at least one surfactant iii), in particular which is chosen from nonionic, cationic and anionic surfactants, more particularly chosen from nonionic and anionic surfactants. 15. Composition according to any one of the preceding claims which comprises at least one surfactant iii) which is chosen from mono- or polyoxyalkylenated nonionic surfactants, more particularly chosen from saturated or unsaturated C8-C30 acid esters, linear or branched, and polyoxyethylenated sorbitol, and anionic surfactants, in particular of alkyl sulphate type, in particular alkaline or alkaline earth salt lauryl ether sulphate. 16. A composition according to any one of the preceding claims which comprises at least one surfactant iii), which is selected from compounds (B1), (B2), (B'2), (B3), (B4), (B5), (B6), (B7), nonionic surfactants, and (B8), as well as their possible salts of organic or inorganic acids or bases, their solvates such as the following hydrates: Ra-C (O) -N ( Z) -CH 2 - (CH 2) n -N + (Rb) (R 1) -CH 2 -C (O) -O-, M +, X- (B 1) Formula (B 1) in which: - Ra represents an alkyl group or C10-C30 alkenyl derived from a carboxylic acid Ra-C (O) -OH, preferably present in hydrolyzed coconut oil, heptyl, nonyl or undecyl; Rb represents a beta-hydroxyethyl group; and - R, represents a carboxymethyl group; - W represents a cationic counterion derived from an alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine, and - X- represents an organic or inorganic anionic counterion, preferably chosen among the halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, C 4) - or (C 1 -C 4) alkylarylsulfonates, in particular methylsulphate and ethylsulphate; m is equal to 0.1 or 2; Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group or else W and X- are absent; 40Ra'-C (O) -N (Z) -CH2- (CH2) n -N (B) (B1) ) (B2) Formula (B2) wherein: - B represents the group -CH2-CH2-0-X '; B 'represents the group - (CH2) z-Y', with z = 1 or 2; X 'represents the group -CH 2 -O (O) -OH, -CH 2 -O (O) -OZ', -CH 2 -CH 2 -O (O) -OH, -CH 2 -CH 2 -O (O) -OZ ', or a hydrogen atom; Y 'represents the group -O (O) -OH, -O (O) -OZ', -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z '; Z 'represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - Ra, represents an alkyl group in 0-10-030 or alkenyl in 010-030 of an acid Ra-C (O) -OH, preferably present in coconut oil or in hydrolyzed linseed oil, an alkyl group , especially 017 and its iso form, an unsaturated 017 group; m is equal to 0.1 or 2; Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group; Ra "-N (H) -CH (Y") - (CH2), - C (O) -N (H) - (CH2) ', - N (Rd) (Re) (B'2) Formula (B) 2) in which: Y "represents the group -O (O) -OH, -O (O) -O-Z", -OH 2 -OH (OH) -SO 3 H or the group -OH 2 -CH (OH) -S03-Z "- Rd and Re, independently of one another, represent a C1-4 alkyl or hydroxyalkyl radical; - Z" represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra "represents a C 10 -C 30 alkyl or alkenyl group of an acid Ra" -C (O) -OH, preferably present in coconut oil or in hydrolysed linseed oil; n and n ', independently of each other, denote an integer ranging from 1 to 3; Wherein: R1 denotes a hydrocarbon chain, saturated or unsaturated, linear or branched, containing from 6 to 100 carbon atoms, in which: R1 is a linear or branched hydrocarbon chain containing from 6 to 100 carbon atoms, in particular from 6 to 50 carbon atoms, and which can be interrupted by one or more heteroatoms, divalent groups, or combinations thereof selected from -O-, -O (O) -, -N (R) -; with R denoting a hydrogen atom or a C 1 -C 4 alkyl radical, and R 1 may also be interrupted by an arylene group or terminated by an aryl group; R 2 and R 3, which may be identical or different, in particular R 2 and R 3 are identical, denote a (C1-C6) alkyl group, preferably R2 and R3 represents a methyl group; - R4 denotes a divalent hydrocarbon radical, linear or branched, preferably linear, comprising from 1 to 10, preferably from 1 to 5 carbon atoms optionally substituted in particular with one or more hydroxyl groups; Z denotes a heteroatom or a divalent group chosen from -O-, -N (R) - with R as defined above, n denotes a number equal to 1 or 2; m denotes an integer equal to 0 or 1; - G- denotes an anionic radical chosen from carboxylates, sulphates, sulphonates, phosphates and phosphonates (* -C (O) -O-, * -S (O) 2-0-, * -O-S (O) 2 -0-, * -P (0) 2-0-, * -P (O) -O-, -P (OH) -O-, ** = P (O) -O- and ** = P -0-, with "* -" designating the point of attachment of the anionic radical to the rest of the molecule via Z or R4 when n is 1, and "** =" representing the two points of attachment of the anionic radical via Z or R4 when n is 2); it being understood that: when n is 2, the radicals R 1 R 2 R 3 N + -R '- (Z), - are identical or different, preferably identical; and the surfactant of formula (B3) being electrically neutral, it may comprise anionic and / or cationic counterions to arrive at the electroneutrality of the molecule; Wherein R8 to R11, which may be identical or different, represent a linear or branched, saturated or initiated aliphatic group containing from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, it being understood that at least one of the groups R8 to R1 contain from 8 to 30 carbon atoms, and preferably from 12 to 24 carbon atoms, and - X-, represents a counterion organic or inorganic anionic, such as that chosen from halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, O 4) - or (C 1 -C 4) alkylarylsulfonates, in particular methylsulphate and ethylsulphate, aliphatic groups from R8 to R11 may further comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens; the aliphatic groups of R8 to R11 are in particular chosen from C1-C30alkyl, C1-C30alkoxy, polyoxyalkylene (02-06), C1-C30alkylamide, (C12-C22alkyl) amidoalkyl (C2-C6alkyl) ), (C12-C22) alkyl and (C1-C30) hydroxyalkyl, is an anionic counterion selected from halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, (C1-C4) alkyl or alkyl (C1-C4) aryl sulfonates; R13 Nj + / 2 2 - "5 / -C (O) -Ri2 X-CH CH -N (R14) (B5) Formula (B5) in which: R12 represents an alkenyl or alkyl group containing from 8 to 30 atoms carbon, eg fatty acid derivatives of tallow; R13 represents a hydrogen atom, a C1-C4 alkyl group or an alkenyl or alkyl group having from 8 to 30 carbon atoms; R14 represents an alkyl group; Cl-04; R15 represents a hydrogen atom, a C1-C4 alkyl group; X- represents an organic or inorganic anionic counterion, such as that chosen from the halides, phosphates, acetates, lactates, alkyls (01 -04) sulfates, 04) - or alkyl (01-04) aryl-sulfonates, preferably R12 and R13 denote a mixture of alkenyl or alkyl groups having from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow R14 denotes a methyl group, R15 denotes a hydrogen atom, such a product is for example marketed under the name REVVOQUATO VV 75 by the company REVVO, c) the quaternary di- or triammonium salts, in particular of the following formula (B6): R17 R19 + + R16 N (CH2) 3 NR X-X 21 R18 R20 (B6) Formula (B6) wherein: R 16 is an alkyl group having about 16 to 30 carbon atoms, optionally hydroxylated and / or interrupted by one or more oxygen atoms; R 17 is chosen from hydrogen, an alkyl group containing from 1 to 4 carbon atoms or a group - (CH 2) 3 -N + (R 16a) (R 17a) (R 18a), - R 16a, R 17a, R 18a, R 18, R19, R20 and R21, which are identical or different, are chosen from hydrogen and an alkyl group containing from 1 to 4 carbon atoms; and - X-, which may be identical or different, represent an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, alkyl (Cl-C4) sulphates, alkyl (Cl-C4) - or alkyl ( C1-C4) aryl sulfonates, in particular methylsulfate and ethylsulfate; X (CsI-12s) R25 O-CrHr2 (OH) r, 17N + CtHt2 (OH) t, O ± R23 1122 Formula (B7) in which: R22 is selected from the group consisting of Hydroxyalkyl or dihydroxyalkyl at 01-06, - R23 is chosen from: O - the R2c- group - R27 hydrocarbon groups in 01-022, linear or branched, saturated or unsaturated, - the hydrogen atom, - R25 is chosen among: o - the group R2-8C- - linear or branched, saturated or unsaturated C-6 hydrocarbon groups R - 06, - R24, R26 and R28, which are identical or different, are chosen from: linear or branched, saturated or unsaturated hydrocarbon groups of 07-021; r, s and t, which may be identical or different, are integers of from 2 to 6, r1 and t1 which are identical or different, equal to 0 or 1 with r2 + r1 = 2r and t1 + t2 = 2t - y is an integer from 1 to 10, - x and z, which may be identical or different, are integers ranging from 0 to 10, - X- represents an anionic counterion, organic or inorganic, provided that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and when z is 0 then R25 is R29; the alkyl groups R22 may be linear or branched, and more particularly linear; preferably, R22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group; advantageously, the sum x + y + z is from 1 to 10; R24 (B7) nonionic surfactants chosen from mono- or polyoxyalkylenated, mono- or polyglycerolated nonionic surfactants, in particular: oxyalkylenated (C 8 -C 24) alkyl phenols; saturated or unsaturated, linear or branched, oxyalkylenated 08-030 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated amides 08-030; saturated or unsaturated, linear or branched, 08-030 acid esters of polyethylene glycols; 08-030 acid esters, saturated or unsaturated, linear or branched, and polyoxyethylenated sorbitol; vegetable oils oxyethylenated, saturated or not; condensates of ethylene oxide and / or propylene oxide, among others, alone or in mixtures; Oxyethylenated and / or oxypropylenated silicones; Surfactants having a number of moles of ethylene oxide and / or propylene oxide of between 1 and 100, preferably between 2 and 50, preferably between 2 and 30; and R2904CH2-CH (CH2OH) -O] --H (B8) Formula (B8) wherein: - R29 represents a linear or branched, linear or branched alkyl or alkenyl radical, at 08-040, preferably at 08-030; and - m represents a number ranging from 1 to 30 and preferably from 1 to 10. 17. Composition according to any one of claims 1, 7 and 14 to 16 which contains 1 to 40% by weight, preferably 2 to 20% by weight, in particular 5 to 20% by weight of surfactant (s) by weight. relative to the total weight of said composition. 18. A composition according to any one of claims 1, 7 and 14 to 17 wherein the pre-dispersion is a pre-emulsion and contains from 1 to 60% by weight, preferably from 5 to 50% by weight, more preferably 10 to 10% by weight. at 40% by weight of surfactant (s) iii) relative to the total weight of said pre-emulsion. 19. Composition according to any one of the preceding claims wherein the water or ingredient iv), in the pre-dispersion is in an amount ranging from 5% to 50% by weight relative to the total weight of said pre-dispersion. dispersion and more particularly from 7% to 40%, better still from 8% to 20% by weight relative to the total weight of said pre-dispersion. 20. Composition according to any one of the preceding claims which contains water in an amount ranging from 3 to 40%, better still from 5 to 20%, particularly from 7 to 15% by weight relative to the total weight of said composition. 21. A composition according to any one of the preceding claims in which the ingredient (s) i) is (are) mixed in a sparse, dispersed manner, within the pre-dispersion in a ratio of ingredient (s) i) and pre-dispersion ranging from 0.015 parts to 0.5 parts of ingredient (s) i) by weight to 1 part by weight of pre-dispersion. 22. Composition according to any one of claims 1 to 20 wherein the ratio of ingredient (s) i) and the pre-dispersion is greater than 0.5 parts by weight of ingredient (s) i) for 1 part by weight of pre-dispersion, preferably the ratio is inclusive between 0.6 and 3 parts by weight of ingredient (s) i) for 1 part by weight of pre-dispersion, more preferably 2 parts by weight of ingredient (s) i) for 1 part by weight of pre-dispersion. 23. Composition according to any one of claims 1 to 21 which is mixed with additional water to give a final composition whose weight ratio of the mixture of the pre-dispersion / the ingredient i) and the additional water varies from 0.1 to 2 parts, preferably 0.5 to 1 part mixture to 1 part additional water. 24. A process for dyeing keratinous fibers chosen from processes P1 and P2 in which: the method P1 consists of: in the first step, the preparation of the composition according to any one of the preceding claims; in the second step, said composition is: a) immediately applied to the keratinous fibers, and is left on the fibers for a minimum of 30 minutes, preferably from 30 minutes to 24 hours, particularly from 1 hour to 12 hours, b) is allowed to stand for several hours, preferably 24 hours, then applied and left on the fibers for a minimum of 30 minutes, preferably 30 minutes to 24 hours, particularly 12 hours; during the third step, the keratinous fibers are rinsed with water until the composition disappears, preferably without shampooing; the keratin fibers may then be dried with a heat source or left to dry naturally at room temperature; and the process P2 consists of: the first step, the preparation of the composition as described above; in the second step, said composition is left to rest for several hours, preferably 24 hours, and then said composition is applied and left on said fibers, preferably a minimum time of 30 minutes, preferably ranging from minutes to 24 hours, particularly hour at 12 o'clock ; during the third step, the keratinous fibers are rinsed with water until the composition disappears, preferably without shampooing; the keratin fibers may then be dried with a heat source or allowed to dry naturally at room temperature; the keratinous fibers are preferably after the third step of P1 or P2: a) either wiped mechanically with a towel, or absorbent paper, b) or dried by heat with a thermal source, for example by sending a hot gas stream such that air necessary for the evaporation of the solvent (s); as a heat source are hair dryers, hair helmets, a hair straightener, an infrared dispenser and other conventional heaters; it being understood that whatever the method of staining P1 or P2 as defined above, if the ingredient i) used is henna powder to each of these processes can be followed another P1 or P2 staining process comprising as an ingredient i ) indigo; and vice versa ie to whatever the method of staining P1 to P4 as defined above, if the ingredient i) used is indigo to each of these processes can be followed another P1 or P2 staining process comprising as an ingredient i) henna powder. 25. Use of the composition according to any one of claims 1 to 23, for dyeing keratin fibers such as the hair.