FR2997076B1 - Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau. - Google Patents

Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau.

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Publication number
FR2997076B1
FR2997076B1 FR1260003A FR1260003A FR2997076B1 FR 2997076 B1 FR2997076 B1 FR 2997076B1 FR 1260003 A FR1260003 A FR 1260003A FR 1260003 A FR1260003 A FR 1260003A FR 2997076 B1 FR2997076 B1 FR 2997076B1
Authority
FR
France
Prior art keywords
objects
nano
electrode
composite material
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1260003A
Other languages
English (en)
Other versions
FR2997076A1 (fr
Inventor
Pascal Tiquet
Lionel Filhol
Jean-Francois Guillet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1260003A priority Critical patent/FR2997076B1/fr
Priority to EP13783282.0A priority patent/EP2909136A1/fr
Priority to US14/436,642 priority patent/US20150303469A1/en
Priority to JP2015537257A priority patent/JP2016504707A/ja
Priority to PCT/EP2013/071757 priority patent/WO2014060532A1/fr
Publication of FR2997076A1 publication Critical patent/FR2997076A1/fr
Application granted granted Critical
Publication of FR2997076B1 publication Critical patent/FR2997076B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F31/00—Mixers with shaking, oscillating, or vibrating mechanisms
    • B01F31/80—Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
    • C09D105/04—Alginic acid; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/52—Electrically conductive inks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/626—Metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Silicon Compounds (AREA)
  • Conductive Materials (AREA)
  • Non-Insulated Conductors (AREA)

Abstract

Matériau nanocomposite comprenant des nano-objets en au moins un premier matériau conducteur électronique, tel que le carbone, et des nano-objets ou des objets submicroniques en au moins un deuxième matériau, tel que le silicium, différent du premier matériau ; ledit matériau composite comprenant des nanostructures constituées chacune par un réseau tridimensionnel constitué par les nano-objets en au moins un premier matériau conducteur électronique liés et maintenus par un polysaccharide, les nano-objets ou les objets submicroniques en au moins un deuxième matériau différent du premier matériau étant autoassemblés autour dudit réseau et étant fixés aux nano-objets en au moins un premier matériau conducteur électronique par ledit polysaccharide et lesdites nanostructures étant réparties de manière homogène dans le matériau. Procédé de préparation dudit matériau nanocomposite. Encre comprenant ledit matériau composite. Electrode comprenant en tant que matière électrochimiquement active ledit matériau composite. Système électrochimique, notamment accumulateur aux ions lithium, comprenant une telle électrode.
FR1260003A 2012-10-19 2012-10-19 Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau. Expired - Fee Related FR2997076B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1260003A FR2997076B1 (fr) 2012-10-19 2012-10-19 Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau.
EP13783282.0A EP2909136A1 (fr) 2012-10-19 2013-10-17 Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau
US14/436,642 US20150303469A1 (en) 2012-10-19 2013-10-17 Composite material comprising nano-objects, in particular carbon nano-objects, process for preparing same, and ink and electrode comprising this material
JP2015537257A JP2016504707A (ja) 2012-10-19 2013-10-17 ナノ物体、特に、カーボンナノ物体を含む複合材料、それを調製する方法およびこの材料を含むインクおよび電極
PCT/EP2013/071757 WO2014060532A1 (fr) 2012-10-19 2013-10-17 Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1260003A FR2997076B1 (fr) 2012-10-19 2012-10-19 Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau.

Publications (2)

Publication Number Publication Date
FR2997076A1 FR2997076A1 (fr) 2014-04-25
FR2997076B1 true FR2997076B1 (fr) 2014-12-26

Family

ID=47429913

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1260003A Expired - Fee Related FR2997076B1 (fr) 2012-10-19 2012-10-19 Materiau composite comprenant des nano-objets notamment des nano-objets de carbone, son procede de preparation, et encre et electrode comprenant ce materiau.

Country Status (5)

Country Link
US (1) US20150303469A1 (fr)
EP (1) EP2909136A1 (fr)
JP (1) JP2016504707A (fr)
FR (1) FR2997076B1 (fr)
WO (1) WO2014060532A1 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3018955B1 (fr) * 2014-03-24 2016-05-06 Commissariat Energie Atomique Procede de fabrication d'une electrode, electrode ainsi fabriquee et systeme electrochimique la comprenant.
CN104269529B (zh) * 2014-09-23 2016-05-11 中南大学 一种锂离子电池负极材料硼酸钒的制备方法
JP2017084759A (ja) * 2015-10-30 2017-05-18 大阪瓦斯株式会社 電極活物質−カーボンナノチューブコンポジット及びその製造方法
CN109219440A (zh) * 2016-04-04 2019-01-15 贝塔O2技术有限公司 用于植入具有抗炎和血管化能力的细胞的可植入设备及其制造方法
JP6892075B2 (ja) * 2017-08-31 2021-06-18 公立大学法人兵庫県立大学 カーボンナノフィラー分散液及び複合材料
CN110212174B (zh) * 2019-05-13 2022-03-18 福建江夏学院 钴酸镁及氮掺杂二氧化锡复合材料及其制备方法、用途
CN112713261B (zh) * 2019-10-24 2023-04-07 中国石油化工股份有限公司 一种三元正极材料的制备方法及包含该三元正极材料的锂离子电池
CN111129466B (zh) * 2019-12-30 2021-04-09 中科廊坊过程工程研究院 一种高性能正极材料及其制备方法和在锂离子电池中的应用
CN112750987B (zh) * 2021-01-04 2022-06-21 北京航空航天大学 一种基于亲锂三维碳基集流体的锂金属负极制备方法
CN114197088B (zh) * 2021-11-09 2023-04-21 华南理工大学 一种超声诱导制备纳米纤维或纳米微球的方法及由纳米材料形成的薄膜
US20250070187A1 (en) * 2021-12-28 2025-02-27 Graphenix Development, Inc. Anodes for lithium-based energy storage devices
CN114628623B (zh) * 2022-02-16 2023-05-23 南京师范大学 一种碳纳米管穿插的KFeSO4F材料的制法及应用
DE102022109533A1 (de) 2022-04-20 2023-10-26 Axalta Coating Systems Gmbh Verfahren zur Reparatur einer Lackzusammensetzung und Verwendung von Schallwellen zur Reparatur einer Lackzusammensetzung
CN117820901B (zh) * 2023-12-13 2025-11-07 北京市农林科学院信息技术研究中心 一种低黏度双重防伪油墨及其制备方法和应用
CN117720132B (zh) * 2024-02-07 2024-05-03 四川易纳能新能源科技有限公司 一种硫酸铁钠及其制备方法与应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101439972B (zh) 2007-11-21 2013-01-09 比亚迪股份有限公司 硅碳复合材料及其制备方法以及电池负极和锂离子电池
FR2935546B1 (fr) * 2008-09-02 2010-09-17 Arkema France Materiau composite d'electrode, electrode de batterie constituee dudit materiau et batterie au lithium comprenant une telle electrode.
JP5886193B2 (ja) * 2009-06-24 2016-03-16 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ＬｉＦｅＰＯ４−炭素合成物を製造するための方法
WO2011140150A1 (fr) * 2010-05-03 2011-11-10 Georgia Tech Research Corporation Compositions contenant de l'alginate destinées à être utilisées dans des applications de batterie
JP2012079471A (ja) * 2010-09-30 2012-04-19 Sanyo Electric Co Ltd 非水電解質二次電池の製造方法及び非水電解質二次電池
US20120237557A1 (en) * 2010-11-30 2012-09-20 Rutgers, The State University Of New Jersey Bioactive carbon-nanotube agarose composites for neural engineering

Also Published As

Publication number Publication date
JP2016504707A (ja) 2016-02-12
WO2014060532A1 (fr) 2014-04-24
FR2997076A1 (fr) 2014-04-25
EP2909136A1 (fr) 2015-08-26
US20150303469A1 (en) 2015-10-22

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