FR2944800B1 - Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues - Google Patents

Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues

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Publication number
FR2944800B1
FR2944800B1 FR0902073A FR0902073A FR2944800B1 FR 2944800 B1 FR2944800 B1 FR 2944800B1 FR 0902073 A FR0902073 A FR 0902073A FR 0902073 A FR0902073 A FR 0902073A FR 2944800 B1 FR2944800 B1 FR 2944800B1
Authority
FR
France
Prior art keywords
rare
systems based
conjugated dienes
catalytic systems
earth complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0902073A
Other languages
English (en)
French (fr)
Other versions
FR2944800A1 (fr
Inventor
Christophe Boisson
Olivier Rolland
Julien Thuilliez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michelin Recherche et Technique SA Switzerland
Centre National de la Recherche Scientifique CNRS
Societe de Technologie Michelin SAS
Universite Claude Bernard Lyon 1
Original Assignee
Michelin Recherche et Technique SA Switzerland
Centre National de la Recherche Scientifique CNRS
Societe de Technologie Michelin SAS
Universite Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0902073A priority Critical patent/FR2944800B1/fr
Application filed by Michelin Recherche et Technique SA Switzerland, Centre National de la Recherche Scientifique CNRS, Societe de Technologie Michelin SAS, Universite Claude Bernard Lyon 1 filed Critical Michelin Recherche et Technique SA Switzerland
Priority to JP2012507715A priority patent/JP5676565B2/ja
Priority to KR1020117028186A priority patent/KR101681043B1/ko
Priority to PL10717618T priority patent/PL2424902T3/pl
Priority to PCT/EP2010/055636 priority patent/WO2010125072A1/fr
Priority to EP10717618.2A priority patent/EP2424902B1/fr
Priority to US13/318,022 priority patent/US8946368B2/en
Publication of FR2944800A1 publication Critical patent/FR2944800A1/fr
Application granted granted Critical
Publication of FR2944800B1 publication Critical patent/FR2944800B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/21—Rubbery or elastomeric properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
FR0902073A 2009-04-28 2009-04-28 Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues Expired - Fee Related FR2944800B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR0902073A FR2944800B1 (fr) 2009-04-28 2009-04-28 Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues
KR1020117028186A KR101681043B1 (ko) 2009-04-28 2010-04-27 공액 디엔의 입체특이적 중합을 위한 희토류 착물로 제조된 촉매 시스템
PL10717618T PL2424902T3 (pl) 2009-04-28 2010-04-27 Układy katalityczne oparte na kompleksie pierwiastków ziem rzadkich dla polimeryzacji stereospecyficznej sprzężonych dienów
PCT/EP2010/055636 WO2010125072A1 (fr) 2009-04-28 2010-04-27 Systèmes catalytiques à base d'un complexe de terres rares pour la polymérisation stéréospécifique des diènes conjugués.
JP2012507715A JP5676565B2 (ja) 2009-04-28 2010-04-27 共役ジエンの立体特異性重合用の希土類元素錯体から製造された触媒系
EP10717618.2A EP2424902B1 (fr) 2009-04-28 2010-04-27 Systèmes catalytiques à base d'un complexe de terres rares pour la polymérisation stéréospécifique des diènes conjugués.
US13/318,022 US8946368B2 (en) 2009-04-28 2010-04-27 Catalytic systems made of a complex of rare earths for stereospecific polymerisation of conjugated dienes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0902073A FR2944800B1 (fr) 2009-04-28 2009-04-28 Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues

Publications (2)

Publication Number Publication Date
FR2944800A1 FR2944800A1 (fr) 2010-10-29
FR2944800B1 true FR2944800B1 (fr) 2012-10-26

Family

ID=41395584

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0902073A Expired - Fee Related FR2944800B1 (fr) 2009-04-28 2009-04-28 Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues

Country Status (7)

Country Link
US (1) US8946368B2 (OSRAM)
EP (1) EP2424902B1 (OSRAM)
JP (1) JP5676565B2 (OSRAM)
KR (1) KR101681043B1 (OSRAM)
FR (1) FR2944800B1 (OSRAM)
PL (1) PL2424902T3 (OSRAM)
WO (1) WO2010125072A1 (OSRAM)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012106694A2 (en) 2011-02-05 2012-08-09 Bridgestone Corporation Lanthanide complex catalyst and polymerization method employing same
CN103459402B (zh) 2011-02-05 2016-09-07 株式会社普利司通 镧系元素络合物催化剂以及使用其的聚合方法
JP2013216850A (ja) * 2012-03-16 2013-10-24 Bridgestone Corp 合成ポリイソプレンの製造方法、合成ポリイソプレン、ゴム組成物及びタイヤ
JP6055824B2 (ja) * 2012-05-30 2016-12-27 株式会社ブリヂストン 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン
SG11201408828TA (en) * 2012-07-04 2015-02-27 Bridgestone Corp Method for producing polybutadiene, polybutadiene, rubber composition and tire
FR2998895B1 (fr) * 2012-12-04 2015-07-31 Michelin & Cie Nouveau systeme catalytique multi-composants, son procede de preparation et procede de polymerisation de l'isoprene le mettant en œuvre
JP6031375B2 (ja) * 2013-02-14 2016-11-24 株式会社ブリヂストン 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン
JP6031374B2 (ja) * 2013-02-14 2016-11-24 株式会社ブリヂストン イソプレン重合触媒組成物、合成ポリイソプレンの製造方法及び合成ポリイソプレン
JP2014208755A (ja) * 2013-03-29 2014-11-06 宇部興産株式会社 新規なイットリウム化合物、共役ジエン重合用触媒、並びにそれを用いた共役ジエン重合体の製造方法
CN103709295B (zh) * 2013-11-26 2016-07-06 中国科学院长春应用化学研究所 一种稀土催化体系及其制备方法和聚间戊二烯制备方法
JP2017082137A (ja) * 2015-10-29 2017-05-18 株式会社ブリヂストン 変性共役ジエン重合体の製造方法、変性共役ジエン重合体、ゴム組成物、及びタイヤ
CN108164558A (zh) * 2016-12-07 2018-06-15 中国石油化工股份有限公司 钕系金属有机化合物和钕系催化剂组合物及其制备方法和应用及制备聚合共轭二烯烃的方法
WO2021133819A1 (en) * 2019-12-23 2021-07-01 Bridgestone Corporation Polymerization processes for the production of cis-1,4-polydienes
FR3108609A1 (fr) 2020-03-26 2021-10-01 Compagnie Generale Des Etablissements Michelin Synthese de polymeres d’olefines
FR3108611A1 (fr) 2020-03-26 2021-10-01 Compagnie Generale Des Etablissements Michelin Synthese de polymeres d’olefines
FR3108612A1 (fr) 2020-03-26 2021-10-01 Compagnie Generale Des Etablissements Michelin Complexe organométallique d’yttrium cationique
FR3108610A1 (fr) 2020-03-26 2021-10-01 Compagnie Generale Des Etablissements Michelin Complexe organométallique d’yttrium cationique
FR3109740A1 (fr) 2020-04-29 2021-11-05 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel, d’un complexe cationique d’yttrium et son utilisation pour l’oligomerisation des olefines
FR3109741A1 (fr) 2020-04-29 2021-11-05 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel, d’un complexe cationique d’yttrium et son utilisation pour l’oligomerisation des olefines

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US4623707A (en) 1985-12-10 1986-11-18 The Dow Chemical Company Polymerization of olefins in the presence of polymer supported Ziegler-Natta catalysts
JPH0791340B2 (ja) * 1990-10-19 1995-10-04 旭化成工業株式会社 共役ジェン類重合体の製造方法
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JP3530020B2 (ja) * 1997-04-25 2004-05-24 三井化学株式会社 オレフィン重合用触媒、遷移金属化合物、オレフィンの重合方法およびα−オレフィン・共役ジエン共重合体
JP2005506404A (ja) 2001-10-12 2005-03-03 ダウ グローバル テクノロジーズ インコーポレイティド 金属錯体組成物、及び金属錯体組成物のポリジエン製造用触媒としての使用法
WO2006078021A1 (ja) * 2005-01-21 2006-07-27 Riken 三座配位子を含む金属錯体、およびそれを含む重合用触媒
CN101906110B (zh) * 2010-08-18 2014-03-05 中国科学院长春应用化学研究所 苯二甲酸钕给电子体配合物及其制备方法和稀土催化剂

Also Published As

Publication number Publication date
JP5676565B2 (ja) 2015-02-25
KR101681043B1 (ko) 2016-11-30
PL2424902T3 (pl) 2014-01-31
KR20110139318A (ko) 2011-12-28
EP2424902A1 (fr) 2012-03-07
WO2010125072A1 (fr) 2010-11-04
FR2944800A1 (fr) 2010-10-29
US20120123070A1 (en) 2012-05-17
US8946368B2 (en) 2015-02-03
JP2012525458A (ja) 2012-10-22
EP2424902B1 (fr) 2013-08-14

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